CN1043965A - The production method of dimensional stability polyester yarn - Google Patents

The production method of dimensional stability polyester yarn Download PDF

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Publication number
CN1043965A
CN1043965A CN89108756A CN89108756A CN1043965A CN 1043965 A CN1043965 A CN 1043965A CN 89108756 A CN89108756 A CN 89108756A CN 89108756 A CN89108756 A CN 89108756A CN 1043965 A CN1043965 A CN 1043965A
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yarn
multifilament
stretch
filament
polyethylene terephthalate
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CN1021919C (en
Inventor
马克斯韦尔·查尔斯·哈姆林
托马斯·霍华德·勒克
查尔斯·杰伊·纳尔逊
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Hearney weir International Co.,Ltd.
Performance fiber Limited by Share Ltd.
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AlliedSignal Inc
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    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/08—Melt spinning methods

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Artificial Filaments (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)

Abstract

The present invention relates to the manufacture method of a kind of dimensional stability drawn polyethylene terephthalate multifilament yarn (having the every filament filament at least 2.5 dawn).This method comprises that making polymer melt body is pressed through spinnerets; Make multifilament at first pass through delay zone,, thereby be cured then by quench zone through extruding; The yarn that makes solid is from the quench zone unwinding; Partially oriented multifilament is carried out hot-stretch.Method of the present invention can be produced the high yarn of birefringence that does not stretch with spinning speed and the lower IV ＇ S that is lower than prior art.

Description

The production method of dimensional stability polyester yarn
The present invention relates to the production method of polyester multifilament stretch yarn, wherein every filamentary fiber number is 2.5 dawn or bigger, makes the yarn of high birefringence (△ n) whereby under spinning speed lower than existing technology and lower inherent viscosity.
High-intensity polyethylene terephthalate is known in the art, and is used in the commercial Application that comprises tire cord (being used for the enhancing of rubber), conveyer belt, chair band, V-type band and flexible pipe usually.
People wish that dimensional stability polyester (DSP) industrial yarn can make the tyre sidewall indenture (SWI) on the meridian tyre body reach minimum, and obtain good tire treatment characteristic.Another target is to make the advanced dimensional stability polyester cord that when the tire working temperature that raises its intensity and modulus all are equivalent to artificial fibre, and the material that uses then reduces 30%.Although existing polyester cord has enough intensity, their high-temperature modulus is too low.People's such as Davis United States Patent (USP) 4,101,525 provides a kind of high-tenacity multifilament yarn polyester yarn, and it has the characteristic of low shrinkage and low power consume.Though, show that the yarn by the pointed feature of Davis is classified as DSP ' S, they also do not meet the modulus requirement that replaces artificial fibre.In addition, every filamentary low-titer (filament denier dpf or be 2 or for littler) and filament after spinning head occurs, cool off fast immediately, the speed that can cause singly spinning dimension is shunk, thereby has produced the relatively poor yarn of mechanical strength.People's such as Saito United States Patent (USP) 4,491,657 has disclosed high-modulus, has hanged down the polyester yarn of shrinkage, but still needs a kind of low whole modulus to obtain good yarn for the treated cord fabric thread conversion efficiency of this dimensional stability yarn.Low whole modulus is transferred to treated cord fabric thread, thereby has caused than the lower toughness of the whole modulus cord fabric thread of height of the present invention.People's such as Saito method needs high spinning speed, thereby just be difficult to this Saito method is combined in the technology of continuous spinning stretching, the present invention then allows to use lower spinning speed, so just can use easier obtain and/or low cost equipment.
People's such as Kumakowa United States Patent (USP) 4,690,560 has also been described a kind of method of making this class yarn, can provide the treated cord fabric thread (using the hyperviscosity polymer) of high dimensional stability.On the basis of comparative experiments, that is, use our solvent system, Kumakowa inherent viscosity (IV) value is then indicated high by 5% in its patent than them, and in other words, they need minimum of a value is the polymer (according to our mensuration) of 0.95IV.Equally, these cords fabric thread also have low whole modulus, thereby can not get the sufficient toughness advantage of given polymer viscosity.
By the above prior art of quoting from, we can see that by increasing the IV of spinning speed or yarn, people can improve the birefringence that does not stretch.
An important need is to obtain a kind of like this technology, promptly produces the high yarn of birefringence (△ nu) that does not stretch with the speed that spins and the lower inherent viscosity (IV) lower than the past.Be important than operation under the low velocity, this is because industrial equipment has restriction, the especially winder of speed.Use the ability of low IV to be meant to remove the additive of expensive operating procedure (for example solid-state polymerization) or expensive/contaminated environment.
The production method of a dimensional stability stretching polyethylene terephthalate multifilament yarn (having the every filament filament at least 2.5 dawn) may further comprise the steps:
A) make polyethylene terephthalate polymer melt body and be pressed through spinnerets to form filament with a plurality of spinneret orifices;
B) multifilament that makes ejection then by quench zone, thereby solidifies this filament by controlled way at first by delay zone;
C) multifilament that makes curing from quench zone with required spinning speed V unwinding;
Thereby step a)-c) is partially oriented have the birefringence of not stretching and be at least 0.020 multifilament (△ nu=R wherein forming fV 2.0IV 2.4, IV is the inherent viscosity of stretch yarn not, and is at least 0.80, R fBe at least 9.0 * 10 -3) condition under carry out;
D) to the hot-stretch in addition of partially oriented multifilament.This technology can produce the high yarn of birefringence that does not stretch under speed that is lower than prior art and IV.
The dimensional stability polyester mutifilament yarn that makes according to the inventive method and be used as fibre reinforced materials and can provide the cord fabric thread of processing of dimensional stability when being incorporated in the rubber composite as tire.
Dimensional stability is defined in the high-modulus under the given shrinkage, and directly relevant with tire running with tire tyre sidewall indenture (SWI).Although the modulus of cord fabric thread is a main variables in the tire, it is arranging SWI and travelling, and shrinkage all is important aspect two.At first, excessive cord fabric thread shrinkage can reduce the modulus of having handled the cord fabric thread modulus from initial significantly in tire vulcanization process.The second, the cord fabric thread shrinkage is the heteropical potential root of tire.So, modulus under given shrinkage and toughness relatively be an important comparison of tire cord.Because tire cord can experience the distortion of a few percent in the course of the work, so the good practical determination method of modulus be should be LASE-5(5% elongation load down).Perhaps, E 4.5(4.5g/d load down elongation) or be used as practical compliance determination method.
Concerning the SWI and travelling of tire, the modulus when elevated temperature (up to 110 ℃) is the important parameter of control performance.Because handled the high crystalline properties of cord fabric thread based on traditional or dimensional stability cord yarn, the modulus when the rising tyre temperature keeps (percentagewising) to be similar in essence to all existing commercially available treated cords fabric thread with this series products of the present invention (when the loss modulus peak value appears at 110 ℃ or higher).So the room temperature measuring of LASE-5 is enough to setting up significant difference aspect the dimensional stability of polyester cord.
This polyester yarn contains the polyethylene terephthalate of 90mol% (PET) at least.In preferred embodiments, this polyester is essentially polyethylene terephthalate.Or, this polyester can contain a spot of derived from one or more components (except pure and mild terephthalic acids of 1,2 ethylene and its derivative) that form esters as polymer unit.Can comprise ethylene glycol with other illustrative example that forms the component of ester of polyethylene terephthalate unit copolymerization, for example diethylene glycol (DEG), trimethylene glycol, 1,4-butanediol, 1,6-hexylene glycol etc., dicarboxylic acids, for example isophthalic acid, hexahydroterephthalic acid, diphenic acid, adipic acid, decanedioic acid, azelaic acid.
The mode of operation that polymer can separate is carried out polymerization or is carried out polymerization with continuous polymerization and direct melting spin processes that direct idol connects.
An importance of the present invention is the high yarn of birefringence that can obtain not stretch, and does not need to use the additive that increases molecular weight, as multifunctional couplant, for example 2,2 '-two (2-oxazolines).The catalyst that is used for this polymerisation is not considered to be included in the definition of the additive that increases molecular weight.
Multifilament textile of the present invention have usually every filamentary dawn number for about 2.5-20(for example, about 3-10), constituted by about 6-600 root continuous filament yarn (for example 20-400 root continuous filament yarn) usually.Radical and every filamentary dawn number of being present in the continuous filament yarn in the yarn can have very big change within the scope of the invention, and this point is obviously to those skilled in the art.
The multifilament textile that makes with this method is particularly suitable for use in the commercial Application that comprises rubber composite, rope, furniture and canvas.This fiber is particularly suitable for use in the environment that runs into elevated temperature (for example 80-110 ℃).
Here the characterisitic parameter of the yarn of indication can be determined easily by test multifilament textile (being made of parallel filament basically).
The not birefringence of La Shening (△ nu) can be determined by the petrographic microscope that use is furnished with the Berek compensator.
The inherent viscosity of polymer and yarn (IV) is that a kind of of the degree of polymerization and molecular weight measures easily.Determine IV by the relative solution viscosity (η r) of measuring PET sample in phenol and tetrachloroethanes (60/40 weight) admixture solvent.This relative solution viscosity (η r) is the flowing time of PET/ solvent solution and the ratio that neat solvent passes through the flowing time of standard capillary.The Billmeyer approximation method (J.Polym, Sci.4 83-86(1949) are used to calculate IV, the following formula that follows:
IV＝1/4 (（ηr-1）)/(C) +3/4 (ln ηr)/(C)
C is the concentration of representing with gm/100ml in the formula.In this research, concentration is 1.3/gms/100ml.Certainly, how many decilitre (dl/g) this units IV has represent with every gram, although this unit is not shown.
Compare with IV determination method in other solvent, in the paper of C.J.Nelson and N.L.Hergenrother, done to introduce (J.Poly, Sci, 12 2905(1974).This invention makes and might obtain the high-modulus stretch yarn, and does not need to use especially high IV polymer.Have high its IV of △ nu(and be at least 0.8, for example 0.85-0.95) gratifying stretch yarn can invent by this and obtain.
Here the tension character of indication is by adopting Ying Site youth's electronics strength tester (model: TM) use the strain rate (according to ASTM D885) of 10 inches measuring lengths and per minute 120% to reach in damping on 2 hours the yarn and carry out.All stretch to measure and all at room temperature carry out.
At 4.5g/d(E 4.5) specified loads under elongation and modulus be inversely proportional to.This is useful especially, because E 4.5+ FS summation is the good indicator to the dimensional stability of the yarn of processing under the loose level of difference.Lower (E 4.5+ FS) summation is indicated dimensional stability preferably.Stretch yarn of the present invention is to produce greater than 0.020 yarn with △ nu, and has by E 4.5The defined dimensional stability of+FS＜16%.Free shrink (FS) value determines that according to ASTM D855 different is that test load is 0.009g/d.This dimensional stability of having improved is even more important, and is to be used for the words of radial as fibre reinforced materials as fruit product.
Here a kind of description that given is to continuous spinning-drawing process, this technology shown can form required improvement yarn.Fig. 1 and Fig. 2 show the device that can be used to put into practice technology of the present invention, although the skilled person in this area will appreciate that cited device can change by known method.
See figures.1.and.2, identical numeral identical equipment.The polymer of melting is extruded screw rod 11 and sends into Spinning pumps 12, and this pump 12 is given filament piece 13 feed that comprise spinnerets and spinning filter (being configured between Spinning pumps and the spinnerets).It is for the one or more thread heads to long filament push that spinnerets is set, and each thread head contains many filaments.Fig. 1 has illustrated two threads, 14 and 15 situation of pushing simultaneously to (continuous filament yarn that comes out from a spinnerets).At 285-320 ℃ spinning temperature and desirable polymer volume flow velocity (Q, cm 3/ mim/ capillary) under, extrude thread 14 and 15 from spinnerets, arrive the preferably heating muff of a static delay zone or required delay length (being preferably the 1-40 inch) of delay zone (chamber 16) chamber 16 downwards from this spinnerets then, it has kept the temperature of desirable heating muff, is preferably 100-450 ℃.The yarn that leaves chamber 16 is directly sent into the top of quench zone (device 17), and device 17 is preferably the radial inflow quench chamber.This quench chamber be conventional lengths extension the path, its length for example is the 1-40 inch.Adopt 18 pairs of threads of feeding means 14 and 15 to be lubricated.The spin finish composition is used to lubricant fiber.For example in this application, feeding means 18 is lubricating oil rollers, and it is to rotate along the direction of motion of yarn.Also can use other means of coating finishing agent.
In order to obtain required character in final stretch yarn, must be to from the in addition hot-stretch of the partially oriented multifilament of quench zone, for example, reaching maximal draw ratio at least is 85%.This step can be finished in off line drawing process process, or preferably finishes in continuous spinning drawing process process.This drawing process can be that multistep is rapid, and comprises relating to or not going on foot and relate to loose high-temperature heat treatment.In this explanation, thread 14 and 15 is transported to spin-drawing plate 21 then.A kind of typical configurations is illustrated among Fig. 1.In Fig. 2, thread 14 and 15 all be advance (the 1st roller 1) at same single cover, stretch (roller 2-3 and roller 5-6) and the device of loose roller (roller 7-8) on handle.The thread head comes out from stretching roller 2, and 4(positions steam jet by the steam impringement drawing point).The thread head of yarn is advanced winder 22 from loose roller 7 and 8.For ease of discussing, following V is got the linear velocity of making roller 1.
About the condition of operating for the device of finishing technology of the present invention, being known that usually can be by increasing the I.V(dl/g of spinning speed (V represents with Km/min) or yarn) increase the not birefringence (△ nu) of stretching.According to the experimental work of finishing in process of the present invention, this is to give quantificational expression by the following relational expression of being determined by experiment:
△nu＝R fV 2.0IV 2.4
Wherein V is the spinning speed with km/minute represent.IV is the inherent viscosity of the not stretch yarn represented with dl/g.R fIt is the characteristic value of the additional processing variable except V and IV.
Concerning traditional and technology prior art, R fBe generally≤8 * 10 -3, and for technology of the present invention, R fBe 〉=9.0 * 10 -3Certainly, R fBe worth highly more, then concerning given IV and V, the birefringence of La Shening is just not high more yet.Obviously, high molecular of PET molecule (IV＞0.8) and intrinsic stiffness combine and can cause enough low relaxation rate to obtain high R in the melting attitude fValue.High R fValue, for example R f〉=15 * 10 -13Can easily obtain by the present invention, and have main commercial interest.
R fCan be divided into two more basic items:
R f＝R rRe
R fBe to keep relevant with the loose orientation afterwards of heat-induced aggregation thing.This parameter increases with the increase of the chilling degree of depth, and reduces with the polymer temperature of extruding and the raising of heating muff length and temperature.Skilled person in this area can adjust these parameters so that make △ n reach maximum, but and remains good spinnability.
Core of the present invention is the Re item, and it is with relevant from effective polymer extension flowing positioning in the spinnerets and that stretch downwards in the spinning post.Even the spinning speed of appropriateness, clean effect also is significant orientation.Experimentally determined relation is:
R C= (D 0.5)/(Q 0.7)
D is the diameter (inch) of spinneret capillary in the formula, and Q is with cm by capillaceous 3/ minute/flow rate of the polymer that capillary is represented.Q is by using 1.2gm/cm 3Density polymer calculate.The present invention shows that also the suitable combination of D and Q can obtain Re and be at least 10.5 * 10 -2Preferable is that Re is at least 13 * 10 -2
If it is 0.80-0.95 that people only are conceived to the IV scope, so just can obtain a kind of expression formula of simplification, it has shown the superiority of the present invention than prior art, wherein △ n is at least 7.0 * 10 -3V 2Preferably obtain for given V even higher birefringence; And be at least 11.5 * 10 with △ n -3V 2So concerning this sticking scope, the present invention also can only define with the V item.
Following special example shows how the suitable selection of state-variable causes R f〉=9.0 * 10 -3, and desirable demonstration improves the improvement yarn of dimensional stability.Comparative example obtains and is summarized in the table I from the patent that quote the front.This table has comprised all examples, and wherein (a) stretch yarn has at least 2.5 dpf, (b) n uBe at least 0.020, and (c) IV of yarn between 0.85 and 0.96.The latter's IV scope is selected to be because it approaches 0.88-0.92 in our embodiment.
Embodiment 1
Pet polymer is being contained the spinnerets of a plurality of spinneret orifices by pump under 296 ℃, the diameter of each spinneret orifice is 0.030 inch (D=0.030 inch).The extension speed Q in each hole is 0.88cm 3/ minute.Make filament pass through one 1 inch heating muff, radially accept chilling in the chilling path one then.This fine sand is being stretched on the plate of Fig. 2 subsequently; make roller 1 remain on 90 ℃; this yarn 1.5/1 roller 2,3(tool Normal Environmental Temperature that arrives heating that stretched not is 40-50 ℃); stretched then and 1.6/1 arrived the roller 5,6 that remains on 200 ℃ from cylinder 2,3; after this; this yarn is arrived roller 7,8 by lax 1-1.5%, and roller 7,8 tool operating temperatures are 150 ℃.This stretch yarn is batched with 2.98km/ branch clock rate.The polymer flow rate at two ends is 85 Pounds Per Hours.Stretch yarn was 1004 dawn, 3.3dpf, 17.5 pounds ultimate strength, the toughness of 7.9g/d, 10.6% ultimate elongation, the LASE-5 of 3.9g/d, 5.5% E 4.5With 9.2% FS.E 4.5+ FS summation is 14%.Not stretch yarn birefringence (△ n u) be 0.026, and IV is 0.92dl/g.R fBe 24 * 10 -3The yarn of being produced in this embodiment, though be produce under the spinning coiling speed (usually relevant) in appropriateness, has the sort of dimensional stability (relevant) that has strengthened with higher significantly spinning speed in the prior art yet show with standard yarn product.R fBe respectively 24 * 10 with Re -3With 19 * 10 -2
Embodiment 2
Produced the PET of super dimensional stability in such a way.Pet polymer is pumped into the spinnerets that contains a plurality of spinneret orifices, and the diameter of each spinneret orifice is 0.027 inch (D=0.027 inch).Q is 1.3cm 3/ minute/capillary.Then, make filament pass through heating muff (HST=220-300 ℃, the holdup time is 0.02-0.03 second), and radially accepting chilling in the chilling path.Spun yarn is at first stretched 1.4/1 between the roller of 90 ℃ roller and not heating, then at these rollers with remain between 220 ℃ the roller and stretched 1.15/1.Stretch yarn then by lax (3%) to the roller that remains on 135 ℃.Then adopt the high speed winder to batch with 4.60km/min speed.Stretch yarn was 924 dawn, 3.3dpf, the toughness of 5.8g/d, the LASE-5 of 4.1g/d, 6.5% E 4.5, 10.3% ultimate elongation, 4.3% free shrink.E 4.5+ FS summation is 10.8%.The stretch yarn birefringence is not 0.082, and IV is 0.92dl/g.R fBe 11 * 10 -3, and Re is 14 * 10 -2
Embodiment 3
Produced yarn (IV=0.92) according to the mode identical with embodiment 1, just (a) 2 inches sleeves are heated to 220-300 ℃, (b) spinneret orifice of spinnerets (diameter) be 0.018 inch and (c) Q be 1.0cm 3/ minute/capillary.After having experienced 2.46/1 hot-draw ratio, stretch yarn with 4.72 kms/minute speed batched.This yarn has the characteristic identical with embodiment 1: 3.3dpf, the toughness of 8.1g/d, 10.0% ultimate elongation, the LASE-5 of 3.9g/d, 5.5% E 4.5, 10.0% free shrink.0.028 the birefringence of La Shening is not corresponding to R fBe 11 * 10 -3Re is 13 * 10 -2
Embodiment 4
Prepared full-bodied yarn (IV=0.88) according to the method identical, D=0.018 inch just, V=3.5km/min with embodiment 2.The birefringence of stretch yarn is not 0.088, and it is corresponding to R f=9.8 * 10 -3Dpf after the stretching is 2.7, and Re is 11 * 10 -2
The table I
The example * of prior art
△ n IV (dl/g) # V (km/min)R f(10 -3) Rc (10 -2) list of references
0.021 0.096 2.0 5.9 7.7 United States Patent (USP)
4，491，657
0.039 0.096 3.05 4.7 6.9 United States Patent (USP)
4,491,657
0.052 0.096 3.5 4.7 6.7 United States Patent (USP)
4,491,657
0.072 0.095 4.0 5.2 6.4 United States Patent (USP)
4,491,657
0.088 0.095 4.5 4.8 6.4 United States Patent (USP)
4,491,657
0.097 0.095 5.0 4.4 6.2 United States Patent (USP)
4,491,657
0.073 0.090 3.5 7.5 8.9 United States Patent (USP)
4,690,866
* only comprise stretching to dpf be at least 2.5 and IV be between 0.85 and 0.96
#60: phenol/tetrachloroethylene solvent of 40.

Claims (10)

1, the manufacture method of a kind of dimensional stability drawn polyethylene terephthalate multifilament yarn (having the every filament filament at least 2.5 dawn) may further comprise the steps:
A) make polyethylene terephthalate polymer melt body and be pressed through spinnerets to form filament with a plurality of spinneret orifices;
B) make multifilament at first pass through delay zone,, thereby solidify this filament by controlled way then by quench zone through extruding;
C) multifilament that makes curing from quench zone with required spinning speed V unwinding;
Thereby step a)-c) is to form partially oriented birefringence (the △ n that does not stretch that has u) be at least 0.020 multifilament textile (△ n wherein u=R fV 2.0IV 2.4, IV is the inherent viscosity of stretch yarn not in the formula, and is at least 0.80, R fBe at least 9.0 * 10 -3) condition under carry out;
D) partially oriented multifilament is carried out hot-stretch.
2, method according to claim 1 is characterized in that R fBe at least 15 * 10 -3
3, method according to claim 1 is characterized in that R f=Rr Re, and Re is at least 10.5 * 10 -2
4, method according to claim 3 is characterized in that Re is at least 13 * 10 -2
5, method according to claim 1 is characterized in that IV is 0.80-0.95, and △ n uBe at least 20 * 10 -3V 2
6, method according to claim 5 is characterized in that △ n uBe at least 11.5 * 10 -3V 2
7, method according to claim 1 is characterized in that IV is at least 0.85.
8, method according to claim 1 is characterized in that the diameter D of described spinneret orifice is at least 0.027 inch.
9, method according to claim 1, it is characterized in that it also comprises carries out step of polymerization to described polyethylene terephthalate polymer, thereby has the continuous polymerization and the direct technical process of melting spinning.
10,, it is characterized in that described polyethylene terephthalate polymer is to carry out polymerization under the condition of the additive that does not increase molecular weight according to the method for claim 1 or 9.
CN89108756A 1989-01-03 1989-11-20 Process or dimensionally stable polyester yarn Expired - Fee Related CN1021919C (en)

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US29286489A 1989-01-03 1989-01-03
US292,864 1989-01-03
USU.S.292864 1989-01-03

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CN1021919C CN1021919C (en) 1993-08-25

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AU (1) AU635241B2 (en)
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1069355C (en) * 1995-03-02 2001-08-08 东丽株式会社 Partially oriented undrawn polyester yarn and process for producing the same
CN102925998A (en) * 2011-08-12 2013-02-13 江苏省衣维新投资发展有限公司 Slow cooling device of tows used for fine denier spinning
CN102925999A (en) * 2011-08-12 2013-02-13 江苏省衣维新投资发展有限公司 Silk flock slowly-cooling method for fine-denier spinning

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ID846B (en) † 1991-12-13 1996-08-01 Kolon Inc FIBER YARN, POLYESTER TIRE THREAD AND HOW TO PRODUCE IT
CN1044500C (en) * 1995-09-12 1999-08-04 南亚塑胶工业股份有限公司 Improved process for making filament-blended profiled-section combined filament yarn of polyester
KR100523809B1 (en) * 2000-10-06 2005-10-25 주식회사 효성 Preparation of Polyester Fiber

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JPS57154410A (en) * 1981-03-13 1982-09-24 Toray Ind Inc Polyethylene terephthalate fiber and its production
US4690866A (en) * 1984-07-09 1987-09-01 Teijin Limited Polyester fiber

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1069355C (en) * 1995-03-02 2001-08-08 东丽株式会社 Partially oriented undrawn polyester yarn and process for producing the same
CN102925998A (en) * 2011-08-12 2013-02-13 江苏省衣维新投资发展有限公司 Slow cooling device of tows used for fine denier spinning
CN102925999A (en) * 2011-08-12 2013-02-13 江苏省衣维新投资发展有限公司 Silk flock slowly-cooling method for fine-denier spinning

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CA2004942A1 (en) 1990-07-03
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AU635241B2 (en) 1993-03-18
CA2004942C (en) 1999-10-05
WO1990007592A1 (en) 1990-07-12
EP0452405A1 (en) 1991-10-23
KR910700365A (en) 1991-03-15
ID1015B (en) 1996-10-17
EP0452405B1 (en) 1992-09-16
TR25058A (en) 1992-11-01
BR8907870A (en) 1991-10-22
KR0140230B1 (en) 1998-07-01
CN1021919C (en) 1993-08-25
AU4969690A (en) 1990-08-01

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