CN104404248B - The leaching method and its leaching agent of lead in a kind of recovery lead oxide ore - Google Patents
The leaching method and its leaching agent of lead in a kind of recovery lead oxide ore Download PDFInfo
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- CN104404248B CN104404248B CN201410592423.7A CN201410592423A CN104404248B CN 104404248 B CN104404248 B CN 104404248B CN 201410592423 A CN201410592423 A CN 201410592423A CN 104404248 B CN104404248 B CN 104404248B
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- lead
- leaching
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- lead oxide
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
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Abstract
The invention belongs to mineral metallurgical technology field, a kind of leaching method and its leaching agent for reclaiming lead in lead oxide ore is specifically disclosed.It is of the invention main using 5 sulfosalicylic acids as leaching agent, quadrat leaching is entered for 14%~75% lead oxide ore to lead grade, extraction temperature is 20 DEG C~60 DEG C, the percentage by weight that ore grain size is less than 65 μm is 70%~96%, the concentration of 5 sulfosalicylic acids is 0.1mol/L~0.5mol/L, by 5 sulfosalicylic acid leaching agents and lead oxide ore miberal powder according to 5~20:1 quality liquid-solid ratio mixing, is sufficiently stirred for 20min~60min;Obtain being adapted to the extraction of next step lead and electrodeposition processing containing lead solution.So as to which leaching agent leaching rate of the present invention is high, make simple, the 5 sulfosalisylic acid waste products also produced using pharmacy and chemical industry;The other leaching method does not need high temperature, pressurized equipment in the case where ensureing that lead leaching rate is high, and simple to operate, and process costs are low.
Description
Technical field
The invention belongs to mineral metallurgical technology field, and in particular in a kind of recovery lead oxide ore the leaching method of lead and its
Leaching agent.
Background technology
Lead is important non-ferrous metal, with the increasingly increase in world wide to lead metal demand, primary lead ore
It is faced with reserves deficient, the pressure for the multiaspect such as dressing and smelting process is seriously polluted.In nature, it can be used for reclaiming the industrial mineral of lead
Sulfide mineral and oxide mineral including lead.The main galena of galena thing (PbS), if lead oxide ore owner's cerussite
(PbCO3).Vulcanized lead mineral have preferable floatability, and concentrate can be readily available using flotation, due to high-grade vulcanized lead
Ore resources are increasingly reduced, and then lead oxide ore becomes the valuable source for reclaiming lead.For the sulfide mineral of lead, oxidation
Mineral dissolution degree is larger, and hydrometallurgy is a kind of approach for reclaiming lead from lead oxide ore well.
Chemically see in nature, lead minerals and metal are soluble in nitric acid (HNO3), boron fluoric acid (HBF4), silicofluoric acid
(H2SiF6), acetic acid (CH3COOH) etc.;Hydrochloric acid only works with the surface of lead and is formed and almost do not dissolved at normal temperatures with sulfuric acid
PbCl2And PbSO4Skin covering of the surface.Therefore, using industrially conventional " three acid " as solvent, all it is less suitable for being used for wet method refining
Lead, because the PbSO of generation4、PbCl2Solubility is smaller in aqueous;And make the Pb (NO of solvent formation with nitric acid3)2In water
Less stable in solution, easily generates volatile nitrogen oxide.Here it is wet method refines the where the shoe pinches of plumbing large-scale production,
It is also that the refining of lead bullion is had to using H costly2SiF6Make the reason of electrolyte.In addition, country advocates ecological environmental protection,
Green economy is encouraged, therefore, the requirement also more and more higher to reclaiming the leaching agent of lead in lead oxide ore.
The content of the invention
The deficiency existed for above-mentioned prior art, it is an object of the present invention to provide a kind of high new recovery oxygen of leaching efficiency
Change the leaching agent of lead in lead ore.
To achieve these goals, technical scheme is specific as follows:
A kind of leaching agent of lead in recovery lead oxide ore, the leaching agent is that 5-sulphosalicylic acid and water are uniformly mixed.
In an embodiment of the present invention, concentration of the leaching agent containing 5-sulphosalicylic acid is 0.1mol/L~0.5mol/
L。
For above-mentioned prior art exist limitation, it is an object of the present invention to provide a kind of leaching efficiency it is high, simple to operate and
The leaching method of lead in the low new recovery lead oxide ore of process costs.
To achieve these goals, another technical scheme of the invention is specific as follows:
A kind of above-mentioned leaching agent of use reclaims the leaching method of lead in lead oxide ore, and this method is specially:It is to lead grade
14%~75% lead oxide ore carries out muck, ore grinding, and the percentage by weight that ore grain size is less than 65 μm is 70%~96%;Will
5-sulphosalicylic acid solution and lead oxide ore miberal powder are according to 5~20:1 quality liquid-solid ratio mixing, and be sufficiently stirred for 20min~
60min, wherein extraction temperature are controlled in 20 DEG C~60 DEG C;Obtain being adapted to next step extraction, electrodeposition with containing lead solution.
The technical principle of technical solution of the present invention:The 5-sulphosalicylic acid includes 3 functional groups-OH ,-COOH ,-
SO3H, 5-sulfosalicylic acid can partly or entirely dehydrogenation, 5-sulfosalicylic acid mainly exists with five kinds of structure types, specifically such as
Shown in lower.
If 5-sulfosalicylic acid is ionized completely in aqueous, carried out by following reaction equation (3) and (4):
C7H6O6S(s)→C7H3O6S3– (aq)+3H+ (aq) (1)
Because the essential mineral in lead oxide ore is cerussite, following reaction side can occur in 5-sulfosalisylic acid solution
Formula (2):
3PbCO3(s)+2C7H6O6S(s)→3Pb2+ (aq)+2C7H3O6S3– (aq)+3H2O(aq)+3CO2(g) (2)
The ionization of 5-sulfosalicylic acid in aqueous produces hydrogen ion, promotes copper oxide mineral to dissolve, this is 5-sulfo group
The acidleach effect that salicylic acid has.
The beneficial effects of the invention are as follows:The present invention by using certain density 5-sulphosalicylic acid as leaching agent, it is right
From lead oxide ore metallurgical extraction obtain contain lead solution, in reaction vessel by control optimal extraction temperature, ore grain size,
Leaching agent and powdered ore quality solid-to-liquid ratio and agent concentration is leached, lead leaching rate in lead oxide ore can be made close to 97%;And should
Leaching method does not need high temperature, pressurized equipment, and simple to operate, and process costs are low, so as to provide suitable next step lead extraction
Take with electrodeposition processing containing lead solution.
Embodiment
Herein below is the detailed description carried out to the present invention.
Embodiment 1:
The embodiments of the invention provide a kind of leaching agent for reclaiming lead in lead oxide ore, the leaching agent is mainly 5- sulfo group water
Poplar acid and water are uniformly mixed, and 5-sulphosalicylic acid concentration is 0.2mol/L.Lead grade is entered for 40% lead oxide ore
Row is leached, and extraction temperature is 30 DEG C, and the percentage by weight that ore grain size is less than 65 μm is 80%, by 5-sulphosalicylic acid leaching agent
With lead oxide ore miberal powder according to 20:1 quality liquid-solid ratio mixing, is sufficiently stirred for 35min, the leaching rate of lead is about 91.1%.
Embodiment 2:
The embodiments of the invention provide a kind of leaching agent for reclaiming lead in lead oxide ore, the leaching agent is mainly 5- sulfo group water
Poplar acid and water are uniformly mixed, and 5-sulphosalicylic acid concentration is 0.4mol/L.Lead grade is entered for 47% lead oxide ore
Row is leached, and extraction temperature is 35 DEG C, and the percentage by weight that ore grain size is less than 65 μm is 85%, by 5-sulphosalicylic acid leaching agent
With lead oxide ore miberal powder according to 20:1 quality liquid-solid ratio mixing, is sufficiently stirred for 45min, the leaching rate of lead is about 94.8%.
Embodiment 3:
The embodiment of the present invention proposes a kind of leaching method for reclaiming lead in lead oxide ore.This method is specially:To lead product
The percentage by weight that granularity is less than 65 μm in lead oxide ore progress muck, ore grinding of the position for 35%, ore is 80%;By concentration
For 0.3mol/L 5-sulphosalicylic acid solution and lead oxide ore miberal powder according to 15:1 quality liquid-solid ratio mixing, and be sufficiently stirred for
40min, wherein extraction temperature are controlled at 25 DEG C;Obtain being adapted to next step extraction, electrodeposition with containing lead solution.The leaching rate of the lead
About 96.4%.
Embodiment 4:
The embodiment of the present invention proposes a kind of leaching method for reclaiming lead in lead oxide ore.This method is specially:To lead product
The percentage by weight that granularity is less than 65 μm in lead oxide ore progress muck, ore grinding of the position for 29%, ore is 90%;By concentration
For 0.5mol/L 5-sulphosalicylic acid solution and lead oxide ore miberal powder according to 15:1 quality liquid-solid ratio mixing, and be sufficiently stirred for
50min, wherein extraction temperature are controlled at 40 DEG C;Obtain being adapted to next step extraction, electrodeposition with containing lead solution.The leaching rate of the lead
About 97.0%.
Above content is only presently preferred embodiments of the present invention, for one of ordinary skill in the art, according to the present invention's
Thought, will change in specific embodiments and applications, and this specification content should not be construed as to the present invention
Limitation.
Claims (1)
1. a kind of leaching method for reclaiming lead in lead oxide ore, it is characterised in that this method is specially:To lead grade be 14%~
75% lead oxide ore carries out muck, ore grinding, and the percentage by weight that ore grain size is less than 65 μm is 70%~96%, and leaching agent is
5-sulphosalicylic acid and water are uniformly mixed, and the concentration of 5-sulphosalicylic acid is 0.1mol/L~0.5mol/L, by 5- sulfo groups
Salicylic acid solution and lead oxide ore miberal powder are according to 5~20:1 quality liquid-solid ratio mixing, and 20min~60min is sufficiently stirred for, its
Middle extraction temperature control is in 20 DEG C~60 DEG C;Obtain being adapted to next step extraction, electrodeposition with containing lead solution.
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CN101530826B (en) * | 2009-03-13 | 2012-05-16 | 昆明理工大学 | Method for combined treatment of high calcium and magnesium low-grade oxidized lead zinc ore by means of concentration |
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