CN104371510A - Ultraviolet light curable metal anticorrosive paint and preparation method thereof - Google Patents
Ultraviolet light curable metal anticorrosive paint and preparation method thereof Download PDFInfo
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- CN104371510A CN104371510A CN201410682953.0A CN201410682953A CN104371510A CN 104371510 A CN104371510 A CN 104371510A CN 201410682953 A CN201410682953 A CN 201410682953A CN 104371510 A CN104371510 A CN 104371510A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
- C09D5/106—Anti-corrosive paints containing metal dust containing Zn
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/67—Particle size smaller than 100 nm
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/69—Particle size larger than 1000 nm
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0893—Zinc
Abstract
The invention relates to the technical field of corrosion protection of metals and in particular relates to ultraviolet light curable metal anticorrosive paint. The ultraviolet light curable metal anticorrosive paint is composed of the following components in percentage by mass: light-cured resin, a light-cured monomer, an adhesion promoter, a photoinitiator, a dispersing agent, zinc powder and graphene. The ultraviolet light curable metal anticorrosive paint provided by the invention has the advantages of no solvent evaporation, no pollution to the environment, no need of heating for curing, direct curing after spraying, high curing speed, low energy consumption, high efficiency, good flexibility, good adhesion force, excellent corrosion resistance and the like; meanwhile, by strictly controlling usage amounts of zinc and graphene, a good effect on corrosion prevention of metal is realized, corrosion of the metal can be slowed down, and cost is reduced; besides, a uniform passivation layer and a uniform corrosion inhibition layer are formed on the surface of the metal, so that corrosion of the whole coating is slowed down at the same time, and excellent water resistance, alkali resistance, artificial weathering aging resistance and corrosion resistance are given to the paint, therefore, the ultraviolet light curable metal anticorrosive paint is an ideal choice for temporary corrosion prevention of steel pipes produced by steel manufacturers.
Description
Technical field
The present invention relates to technical field of metal anti-corrosion, particularly relate to a kind of ultraviolet light polymerization metal anti-corrosive paint and preparation method thereof.
Background technology
Metallic substance damages by the effect of surrounding medium, is called metallic corrosion.The corrosion of metal is modal etch state.During corrosion, the interface of metal there occurs chemistry or electrochemistry heterogeneous reaction, make metal proceed to oxidation (ion) state.This significantly can reduce the mechanical property such as intensity, plasticity, toughness of metallic substance, destroy the geometrical shape of hardware, increase the wearing and tearing between part, worsen the physicals such as electricity and optics, in the work-ing life of shortening equipment, even cause the catastrophic failure such as fire, blast.The financial loss that U.S. 1975 causes because of metallic corrosion is 70,000,000,000 dollars, account for the 4.2%. of national economy total output value then according to statistics, the indirect loss such as stopping production, power failure that 10 ~ 20%. metallic corrosion accidents that the iron and steel loss of causing due to metallic corrosion every year accounts for output of steel then cause just more cannot calculate.Corrosion of metal phenomenon is very general.As ferrous products gets rusty (Fe
2o
3xH
2o), there is hickie (Al in aluminum products surface
2o
3), brass work surface produces verdigris [Cu
2(OH)
2cO
3], silverware surface stain (Ag
2s, Ag
2etc. O) all belong to metallic corrosion, the corrosion of the metal that wherein consumption is maximum---ferrous products is the most common.Meanwhile, corrosion also may become the obstacle of production development and scientific-technical progress.
Graphene is a kind of novel material of the individual layer sheet structure be made up of carbon atom.Be a kind ofly form with sp2 hybridized orbital the flat film that hexangle type is honeycomb lattice by carbon atom, only have the two-dimensional material of a carbon atom thickness.Graphene is the thinnest in the world is at present the hardest nano material also, and it is almost completely transparent, only absorbs the light of 2.3%; Thermal conductivity is up to 5300W/mK, and higher than carbon nanotube and diamond, under normal temperature, its electronic mobility is more than 15000cm2/Vs, again than CNT (carbon nano-tube) or silicon wafer height, and resistivity only about 10-6 Ω cm, than copper or silver lower, be the material that resistivity is minimum in the world at present.At present, also report that no matter Graphene is directly prepare on copper or nickel, or transfer on other metals, all can provide anti-corrosion protection.Copper coating cultivates single-layer graphene, adopts chemical Vapor deposition process, and slower than naked copper seven times of corrosion meeting, nickel coating cultivates multi-layer graphene, corrodes slower than naked nickel more than 20 times.Single-layer graphene has identical anti-corrosion protection effect, and just as conventional organic coating, but the latter wants thick more than five times.
Summary of the invention
The object of the invention is: a kind of ultraviolet light polymerization metal anti-corrosive paint is provided, there is solvent-free volatilization, environmentally safe, without the need to being heating and curing, spray complete namely curable, curing speed is fast, energy consumption is low, efficiency is high, snappiness is good, sticking power is good, the advantages such as antiseptic property is excellent, simultaneously, by strictly controlling the consumption of zinc and Graphene, good effect is played to the antirust of metal, metallic corrosion can be slowed down, reduce costs, form uniform passivation layer and corrosion-inhibiting layer in metallic surface simultaneously, make the synchronous inhibition of whole coating, and impart the water-fast of this coating excellence, alkaline-resisting and artificial weathering ageing resistance's antiseptic property, it is the interim anticorrosion desirable selection of iron and steel producer steel pipe.
The technical solution adopted for the present invention to solve the technical problems is:
A kind of ultraviolet light polymerization metal anti-corrosive paint, composed of the following components by mass percentage:
Light-cured resin 20-30%,
Photo-curing monomer 25-50%,
Adhesion promoter 0.1-5%,
Light trigger 5-10%,
Dispersion agent 0-2%,
Zinc powder 10-20%,
Graphene 25-30%.
Particularly, described light-cured resin is one or more in epoxy acrylate, urethane acrylate, polyester acrylate and acrylic resin.
Particularly, described photo-curing monomer is (methyl) acrylate of 1 ~ 6 official's energy.
As preferably, described photo-curing monomer be 1 ~ 3 official can (methyl) acrylate.
Photo-curing monomer is chosen as one or more in tri (propylene glycol) diacrylate, neopentylglycol diacrylate, 1,6 hexanediol diacrylate, hydroxyethyl methylacrylate, Viscoat 295.
Particularly, described dispersion agent is silicon class coupling agent or titanium system coupling agent.
Particularly; described light trigger adopts 1-hydroxy-cyclohexyl-phenyl ketone, 2; 4; 6-trimethyl benzoyl diphenyl base phosphine oxide, 2-hydroxy-2-methyl-1-phenyl-1-acetone, two (2; 4,6-trimethylbenzoyl)-phenyl phosphine oxide, 1-hydroxy-cyclohexan alkyl-phenyl ketone, one in 2-methyl isophthalic acid-[4-methylthio group phenyl]-2-morpholinyl-1-acetone.
Particularly, described adhesion promoter is titanate ester or alkyl phosphate class.
Particularly, described zinc powder is flake zinc powder, and the mean diameter of described zinc powder is 1-10 μm.
Particularly, described Graphene is graphene microchip powder, and the thickness of described graphene microchip powder is 1-10nm, and diameter is 5-10 μm.
A preparation method for ultraviolet light polymerization metal anti-corrosive paint, comprises the steps:
1) take the half of above-mentioned photo-curing monomer weight in container, add light-cured resin while stirring, then adhesion promoter, dispersion agent, zinc powder and Graphene mix 30 minutes;
2) then light trigger is dispersed in remaining photo-curing monomer, stirs 5 minutes;
3) by step 1) and step 2) liquid mixing that obtains, fully stir 10 minutes, obtain ultraviolet light polymerization metal anti-corrosive paint.
Embodiment
A preparation method for ultraviolet light polymerization metal anti-corrosive paint, comprises the steps:
1) take the half of above-mentioned photo-curing monomer weight in container, add light-cured resin while stirring, then adhesion promoter, dispersion agent, zinc powder and Graphene mix 30 minutes;
2) then light trigger is dispersed in remaining photo-curing monomer, stirs 5 minutes;
3) by step 1) and step 2) liquid mixing that obtains, fully stir 10 minutes, obtain ultraviolet light polymerization metal anti-corrosive paint.
The metallic paint general property that above-described embodiment 1 to embodiment 4 and comparative example 1 to comparative example 4 provide is tested according to GB/T 9755-2001:
With above-mentioned according to desirable embodiment of the present invention for enlightenment, by above-mentioned description, relevant staff in the scope not departing from this invention technological thought, can carry out various change and amendment completely.The technical scope of this invention is not limited to the content on specification sheets, must determine its technical scope according to right.
Claims (10)
1. a ultraviolet light polymerization metal anti-corrosive paint, composed of the following components by mass percentage:
Light-cured resin 20-30%,
Photo-curing monomer 25-50%,
Adhesion promoter 0.1-5%,
Light trigger 5-10%,
Dispersion agent 0-2%,
Zinc powder 10-20%,
Graphene 25-30%.
2. a kind of ultraviolet light polymerization metal anti-corrosive paint as claimed in claim 1, is characterized in that: described light-cured resin is one or more in epoxy acrylate, urethane acrylate, polyester acrylate and acrylic resin.
3. a kind of ultraviolet light polymerization metal anti-corrosive paint as claimed in claim 1, is characterized in that: described photo-curing monomer is (methyl) acrylate of 1 ~ 6 official's energy.
4. a kind of ultraviolet light polymerization metal anti-corrosive paint as claimed in claim 3, is characterized in that: described photo-curing monomer is (methyl) acrylate of 1 ~ 3 official's energy.
5. a kind of ultraviolet light polymerization metal anti-corrosive paint as claimed in claim 1, is characterized in that: described dispersion agent is silicon class coupling agent or titanium system coupling agent.
6. a kind of ultraviolet light polymerization metal anti-corrosive paint as claimed in claim 1; it is characterized in that: described light trigger adopts 1-hydroxy-cyclohexyl-phenyl ketone, 2; 4; 6-trimethyl benzoyl diphenyl base phosphine oxide, 2-hydroxy-2-methyl-1-phenyl-1-acetone, two (2; 4,6-trimethylbenzoyl)-phenyl phosphine oxide, 1-hydroxy-cyclohexan alkyl-phenyl ketone, one in 2-methyl isophthalic acid-[4-methylthio group phenyl]-2-morpholinyl-1-acetone.
7. a kind of ultraviolet light polymerization metal anti-corrosive paint as claimed in claim 1, is characterized in that: described adhesion promoter is titanate ester or alkyl phosphate class.
8. a kind of ultraviolet light polymerization metal anti-corrosive paint as claimed in claim 1, is characterized in that: described zinc powder is flake zinc powder, and the mean diameter of described zinc powder is 1-10 μm.
9. a kind of ultraviolet light polymerization metal anti-corrosive paint as claimed in claim 1, is characterized in that: described Graphene is graphene microchip powder, the thickness of described graphene microchip powder is 1-10nm, and diameter is 5-10 μm.
10. a preparation method for ultraviolet light polymerization metal anti-corrosive paint, comprises the steps:
1) take the half of above-mentioned photo-curing monomer weight in container, add light-cured resin while stirring, then adhesion promoter, dispersion agent, zinc powder and Graphene mix 30 minutes;
2) then light trigger is dispersed in remaining photo-curing monomer, stirs 5 minutes;
3) by step 1) and step 2) liquid mixing that obtains, fully stir 10 minutes, obtain ultraviolet light polymerization metal anti-corrosive paint.
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| CN201410682953.0A CN104371510A (en) | 2014-11-24 | 2014-11-24 | Ultraviolet light curable metal anticorrosive paint and preparation method thereof |
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| CN201410682953.0A CN104371510A (en) | 2014-11-24 | 2014-11-24 | Ultraviolet light curable metal anticorrosive paint and preparation method thereof |
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Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104877562A (en) * | 2015-05-15 | 2015-09-02 | 成都纳硕科技有限公司 | Ultraviolet curable high-performance anti-adhesive agent used in electronic field |
| CN104877568A (en) * | 2015-05-15 | 2015-09-02 | 成都纳硕科技有限公司 | Ultraviolet curable high-strippability anti-adhesive agent used in electronic field |
| CN104877546A (en) * | 2015-05-15 | 2015-09-02 | 成都纳硕科技有限公司 | Ultraviolet curing anti-corrosion anti-electrostatic coating for metal |
| CN104877550A (en) * | 2015-05-15 | 2015-09-02 | 成都纳硕科技有限公司 | Ultraviolet-curing composite antimicrobial anticorrosive paint for metals |
| CN104877529A (en) * | 2015-05-15 | 2015-09-02 | 成都纳硕科技有限公司 | Ultraviolet curable high-gloss environmental protection paint used for plastics |
| CN104877547A (en) * | 2015-05-15 | 2015-09-02 | 成都纳硕科技有限公司 | Ultraviolet-light curing antibacterial, antiseptic and antistatic coating for metals |
| CN104910721A (en) * | 2015-06-09 | 2015-09-16 | 成都纳硕科技有限公司 | Antirust ultraviolet-curing paint |
| CN104927628A (en) * | 2015-06-09 | 2015-09-23 | 成都纳硕科技有限公司 | Anti-aging UV curing coating |
| CN104927629A (en) * | 2015-06-09 | 2015-09-23 | 成都纳硕科技有限公司 | Wear-resistant fluorescent UV curing waterborne coating |
| CN104962150A (en) * | 2015-06-09 | 2015-10-07 | 成都纳硕科技有限公司 | Antirust UV-cured water-based paint |
| CN105086808A (en) * | 2015-07-30 | 2015-11-25 | 东莞英铭化工有限公司 | Anti-falling photocureable coating |
| CN105176326A (en) * | 2015-09-23 | 2015-12-23 | 常州大学 | Photocuring joint coating provided with graphene filler and preparing method thereof |
| CN105331275A (en) * | 2015-08-11 | 2016-02-17 | 国网山东省电力公司临沂供电公司 | Closed low-voltage distribution box |
| CN105440932A (en) * | 2015-08-11 | 2016-03-30 | 国网山东省电力公司临沂供电公司 | High-temperature-resistant corrosion-resistant power distribution box |
| CN106189418A (en) * | 2016-07-22 | 2016-12-07 | 长飞光纤光缆股份有限公司 | A kind of photocureable coating based on Graphene and preparation method thereof |
| CN107218449A (en) * | 2017-06-07 | 2017-09-29 | 江苏万奇电器集团有限公司 | A kind of pipe fitting with heat insulation function |
| CN108288085A (en) * | 2018-02-09 | 2018-07-17 | 黄唏 | Graphene slurry, preparation method and applications |
| CN108384406A (en) * | 2018-05-29 | 2018-08-10 | 四川理工学院 | A kind of graphene oxide UV is coating material solidified and preparation method thereof |
| CN110423496A (en) * | 2019-07-29 | 2019-11-08 | 湖南省金海科技有限公司 | Low-light curing and anticorrosive coating |
| CN110423542A (en) * | 2019-09-11 | 2019-11-08 | 中国科学院兰州化学物理研究所 | A kind of anticorrosive paint and the preparation method and application thereof |
| CN113770009A (en) * | 2021-09-14 | 2021-12-10 | 云南大泽电极科技股份有限公司 | Liquid level anticorrosion process for negative plate for electrolytic zinc |
| CN116396676A (en) * | 2023-04-24 | 2023-07-07 | 贵州航天风华精密设备有限公司 | Graphene high-hardness heavy-duty anticorrosive paint and preparation method thereof |
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Application publication date: 20150225 |