CN104418880A - Formula and preparation process of novel azocyclotin - Google Patents
Formula and preparation process of novel azocyclotin Download PDFInfo
- Publication number
- CN104418880A CN104418880A CN201310384040.6A CN201310384040A CN104418880A CN 104418880 A CN104418880 A CN 104418880A CN 201310384040 A CN201310384040 A CN 201310384040A CN 104418880 A CN104418880 A CN 104418880A
- Authority
- CN
- China
- Prior art keywords
- azocyclotin
- novel
- formula
- triazole
- preparation process
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- ONHBDDJJTDTLIR-UHFFFAOYSA-N azocyclotin Chemical compound C1CCCCC1[Sn](N1N=CN=C1)(C1CCCCC1)C1CCCCC1 ONHBDDJJTDTLIR-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title abstract 4
- 238000009472 formulation Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 claims abstract description 12
- 238000005660 chlorination reaction Methods 0.000 claims abstract description 11
- UNFUYWDGSFDHCW-UHFFFAOYSA-N monochlorocyclohexane Chemical compound ClC1CCCCC1 UNFUYWDGSFDHCW-UHFFFAOYSA-N 0.000 claims abstract description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 claims abstract description 6
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 6
- 239000000460 chlorine Substances 0.000 claims abstract description 6
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 claims abstract description 6
- 238000004519 manufacturing process Methods 0.000 claims description 12
- SNTWKPAKVQFCCF-UHFFFAOYSA-N 2,3-dihydro-1h-triazole Chemical compound N1NC=CN1 SNTWKPAKVQFCCF-UHFFFAOYSA-N 0.000 claims description 7
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 5
- -1 polyoxy Polymers 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 2
- NSPMIYGKQJPBQR-UHFFFAOYSA-N 4H-1,2,4-triazole Chemical compound C=1N=CNN=1 NSPMIYGKQJPBQR-UHFFFAOYSA-N 0.000 abstract description 5
- 229930182764 Polyoxin Natural products 0.000 abstract 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 239000003899 bactericide agent Substances 0.000 abstract 1
- YEBIHIICWDDQOL-YBHNRIQQSA-N polyoxin Polymers O[C@@H]1[C@H](O)[C@@H](C(C=O)N)O[C@H]1N1C(=O)NC(=O)C(C(O)=O)=C1 YEBIHIICWDDQOL-YBHNRIQQSA-N 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 241000207199 Citrus Species 0.000 description 4
- 235000020971 citrus fruits Nutrition 0.000 description 4
- 239000003905 agrochemical Substances 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 239000000642 acaricide Substances 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 241000488581 Panonychus citri Species 0.000 description 1
- 241000488583 Panonychus ulmi Species 0.000 description 1
- 208000031320 Teratogenesis Diseases 0.000 description 1
- 241001454294 Tetranychus Species 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000002703 mutagenesis Methods 0.000 description 1
- 231100000350 mutagenesis Toxicity 0.000 description 1
- 239000002420 orchard Substances 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a formula and preparation process of novel azocyclotin. Novel azocyclotin comprises the following raw components: 1600-1800kg/t of chlorocyclohexane, 230-250kg/t of 1,2,4-triazole, 50-100kg/t of polyoxin, 200-300kg/t of tin and 1600-1800kg/t of chlorine. The preparation process of novel azocyclotin is characterized in that tin tetrachloride and chlorocyclohexane react, and then the reactant and 1,2,4-triazole react to prepare azocyclotin after a chlorination process and an alkalization process. A broad-spectrum, efficient and multifunctional bactericide is prepared by adopting the formula and the preparation process.
Description
Technical field
The invention belongs to agricultural chemicals and manufacture field, be specifically related to a kind of formula and manufacturing process of novel azocyclotin.
Background technology
Azocyclotin is that upper conventional main miticide produced by citrus, and toxicity is medium, by force contact, if can kill mite, one-tenth mite and summer egg, without teratogenesis, carcinogenic and mutagenesis in test dose.Azocyclotin is applicable to multiple harmful mite on control fruit tree, vegetables.But azocyclotin improper use can cause citrus poisoning in various degree.In actual production, azocyclotin and different agents, in order to save manpower financial capacity, mix and execute, often make citrus produce poisoning by some orchard workers.
summary of the invention
The present invention proposes a kind of formula and manufacturing process of novel azocyclotin, and the present invention substantially increases sterilizing ability, respond well.Technical scheme is: the formula of novel azocyclotin and manufacturing process, its feed composition is: chlorocyclohexane 1600-1800kg/t, 1, the clear 50-100 kg/t of 2,4-triazole 230-250kg/t, polyoxy, tin 200-300kg/t, chlorine 1600-1800kg/t form, its manufacturing process is that tin tetrachloride and chlorination hexanaphthene react, through chlorination flow process, after alkalization flow process, then with 1, the obtained azocyclotin of 2,4-triazole reaction.
This agricultural chemicals i.e. tool outer protection and therapeutic action but also have interior suction sterilizing function.
Azocyclotin is a kind of contact acaricide, can with some other combined use of pesticides, with expanding prevention scope, the lasting period is long.The immature concentration of control European red mite, tetranychus vinenensis zacher is 167 ~ 250ml/L, and the effective concentration of control citrus red mite is 250ml/L, and safety interval is 15 days.After understanding azocyclotin use, the residual condition in citrus and environment thereof, evaluates its security, is reasonable employment agricultural chemicals, and guiding agricultural production, guarantees that agricultural product quality and safety and environmental safety provide foundation.
the present invention has following beneficial effect:
The present invention substantially increases sterilizing ability, and characteristic is also fine, and economic benefit and social benefit improve greatly.
Embodiment:
Embodiment 1:
Its feed composition of the present invention is: chlorocyclohexane 1600kg/t, 1,2, clear 50 kg/t of 4-triazole 230kg/t, polyoxy, tin 200kg/t, chlorine 1600kg/t form, and its manufacturing process is that tin tetrachloride and chlorination hexanaphthene react, through chlorination flow process, after alkalization flow process, obtained azocyclotin is reacted again with 1,2,4-triazole.
Embodiment 2:
Feed composition is: chlorocyclohexane 1800kg/t, 1,2, clear 100 kg/t of 4-triazole 250kg/t, polyoxy, tin 300kg/t, chlorine 1800kg/t form, and its manufacturing process is that tin tetrachloride and chlorination hexanaphthene react, through chlorination flow process, after alkalization flow process, obtained azocyclotin is reacted again with 1,2,4-triazole.
Embodiment 3:
Feed composition is: chlorocyclohexane 17000kg/t, 1,2, clear 150 kg/t of 4-triazole 240kg/t, polyoxy, tin 250kg/t, chlorine 1700kg/t form, and its manufacturing process is that tin tetrachloride and chlorination hexanaphthene react, through chlorination flow process, after alkalization flow process, obtained azocyclotin is reacted again with 1,2,4-triazole.
Claims (1)
1. the formula of novel azocyclotin and manufacturing process, it is characterized in that: its feed composition is: chlorocyclohexane 1600-1800kg/t, 1, the clear 50-100 kg/t of 2,4-triazole 230-250kg/t, polyoxy, tin 200-300kg/t, chlorine 1600-1800kg/t form, its manufacturing process is that tin tetrachloride and chlorination hexanaphthene react, through chlorination flow process, after alkalization flow process, then with 1, the obtained azocyclotin of 2,4-triazole reaction.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310384040.6A CN104418880A (en) | 2013-08-29 | 2013-08-29 | Formula and preparation process of novel azocyclotin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310384040.6A CN104418880A (en) | 2013-08-29 | 2013-08-29 | Formula and preparation process of novel azocyclotin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104418880A true CN104418880A (en) | 2015-03-18 |
Family
ID=52969071
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310384040.6A Pending CN104418880A (en) | 2013-08-29 | 2013-08-29 | Formula and preparation process of novel azocyclotin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104418880A (en) |
-
2013
- 2013-08-29 CN CN201310384040.6A patent/CN104418880A/en active Pending
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150318 |
|
| WD01 | Invention patent application deemed withdrawn after publication |