CN104388766B - Production method of aluminum foil for lithium-ion battery - Google Patents
Production method of aluminum foil for lithium-ion battery Download PDFInfo
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- CN104388766B CN104388766B CN201410695087.9A CN201410695087A CN104388766B CN 104388766 B CN104388766 B CN 104388766B CN 201410695087 A CN201410695087 A CN 201410695087A CN 104388766 B CN104388766 B CN 104388766B
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- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 25
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 25
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 229910001416 lithium ion Inorganic materials 0.000 title claims abstract description 18
- 239000011888 foil Substances 0.000 title claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- 238000005096 rolling process Methods 0.000 claims abstract description 19
- 238000003723 Smelting Methods 0.000 claims abstract description 7
- -1 ferrous metals Chemical class 0.000 claims abstract description 6
- 238000005266 casting Methods 0.000 claims description 36
- 238000005097 cold rolling Methods 0.000 claims description 30
- 229910000838 Al alloy Inorganic materials 0.000 claims description 22
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 20
- 238000000137 annealing Methods 0.000 claims description 19
- 239000005030 aluminium foil Substances 0.000 claims description 14
- 239000004411 aluminium Substances 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 12
- 229910052786 argon Inorganic materials 0.000 claims description 10
- 229910052802 copper Inorganic materials 0.000 claims description 10
- 229910052742 iron Inorganic materials 0.000 claims description 10
- 230000002427 irreversible effect Effects 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 229910052710 silicon Inorganic materials 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 229910052804 chromium Inorganic materials 0.000 claims description 8
- 229910052749 magnesium Inorganic materials 0.000 claims description 8
- 229910052748 manganese Inorganic materials 0.000 claims description 8
- 229910052725 zinc Inorganic materials 0.000 claims description 8
- 229910045601 alloy Inorganic materials 0.000 claims description 7
- 239000000956 alloy Substances 0.000 claims description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 5
- VVTRNRPINJRHBQ-UHFFFAOYSA-N [Cl].[Ar] Chemical compound [Cl].[Ar] VVTRNRPINJRHBQ-UHFFFAOYSA-N 0.000 claims description 5
- 239000000460 chlorine Substances 0.000 claims description 5
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- 238000009749 continuous casting Methods 0.000 claims description 5
- 238000005520 cutting process Methods 0.000 claims description 5
- 238000007872 degassing Methods 0.000 claims description 5
- 210000005069 ears Anatomy 0.000 claims description 5
- 239000004744 fabric Substances 0.000 claims description 5
- 239000006025 fining agent Substances 0.000 claims description 5
- 230000014759 maintenance of location Effects 0.000 claims description 5
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 238000004806 packaging method and process Methods 0.000 claims description 5
- 238000001953 recrystallisation Methods 0.000 claims description 5
- 235000013619 trace mineral Nutrition 0.000 claims description 5
- 239000011573 trace mineral Substances 0.000 claims description 5
- 238000003490 calendering Methods 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 5
- 239000010936 titanium Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
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Abstract
The invention relates to smelting, cast rolling and calendering of non-ferrous metals, and in particular relates to a production method of an aluminum foil for a lithium-ion battery. By using the production method of the aluminum foil for the lithium-ion battery, the mechanical property and the plasticity of the aluminum foil for the lithium-ion battery are improved, meanwhile, the thickness of the aluminum foil is reduced, and the battery capacity is increased. The production method of the aluminum foil for the lithium-ion battery is simple.
Description
Technical field
The present invention relates to smelting non-ferrous metal, casting and calendering, the production method of a kind of lithium ion battery aluminium foil.
Background technology
At present, the aluminium foil of the lithium ion battery sold on market, tensile strength and elongation percentage index are low, material plasticity is poor, easily there is backfin problem of Cracking in the coating that uses in lower operation, nipping process, lifting battery electric quantity and product are had a negative impact service life, is also one of bottleneck that govern lithium-ion-power cell industry development.
Summary of the invention
Solve the technical problem that the production method being to provide a kind of lithium ion battery aluminium foil needed for the present invention, improve lithium ion battery aluminium foil tensile strength and elongation percentage index, meanwhile, thinning aluminum foil thickness, promote battery capacity.
The technical solution adopted for the present invention to solve the technical problems is: include following several step: include following several step: first step melting: 1. by the fine aluminium ingot through dispensing, add a small amount of aluminium alloy scrap, Fe, Si, Cu intermediate alloy ingot loads in fusing stove, 2. fusing: a. stirring melt for the first time;B. thermometric;C. second time stirring melt;D. preanalysis is sampled;E. composition adjustment;F. argon refine is used;G. skim;H. 20~30 points are stood;I. aluminium titanium boron wire fining agent, addition 1.4~2.1kg/t are added;J. extreme climate emergency processing;K. smelting temperature is 730~750 DEG C, and 3. holding temperature is 710~740 DEG C, 4. uses chlorine to add argon and carries out degasification, and argon chlorine fraction is 20:1,5. uses three well tubular filters to filter;Second step casting: a. uses drop of water god φ 960 horizontal continuity casting and rolling machine casting;B. lip reasonable cloth stream, the clearance control between lip and lower Casting Roller is 0.1~0.2mm;The most front case temperature is 690~710 DEG C, and front case aluminum water fluctuation of level scope control is at ± 0.5mm;D. the hard ears or side handles of a utensil are used;E. roll casting zone is 65mm~75mm;F. roll casting speed is 1050~1100mm/min, and g. is 6~7mm through 3 passage casting-rolling aluminum alloy coiled strips of continuous casting & rolling line;H. casting temperature 690~710 DEG C;3rd step is cold rolling: the irreversible rolled by cold rolling machine of a. IHI tetra-roller;B. roll-force is 300~600 tons;C. mill speed is 110~500m/min;D. uncoiling tension is 13~22MPa;E. coiling tension is 18~30MPa;F. through cold rolling 4 passage aluminium alloy coiled strip cold processing ratios be 80%~92%;4th step intermediate heat-treatment annealing;After 5th step annealing cold rolling: a. uses the IHI tetra-irreversible cold-rolling mill of roller;B. roll-force 100~200 tons;C. mill speed is 110~400m/min;D. uncoiling tension is 18~22MPa;E. coiling tension is 22~30MPa;F. through cold rolling 1 passage;6th step paper tinsel rolls: a. uses IHI tetra-roller irreversible foil mill paper tinsel to roll;B. roll-force is 90~200 tons;C. mill speed is 350~750m/min;D uncoiling tension is 3.5~7.5MPa;E. coiling tension is 3.5~5.0MPa;F. paper tinsel rolls 4 passages;7th step is cut: cutting speed is 500~700m/min, and uncoiling tension is 500N 900N;Coiling tension is 300N 700N;8th step: packaging.By the fine aluminium ingot through dispensing in the described first step, add a small amount of aluminium alloy scrap, Fe, Si, Cu intermediate alloy ingot loads in fusing stove, wherein the percentage by weight of composition is: Al >=99.35%, Si0.05~0.12%, Fe0.35~0.45%, Cu0.02~0.03%, Mn0.005%, Mg0.001%, Zn0.023%, Cr0.001%, Ti0.015%, Mg, Mn, Zn, Cr trace element is pressed the control standard of fine aluminium ingot and is controlled, and adds the most separately;In the 4th described step intermediate heat-treatment annealing, big volume aluminium alloy coiled strip blank is put into and is carried out perfect recrystallization annealing in heat-treatment furnace, and annealing temperature is 280~320 DEG C, and temperature retention time is 3~5 hours.
The invention has the beneficial effects as follows: method is simple, not only can improve aluminium foil mechanical property and improve plasticity, and the thinning aluminum foil thickness of energy, promote battery capacity.
Accompanying drawing explanation
The invention will be further described with embodiment below in conjunction with the accompanying drawings.
Fig. 1 is the flow chart of the production method of a kind of lithium ion battery aluminium foil of the present invention.
Detailed description of the invention
Embodiment 1:
As a example by the lithium ion battery aluminium foil producing electronic bus battery, general thickness specification is: 0.02mm, and width specifications is according to Battery Plant's equipment choice 300~600mm unequal width.Refering to Fig. 1, the casting-rolling method of the lithium ion battery aluminium foil of this example, including following several steps: first step melting: 1. by the fine aluminium ingot through dispensing, add a small amount of aluminium alloy scrap, Fe, Si, Cu intermediate alloy ingot loads in fusing stove, wherein the percentage by weight of composition is: Al >=99.35%, Si:0.05%, Fe:0.35%, Cu:0.02%, Mn:0.005%, Mg:0.001%, Zn:0.023%, Cr:0.001%, Ti:0.015%, Mg, Mn, Zn, Cr trace element is pressed the control standard of fine aluminium ingot and is controlled, and adds the most separately.2. fusing: a. stirring melt for the first time;B. thermometric;C. second time stirring melt;D. preanalysis is sampled;E. composition adjustment;F. argon refine is used;G. skim;H. 20~30 points are stood;I. aluminium titanium boron wire fining agent, addition 1.4~2.1kg/t are added;J. extreme climate emergency processing;K. smelting temperature is 730~750 DEG C.3. holding temperature is 710~740 DEG C.4. using chlorine to add argon and carry out degasification, argon chlorine fraction is 20:1.5. use three well tubular filters to filter.Second step: casting, a. uses drop of water god φ 960 horizontal continuity casting and rolling machine casting;B. lip reasonable cloth stream, the clearance control between lip and lower Casting Roller is 0.1~0.2mm;The most front case temperature is 690~710 DEG C, and front case aluminum water fluctuation of level scope control is at ± 0.5mm;D. the hard ears or side handles of a utensil are used;E. roll casting zone is 65mm~75mm;F. roll casting speed is 1050~1100mm/min, and g. is 6~7mm through 3 passage casting-rolling aluminum alloy coiled strips of continuous casting & rolling line;H. casting temperature 690~710 DEG C.3rd step: cold rolling, the irreversible rolled by cold rolling machine of a. IHI tetra-roller;B. roll-force is 300~600 tons;C. mill speed is 110~500m/min;D. uncoiling tension is 13~22MPa;E. coiling tension is 18~30MPa;F. through cold rolling 4 passage aluminium alloy coiled strip cold processing ratios be 80%~92%.4th step: intermediate heat-treatment is annealed, carries out perfect recrystallization annealing in big volume aluminium alloy coiled strip blank threading heat-treatment furnace, and annealing temperature is 280 DEG C, and temperature retention time is 3 hours.5th step: cold rolling after annealing, a. uses the IHI tetra-irreversible cold-rolling mill of roller;B. roll-force 100~200 tons;C. mill speed is 110~400m/min;D. uncoiling tension is 18~22MPa;E. coiling tension is 22~30MPa;F. through cold rolling 1 passage.6th step: paper tinsel rolls, a. uses IHI tetra-roller irreversible foil mill paper tinsel to roll;B. roll-force is 90~200 tons;C. mill speed is 350~750m/min;D uncoiling tension is 3.5~7.5MPa;E. coiling tension is 3.5~5.0MPa;F. paper tinsel rolls 4 passages.7th step: cut, cutting speed is 500~700m/min, and uncoiling tension is 500N 900N;Coiling tension is 300N 700N.8th step: packaging.
Embodiment 2:
As a example by the lithium ion battery aluminium foil producing electronic bus battery, general thickness specification is: 0.02mm, and width specifications is according to Battery Plant's equipment choice 300~600mm unequal width.Refering to Fig. 1, a kind of casting-rolling method of the lithium ion battery aluminium foil of this example, including following several steps: the first step: melting, 1. by the fine aluminium ingot through dispensing, add a small amount of aluminium alloy scrap, Fe, Si, Cu intermediate alloy ingot loads in fusing stove, wherein the percentage by weight of composition is: Al >=99.35%, Si:0.09%, Fe:0.4%, Cu:0.025%, Mn:0.005%, Mg:0.001%, Zn:0.023%, Cr:0.001%, Ti:0.015%, Mg, Mn, Zn, Cr trace element is pressed the control standard of fine aluminium ingot and is controlled, and adds the most separately.2. fusing: a. stirring melt for the first time;B. thermometric;C. second time stirring melt;D. preanalysis is sampled;E. composition adjustment;F. argon refine is used;G. skim;H. 20~30 minutes are stood;I. aluminium titanium boron wire fining agent, addition 1.4~2.1kg/t are added;J. extreme climate emergency processing;K. smelting temperature is 730~750 DEG C.3. holding temperature is 710~740 DEG C.4. using chlorine to add argon and carry out degasification, argon chlorine fraction is 20:1.5. use three well tubular filters to filter.Second step: casting, a. uses drop of water god φ 960 horizontal continuity casting and rolling machine casting;B. lip reasonable cloth stream, the clearance control between lip and lower Casting Roller is 0.1~0.2mm;The most front case temperature is 690~710 DEG C, and front case aluminum water fluctuation of level scope control is at ± 0.5mm;D. the hard ears or side handles of a utensil are used;E. roll casting zone is 65mm~75mm;F. roll casting speed is 1050~1100mm/min;G. leading to 3 passage casting-rolling aluminum alloy coiled strips of continuous casting & rolling line is 6~6.5mm;H. casting temperature 690~710 DEG C.3rd step: cold rolling, a. uses the IHI tetra-irreversible rolled by cold rolling machine of roller;B. roll-force is 300~600 tons;C. mill speed is 110~500m/min;D. uncoiling tension is 13~22MPa;E. coiling tension is 18~30MPa;F. through cold rolling 4 passage aluminium alloy coiled strip cold processing ratios be 80%~92%.4th step: intermediate heat-treatment is annealed, carries out perfect recrystallization annealing in big volume aluminium alloy coiled strip blank threading heat-treatment furnace, and annealing temperature is 300 DEG C, and temperature retention time is 4 hours.5th step: cold rolling after annealing, the irreversible rolled by cold rolling machine of a. IHI tetra-roller;B. roll-force is 100~200 tons;C. mill speed is 110~400m/min;D. uncoiling tension is 18~22MPa;E. coiling tension is 22~30MPa.F. through cold rolling 1 passage.6th step: paper tinsel rolls, a. uses IHI tetra-roller irreversible foil mill paper tinsel to roll;B. roll-force is 90~200 tons;C. mill speed is 350~750m/min;D. uncoiling tension is 3.5~7.5MPa;E. coiling tension is 3.5~5.0MPa;F. paper tinsel rolls 4 passages.7th step: cut, cutting speed is 500~700m/min, and uncoiling tension is 500N 900N;Coiling tension is 300N 700N.8th step: packaging.
Embodiment 3:
As a example by the lithium ion battery aluminium foil producing electronic bus battery, general thickness specification is: 0.02mm, and width specifications is according to Battery Plant's equipment choice 300~600mm unequal width.Refering to Fig. 1, a kind of casting-rolling method of the lithium ion battery aluminium foil of this example, including following several steps: the first step: melting, 1. by the fine aluminium ingot through dispensing, add a small amount of aluminium alloy scrap, Fe, Si, Cu intermediate alloy ingot loads in fusing stove, wherein the percentage by weight of composition is: Al >=99.35%, Si:0.12%, Fe:0.45%, Cu:0.03%, Mn:0.005%, Mg:0.001%, Zn:0.023%, Cr:0.001%, Ti:0.015%, Mg, Mn, Zn, Cr trace element is pressed the control standard of fine aluminium ingot and is controlled, and adds the most separately.2. fusing: a. stirring melt for the first time;B. thermometric;C. second time stirring melt;D. preanalysis is sampled;E. composition adjustment;F. argon refine is used;G. skim;H. 20~30 points are stood;I. aluminium titanium boron wire fining agent, addition 1.4~2.1kg/t are added;J. extreme climate emergency processing;K. smelting temperature is 730~750 DEG C.3. holding temperature is 710~740 DEG C.4. using chlorine to add argon and carry out degasification, argon chlorine fraction is 20:1,5. filters with three well tubular filters.Second step: casting, a. uses drop of water god φ 960 horizontal continuity casting and rolling machine casting;B. lip reasonable cloth stream, the clearance control between lip and lower Casting Roller is 0.1~0.2mm;The most front case temperature is 690~710 DEG C, and front case aluminum water fluctuation of level scope control is at ± 0.5mm;D. the hard ears or side handles of a utensil are used;E. roll casting zone is 65mm~75mm;F. roll casting speed is 1050~1100mm/min;G. leading to 3 passage casting-rolling aluminum alloy coiled strips of continuous casting & rolling line is 6~6.5mm;H. casting temperature 690~710 DEG C.3rd step: cold rolling, the irreversible rolled by cold rolling machine of a. IHI tetra-roller;B roll-force is 300~600 tons;C. mill speed is 110~500m/min;D. uncoiling tension is 13~22MPa;E. coiling tension is 18~30MPa;F. through cold rolling 4 passage aluminium alloy coiled strip cold processing ratios be 80%~92%.4th step: intermediate heat-treatment is annealed, carries out perfect recrystallization annealing in big volume aluminium alloy coiled strip blank threading heat-treatment furnace, and annealing temperature is 320 DEG C, and temperature retention time is 5 hours.5th step: cold rolling after annealing, a. uses the IHI tetra-irreversible rolled by cold rolling machine of roller;B. roll-force is 100~200 tons;C. mill speed is 110~400m/min;D. uncoiling tension is 18~22MPa;E. coiling tension is 22~30MPa;F. through cold rolling 1 passage.6th step: paper tinsel rolls, a. uses IHI tetra-roller irreversible foil mill paper tinsel to roll;B. roll-force is 90~200 tons;C. mill speed is 350~750m/min;D. uncoiling tension is 3.5~7.5MPa;E. coiling tension is 3.5~5.0MPa;F. paper tinsel rolls 4 passages.7th step: cut, cutting speed is 500~700m/min, and uncoiling tension is 500N 900N;Coiling tension is 300N 700N.8th step: packaging.
Claims (1)
1. a production method for lithium ion battery aluminium foil, including following several steps: first step melting: 1. by the fine aluminium ingot through dispensing, adds in a small amount of aluminium alloy scrap, Fe, Si, Cu intermediate alloy ingot loading fusing stove, 2. fusing: a. stirring melt for the first time;B. thermometric;C. second time stirring melt;D. preanalysis is sampled;E. composition adjustment;F. argon refine is used;G. skim;H. 20~30 points are stood;I. aluminium titanium boron wire fining agent, addition 1.4~2.1kg/t are added;J. extreme climate emergency processing;K. smelting temperature is 730~750 DEG C, and 3. holding temperature is 710~740 DEG C, 4. uses chlorine to add argon and carries out degasification, and argon chlorine fraction is 20:1,5. uses three well tubular filters to filter;Second step casting: a. uses drop of water god φ 960 horizontal continuity casting and rolling machine casting;B. lip reasonable cloth stream, the clearance control between lip and lower Casting Roller is 0.1~0.2mm;The most front case temperature is 690~710 DEG C, and front case aluminum water fluctuation of level scope control is at ± 0.5mm;D. the hard ears or side handles of a utensil are used;E. roll casting zone is 65mm~75mm;F. roll casting speed is 1050~1100mm/min, and g. is 6~7mm through 3 passage casting-rolling aluminum alloy coiled strips of continuous casting & rolling line;H. casting temperature 690~710 DEG C;3rd step is cold rolling: the irreversible rolled by cold rolling machine of a. IHI tetra-roller;B. roll-force is 300~600 tons;C. mill speed is 110~500m/min;D. uncoiling tension is 13~22MPa;E. coiling tension is 18~30MPa;F. through cold rolling 4 passage aluminium alloy coiled strip cold processing ratios be 80%~92%;4th step intermediate heat-treatment annealing: cold rolling after the 5th step annealing: a. uses the IHI tetra-irreversible cold-rolling mill of roller;B. roll-force 100~200 tons;C. mill speed is 110~400m/min;D. uncoiling tension is 18~22MPa;E. coiling tension is 22~30MPa;F. through cold rolling 1 passage;6th step paper tinsel rolls: a. uses IHI tetra-roller irreversible foil mill paper tinsel to roll;B. roll-force is 90~200 tons;C. mill speed is 350~750m/min;D uncoiling tension is 3.5~7.5MPa;E. coiling tension is 3.5~5.0MPa;F. paper tinsel rolls 4 passages;7th step is cut: cutting speed is 500~700m/min, and uncoiling tension is 500N 900N;Coiling tension is 300N 700N;8th step packaging, it is characterized in that: by the fine aluminium ingot through dispensing in the described first step, add a small amount of aluminium alloy scrap, Fe, Si, Cu intermediate alloy ingot loads in fusing stove, wherein the percentage by weight of composition is: Al >=99.35%, Si0.05~0.12%, Fe0.35~0.45%, Cu0.02~0.03%, Mn0.005%, Mg0.001%, Zn0.023%, Cr0.001%, Ti0.015%, Mg, Mn, Zn, Cr trace element is pressed the control standard of fine aluminium ingot and is controlled, and adds the most separately;In the 4th described step intermediate heat-treatment annealing, big volume aluminium alloy coiled strip blank is put into and is carried out perfect recrystallization annealing in heat-treatment furnace, and annealing temperature is 280~320 DEG C, and temperature retention time is 3~5 hours.
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CN105063520B (en) * | 2015-07-15 | 2018-05-11 | 浙江中金铝业有限公司 | A kind of annealing of aluminum foil for lithium battery |
CN105921516B (en) * | 2016-05-05 | 2018-01-05 | 广东金兰新材料有限公司 | Aluminium foil suitable for lithium ion battery and preparation method thereof |
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JP7312760B2 (en) * | 2017-11-21 | 2023-07-21 | スペイラ ゲゼルシャフト ミット ベシュレンクテル ハフツング | Battery electrode foil for the production of lithium-ion accumulators |
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WO2024261047A1 (en) | 2023-06-23 | 2024-12-26 | Gränges Ab | Aluminium alloy foil |
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CN103003457A (en) * | 2010-07-16 | 2013-03-27 | 株式会社神户制钢所 | Hardened aluminum foil for battery collectors |
CN104769141A (en) * | 2012-10-30 | 2015-07-08 | 株式会社Uacj | Aluminum alloy foil |
CN103397227A (en) * | 2013-07-22 | 2013-11-20 | 苏州有色金属研究院有限公司 | Aluminum alloy foil for lithium ion battery positive electrode current collector and preparation method thereof |
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