CN104386777A - Solar photo-catalytic sewage degradation system - Google Patents

Solar photo-catalytic sewage degradation system Download PDF

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Publication number
CN104386777A
CN104386777A CN201410720614.7A CN201410720614A CN104386777A CN 104386777 A CN104386777 A CN 104386777A CN 201410720614 A CN201410720614 A CN 201410720614A CN 104386777 A CN104386777 A CN 104386777A
Authority
CN
China
Prior art keywords
sewage
film layer
photo
catalytic
thin film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410720614.7A
Other languages
Chinese (zh)
Inventor
陈逸
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHANGZHOU SAIJIA MACHINERY Co Ltd
Original Assignee
CHANGZHOU SAIJIA MACHINERY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CHANGZHOU SAIJIA MACHINERY Co Ltd filed Critical CHANGZHOU SAIJIA MACHINERY Co Ltd
Priority to CN201410720614.7A priority Critical patent/CN104386777A/en
Publication of CN104386777A publication Critical patent/CN104386777A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/725Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/20Controlling water pollution; Waste water treatment
    • Y02A20/208Off-grid powered water treatment
    • Y02A20/212Solar-powered wastewater sewage treatment, e.g. spray evaporation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/30Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37Wastewater or sewage treatment systems using renewable energies using solar energy

Abstract

The invention relates to the technical field of sewage treatment and particularly relates to a solar photo-catalytic sewage degradation system. The system comprises a base plate, at least one photo-catalytic film layer arranged on the upper surface of the base plate, and a conveying pipeline for conveying sewage, wherein the conveying pipeline is provided with a water distributor spray nozzle for spraying the sewage on the photo-catalytic film layer. By arranging the photo-catalytic film layer on the base plate, a photo-catalytic degradation reactor is formed to absorb solar energy to generate micro-current so that organic macromolecular substances in the sewage can be degraded in a photo-catalytic manner, and thus the aim of sewage treatment is realized; the system disclosed by the invention is free of energy consumption, high in sewage treatment efficiency and low in emission of BOD and COD.

Description

Solar energy photocatalytic degradation of sewage system
Technical field
The present invention relates to technical field of sewage, be specifically related to a kind of solar energy photocatalytic degradation of sewage system.
Background technology
Current great majority research concentrates on research TiO 2the properties of photocatalyst itself, as improved photocatalysis efficiency, mixing up and make responsive bandwidth red shift etc.In addition, the application in family's air pollution treatment is that photocatalyst and the small light catalyst formaldehyde digestion device of main component has a large amount of use with TiO2.But industrially, large-scale TiO 2the application of photocatalyst is little.
Summary of the invention
For above-mentioned technical problem, the invention provides a kind of solar energy photocatalytic degradation of sewage system, by arranging photocatalysis thin film layer on substrate, form photocatalytic degradation reactor, absorb sun power and produce micro-electric current, the organic macromolecule material in photocatalysis Decomposition sewage, reaches the object to sewage disposal, its Non-energy-consumption, efficiency of disposing of sewage are high, reduce the discharge of BOD, COD.
Realize technical scheme of the present invention as follows:
Solar energy photocatalytic degradation of sewage system, this system comprises substrate, and at least one deck is arranged on the photocatalysis thin film layer of upper surface of base plate, and the transport pipe of conveying sewage, described transport pipe is provided with the water distributor fog nozzle be sprayed onto by sewage on photocatalysis thin film layer.
Described photocatalysis thin film layer is photocatalytic nanometer TiO 2layer, described photocatalytic nanometer TiO 2particle diameter at 23nm-28nm.Nano_scale particle, being applied to after on substrate and can being closely attached on substrate, has self-cleaning function, does not need frequent cleaning; And the strong oxidizing property of photocatalysis thin film layer can kill part bacterium.
Described photocatalytic nanometer TiO 2particle diameter be 25nm.
The described water distributor fog nozzle sewage be sprayed onto on photocatalysis thin film layer forms one deck liquid film, and the thickness of liquid film is between 100 microns-500 microns.
Have employed such scheme, by arranging photocatalysis thin film layer on substrate, forming photocatalytic degradation reactor, absorb sun power and produce micro-electric current, the organic macromolecule material in photocatalysis Decomposition sewage; Namely sewage forms liquid film by water distributor spray nozzle and slowly flows down on photocatalysis thin film layer, organic pollutant molecule in sewage constantly contacts with the TiO2 in photocatalysis thin film layer, energy is provided under the irradiation of sunlight, produce microelectronics chemical reaction, produce the hole with very strong oxidizing property, be combined with organic pollutant molecule and oxidizing reaction occurs, reach the effect of decomposing organic pollutant molecule, reach the object to sewage disposal, its Non-energy-consumption, efficiency of disposing of sewage are high, reduce the discharge of BOD, COD.
Accompanying drawing explanation
Fig. 1 is embodiments of the invention schematic diagram;
In figure, 1 is factory building, and 2 is substrate, and 3 is photocatalysis thin film layer, and 4 is transport pipe, and 5 is water distributor fog nozzle, and 6 is water pump.
Embodiment
Below in conjunction with the drawings and specific embodiments, the present invention is further described.
See Fig. 1, solar energy photocatalytic degradation of sewage system, comprise the substrate 2 be installed in factory building 1 inclined roof, and at least one deck is arranged on the photocatalysis thin film layer 3 of upper surface of base plate, and the transport pipe 4 of conveying sewage, transport pipe is provided with the water distributor fog nozzle 5 be sprayed onto by sewage on photocatalysis thin film layer, the water distributor fog nozzle sewage be sprayed onto on photocatalysis thin film layer forms one deck liquid film, and the thickness of liquid film is between 100 microns-500 microns.During concrete enforcement, substrate adopts glass board material to be laid on factory building or house roof, and such substrate shape can have a certain degree and better receive the irradiation of sunlight, and transport pipe is communicated with a water pump 6, carries out active like this carry by water pump to sewage;
Wherein, photocatalysis thin film layer is photocatalytic nanometer TiO 2layer, photocatalytic nanometer TiO 2particle diameter at 23nm-28nm.In concrete enforcement, photocatalytic nanometer TiO 2particle diameter can be 25nm.Use spraying method by photocatalytic nanometer TiO 2the solvent of particle is laid on substrate, and concrete selection high-efficient atomizing spray gun, utilizes air pressure pump that solvent is evenly sprayed on upper surface of base plate, make TiO at UV light irradiates 2 hours 2solidification; Wherein, multilayer can be sprayed, to increase the density of catalytic film layer, due to photocatalytic nanometer TiO 2containing a certain proportion of glue crosslinking agent in the solvent of particle, contribute to firmly adhering to.
The present invention utilizes natural diffuse-reflectance sunlight, also can keep certain reaction efficiency at the cloudy day, is specially adapted to the sewage disposal of dye molecule and other hardly degraded organic substances.Sewage through process of the present invention can adopt receiving tank to carry out collecting with his use, can also couple together, reach the landscape utilization of waste water, beautify plant area with the view such as artificial hillock, waterfall.The present invention can also use heavy metal to mix up type photocatalyst, can improve ultraviolet-responsive region, increases sunlight utilization ratio; Adopt large-scale vacuum sputter TiO on plated surface on the glass substrate 2, film forming is evenly adhered to by force, and processing efficiency increases, and can increase process of industrialization.

Claims (4)

1. solar energy photocatalytic degradation of sewage system, it is characterized in that: this system comprises substrate, and at least one deck is arranged on the photocatalysis thin film layer of upper surface of base plate, and the transport pipe of conveying sewage, described transport pipe is provided with the water distributor fog nozzle be sprayed onto by sewage on photocatalysis thin film layer.
2. solar energy photocatalytic degradation of sewage system according to claim 1, is characterized in that: described photocatalysis thin film layer is photocatalytic nanometer TiO 2layer, described photocatalytic nanometer TiO 2particle diameter at 23nm-28nm.
3. solar energy photocatalytic degradation of sewage system according to claim 2, is characterized in that: described photocatalytic nanometer TiO 2particle diameter be 25nm.
4. solar energy photocatalytic degradation of sewage system according to claim 1 and 2, is characterized in that: the described water distributor fog nozzle sewage be sprayed onto on photocatalysis thin film layer forms one deck liquid film, and the thickness of liquid film is between 100 microns-500 microns.
CN201410720614.7A 2014-12-02 2014-12-02 Solar photo-catalytic sewage degradation system Pending CN104386777A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410720614.7A CN104386777A (en) 2014-12-02 2014-12-02 Solar photo-catalytic sewage degradation system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410720614.7A CN104386777A (en) 2014-12-02 2014-12-02 Solar photo-catalytic sewage degradation system

Publications (1)

Publication Number Publication Date
CN104386777A true CN104386777A (en) 2015-03-04

Family

ID=52604759

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410720614.7A Pending CN104386777A (en) 2014-12-02 2014-12-02 Solar photo-catalytic sewage degradation system

Country Status (1)

Country Link
CN (1) CN104386777A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108751332A (en) * 2018-06-06 2018-11-06 浙江理工大学 A kind of photocatalysis-biodegradation water treatment facilities and method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108751332A (en) * 2018-06-06 2018-11-06 浙江理工大学 A kind of photocatalysis-biodegradation water treatment facilities and method
CN108751332B (en) * 2018-06-06 2021-06-01 浙江理工大学 Photocatalysis-biodegradation water treatment device and method

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C06 Publication
PB01 Publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20150304

WD01 Invention patent application deemed withdrawn after publication