CN104439251B - A kind of Copper infiltration agent for powder metallurgy - Google Patents

A kind of Copper infiltration agent for powder metallurgy Download PDF

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CN104439251B
CN104439251B CN201410577691.1A CN201410577691A CN104439251B CN 104439251 B CN104439251 B CN 104439251B CN 201410577691 A CN201410577691 A CN 201410577691A CN 104439251 B CN104439251 B CN 104439251B
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parts
copper
powder metallurgy
infiltration agent
ferrum
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CN104439251A (en
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王栩
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Chongqing Jiangzhou Powder Metallurgy Technology Co., Ltd.
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Qingdao Jinzhi High And New Technology Co Ltd
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Abstract

The invention provides a kind of Copper infiltration agent for powder metallurgy, described copper seeping agent includes in parts by weight: copper 93.6~94.4 parts, ferrum 2.1~3.5 parts, carbon 1.4~2.7 parts, manganese 0.7~1.8 parts, chromium 0.4~1.5 parts, silicon 0.2~0.9 part, molybdenum 0.3~1.2 parts, phosphorus 0.1~0.8 part, cobalt 0.2~0.9 part, bismuth 0.5~1.9 parts.Copper seeping agent of the present invention has that formability is good, infiltration efficiency is high, non-corrosive, low-residual, significantly improve the feature of density of material and mechanical property.

Description

A kind of Copper infiltration agent for powder metallurgy
Technical field
The invention belongs to powdered metallurgical material technical field, be specifically related to a kind of Copper infiltration agent for powder metallurgy.
Background technology
At present, powder metallurgy sintered steel parts are owing to its low cost, the easy feature processed are at commercial production especially vapour Application in car mechanical industry is more and more extensive, and conventional have sintered steel gear, cam, valve seat, an exhaust valve seat etc., these zero When part is on active service under some rugged environment, it is desirable to there is good wearability, resistance to impact, keep again higher intensity and Hardness.But the powder metallurgy sintered steel parts using conventional compacting-sintering process to manufacture, can not reach in pressing process Densifie state completely, the hole wherein remained is its tensile strength, impact flexibility, fatigue strength as a kind of defective effect With performances such as hardness, cause it can not meet use requirement.Therefore, eliminate or reduce its residual porosity be obtain high compactness, The most effective approach of high performance sintered steel, and oozing copper is exactly a kind of conventional method.Research shows, by copper or copper alloy powder foot couple Sintered steel carries out hole that infiltration can significantly reduce or eliminate in sintered steel, improves density, improves its mechanical property and kinetics Performance (such as impact flexibility, fatigue) etc..Ooze the densification processes such as the more traditional repressing and re-sintering of copper, power forging, temperature and pressure to have into The advantages such as this low, operation is simple, easy adjustment, the most this method since the U.S. comes out, has applied model from the forties in last century Enclose expanding day, the most become and produced the densification process that high-performance Fe-based powder metallurgy parts are indispensable.
Powder metallurgy copperized technique is a kind of acquisition high density or even densification under common pressing pressure (500~600MPa) The technique of powdered metal parts.The property such as the impulsive force of part, sealing, wearability and the machinability produced by this technique Can be far above the technique such as temperature and pressure, repressing and re-sintering, therefore it occupies suitable share in high-end powder metallurgy product.But due to powder What end was metallurgical ooze, and copper is carries out the temperature range of 1090~1150 DEG C, generally takes 1120 DEG C, and at this temperature range ferrum at copper Middle dissolubility is about 3.8~4%, result in and directly oozes copper with Cu block and powdered metal parts, oozes copper efficiency and be about 85%, part Surface and inside can form corrosion cracking, affect outward appearance and the impact strength of product, which results in high volume (25~35%) Substandard products occur.Generally use mach method to remove substandard products, which increase processing cost.It is therefore desirable to exploitation one is not Corrosion products, do not affect the copper seeping agent of product strength.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art to provide a kind of Copper infiltration agent for powder metallurgy, this copper seeping agent becomes Shape is good, infiltration efficiency is high, non-corrosive, low-residual, can significantly improve density of material and mechanical property.
A kind of Copper infiltration agent for powder metallurgy, includes: copper 93.6~94.4 parts, ferrum 2.1~3.5 parts, carbon 1.4 in parts by weight ~2.7 parts, manganese 0.7~1.8 parts, chromium 0.4~1.5 parts, silicon 0.2~0.9 part, molybdenum 0.3~1.2 parts, phosphorus 0.1~0.8 part, cobalt 0.2~0.9 part, bismuth 0.5~1.9 parts.
As the further improvement of foregoing invention, described Copper infiltration agent for powder metallurgy the most also include boron 0.3~ 0.8 part.
As the further improvement of foregoing invention, described Copper infiltration agent for powder metallurgy the most also include stannum 0.2~ 1.1 part.
As the further improvement of foregoing invention, described Copper infiltration agent for powder metallurgy the most also include zinc 0.1~ 0.5 part.
As the further improvement of foregoing invention, Copper infiltration agent for powder metallurgy, include in parts by weight: copper 94.1 parts, ferrum 2.9 parts, 1.8 parts of carbon, 1.4 parts of manganese, chromium 0.9 part, silicon 0.6 part, molybdenum 0.8 part, 0.4 part of phosphorus, cobalt 0.6 part, bismuth 1.5 parts, boron 0.7 Part, 0.6 part of stannum, 0.2 part of zinc.
As the further improvement of foregoing invention, described copper, ferrum, carbon, manganese, chromium, silicon, molybdenum, phosphorus, cobalt, bismuth, boron, stannum and zinc Granularity less than 200 mesh.
From ferrum copper phasor, when 1120 DEG C, ferrum dissolubility in copper is 3.8%, if not iron content in copper seeping agent, When then oozing copper, matrix skeleton with the ferrum generation solid solution in sintered steel matrix, thus can be caused erosion by part copper, crack or Aperture so that the impact flexibility oozing copper sintered steel is decreased obviously.In order to reduce the erosion of copper, add a certain amount of in copper seeping agent Iron powder, makes copper liquid saturated by ferrum before infiltration, thus reduces copper liquid to the dissolving of ferrum in matrix, can reduce to a certain extent Corrode.Carbon dust can form steel matrix with ferroalloy by diffusion, thus increases material hardness, it is easy to removes residue.Manganese one side Face can be with copper alloy, it is possible to decrease surface tension of liquid, is on the other hand prone to away the residue after oozing copper, reduces and corrodes, carries Height oozes the mechanical property of copper sintered steel.Appropriate boron powder can improve the ferrum-density of carbon sintered material, intensity, crushing strength, tough Property.Chromium can form carbide and alloyed cementite with carbon, thus improves material hardness.Silicon can form high-strength material with manganese, When oozing copper, silicon forms reinforcing particle with cobalt, chromium, molybdenum etc., thus improves material hardness.Phosphorus can improve copper wettability in ferrum, There is fluxing action.Stannum can not only improve the mobility of infiltration copper, and the infiltration effect to open pores has the effect of being obviously promoted, also Lubrication can be played, increase toughness, reduce the abrasion of material.
The copper seeping agent of the present invention oozes in copper temperature range (1090~1150 DEG C) whole, oozes copper efficiency > 98%, produces Powder metallurgy copperized piece surface corrosion-free, noresidue scum.
Detailed description of the invention
Embodiment 1
A kind of Copper infiltration agent for powder metallurgy, includes: copper 93.6 parts, ferrum 2.1 parts, 1.4 parts of carbon, 0.7 part of manganese in parts by weight, Chromium 0.4 part, silicon 0.2 part, molybdenum 0.3 part, 0.1 part of phosphorus, cobalt 0.2 part, bismuth 0.5 part.
The granularity of described raw material is less than 200 mesh.
Above-mentioned raw materials is mixed 30~35min with the rotating speed of 19~21tpm in double cone mixer and get final product.
Embodiment 2
A kind of Copper infiltration agent for powder metallurgy, includes: copper 94.1 parts, ferrum 2.8 parts, 1.9 parts of carbon, 1.2 parts of manganese in parts by weight, Chromium 0.9 part, silicon 0.5 part, molybdenum 0.8 part, 0.4 part of phosphorus, cobalt 0.7 part, bismuth 1.4 parts.
The granularity of described raw material is less than 200 mesh.
Above-mentioned raw materials is mixed 30~35min with the rotating speed of 19~21tpm in double cone mixer and get final product.
Embodiment 3
A kind of Copper infiltration agent for powder metallurgy, includes: copper 94.4 parts, ferrum 3.5 parts, 2.7 parts of carbon, 1.8 parts of manganese in parts by weight, Chromium 1.5 parts, silicon 0.9 part, molybdenum 1.2 parts, 0.8 part of phosphorus, cobalt 0.9 part, bismuth 1.9 parts.
The granularity of described raw material is less than 200 mesh.
Above-mentioned raw materials is mixed 30~35min with the rotating speed of 19~21tpm in double cone mixer and get final product.
Embodiment 4
A kind of Copper infiltration agent for powder metallurgy, includes: copper 94.4 parts, ferrum 3.5 parts, 2.7 parts of carbon, 1.8 parts of manganese in parts by weight, Chromium 1.5 parts, silicon 0.9 part, molybdenum 1.2 parts, 0.8 part of phosphorus, cobalt 0.9 part, bismuth 1.9 parts, boron 0.7 part.
The granularity of described raw material is less than 200 mesh.
Above-mentioned raw materials is mixed 30~35min with the rotating speed of 19~21tpm in double cone mixer and get final product.
Embodiment 5
A kind of Copper infiltration agent for powder metallurgy, includes: copper 94.1 parts, ferrum 2.8 parts, 1.9 parts of carbon, 1.2 parts of manganese in parts by weight, Chromium 0.9 part, silicon 0.5 part, molybdenum 0.8 part, 0.4 part of phosphorus, cobalt 0.7 part, bismuth 1.4 parts, 0.6 part of stannum.
The granularity of described raw material is less than 200 mesh.
Above-mentioned raw materials is mixed 30~35min with the rotating speed of 19~21tpm in double cone mixer and get final product.
Embodiment 6
A kind of Copper infiltration agent for powder metallurgy, includes: copper 94.1 parts, ferrum 2.8 parts, 1.9 parts of carbon, 1.2 parts of manganese in parts by weight, Chromium 0.9 part, silicon 0.5 part, molybdenum 0.8 part, 0.4 part of phosphorus, cobalt 0.7 part, bismuth 1.4 parts, 0.3 part of zinc.
The granularity of described raw material is less than 200 mesh.
Above-mentioned raw materials is mixed 30~35min with the rotating speed of 19~21tpm in double cone mixer and get final product.
Embodiment 7
A kind of Copper infiltration agent for powder metallurgy, includes: copper 94.1 parts, ferrum 2.9 parts, 1.8 parts of carbon, 1.4 parts of manganese in parts by weight, Chromium 0.9 part, silicon 0.6 part, molybdenum 0.8 part, 0.4 part of phosphorus, cobalt 0.6 part, bismuth 1.5 parts, boron 0.7 part, 0.6 part of stannum, 0.2 part of zinc.
The granularity of described raw material is less than 200 mesh.
Above-mentioned raw materials is mixed 30~35min with the rotating speed of 19~21tpm in double cone mixer and get final product.
Embodiment 1 to 7 gained copper seeping agent and commercially available prod are carried out performance test, and result is as follows:
From upper table result, Copper infiltration agent for powder metallurgy physical property and the infiltration performance of the present invention are superior to commercially available prod.

Claims (4)

1. a Copper infiltration agent for powder metallurgy, it is characterised in that: include in parts by weight: copper 93.6~94.4 parts, ferrum 2.1~ 3.5 parts, carbon 1.4~2.7 parts, manganese 0.7~1.8 parts, chromium 0.4~1.5 parts, silicon 0.2~0.9 part, molybdenum 0.3~1.2 parts, phosphorus 0.1 ~0.8 part, cobalt 0.2~0.9 part, bismuth 0.5~1.9 parts.
Copper infiltration agent for powder metallurgy the most according to claim 1, it is characterised in that: described Copper infiltration agent for powder metallurgy is with weight Amount part meter also includes boron 0.3~0.8 part.
Copper infiltration agent for powder metallurgy the most according to claim 1, it is characterised in that: described Copper infiltration agent for powder metallurgy is with weight Amount part meter also includes stannum 0.2~1.1 parts.
Copper infiltration agent for powder metallurgy the most according to claim 1, it is characterised in that: described Copper infiltration agent for powder metallurgy is with weight Amount part meter also includes zinc 0.1~0.5 part.
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CN105665716A (en) * 2016-01-25 2016-06-15 金华市宇辰粉末冶金有限公司 Powder metallurgy spiral bevel gear and preparation method and application thereof
CN105750552A (en) * 2016-02-18 2016-07-13 南京子牙湖合金材料有限公司 Copper infiltration agent for iron-based powder metallurgy and preparation method thereof
CN108637259B (en) * 2018-04-12 2020-04-14 金华市宇辰粉末冶金有限公司 Powder metallurgy saw blade upper and lower pressing plates and production method thereof
CN109158593B (en) * 2018-08-17 2021-04-30 宁波瑞丰汽车零部件有限公司 Preparation method of office table connecting bracket

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US6551373B2 (en) * 2000-05-11 2003-04-22 Ntn Corporation Copper infiltrated ferro-phosphorous powder metal
US7341093B2 (en) * 2005-02-11 2008-03-11 Llc 2 Holdings Limited, Llc Copper-based alloys and their use for infiltration of powder metal parts
CN100441711C (en) * 2006-08-09 2008-12-10 海门市常乐粉末冶金厂 Manufacture method of high-strength powder metallurgy bevel gear and copper seeping agent for the same
JP4857206B2 (en) * 2007-06-29 2012-01-18 福田金属箔粉工業株式会社 Infiltration powder
CN101736285B (en) * 2008-11-21 2011-11-09 北京有色金属研究总院 Copperizing solvent and preparation method thereof
CN101961789A (en) * 2010-10-15 2011-02-02 苏州莱特复合材料有限公司 Process for manufacturing cylinder block blank of powder metallurgy plunger pump
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