CN104403292A - Resin composition capable of being subjected to direct water transfer printing and preparation method of resin composition - Google Patents
Resin composition capable of being subjected to direct water transfer printing and preparation method of resin composition Download PDFInfo
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- CN104403292A CN104403292A CN201410712201.4A CN201410712201A CN104403292A CN 104403292 A CN104403292 A CN 104403292A CN 201410712201 A CN201410712201 A CN 201410712201A CN 104403292 A CN104403292 A CN 104403292A
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- transfer printing
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92009—Measured parameter
- B29C2948/92209—Temperature
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Decoration By Transfer Pictures (AREA)
Abstract
The invention relates to a resin composition capable of being subjected to direct water transfer printing and a preparation method of the resin composition. The resin composition comprises the following components in parts by weight: 90-99 parts of thermoplastic resin, 1-10 parts of a bonder and 0.1-0.5 part of an antioxidant. The preparation method comprises the following steps: premixing the components in a high-speed mixer, adding a mixture into the feeding hole of a double-screw extruder with a degassing device, and melting and mixing at 200-280 DEG C to obtain a melt; applying low pressure of less than 100 mbar to a degassing region, retaining the melt in the degassing region for 10-30 seconds, and extruding and cooling to obtain the resin composition capable of being subjected to direct water transfer printing. Compared with the prior art, very few small molecules are separated out from the resin composition during high-temperature storage, a conventional printing process can be simplified to realize direct printing, and the resin composition is particularly suitable for direct water transfer printing.
Description
Technical field
The present invention relates to resin combination field, especially relate to a kind of can the resin combination and preparation method thereof of direct water transfer printing.
Background technology
Along with the development of economy, the requirement of human consumer to packing of product application, class is more and more higher.For printing industry, the concept of printing is not that stationery traditional in people's impression prints from daily living article to office accommodations already yet. even house fitting-up and automobile industry etc. all need more, better, more practical surfactant package.This packaging major part all will realize by transfer printing.Wherein water transfer printing is surface decoration mode popular in recent years, as water transfer technique is used for IP ornamental strip to show kinesthesia and the science and technology sense of automobile by Automobile Design teacher.
Because water transfer printing adopts special carrier that pattern is posted stock surface, and the main component of transfer printing layer (pattern) is ink, and general plastics material and ink layer bonding force poor, so usually first spray one deck priming paint to obtain smooth transfer surface at stock (thermoplastic resin), improve the bonding force of resin layer and transfer printing layer simultaneously, often surface quality is better for the water transfer product obtained by this method, and the high temperature that automobile industry is carried out usually deposit with high/low temperature round-robin test in can not there is cosmetic issue, but the weak point of this method is usually to need source mill to possess water transfer printing production line and spraying coating line simultaneously, and need two complete independent operations of program, if there is crossed contamination, serious surface imperfection can be caused, as pit, rete comes off.
The technology of current water transfer printing need to improve further and break through, and water transfer printing later all will towards convenient, practical three-dimensional direction development on all fronts.So-called convenient. simplify manufacturing process steps. so not only reduced costs but also saved time. user uses also more direct simple.Practical on material technology, carry out large breakthrough exactly, thus reach and be convenient to the requirement that user carries out operation.
Chinese patent CN102964762A discloses a kind of screen printing swabbing transfer printing high thixotropic ink adhesive resin combination, comprises the component of following masses number: propylene (being total to) polymer: 100 parts; Plasticizer: 0-40 part; Additive: 0-10 part; Thixotropic agent: 0-10 part; Solvent: 50-300 part.Wherein, propylene (being total to) polymer is based on thermoplastically acrylic acid alkyl fat, and its glass transition temperature Tg is-10 DEG C to 100 DEG C, clogging when can reduce printing, the residue produced when burning till, but in this, resin combination cannot improve sprawling of ink layer and causes surface bonding power poor.
Summary of the invention
Object of the present invention be exactly provide to overcome defect that above-mentioned prior art exists a kind of can the directly resin combination of water transfer printing and preparation method.The moulded products of resin combination of the present invention can be exempted spray base technique and for direct water transfer printing, deposit with performance in high/low temperature round-robin test good at high temperature simultaneously, has clear and definite application direction and market outlook in automobile industry.
Object of the present invention can be achieved through the following technical solutions:
Can the resin combination of direct water transfer printing, comprise each component of following weight part: thermoplastic resin 90 ~ 99, tackiness agent 1 ~ 10, oxidation inhibitor 0.1 ~ 0.5,
Described tackiness agent is the suspension copolymer (SAG) of styrene-acrylonitrile-glycidyl methacrylate, wherein the weight-average molecular weight of styrene-acrylonitrile copolymer is 5000-30000, the mechanical property of molecular weight < 5000 tackiness agents can sharply worsen, molecular weight > 30000 transfer printing layers and resin layers power poor, utilize the reactive functional groups in tackiness agent, specifically, the glycidyl methacrylate functional group in SAG) improve the bonding force of resin layer and transfer printing layer with the polarity similarity principle of ink layer, low-molecular-weight styrene-acrylonitrile (SAN) multipolymer contributes to reactive functional groups at surface enrichment simultaneously, thus improve moulded products surface tension, make ink layer (transfer printing layer) can better at surface spreading,
The low pressure applying to be not more than 100mbar in forcing machine degas zone prepares resin combination, thus reduces the small molecules in extruded product, in rear transfer process, obtain good surface quality.
Described thermoplastic resin is selected from one or more in polycarbonate, phenylethylene resin series, polyethylene terephthalate, polybutylene terephthalate, polymeric amide or polymethylmethacrylate.
Described phenylethylene resin series is ABS, ASA or AES resin.
In described tackiness agent, the content of glycidyl methacrylate is 1 ~ 8wt%.
As preferred embodiment, in tackiness agent, styrene-acrylonitrile copolymer weight-average molecular weight is 10000-20000, and the content of glycidyl methacrylate is 2 ~ 5wt%.
Described oxidation inhibitor is a kind of or several in the CIBA company that the refines Irganox 1010, the Irganox 1076 that produce or Irganox 168.
Can the preparation method of the direct resin combination of water transfer printing, adopt following steps:
Step one, thermoplastic resin, tackiness agent and oxidation inhibitor to be added respectively from the twin-screw extrusion charging opening of band de-gassing vessel by formula after high-speed mixer premix, and carry out melting mixing in 200 ~ 280 DEG C, obtain melt;
Step 2, apply to be not more than the low pressure of 100mbar to degas zone, melt is 10 ~ 30s in the residence time of degas zone, then prepare can the resin combination of direct water transfer printing through extruding, cooling.
Described twin screw extruder length-to-diameter ratio is 30 ~ 48.
The described low pressure applied degas zone is 10 ~ 100mbar, and degas zone temperature is 200 ~ 280 DEG C.
The mixed cell of the degas zone of described twin screw extruder is made up of the delivery element of large pitch, and this delivery element is profile of tooth screwing element.
Compared with prior art, preparation technology of the present invention is simple, implement convenient and do not sacrifice the cohesive force of transfer printing layer and resin layer, carry out the common high temperature of automobile industry deposit with high/low temperature round-robin test after performance well, there is clear and definite market application foreground and economic worth.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.Following examples will contribute to those skilled in the art and understand the present invention further, but not limit the present invention in any form.It should be pointed out that to those skilled in the art, without departing from the inventive concept of the premise, can also make certain adjustments and improvements.These all belong to protection scope of the present invention.
Embodiment 1
Can the directly resin combination of water transfer printing and a preparation method, comprise the following steps:
Get the raw materials ready according to following component and content:
| Thermoplastic resin 1 | PC/ABS | 90 |
| Tackiness agent 1 | SAG-001 | 10 |
| Oxidation inhibitor | 1076 | 0.1 |
PC/ABS: bright and beautiful lake day beautiful HAC8250,
Tackiness agent: the liter of Nantong day is produced, and SAG-001, GMA content is 1%, SAN molecular weight is 30000.
(2) in high-speed mixer, PC/ABS and other components add in the forcing machine of L/D=30 respectively, temperature is set as 260 DEG C, degas zone absolute pressure is 100mbar, the profile of tooth delivery element that degas zone is 56mm by length forms, melt is 10S in the degas zone residence time, and being obtained by melting, degassed, metering, cooling can the thermoplastic resin composition of direct water transfer printing.
Embodiment 2
Can the directly resin combination of water transfer printing and a preparation method, comprise the following steps:
(1) get the raw materials ready according to following component and content:
| Thermoplastic resin 2 | ABS | 99 |
| Tackiness agent 2 | SAG-005 | 1 |
| Oxidation inhibitor | 1076 | 0.1 |
ABS: Shanghai Jin Hu day beautiful ABSH2938
Tackiness agent: the liter of Nantong day is produced, and SAG-005, GMA content is 5%, SAN molecular weight is 20000
(2) in high-speed mixer, ABS and other components add in the forcing machine of L/D=40 respectively, temperature is set as 250 DEG C, degas zone absolute pressure is 100mbar, the profile of tooth delivery element that degas zone is 56mm by length forms, melt is 20S in the degas zone residence time, and being obtained by melting, degassed, metering, cooling can the thermoplastic resin composition of direct water transfer printing.
Embodiment 3
Can the directly resin combination of water transfer printing and a preparation method, comprise the following steps:
(1) get the raw materials ready according to following component and content:
| Thermoplastic resin 1 | PC/ABS | 99 |
| Tackiness agent 1 | SAG-008 | 1 |
| Oxidation inhibitor | 1076 | 0.1 |
PC/ABS: bright and beautiful lake day beautiful HAC8250
Tackiness agent: the liter of Nantong day is produced, and SAG-008, GMA content is 8%, SAN molecular weight is 10000
(2) in high-speed mixer, PC/ABS and other components add in the forcing machine of L/D=40 respectively, temperature is set as 260 DEG C, degas zone absolute pressure is 100mbar, the profile of tooth delivery element that degas zone is 56mm by length forms, melt is 30S in the degas zone residence time, and being obtained by melting, degassed, metering, cooling can the thermoplastic resin composition of direct water transfer printing.
Embodiment 4
Can the directly resin combination of water transfer printing and a preparation method, comprise the following steps:
(1) get the raw materials ready according to following component and content:
| Thermoplastic resin 3 | ABS/PMMA | 95 |
| Tackiness agent 1 | SAG-002 | 5 |
| Oxidation inhibitor | 1076 | 0.1 |
ABS/PMMA: Shanghai Jin Hu day beautiful HAM8541
Tackiness agent: the liter of Nantong day is produced, and SAG-002, GMA content is 2%, SAN molecular weight is 25000
(2) in high-speed mixer, ABS/PMMA and other components add in the forcing machine of L/D=40 respectively, temperature is set as 230 DEG C, degas zone absolute pressure is 100mbar, the profile of tooth delivery element that degas zone is 56mm by length forms, melt is 20S in the degas zone residence time, and being obtained by melting, degassed, metering, cooling can the thermoplastic resin composition of direct water transfer printing.
Embodiment 5
Can the directly resin combination of water transfer printing and a preparation method, comprise the following steps:
(1) get the raw materials ready according to following component and content:
| Thermoplastic resin 3 | ABS/PMMA | 95 |
| Tackiness agent 1 | SAG-002 | 5 |
| Oxidation inhibitor | 1076 | 0.1 |
ABS/PMMA: Shanghai Jin Hu day beautiful HAM8541
Tackiness agent: the liter of Nantong day is produced, and SAG-002, GMA content is 2%, SAN molecular weight is 25000
(2) in high-speed mixer, ABS/PMMA and other components add in the forcing machine of L/D=40 respectively, temperature is set as 230 DEG C, degas zone absolute pressure is 10mbar, the profile of tooth delivery element that degas zone is 56mm by length forms, melt is 20S in the degas zone residence time, and being obtained by melting, degassed, metering, cooling can the thermoplastic resin composition of direct water transfer printing.
Comparative example 1
Can the directly resin combination of water transfer printing and a preparation method, comprise the following steps:
(1) get the raw materials ready according to following component and content:
| Thermoplastic resin 3 | ABS/PMMA | 95 |
| Tackiness agent 4 | SAG-002L | 5 |
| Oxidation inhibitor | 1076 | 0.1 |
ABS/PMMA: Shanghai Jin Hu day beautiful HAM8541
Tackiness agent: the liter of Nantong day is produced, and SAG-002L, GMA content is 2%, SAN molecular weight is 80000
(2) in high-speed mixer, ABS/PMMA and other components add in the forcing machine of L/D=40 respectively, temperature is set as 230 DEG C, degas zone absolute pressure is 10mbar, the profile of tooth delivery element that degas zone is 56mm by length forms, melt is 20S in the degas zone residence time, and being obtained by melting, degassed, metering, cooling can the thermoplastic resin composition of direct water transfer printing.
Comparative example 2
Can the directly resin combination of water transfer printing and a preparation method, comprise the following steps:
(1) get the raw materials ready according to following component and content:
| Thermoplastic resin 3 | ABS/PMMA | 95 |
| Tackiness agent 3 | SAG-002 | 5 |
| Oxidation inhibitor | 1076 | 0.1 |
ABS/PMMA: Shanghai Jin Hu day beautiful HAM8541
Tackiness agent: the liter of Nantong day is produced, and SAG-002, GMA content is 2%, SAN molecular weight is 25000
(2) in high-speed mixer, ABS/PMMA and other components add in the forcing machine of L/D=48 respectively, temperature is set as 230 DEG C, degas zone absolute pressure is 300mbar, the profile of tooth delivery element that degas zone is 56mm by length forms, melt is 30S in the degas zone residence time, and being obtained by melting, degassed, metering, cooling can the thermoplastic resin composition of direct water transfer printing.
Comparative example 3
Can the directly resin combination of water transfer printing and a preparation method, comprise the following steps:
(1) get the raw materials ready according to following component and content:
| Thermoplastic resin 1 | PC/ABS | 98 |
| Tackiness agent 5 | SAG-005L | 2 |
| Oxidation inhibitor | 1076 | 0.1 |
PC/ABS: Shanghai Jin Hu day beautiful HAC8250
Tackiness agent: the liter of Nantong day is produced, and SAG-005L, GMA content is 5%, SAN molecular weight is 20000
(2) in high-speed mixer, PC/ABS and other components add in the forcing machine of L/D=48 respectively, temperature is set as 230 DEG C, degas zone absolute pressure is 300mbar, the profile of tooth delivery element that degas zone is 44mm by length forms, melt is 40S in the degas zone residence time, and being obtained by melting, degassed, metering, cooling can the thermoplastic resin composition of direct water transfer printing.
Comparative example 4
Can the directly resin combination of water transfer printing and a preparation method, comprise the following steps:
(1) get the raw materials ready according to following component and content:
| Thermoplastic resin 1 | PC/ABS | 85 |
| Tackiness agent 1 | SAG-001 | 15 |
| Oxidation inhibitor | 1076 | 0.1 |
PC/ABS: Shanghai Jin Hu day beautiful HAC8250
Tackiness agent: the liter of Nantong day is produced, and SAG-001, GMA content is 1%, SAN molecular weight is 30000
(2) in high-speed mixer, PC/ABS and other components add in the forcing machine of L/D=40 respectively, temperature is set as 230 DEG C, degas zone absolute pressure is 200mbar, the profile of tooth delivery element that degas zone is 56mm by length forms, melt is 20S in the degas zone residence time, and being obtained by melting, degassed, metering, cooling can the thermoplastic resin composition of direct water transfer printing.
Performance test
Performance test is carried out to the resin that embodiment 1 ~ 5 and comparative example 1 ~ 4 obtain, specific as follows:
High temperature shelf test: by resin model by the shaping 140*90*3mm of injection moulding machine of 80T after 90 DEG C of dry 4h, then directly carry out water transfer printing, does hundred lattice tests, statistics qualification rate after carrying out the hot shelf test of 90 DEG C/500h by each for model that water transfer printing is good 10 pieces
Notched Izod impact strength evaluation method: by resin shaping 3.2mm batten of injection moulding machine by 80T after 90 DEG C of dry 4h, test notched Izod impact strength by ASTM D256.
The corresponding performance test evaluation of embodiment 1 ~ 5 and comparative example 1 ~ 4 the results are shown in Table 1:
Table 1
| High temperature shelf test qualification rate | Notched Izod impact strength (J/m) | |
| Embodiment 1 | 85％ | 420 |
| Embodiment 2 | 92％ | 195 |
| Embodiment 3 | 85％ | 650 |
| Embodiment 4 | 95％ | 110 |
| Embodiment 5 | 90％ | 105 |
| Comparative example 1 | 65％ | 132 |
| Comparative example 2 | 58％ | 112 |
| Comparative example 3 | 42％ | 645 |
| Comparative example 4 | 78％ | 270 |
As shown in Table 1, the present invention passes through the absolute pressure applying to be no more than 100mbar in degas zone in the twin screw extruder of band de-gassing vessel, and coordinate binding agent, resin combination of the present invention is made to have higher high temperature shelf test qualification rate, resin combination is deposited in process at high temperature only has few small molecules to separate out, this is because, adopt the suspension copolymer (SAG) of styrene-acrylonitrile-glycidyl methacrylate as tackiness agent, weight-average molecular weight is 5000-30000, the mechanical property of molecular weight < 5000 tackiness agents can sharply worsen, molecular weight > 30000 transfer printing layers and resin layers power poor, utilize the reactive functional groups in tackiness agent, specifically, it is the bonding force that the polarity similarity principle of glycidyl methacrylate functional group in SAG and ink layer improves resin layer and transfer printing layer, low-molecular-weight styrene-acrylonitrile (SAN) multipolymer contributes to reactive functional groups at surface enrichment simultaneously, thus improve moulded products surface tension, make ink layer (transfer printing layer) can better at surface spreading.In addition, the low pressure applying to be not more than 100mbar in forcing machine degas zone prepares resin combination, thus the small molecules in minimizing extruded product, good surface quality is obtained in rear transfer process, can Conventional printing process be simplified and realize direct printing, being specially adapted to direct water transfer printing, and not sacrificing the bonding force of transfer printing layer and resin layer, direct water transfer surface decoration can be realized, there is obvious market outlook and using value.
Claims (10)
1. can the resin combination of direct water transfer printing, it is characterized in that, comprise each component of following weight part: thermoplastic resin 90 ~ 99, tackiness agent 1 ~ 10, oxidation inhibitor 0.1 ~ 0.5,
Described tackiness agent is the suspension copolymer (SAG) of styrene-acrylonitrile-glycidyl methacrylate, and wherein the weight-average molecular weight of styrene-acrylonitrile copolymer is 5000-30000;
The low pressure applying to be not more than 100mbar in forcing machine degas zone prepares resin combination.
2. according to claim 1 a kind of can the resin combination of direct water transfer printing, it is characterized in that, described thermoplastic resin is selected from one or more in polycarbonate, phenylethylene resin series, polyethylene terephthalate, polybutylene terephthalate, polymeric amide or polymethylmethacrylate.
3. according to claim 2 a kind of can the resin combination of direct water transfer printing, it is characterized in that, described phenylethylene resin series is ABS, ASA or AES resin.
4. according to claim 1 a kind of can the resin combination of direct water transfer printing, it is characterized in that, in described tackiness agent, the content of glycidyl methacrylate is 1 ~ 8wt%.
5. according to claim 1 a kind of can the resin combination of direct water transfer printing, it is characterized in that, the preferred 10000-20000 of styrene-acrylonitrile copolymer weight-average molecular weight in described tackiness agent, the content preferably 2 ~ 5wt% of glycidyl methacrylate.
6. according to claim 1 a kind of can the resin combination of direct water transfer printing, it is characterized in that, described oxidation inhibitor is a kind of or several in the CIBA company that the refines Irganox 1010, the Irganox 1076 or Irganox168 that produce.
7. as claimed in claim 1 can the preparation method of the direct resin combination of water transfer printing, it is characterized in that, the method adopts following steps:
Step one, thermoplastic resin, tackiness agent and oxidation inhibitor to be added respectively from the twin-screw extrusion charging opening of band de-gassing vessel by formula after high-speed mixer premix, and carry out melting mixing in 200 ~ 280 DEG C, obtain melt;
Step 2, apply to be not more than the low pressure of 100mbar to degas zone, melt is 10 ~ 30s in the residence time of degas zone, then prepare can the resin combination of direct water transfer printing through extruding, cooling.
8. according to claim 7 can the preparation method of the direct resin combination of water transfer printing, it is characterized in that, described twin screw extruder length-to-diameter ratio is 30 ~ 48.
9. according to claim 7 can the preparation method of the direct resin combination of water transfer printing, it is characterized in that, the described low pressure applied degas zone is 10 ~ 100mbar, and degas zone temperature is 200 ~ 280 DEG C.
10. according to claim 7 can the preparation method of the direct resin combination of water transfer printing, it is characterized in that, the mixed cell of the degas zone of described twin screw extruder is made up of the delivery element of large pitch, and this delivery element is profile of tooth screwing element.
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| CN201410712201.4A CN104403292B (en) | 2014-11-28 | 2014-11-28 | A kind of can the resin combination and preparation method thereof of direct water transfer |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110804295A (en) * | 2019-10-15 | 2020-02-18 | 金发科技股份有限公司 | Polycarbonate composition and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101007894A (en) * | 2006-01-23 | 2007-08-01 | 上海锦湖日丽塑料有限公司 | PBT and ABS flame-proof material |
| CN102464859A (en) * | 2010-11-09 | 2012-05-23 | 东丽纤维研究所（中国）有限公司 | Heat-resistant thermoplastic resin composition |
| CN102516734A (en) * | 2011-12-09 | 2012-06-27 | 上海锦湖日丽塑料有限公司 | PC/ABS halogen-free flame-retardant alloy with high surface impact strength and preparation method thereof |
-
2014
- 2014-11-28 CN CN201410712201.4A patent/CN104403292B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101007894A (en) * | 2006-01-23 | 2007-08-01 | 上海锦湖日丽塑料有限公司 | PBT and ABS flame-proof material |
| CN102464859A (en) * | 2010-11-09 | 2012-05-23 | 东丽纤维研究所（中国）有限公司 | Heat-resistant thermoplastic resin composition |
| CN102516734A (en) * | 2011-12-09 | 2012-06-27 | 上海锦湖日丽塑料有限公司 | PC/ABS halogen-free flame-retardant alloy with high surface impact strength and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110804295A (en) * | 2019-10-15 | 2020-02-18 | 金发科技股份有限公司 | Polycarbonate composition and preparation method and application thereof |
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