CN104403044A - 一种罩光型水溶性丙烯酸树脂及其制备方法 - Google Patents
一种罩光型水溶性丙烯酸树脂及其制备方法 Download PDFInfo
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- CN104403044A CN104403044A CN201410637151.8A CN201410637151A CN104403044A CN 104403044 A CN104403044 A CN 104403044A CN 201410637151 A CN201410637151 A CN 201410637151A CN 104403044 A CN104403044 A CN 104403044A
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- Prior art keywords
- acrylic resin
- methacrylate
- soluble acrylic
- water soluble
- ethanol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004925 Acrylic resin Substances 0.000 title claims abstract description 43
- 229920000178 Acrylic resin Polymers 0.000 title claims abstract description 43
- 238000002360 preparation method Methods 0.000 title abstract description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 54
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 53
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims abstract description 34
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 22
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 claims abstract description 17
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 claims abstract description 16
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims abstract description 16
- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 claims abstract description 16
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 15
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 15
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 15
- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical compound COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 claims abstract description 15
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 claims abstract description 12
- IAXXETNIOYFMLW-COPLHBTASA-N [(1s,3s,4s)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical compound C1C[C@]2(C)[C@@H](OC(=O)C(=C)C)C[C@H]1C2(C)C IAXXETNIOYFMLW-COPLHBTASA-N 0.000 claims abstract description 12
- 229940119545 isobornyl methacrylate Drugs 0.000 claims abstract description 12
- 239000000178 monomer Substances 0.000 claims abstract description 12
- 239000004922 lacquer Substances 0.000 claims description 28
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 claims description 16
- GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 claims description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- 238000010992 reflux Methods 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- -1 n-dodecyl Chemical group 0.000 claims description 9
- 238000010926 purge Methods 0.000 claims description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical compound C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 claims description 5
- DTGKSKDOIYIVQL-MRTMQBJTSA-N Isoborneol Natural products C1C[C@@]2(C)[C@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-MRTMQBJTSA-N 0.000 claims description 5
- UEEJHVSXFDXPFK-UHFFFAOYSA-O N-dimethylethanolamine Chemical compound C[NH+](C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-O 0.000 claims description 5
- 238000009835 boiling Methods 0.000 claims description 5
- CKDOCTFBFTVPSN-UHFFFAOYSA-N borneol Natural products C1CC2(C)C(C)CC1C2(C)C CKDOCTFBFTVPSN-UHFFFAOYSA-N 0.000 claims description 5
- DTGKSKDOIYIVQL-UHFFFAOYSA-N dl-isoborneol Natural products C1CC2(C)C(O)CC1C2(C)C DTGKSKDOIYIVQL-UHFFFAOYSA-N 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 238000010792 warming Methods 0.000 claims description 5
- 239000011347 resin Substances 0.000 abstract description 14
- 229920005989 resin Polymers 0.000 abstract description 14
- 239000003973 paint Substances 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 6
- 239000002253 acid Substances 0.000 abstract description 4
- 150000003839 salts Chemical class 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 abstract 1
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000002966 varnish Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 description 14
- 239000007787 solid Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229960002887 deanol Drugs 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000012972 dimethylethanolamine Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201410637151.8A CN104403044B (zh) | 2014-11-12 | 2014-11-12 | 一种罩光型水溶性丙烯酸树脂及其制备方法 |
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CN201410637151.8A CN104403044B (zh) | 2014-11-12 | 2014-11-12 | 一种罩光型水溶性丙烯酸树脂及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN104403044A true CN104403044A (zh) | 2015-03-11 |
CN104403044B CN104403044B (zh) | 2016-09-28 |
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CN201410637151.8A Active CN104403044B (zh) | 2014-11-12 | 2014-11-12 | 一种罩光型水溶性丙烯酸树脂及其制备方法 |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105038476A (zh) * | 2015-08-26 | 2015-11-11 | 安徽优科新材料科技有限公司 | 一种汽车用高固体份罩光型油性丙烯酸树脂及其制备方法 |
CN105175602A (zh) * | 2015-09-10 | 2015-12-23 | 广州慧谷化学有限公司 | 无气味亲水涂层用有机亲水树脂及其涂料组合物与应用 |
CN106349422A (zh) * | 2016-08-31 | 2017-01-25 | 江苏李文甲化工有限公司 | 一种水溶性丙烯酸酯树脂及其合成方法 |
CN107216761A (zh) * | 2017-07-17 | 2017-09-29 | 江苏三木化工股份有限公司 | 高固体分的水溶性丙烯酸树脂的制备方法 |
CN107573739A (zh) * | 2017-10-10 | 2018-01-12 | 临汾铁环漆业有限公司 | 一种三聚氰胺板用的丙烯酸树脂及其制备方法 |
CN107573738A (zh) * | 2017-10-10 | 2018-01-12 | 临汾铁环漆业有限公司 | 一种水性玻璃用丙烯酸树脂及其制备方法 |
CN109293817A (zh) * | 2018-09-27 | 2019-02-01 | 韶关市合众化工有限公司 | 一种水性丙烯酸树脂的制备 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101177468A (zh) * | 2007-12-05 | 2008-05-14 | 东莞市英科水墨有限公司 | 水溶性丙烯酸树脂及其制备方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102504086A (zh) * | 2011-10-27 | 2012-06-20 | 中国海洋石油总公司 | 一种改进的制备涂料用溶剂型丙烯酸树脂的方法 |
-
2014
- 2014-11-12 CN CN201410637151.8A patent/CN104403044B/zh active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101177468A (zh) * | 2007-12-05 | 2008-05-14 | 东莞市英科水墨有限公司 | 水溶性丙烯酸树脂及其制备方法 |
Non-Patent Citations (1)
Title |
---|
陈治良: "《现代涂装手册》", 31 January 2010, article "丙烯酸阳极电泳涂料", pages: 359 * |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105038476A (zh) * | 2015-08-26 | 2015-11-11 | 安徽优科新材料科技有限公司 | 一种汽车用高固体份罩光型油性丙烯酸树脂及其制备方法 |
CN105175602A (zh) * | 2015-09-10 | 2015-12-23 | 广州慧谷化学有限公司 | 无气味亲水涂层用有机亲水树脂及其涂料组合物与应用 |
CN106349422A (zh) * | 2016-08-31 | 2017-01-25 | 江苏李文甲化工有限公司 | 一种水溶性丙烯酸酯树脂及其合成方法 |
CN107216761A (zh) * | 2017-07-17 | 2017-09-29 | 江苏三木化工股份有限公司 | 高固体分的水溶性丙烯酸树脂的制备方法 |
CN107573739A (zh) * | 2017-10-10 | 2018-01-12 | 临汾铁环漆业有限公司 | 一种三聚氰胺板用的丙烯酸树脂及其制备方法 |
CN107573738A (zh) * | 2017-10-10 | 2018-01-12 | 临汾铁环漆业有限公司 | 一种水性玻璃用丙烯酸树脂及其制备方法 |
CN109293817A (zh) * | 2018-09-27 | 2019-02-01 | 韶关市合众化工有限公司 | 一种水性丙烯酸树脂的制备 |
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CN104403044B (zh) | 2016-09-28 |
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Address after: 1055 No. 243000 Anhui city of Ma'anshan province high tech Zone Chihu Prince Avenue Applicant after: ANHUI UCTEC NEW MATERIAL SCIENCE & TECHNOLOGY Co.,Ltd. Address before: 1055 No. 243000 Anhui city of Ma'anshan province high tech Zone Chihu Prince Avenue Applicant before: Maanshan Youke Chemical Co.,Ltd. |
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Denomination of invention: Finishing water-soluble acrylic resin and preparation method thereof Effective date of registration: 20181204 Granted publication date: 20160928 Pledgee: Huizhou Merchants Bank Limited by Share Ltd. Ma'anshan Jia Shan Road sub branch Pledgor: ANHUI UCTEC NEW MATERIAL SCIENCE & TECHNOLOGY Co.,Ltd. Registration number: 2018340000695 |
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Date of cancellation: 20191223 Granted publication date: 20160928 Pledgee: Huizhou Merchants Bank Limited by Share Ltd. Ma'anshan Jia Shan Road sub branch Pledgor: ANHUI UCTEC NEW MATERIAL SCIENCE & TECHNOLOGY Co.,Ltd. Registration number: 2018340000695 |
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Denomination of invention: A kind of glossy water soluble acrylic resin and its preparation method Effective date of registration: 20201229 Granted publication date: 20160928 Pledgee: Huishang Bank Co.,Ltd. Ma'anshan Yuxi Road sub branch Pledgor: ANHUI UCTEC NEW MATERIAL SCIENCE & TECHNOLOGY Co.,Ltd. Registration number: Y2020980010185 |
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Date of cancellation: 20220107 Granted publication date: 20160928 Pledgee: Huishang Bank Co.,Ltd. Ma'anshan Yuxi Road sub branch Pledgor: ANHUI UCTEC NEW MATERIAL SCIENCE & TECHNOLOGY Co.,Ltd. Registration number: Y2020980010185 |
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Denomination of invention: A light masking water-soluble acrylic resin and its preparation method Effective date of registration: 20231211 Granted publication date: 20160928 Pledgee: Ma'anshan branch of Bank of China Ltd. Pledgor: ANHUI UCTEC NEW MATERIAL SCIENCE & TECHNOLOGY Co.,Ltd. Registration number: Y2023980070676 |
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