CN104441301B - A kind of tandem rubber compound continuous mixing method - Google Patents

A kind of tandem rubber compound continuous mixing method Download PDF

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CN104441301B
CN104441301B CN201410648268.6A CN201410648268A CN104441301B CN 104441301 B CN104441301 B CN 104441301B CN 201410648268 A CN201410648268 A CN 201410648268A CN 104441301 B CN104441301 B CN 104441301B
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mixing
rubber
rotor
banbury
upstream
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CN104441301A (en
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汪传生
潘弋人
吴浩
位冬
于本会
付平
边慧光
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Qingdao University of Science and Technology
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/74Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
    • B29B7/7476Systems, i.e. flow charts or diagrams; Plants
    • B29B7/7495Systems, i.e. flow charts or diagrams; Plants for mixing rubber
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/02Mixing; Kneading non-continuous, with mechanical mixing or kneading devices, i.e. batch type
    • B29B7/06Mixing; Kneading non-continuous, with mechanical mixing or kneading devices, i.e. batch type with movable mixing or kneading devices
    • B29B7/10Mixing; Kneading non-continuous, with mechanical mixing or kneading devices, i.e. batch type with movable mixing or kneading devices rotary
    • B29B7/18Mixing; Kneading non-continuous, with mechanical mixing or kneading devices, i.e. batch type with movable mixing or kneading devices rotary with more than one shaft
    • B29B7/183Mixing; Kneading non-continuous, with mechanical mixing or kneading devices, i.e. batch type with movable mixing or kneading devices rotary with more than one shaft having a casing closely surrounding the rotors, e.g. of Banbury type
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/02Mixing; Kneading non-continuous, with mechanical mixing or kneading devices, i.e. batch type
    • B29B7/22Component parts, details or accessories; Auxiliary operations
    • B29B7/28Component parts, details or accessories; Auxiliary operations for measuring, controlling or regulating, e.g. viscosity control
    • B29B7/286Component parts, details or accessories; Auxiliary operations for measuring, controlling or regulating, e.g. viscosity control measuring properties of the mixture, e.g. temperature, density
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/30Mixing; Kneading continuous, with mechanical mixing or kneading devices
    • B29B7/58Component parts, details or accessories; Auxiliary operations
    • B29B7/60Component parts, details or accessories; Auxiliary operations for feeding, e.g. end guides for the incoming material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/74Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
    • B29B7/7461Combinations of dissimilar mixers

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)

Abstract

本发明属于橡胶成型的加工方法技术领域,涉及一种串联式橡胶连续混炼方法,先以密炼机的具体型号和混炼胶的生产配方为根据,计算出各种物料的质量并设定密炼机的工作参数;再将基体胶和各种配合剂加入密炼机中进行混炼,待胶料温度达到95±5℃时将形成的初混胶排入到存料斗中;初混胶经压砣通过喂料口压入异向双转子连续混炼机中,通过五段冷却通道的配合进行控温二段混炼,形成半成品胶片由排料口排出;将半成品胶片经开炼机压片后再加入促进剂和硫磺进行后续相关工艺及测试对比分析;该方法实现了混炼技术的连续性,避免了小料和胶料混炼不均匀,提高了生产效率,保证了胶品质量,减少了混炼过程中能量损失,节约了人力物力应用。

The invention belongs to the technical field of processing methods for rubber molding, and relates to a tandem rubber continuous mixing method. Based on the specific model of the internal mixer and the production formula of the mixed rubber, the quality of various materials is calculated and set. The working parameters of the internal mixer; then add the matrix rubber and various compounding ingredients into the internal mixer for mixing, and when the temperature of the rubber material reaches 95±5°C, discharge the formed primary mixed rubber into the storage hopper; primary mixed The rubber is pressed into the counter-rotating double-rotor continuous mixer through the feeding port, and the temperature-controlled two-stage mixing is carried out through the cooperation of the five-stage cooling channel, and the semi-finished film is discharged from the discharge port; the semi-finished film is kneaded After tableting by machine, accelerator and sulfur are added for subsequent related process and test comparative analysis; this method realizes the continuity of mixing technology, avoids uneven mixing of small materials and rubber materials, improves production efficiency, and ensures Improve product quality, reduce energy loss during the mixing process, and save manpower and material resources.

Description

一种串联式橡胶连续混炼方法A kind of tandem rubber continuous mixing method

技术领域:Technical field:

本发明属于橡胶成型的加工方法技术领域,涉及一种串联式橡胶连续混炼方法,能够适用于不同配方橡胶的混炼。The invention belongs to the technical field of processing methods for rubber molding, and relates to a serial rubber continuous mixing method, which is applicable to the mixing of rubbers with different formulas.

背景技术:Background technique:

橡胶行业是国民经济的重要基础产业之一,它不仅为人们提供日常生活不可或缺的日用和医用等轻工橡胶产品,而且向采掘、交通、建筑、机械、电子等重工业和新兴产业提供各种橡胶制生产设备或橡胶部件,而混炼技术的好坏对橡胶加工品的质量有着决定性作用,因此,生产出低能耗、高效率、高品质的橡胶是橡胶行业不断要解决的问题。当前,橡胶混炼的方法大体可以分为开炼机混炼和密炼机混炼,此二种混炼方法均属于间歇式的混炼技术,存在以下弊端:需要不断的停车、卸料、装料,生产效率较低、能源消耗较大;两种设备体积庞大、占地面积较大;混炼过程中胶料各部位受到的压力、温度不均匀,造成橡胶性能大有差异,最终影响成品的质量;配合剂浪费严重、环境污染较大。The rubber industry is one of the important basic industries of the national economy. It not only provides people with daily and medical light industrial rubber products that are indispensable in daily life, but also provides heavy and emerging industries such as mining, transportation, construction, machinery, and electronics. All kinds of rubber production equipment or rubber parts, and the quality of mixing technology has a decisive effect on the quality of rubber processed products. Therefore, the production of low energy consumption, high efficiency and high quality rubber is a problem that the rubber industry must constantly solve. At present, rubber mixing methods can be roughly divided into open mill mixing and internal mixer mixing. Both of these two mixing methods belong to batch mixing technology, which has the following disadvantages: continuous parking, unloading, Loading, low production efficiency and high energy consumption; the two types of equipment are bulky and occupy a large area; the pressure and temperature on each part of the rubber material during the mixing process are not uniform, resulting in large differences in rubber properties, which ultimately affect The quality of the finished product; the waste of compounding agents is serious, and the environmental pollution is relatively large.

相比较而言,连续式混炼技术具有以下优势:能够充分利用混炼本身的优点实现连续化生产,以提高生产效率;混炼过程中能够保证胶料各部分受到的压力、温度、炼胶时间相同,以提高橡胶的品质;自动化程度高,能够在稳定的工艺条件下混炼胶料,降低了人力物力的消耗;设备间相互配合紧密,占地面积较小、投资成本低。例如中国专利200910229437.1公开的一种橡胶混炼的方法,其先将配合剂混合均匀,并在密炼机内投入超促进剂和硫化剂,实现橡胶混炼一步到位;此法能够减少飞尘,且预混好的配合剂与生胶容易亲和、分散性好,缩短了混炼时间、降低了混炼功耗,有利于防止焦烧,但是上述方法的自动化程度不高,对配合剂预混也难以达到均匀性的标准,容易导致胶料的性能产生偏差;中国专利200580035588.3公开了一种橡胶混炼装置和混炼方法,其利用串联式混炼技术,将密炼机和开炼机组成为一条混炼线,通过分配传送带将由密闭型混炼机混炼的预混炼橡胶有选择的供给到并列设置的混炼线中,这种混炼技术虽然提高了混炼效率,但是对于恒温混炼和低温混炼来说,无法保证混炼中需要恒定保持的温度,同时会带来能量的损失,增大成本;因此,实现真正意义上自动化程度高的连续混炼,同时保证橡胶性能质量是本发明的研究方向。In comparison, continuous mixing technology has the following advantages: it can make full use of the advantages of mixing itself to realize continuous production to improve production efficiency; during the mixing process, it can ensure that the pressure, temperature, and mixing The time is the same to improve the quality of rubber; the degree of automation is high, and the rubber can be mixed under stable process conditions, which reduces the consumption of manpower and material resources; the equipment is closely coordinated with each other, the floor area is small, and the investment cost is low. For example, Chinese patent 200910229437.1 discloses a method of rubber mixing, which first mixes the compounding ingredients evenly, and puts super-accelerator and vulcanizing agent into the internal mixer to realize rubber mixing in one step; this method can reduce flying dust, Moreover, the premixed compounding agent and raw rubber are easy to be compatible and have good dispersibility, which shortens the mixing time, reduces the power consumption of mixing, and is beneficial to prevent scorching. However, the above-mentioned method is not highly automated. Mixing is also difficult to achieve the standard of uniformity, and it is easy to cause deviations in the performance of the rubber compound; Chinese patent 200580035588.3 discloses a rubber mixing device and mixing method, which utilizes serial mixing technology to combine the internal mixer and the open mixing unit It becomes a mixing line, and the pre-mixed rubber mixed by the closed mixer is selectively supplied to the parallel mixing line through the distribution conveyor belt. Although this mixing technology improves the mixing efficiency, it is not suitable for constant temperature. For mixing and low-temperature mixing, it is impossible to guarantee the temperature that needs to be kept constant during mixing, and at the same time it will cause energy loss and increase costs; therefore, continuous mixing with a high degree of automation in the true sense can be achieved while ensuring rubber properties Quality is the research direction of this invention.

发明内容:Invention content:

本发明主要解决现有连续混炼方法中处理工序多、设备工艺复杂、生产投资大、高能耗和胶料品质低等技术问题,提供一种能够适用于各种配方的串联式橡胶连续混炼方法,解决在保证胶料混炼质量的同时避免配合剂与基体胶混炼不均匀等问题。The invention mainly solves the technical problems in the existing continuous mixing method, such as many processing steps, complex equipment process, large production investment, high energy consumption and low rubber quality, and provides a serial rubber continuous mixing method applicable to various formulations. method to solve the problems of avoiding uneven mixing of compounding agent and matrix rubber while ensuring the quality of rubber mixing.

为了解决上述问题,本发明设计的串联式橡胶连续混炼方法的具体工艺步骤如下:In order to solve the above problems, the concrete processing steps of the tandem rubber continuous mixing method designed by the present invention are as follows:

(1)采用65±5%的填充系数,以上游密炼机的具体型号和混炼胶的生产配方为根据,计算出各种物料的质量并精确称量后备用,设定初混阶段中上游密炼机的工作参数为:转子转速60±15r/min,温控为50±10℃,上顶栓压力0.6±0.05MPa;其中物料包括基体胶和配合剂;(1) Using a filling factor of 65±5%, based on the specific model of the upstream internal mixer and the production formula of the mixed rubber, the mass of each material is calculated and accurately weighed for later use. The working parameters of the upstream internal mixer are: the rotor speed is 60±15r/min, the temperature control is 50±10°C, and the upper bolt pressure is 0.6±0.05MPa; the materials include matrix glue and compounding agent;

(2)将步骤(1)中称量的基体胶投入上游密炼机中进行40±10s的塑炼形成塑炼橡胶,然后再分别加入除硫磺和促进剂之外的配合剂进行混炼,当密炼室中的胶料温度达到80±5℃时升降上顶栓一次,使得配合剂和塑炼橡胶充分混合,当密炼室中的胶料温度达到95±5℃时,打开上游密炼机的下顶栓将形成的初混胶排入到存料斗中;(2) Put the matrix rubber weighed in step (1) into the upstream internal mixer and carry out 40 ± 10s of masticating to form masticated rubber, and then add compounding agents except sulfur and accelerators respectively for mixing, When the temperature of the rubber in the mixing room reaches 80±5°C, lift and lower the top bolt once, so that the compounding agent and plasticized rubber are fully mixed. When the temperature of the rubber in the mixing room reaches 95±5°C, open the upstream seal. The lower jack bolt of the mill discharges the formed primary mixed rubber into the storage hopper;

(3)存料斗中的初混胶在压砣的作用下通过喂料口进入下游异向双转子连续混炼机中,设定混炼机转子的转速30±15r/min进行二段混炼;设定混炼机机筒内部自右往左开设的共四段冷却通道温度分别为:95±5℃、85±5℃、75±5℃和65±5℃,设定混炼机机头内部的冷却通道温度为55±5℃,混炼5.5±3min后形成半成品胶片由排料口排出;(3) The initial mixed rubber in the storage hopper enters the downstream counter-rotating double-rotor continuous mixer through the feeding port under the action of the weight, and the second-stage mixing is carried out by setting the rotation speed of the mixer rotor at 30±15r/min ;Set the temperature of the four cooling passages opened from right to left inside the kneader barrel as follows: 95±5°C, 85±5°C, 75±5°C and 65±5°C. The temperature of the cooling channel inside the head is 55±5°C. After mixing for 5.5±3 minutes, the semi-finished film is formed and discharged from the discharge port;

(4)将排出的半成品胶片经过现有技术中的开炼机进行多次压片后,再加入步骤(1)中混炼胶的生产配方中促进剂和硫磺通过打三角包的方式使其充分混合,然后进行后续的相关工艺及测试对比分析。(4) After the semi-finished film of discharging is carried out repeatedly tableting through the open mill in the prior art, then add accelerator and sulfur in the production formula of compound rubber in step (1) to make it by the mode of making triangular bag Mix well, and then carry out subsequent related process and test comparative analysis.

本发明涉及的串联式橡胶连续混炼方法能够适用于全钢子午胎胎面胶配方、子午线乘用胎胎面胶配方或斜交载重胎胎体胶配方等胶料的混炼。The tandem rubber continuous mixing method of the present invention can be applied to the mixing of rubber materials such as all-steel radial tire tread rubber formula, radial passenger tire tread rubber formula or bias truck tire carcass rubber formula.

本发明中实现串联式橡胶连续混炼方法的混炼装置整体结构分为上游密炼机和下游异向双转子连续混炼机两部分,两者之间通过存料斗采用端面密封方式贯通连接以实现保温控温作用,具体结构包括上游密炼机、Ⅰ号底座、Ⅰ号机架、Ⅱ号底座、下游异向双转子连续混炼机、Ⅱ号机架、压砣、存料斗和Ⅱ号油缸,Ⅰ号机架和Ⅱ号机架分别通过螺栓固定连接在Ⅱ号底座上,Ⅰ号底座上通过螺栓固定连接有用于进行胶料初混的上游密炼机,下游异向双转子连续混炼机通过螺栓固定设置在Ⅰ号机架和Ⅱ号机架上用于进行二段混炼,上游密炼机的下端通过存料斗与下游异向双转子连续混炼机的上端之间贯通对接,存料斗的左侧上端与Ⅰ号底座通过螺栓连接,其右侧上端通过螺栓固定安装有Ⅱ号油缸,Ⅱ号油缸下端通过传动杆结构连接设置有压砣,用于将存料斗中由上游密炼机排出的初混胶压入下游异向双转子连续混炼机中进行连续式二段混炼;所述下游异向双转子连续混炼机的主体结构包括排料口、混炼机机头、混炼机转子、混炼机机筒、喂料口、Ⅰ号联轴器、Ⅰ号减速器、Ⅱ号联轴器、Ⅰ号电机和冷却通道,混炼机机头的左端开设有排料口用于排出制得的半成品胶片,混炼机机头的右端与内部配套安装有混炼机转子的混炼机机筒固定对接,混炼机机筒的右端上方开设有喂料口,喂料口与存料斗贯通对接用于下游异向双转子连续混炼机吃进上游密炼机排出的初混胶;混炼机机头的内部开设有冷却通道用于控制混炼机机头的温度,混炼机机筒的内壁自右往左依次开设有共四段冷却通道用于控制混炼机机筒的温度,冷却通道中根据不同炼胶配方所需温度选用油或水作为冷却介质以扩大温控范围;从右往左依次串联的Ⅰ号电机、Ⅱ号联轴器、Ⅰ号减速器和Ⅰ号联轴器共同组成动力系统,为下游异向双转子连续混炼机提供动力。In the present invention, the overall structure of the mixing device for realizing the tandem rubber continuous mixing method is divided into two parts: an upstream internal mixer and a downstream counter-rotating double-rotor continuous mixing machine. Realize the effect of heat preservation and temperature control. The specific structure includes the upstream internal mixer, No. 1 base, No. 1 frame, No. 2 base, downstream counter-rotating double-rotor continuous mixer, No. 2 frame, weight, storage hopper and No. 2 Oil cylinder, No. 1 frame and No. 2 frame are fixedly connected to No. 2 base by bolts respectively. No. 1 base is fixedly connected by bolts to the upstream internal mixer for primary mixing of rubber materials, and the downstream counter-rotating double-rotor continuous mixer. The mixer is fixed on the No. 1 rack and No. 2 rack by bolts for two-stage mixing. The lower end of the upstream internal mixer is connected to the upper end of the downstream counter-rotating double-rotor continuous mixer through the storage hopper. , the left upper end of the storage hopper is connected with the No. 1 base by bolts, and the No. 2 oil cylinder is fixed on the right upper end by bolts. The primary mixed rubber discharged from the internal mixer is pressed into the downstream counter-rotating double-rotor continuous mixer for continuous two-stage mixing; the main structure of the downstream counter-rotating dual-rotor continuous mixer includes a discharge port, a mixer Machine head, kneading machine rotor, kneading machine barrel, feeding port, No. I coupling, No. I reducer, No. II coupling, No. I motor and cooling passage, the left end of the kneading machine head is opened There is a discharge port for discharging the prepared semi-finished film. The right end of the mixer head is fixedly connected with the mixer barrel with the mixer rotor installed inside. There is a feeding device above the right end of the mixer barrel. The mouth, the feeding port is connected with the storage hopper for the downstream counter-rotating double-rotor continuous mixer to eat the primary compound discharged from the upstream internal mixer; the inside of the mixer head is provided with a cooling channel for controlling the mixer The temperature of the machine head, the inner wall of the kneading machine barrel is opened from right to left, and there are a total of four sections of cooling channels to control the temperature of the kneading machine barrel. In the cooling channel, oil or water is selected according to the temperature required by different rubber mixing formulas. As a cooling medium to expand the range of temperature control; from right to left, No. I motor, No. II coupling, No. I reducer and No. I coupling together form a power system, which is the continuous mixing of downstream counter-rotating double rotors. machine provides power.

本发明中涉及到的上游密炼机的主体结构包括下顶栓、密炼机转子、密炼室、加料门、上顶栓、Ⅰ号油缸、Ⅲ号机架、Ⅲ号联轴器、Ⅱ号减速器、Ⅳ号联轴器和Ⅱ号电机,密炼室通过螺栓连接安装在Ⅰ号底座上,Ⅲ号机架左侧开设有可关闭式结构的加料门,加料门与密炼室贯通,密炼室内设置有密炼机转子,密炼室上部通过螺栓连接设置有Ⅲ号机架,Ⅲ号机架上固定安装有Ⅰ号油缸,Ⅰ号油缸下端通过传动杆连接设置有上顶栓,用于保证密炼机工作时密炼室中的压力,下顶栓通过铰链连接在Ⅰ号底座上用于卸料;从右往左依次串联固定在Ⅰ号底座上的Ⅱ号电机、Ⅳ号联轴器、Ⅱ号减速器和Ⅲ号联轴器共同组成动力系统为上游密炼机提供动力。The main structure of the upstream internal mixer involved in the present invention includes the lower top bolt, the rotor of the internal mixer, the mixing chamber, the feeding door, the upper top bolt, No. I oil cylinder, No. III frame, No. III coupling, II No. reducer, No. IV coupling and No. II motor. The mixing chamber is installed on the No. I base through bolt connection. There is a closable feeding door on the left side of the No. III frame, and the feeding door is connected with the mixing chamber. , the mixing room is equipped with a mixer rotor, and the upper part of the mixing room is connected with a No. Ⅲ frame by bolts. The No. 1 oil cylinder is fixedly installed on the No. 3 frame, and the lower end of the No. 1 oil cylinder is connected by a transmission rod. , which is used to ensure the pressure in the mixing chamber when the internal mixer is working. The lower top bolt is connected to the No. 1 base by a hinge for unloading; The No. coupling, No. II reducer and No. III coupling together form a power system to provide power for the upstream internal mixer.

本发明与现有技术相比,将密炼机混炼的方法和异向双转子连续混炼机的混炼方法相结合,实现了混炼技术的连续性,避免了小料和胶料混炼不均匀的现象,大大提高了生产效率,保证了胶品的质量,在下游异向双转子连续混炼机的混炼过程中,配合五段冷却通道和利用不同冷却介质能够增大控温范围,针对不同配方所需的混炼和排胶温度进行控温保温,较好的实现了低温混炼和恒温混炼,并减少了混炼过程中能量的损失,节约了人力物力的应用,所生产出的胶料具有良好的拉伸强度,撕裂强度和炭黑分散度等。Compared with the prior art, the present invention combines the mixing method of the internal mixer with the mixing method of the counter-rotating double-rotor continuous mixer, realizes the continuity of the mixing technology, and avoids the mixing of small materials and rubber materials. The phenomenon of uneven refining greatly improves the production efficiency and ensures the quality of rubber products. During the mixing process of the downstream counter-rotating double-rotor continuous mixer, the five-stage cooling channel and the use of different cooling media can increase the temperature control. Range, according to the mixing and debinding temperature required by different formulas, temperature control and heat preservation are carried out, which better realizes low-temperature mixing and constant temperature mixing, reduces energy loss during the mixing process, and saves the application of manpower and material resources. The produced compound has good tensile strength, tear strength and carbon black dispersion.

附图说明:Description of drawings:

图1为本发明涉及的串联式橡胶连续混炼方法的工艺流程示意框图。Fig. 1 is a schematic block diagram of the technological process of the tandem rubber continuous mixing method involved in the present invention.

图2为本发明涉及的连续混炼装置的主体结构原理示意图。Fig. 2 is a schematic diagram of the main structure of the continuous mixing device involved in the present invention.

图3为本发明涉及的连续混炼装置中上游密炼机的结构原理侧视图。Fig. 3 is a side view of the structural principle of the upstream internal mixer in the continuous mixing device involved in the present invention.

图4为本发明涉及的串联式橡胶连续混炼方法与传统密炼机混炼方法分别生产五组胶料对应的拉伸强度对比柱状示意图,其中横轴代表样本编号分为第1组、第2组、第3组、第4组和第5组,纵轴代表拉伸强度/MPa,黑色柱代表传统密炼机混炼方法,白色柱代表本发明恒温混炼方法。Fig. 4 is a columnar schematic diagram of the comparison of tensile strength corresponding to five groups of rubber materials produced by the tandem rubber continuous mixing method involved in the present invention and the traditional internal mixer mixing method, wherein the horizontal axis represents the sample number and is divided into the first group and the second group. Group 2, Group 3, Group 4 and Group 5, the vertical axis represents the tensile strength/MPa, the black column represents the traditional internal mixer mixing method, and the white column represents the constant temperature mixing method of the present invention.

图5为本发明涉及的串联式橡胶连续混炼方法与传统密炼机混炼方法分别生产五组胶料对应的撕裂强度对比柱状示意图,其中横轴代表样本编号分为第1组、第2组、第3组、第4组和第5组,纵轴代表撕裂强度KN/m,黑色柱代表传统密炼机混炼方法,白色柱代表本发明恒温混炼方法。Fig. 5 is a columnar schematic diagram of the comparison of tear strength corresponding to five groups of rubber materials produced by the tandem rubber continuous mixing method and the traditional internal mixer mixing method of the present invention, wherein the horizontal axis represents the sample numbers divided into the first group and the second group. Group 2, Group 3, Group 4 and Group 5, the vertical axis represents the tear strength KN/m, the black column represents the traditional internal mixer mixing method, and the white column represents the constant temperature mixing method of the present invention.

图6为本发明涉及的串联式橡胶连续混炼方法与传统密炼机混炼方法分别生产五组胶料对应的炭黑分散度对比柱状示意图,其中横轴代表样本编号分为第1组、第2组、第3组、第4组和第5组,纵轴代表炭黑分散度,黑色柱代表传统密炼机混炼方法,白色柱代表本发明恒温混炼方法。Fig. 6 is a columnar schematic diagram of the comparison of carbon black dispersion corresponding to five groups of sizing materials produced by the tandem rubber continuous mixing method and the traditional internal mixer mixing method involved in the present invention, wherein the horizontal axis represents the sample number and is divided into the first group, The 2nd group, the 3rd group, the 4th group and the 5th group, the vertical axis represents the dispersion degree of carbon black, the black column represents the traditional internal mixer mixing method, and the white column represents the constant temperature mixing method of the present invention.

具体实施方式:detailed description:

下面通过实施例并结合附图对本发明作进一步详细描述。The present invention will be described in further detail below through embodiments and in conjunction with the accompanying drawings.

实施例1:Example 1:

本实施例以全钢子午胎胎面胶配方为例进行说明,涉及的串联式橡胶连续混炼方法具体包括以下工艺步骤:In this embodiment, the formula of all-steel radial tire tread rubber is taken as an example for illustration. The tandem rubber continuous mixing method involved specifically includes the following process steps:

(1)采用65±5%的填充系数,以上游密炼机1的具体型号和混炼胶的生产配方为根据,计算出各种物料的质量并称量后备用,设定初混阶段中上游密炼机1的工作参数为:转子转速60±15r/min优选为65±3r/min,温控为50±10℃优选45±3℃,上顶栓压力0.6±0.05MPa;其中物料包括基体胶和配合剂;(1) Using a filling factor of 65±5%, based on the specific model of the upstream internal mixer 1 and the production formula of the mixed rubber, the mass of various materials is calculated and weighed for later use. The working parameters of the upstream internal mixer 1 are: the rotor speed is 60±15r/min, preferably 65±3r/min, the temperature control is 50±10°C, preferably 45±3°C, and the pressure of the top bolt is 0.6±0.05MPa; the materials include Base glue and compounding agent;

(2)将步骤(1)中称量的基体胶投入上游密炼机1中进行40±10s优选35±3s的塑炼形成塑炼橡胶,然后再分别加入配合剂包括炭黑N330、氧化锌、防老剂RD、增塑剂A和硬脂酸SA进行混炼,使得配合剂与塑炼橡胶充分混合,当密炼室21中的胶料温度达到80±5℃时升降上顶栓23一次,当密炼室21中的胶料温度达到95±5℃时,打开上游密炼机1的下顶栓19将形成的初混胶排入到存料斗8中;(2) Put the matrix rubber weighed in step (1) into the upstream internal mixer 1 for 40 ± 10s, preferably 35 ± 3s of masticating to form masticated rubber, and then add compounding agents including carbon black N330, zinc oxide , anti-aging agent RD, plasticizer A and stearic acid SA are mixed, so that the compounding agent is fully mixed with the masticated rubber, and when the temperature of the rubber in the mixing chamber 21 reaches 80±5°C, the top bolt 23 is lifted and lowered once , when the temperature of the rubber material in the mixing chamber 21 reaches 95±5°C, open the lower top bolt 19 of the upstream internal mixer 1 to discharge the formed initial mixed rubber into the storage hopper 8;

(3)存料斗8中的初混胶在压砣7的作用下通过喂料口14进入下游异向双转子连续混炼机5中,设定混炼机转子12的转速30±15r/min优选35±3r/min进行二段混炼;设定混炼机机筒13内部自右往左开设的共四段冷却通道温度分别为:95±5℃、85±5℃、75±5℃和65±5℃,设定混炼机机头11内部的冷却通道温度为55±5℃,混炼5.5±3min优选3.6±0.5min后形成半成品胶片由排料口10排出;(3) The initial mixed rubber in the storage hopper 8 enters the downstream counter-rotating double-rotor continuous mixer 5 through the feed port 14 under the action of the weight 7, and the rotational speed of the mixer rotor 12 is set to 30±15r/min Preferably 35±3r/min for two-stage mixing; set the temperature of the four-stage cooling channels opened from right to left inside the kneader barrel 13 as follows: 95±5°C, 85±5°C, 75±5°C and 65±5°C, set the temperature of the cooling channel inside the head 11 of the mixer to 55±5°C, and knead for 5.5±3min, preferably 3.6±0.5min to form a semi-finished film and discharge it from the discharge port 10;

(4)将排出的半成品胶片经过现有技术中的开炼机进行多次压片后,再加入步骤(1)的生产配方中配合剂包括促进剂NOBS和硫磺,通过打三角包的方式使其充分混合,然后进行后续的相关工艺及测试对比分析。(4) after the semi-finished film of discharging is carried out repeatedly tabletting through the open mill in the prior art, then add compounding agent in the production formula of step (1) and comprise promotor NOBS and sulfur, make by the mode of making triangular bag It is fully mixed, and then the subsequent related processes and tests are compared and analyzed.

本实施例中涉及的混炼胶的生产配方为:The production formula of the mixed rubber involved in the present embodiment is:

本实施例中涉及的混炼装置整体结构分为上游密炼机1和下游异向双转子连续混炼机5两大部分,两者之间通过存料斗8采用端面密封方式贯通连接以实现保温控温作用,具体结构包括上游密炼机1、Ⅰ号底座2、Ⅰ号机架3、Ⅱ号底座4、下游异向双转子连续混炼机5、Ⅱ号机架6、压砣7、存料斗8和Ⅱ号油缸9,Ⅰ号机架3和Ⅱ号机架6分别通过螺栓固定连接在Ⅱ号底座4上,Ⅰ号底座2上通过螺栓固定连接有用于进行胶料初混的上游密炼机1,下游异向双转子连续混炼机5通过螺栓固定设置在Ⅰ号机架3和Ⅱ号机架6上用于进行二段混炼,上游密炼机1的下端通过存料斗8与下游异向双转子连续混炼机5的上端之间贯通对接,存料斗8的左侧上端与Ⅰ号底座2通过螺栓连接,其右侧上端通过螺栓固定安装有Ⅱ号油缸9,Ⅱ号油缸9下端通过传动杆连接设置有压砣7,用于将存料斗8中由上游密炼机1排出的初混胶压入下游异向双转子连续混炼机5中进行连续式二段混炼;所述下游异向双转子连续混炼机5的主体结构包括排料口10、混炼机机头11、混炼机转子12、混炼机机筒13、喂料口14、Ⅰ号联轴器15、Ⅰ号减速器16、Ⅱ号联轴器17、Ⅰ号电机18和冷却通道30,混炼机机头11的左端开设有排料口10用于排出制得的半成品胶片,混炼机机头11的右端与内部配套安装有混炼机转子12的混炼机机筒13固定对接,混炼机机筒13的右端上方开设有喂料口14,喂料口14与存料斗8贯通对接用于下游异向双转子连续混炼机5吃进上游密炼机1排出的初混胶;混炼机机头11的内部开设有冷却通道30用于控制混炼机机头11的温度,混炼机机筒13的内壁自右往左依次开设有共四段冷却通道30用于控制混炼机机筒13的温度,冷却通道30中选用水作为冷却介质;从右往左依次串联的Ⅰ号电机18、Ⅱ号联轴器17、Ⅰ号减速器16和Ⅰ号联轴器15共同组成动力系统,为下游异向双转子连续混炼机5提供动力。The overall structure of the mixing device involved in this embodiment is divided into two parts: the upstream internal mixer 1 and the downstream counter-rotating double-rotor continuous mixer 5, and the two are connected through the storage hopper 8 by means of end face sealing to achieve heat preservation. Temperature control function, the specific structure includes upstream internal mixer 1, No. 1 base 2, No. 1 frame 3, No. 2 base 4, downstream counter-rotating double-rotor continuous mixer 5, No. 2 frame 6, weight 7, Storage hopper 8 and No. Ⅱ oil cylinder 9, No. 1 frame 3 and No. 2 frame 6 are respectively fixedly connected to No. 2 base 4 by bolts, and No. 1 base 2 is fixedly connected to the upper stream for primary rubber mixing by bolts. The internal mixer 1 and the downstream counter-rotating double-rotor continuous mixer 5 are fixed on the No. 1 frame 3 and the No. 2 frame 6 by bolts for two-stage mixing, and the lower end of the upstream internal mixer 1 passes through the storage hopper 8 is connected to the upper end of the downstream counter-rotating double-rotor continuous mixer 5. The upper left end of the storage hopper 8 is connected to the No. I base 2 by bolts, and the No. II oil cylinder 9 is installed on the upper right end of the storage hopper by bolts. The lower end of No. 9 oil cylinder 9 is connected with a weight 7 through a transmission rod, which is used to press the primary mixed rubber discharged from the upstream internal mixer 1 in the storage hopper 8 into the downstream counter-rotating double-rotor continuous mixer 5 for continuous two-stage Mixing; the main structure of the downstream different-direction double-rotor continuous kneader 5 includes a discharge port 10, a kneader head 11, a kneader rotor 12, a kneader barrel 13, a feed port 14, I No. coupling 15, No. 1 reducer 16, No. 2 coupling 17, No. 1 motor 18 and cooling channel 30, and the left end of the mixing machine head 11 is provided with a discharge port 10 for discharging the prepared semi-finished film , the right end of the kneader head 11 is fixedly connected to the kneader barrel 13 with the kneader rotor 12 installed inside, and a feed port 14 is provided above the right end of the kneader barrel 13, and the feed port 14 is connected to The storage hopper 8 is connected through the joint for the downstream counter-rotating double-rotor continuous mixer 5 to eat the primary compound discharged from the upstream internal mixer 1; the inside of the mixer head 11 is provided with a cooling channel 30 for controlling the mixer The temperature of the head 11, the inner wall of the kneading machine barrel 13 is provided with a total of four sections of cooling channels 30 from right to left to control the temperature of the kneading machine barrel 13, and water is used as the cooling medium in the cooling channel 30; The No. I motor 18, No. II shaft coupling 17, No. I reducer 16 and No. I shaft coupling 15 connected in series to the left together form a power system to provide power for the downstream counter-rotating double-rotor continuous mixer 5.

本实施例中所述上游密炼机1的主体结构(如图2和图3所示)包括下顶栓19、密炼机转子20、密炼室21、加料门22、上顶栓23、Ⅰ号油缸24、Ⅲ号机架25、Ⅲ号联轴器26、Ⅱ号减速器27、Ⅳ号联轴器28和Ⅱ号电机29,密炼室21通过螺栓连接安装在Ⅰ号底座2上,Ⅲ号机架25左侧开设有可关闭式结构的加料门22,加料门22与密炼室21贯通,密炼室21内设置有密炼机转子20,密炼室21上部通过螺栓连接设置有Ⅲ号机架25,Ⅲ号机架25上固定安装有Ⅰ号油缸24,Ⅰ号油缸24下端通过传动杆连接设置有上顶栓23,用于保证密炼机工作时密炼室21中的压力,下顶栓19通过铰链连接在Ⅰ号底座2上用于卸料;从右往左依次串联固定在Ⅰ号底座2上的Ⅱ号电机29、Ⅳ号联轴器28、Ⅱ号减速器27和Ⅲ号联轴器26共同组成动力系统为上游密炼机1提供动力。The main structure of the upstream internal mixer 1 described in this embodiment (as shown in Figure 2 and Figure 3) includes a lower top bolt 19, an internal mixer rotor 20, a mixing chamber 21, a charging door 22, an upper top bolt 23, No. I oil cylinder 24, No. III rack 25, No. III coupling 26, No. II reducer 27, No. IV coupling 28 and No. II motor 29, and the mixing chamber 21 is installed on No. I base 2 through bolt connection On the left side of No. Ⅲ frame 25, there is a closable feeding door 22. The feeding door 22 communicates with the mixing chamber 21. The mixing chamber 21 is provided with a mixer rotor 20, and the upper part of the mixing chamber 21 is connected by bolts. No. Ⅲ frame 25 is set, and No. 1 oil cylinder 24 is fixedly installed on No. Ⅲ frame 25. The lower end of No. 1 oil cylinder 24 is connected with a transmission rod and provided with an upper jack bolt 23, which is used to ensure that the internal mixing chamber 21 The lower jacking bolt 19 is connected to the No. I base 2 through a hinge for unloading; from right to left, the No. II motor 29, the No. IV coupling 28, and the No. The speed reducer 27 and the No. III shaft coupling 26 together form a power system to provide power for the upstream internal mixer 1 .

实施例2:Example 2:

本实施例以全钢子午胎胎面胶配方为例,通过实施例1中涉及的串联式橡胶连续混炼方法与传统密炼机混炼方法进行对比说明。In this example, taking the formula of all-steel radial tire tread rubber as an example, the serial rubber continuous mixing method involved in Example 1 is compared with the traditional internal mixer mixing method.

传统密炼机混炼方法的具体工艺步骤为:The specific process steps of the traditional internal mixer mixing method are:

(1)采用65±3%的填充系数,以密炼机的具体型号和实施例1中所述混炼胶的生产配方为根据,计算出各种物料的质量并称量后备用,设定密炼机的工作参数为:转子转速65±3r/min,温控为45±3℃,上顶栓压力0.6±0.05MPa;(1) adopt the filling factor of 65 ± 3%, based on the specific model of the internal mixer and the production formula of the mixed rubber described in Example 1, calculate the quality of various materials and weigh them for later use, set The working parameters of the internal mixer are: the rotor speed is 65±3r/min, the temperature control is 45±3℃, and the pressure of the top bolt is 0.6±0.05MPa;

(2)将步骤(1)中称量的天然橡胶投入密炼机中进行35±3s的塑炼,然后再分别加入炭黑N330、氧化锌、防老剂RD、增塑剂A、硬脂酸SA进行混炼;当密炼室中的混炼胶温度达到110±3℃和120±3℃时,各上升和下降上顶栓1次,使得胶料混炼充分,当密炼室中的胶料混炼胶温度达到140±3℃,完成混炼打开下顶栓排出胶料;(2) Put the natural rubber weighed in the step (1) into the internal mixer and carry out 35 ± 3s masticating, then add carbon black N330, zinc oxide, antioxidant RD, plasticizer A, stearic acid respectively SA for mixing; when the temperature of the mixed rubber in the mixing room reaches 110±3°C and 120±3°C, each raise and lower the top bolt once, so that the rubber is fully mixed. The temperature of the rubber compounded rubber reaches 140±3°C, after the mixing is completed, the lower top bolt is opened to discharge the rubber material;

(3)将排出的胶料经过现有技术中的开炼机进行多次压片后,再加入配方中所述促进剂NOBS和硫磺通过打三角包的方式使其充分混合,然后进行后续的相关工艺及测试对比。(3) After the discharged sizing material is pressed through the open mill in the prior art for many times, then the accelerator NOBS and sulfur described in the formula are added to make it fully mixed by making a triangular bag, and then follow-up Related process and test comparison.

本实施例中所述的传统密炼机混炼方法与实施例1中串联式橡胶连续混炼方法相比,生产能力明显缺乏优势;所生产出的胶料在拉伸强度、撕裂强度和炭黑分散度方面均不如实施例1中串联式橡胶连续混炼方法生产的胶料,具体对比结果如图4-6所示。Compared with the tandem rubber continuous mixing method in Example 1, the traditional internal mixer mixing method described in this example has obvious lack of advantages in production capacity; The dispersion of carbon black is not as good as the compound produced by the serial rubber continuous mixing method in Example 1, and the specific comparison results are shown in Figures 4-6.

Claims (2)

1. a kind of tandem rubber compound continuous mixing method, it is characterised in that concrete technology step is as follows:
(1) 65 ± 5% fill factor is used, according to the factory formula of the concrete model of upstream banbury and elastomeric compound, Calculate various materials quality and accurate weighing after it is standby, set just mix the stage middle and upper reaches banbury running parameter as:Turn 60 ± 15r/min of rotor speed, temperature control is 50 ± 10 DEG C, 0.6 ± 0.05MPa of ram piston pressure;Wherein material include matrix glue and Compounding ingredient;
(2) carry out plasticating for 40 ± 10s to form softened rubber in the matrix glue input upstream banbury that will be weighed in step (1), Then the compounding ingredient in addition to sulphur and accelerator is separately added into again to be kneaded, 80 are reached when the sizing material temperature in banburying chamber ± Floating weight is lifted at 5 DEG C once so that compounding ingredient and softened rubber are sufficiently mixed, 95 are reached when the sizing material temperature in banburying chamber ± At 5 DEG C, be drained into the first mixed glue for being formed in storaging bucket by the lower top bolt for opening upstream banbury;
(3) the first mixed glue in storaging bucket enters the incorgruous two-rotor continuous mixer in downstream in the presence of ram by spout In, the 30 ± 15r/min of rotating speed for setting mixing machine rotor carries out two-stage mixing;Turned left from the right side and opened up in setting kneading machine machine barrel inside Totally four sections of cooling duct temperature be respectively:95 ± 5 DEG C, 85 ± 5 DEG C, 75 ± 5 DEG C and 65 ± 5 DEG C, in setting kneading machine head The cooling duct temperature in portion is 55 ± 5 DEG C, and form semi-finished product film after 5.5 ± 3min of mixing is discharged by discharge gate;
(4) by the semi-finished product film of discharge after mill of the prior art carries out multiple compressing tablet, in adding step (1) Accelerator and sulphur are sufficiently mixed it by way of beating triangle bag in the factory formula of elastomeric compound, then carry out follow-up phase Close technique and test comparison analysis;
Realize that the kneading device overall structure of the compounding process is divided into the incorgruous two-rotor continuous mixer of upstream banbury and downstream Two parts, use the insertion of end face seal mode to connect to realize being incubated temperature control function, concrete structure by storaging bucket between the two Including upstream banbury, No. I base, No. I frame, No. II base, the incorgruous two-rotor continuous mixer in downstream, No. II frame, pressure Stone roller, storaging bucket and No. II oil cylinder, No. I frame and No. II frame are bolted to connection on No. II base respectively, No. I base On be bolted to connection the upstream banbury mixed at the beginning of for carrying out sizing material, the incorgruous two-rotor continuous mixer in downstream passes through Bolt is fixedly installed in No. I frame and No. II frame to be used to carry out two-stage mixing, and the lower end of upstream banbury passes through storaging bucket Insertion is docked between the upper end of the incorgruous two-rotor continuous mixer in downstream, and the left side upper end of storaging bucket passes through spiral shell with No. I base Tether and connect, its right side upper end is bolted and is provided with No. II oil cylinder, and No. II oil cylinder lower end is connected by drive link structure and set Ram is equipped with, in the first mixed glue laminated discharged by upstream banbury in storaging bucket entered into the incorgruous two-rotor continuous mixer in downstream Carry out continous way two-stage mixing;The agent structure of the incorgruous two-rotor continuous mixer in downstream includes discharge gate, kneading machine machine Head, mixing machine rotor, kneading machine machine barrel, spout, No. I shaft coupling, No. I decelerator, No. II shaft coupling, No. I motor and cooling Passage, the left end of kneading machine head offers discharge gate for discharging obtained semi-finished product film, the right-hand member of kneading machine head with The internal supporting kneading machine machine barrel for being provided with mixing machine rotor fixes docking, and the right-hand member top of kneading machine machine barrel offers feeding Mouthful, spout is docked with storaging bucket insertion eats the first mixed of upstream banbury discharge for the incorgruous two-rotor continuous mixer in downstream Glue;The inside of kneading machine head offers cooling duct for controlling the temperature of kneading machine head, and the inwall of kneading machine machine barrel is certainly The right side is turned left and offers totally four sections of cooling ducts successively and be used to control the temperature of kneading machine machine barrel, according to different refining glues in cooling duct Temperature needed for formula selects oil or water as cooling medium to expand temperature-control range;Turn left No. I motor, II being sequentially connected in series from the right side Number shaft coupling, No. I decelerator and No. I shaft coupling collectively constitute dynamical system, for the incorgruous two-rotor continuous mixer in downstream is provided Power;The agent structure of upstream banbury include lower top bolt, closed-smelting machine rotor, banburying chamber, gallery ports, floating weight, No. I oil cylinder, No. III frame, No. III shaft coupling, No. II decelerator, No. IV shaft coupling and No. II motor, banburying chamber are bolted installed in I On number base, No. III frame left side offer can closing type structure gallery ports, gallery ports and banburying chamber's insertion set in banburying chamber Closed-smelting machine rotor is equipped with, banburying chamber top is bolted and is provided with No. III frame, and No. I oil is installed with No. III frame Cylinder, No. I oil cylinder lower end is connected with floating weight by drive link, for ensureing pressure during banbury work in banburying chamber, Lower top bolt is connected through the hinge and is used for discharging on No. I base;Turned left from the right side No. II electricity for being sequentially connected in series and being fixed on No. I base Machine, No. IV shaft coupling, No. II decelerator and No. III shaft coupling collectively constitute dynamical system for upstream banbury provides power.
2. tandem rubber compound continuous mixing method according to claim 1, it is characterised in that all-steel radial tire tire can be used for The compounding rubber that face glue is formulated, the riding tire tread glue formula of meridian or oblique load-carrying tire carcass glue are formulated.
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