CN104371297A - Composite material for water quality monitoring sensor and preparation method thereof - Google Patents
Composite material for water quality monitoring sensor and preparation method thereof Download PDFInfo
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- CN104371297A CN104371297A CN201410662943.0A CN201410662943A CN104371297A CN 104371297 A CN104371297 A CN 104371297A CN 201410662943 A CN201410662943 A CN 201410662943A CN 104371297 A CN104371297 A CN 104371297A
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 51
- 238000012544 monitoring process Methods 0.000 title claims abstract description 50
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 239000002131 composite material Substances 0.000 title abstract 5
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 claims abstract description 66
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 33
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 33
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims abstract description 33
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 claims abstract description 33
- 229940082004 sodium laurate Drugs 0.000 claims abstract description 33
- 239000000843 powder Substances 0.000 claims abstract description 31
- 239000002994 raw material Substances 0.000 claims abstract description 24
- 239000011159 matrix material Substances 0.000 claims description 47
- 238000005453 pelletization Methods 0.000 claims description 10
- QXOXHPTYHCESTD-UHFFFAOYSA-N SBS Chemical compound SBS QXOXHPTYHCESTD-UHFFFAOYSA-N 0.000 claims description 9
- 239000000463 material Substances 0.000 abstract description 12
- 230000032683 aging Effects 0.000 abstract description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- -1 polyethylene terephthalate Polymers 0.000 abstract description 3
- 239000011787 zinc oxide Substances 0.000 abstract description 2
- 239000004417 polycarbonate Substances 0.000 abstract 2
- 229920000139 polyethylene terephthalate Polymers 0.000 abstract 2
- 239000005020 polyethylene terephthalate Substances 0.000 abstract 2
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 abstract 2
- 229910052982 molybdenum disulfide Inorganic materials 0.000 abstract 1
- 229920000515 polycarbonate Polymers 0.000 abstract 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 abstract 1
- 239000004810 polytetrafluoroethylene Substances 0.000 abstract 1
- 239000004065 semiconductor Substances 0.000 description 4
- 230000007812 deficiency Effects 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 1
- JBRZTFJDHDCESZ-UHFFFAOYSA-N AsGa Chemical compound [As]#[Ga] JBRZTFJDHDCESZ-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 description 1
- 229910002113 barium titanate Inorganic materials 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910052980 cadmium sulfide Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- WPYVAWXEWQSOGY-UHFFFAOYSA-N indium antimonide Chemical compound [Sb]#[In] WPYVAWXEWQSOGY-UHFFFAOYSA-N 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000005518 polymer electrolyte Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- OCGWQDWYSQAFTO-UHFFFAOYSA-N tellanylidenelead Chemical compound [Pb]=[Te] OCGWQDWYSQAFTO-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Investigating Or Analyzing Materials By The Use Of Fluid Adsorption Or Reactions (AREA)
Abstract
The invention relates to a composite material for a water quality monitoring sensor and a preparation method of the composite material, belonging to the field of materials. The composite material for water quality is prepared from the following raw materials in parts by mass: 20-30 parts of PC (polycarbonate), 12-25 parts of PET (polyethylene terephthalate), 8-15 parts of SBS (styrene butadiene styrene block copolymer), 15-26 parts of butyl acrylate, 5-12 parts of molybdenum disulfide, 6-18 parts of maleic anhydride, 14-26 parts of nano zinc oxide, 6-15 parts of polytetrafluoroethylene powder, 2-10 parts of sodium laurate and 3-10 parts of triethylene diamine. The composite material for the water quality monitoring sensor disclosed by the invention has excellent mechanical performances and excellent ageing resistance and corrosion resistance.
Description
Technical field
The invention belongs to Material Field, be specifically related to a kind of water quality monitoring (WQM) sensor matrix material and preparation method thereof.
Background technology
Sensor material divides semiconductor material, stupalith, metallic substance and organic materials four large class.Secondly semiconductor transducer material mainly silicon be germanium, gallium arsenide, indium antimonide, lead telluride, Cadmium Sulfide etc., temperature-sensitive quick mainly for the manufacture of power, the sensor such as photosensitive, magnetosensitive, ray are quick; Ceramic sensor material mainly contains ferric oxide, stannic oxide, zinc oxide, zirconium white, titanium oxide, aluminum oxide, barium titanate etc., for the manufacture of air-sensitive, wet sensitive, temperature-sensitive, infrared quick, the sensor such as ion is quick; The functional materials that metal is used as sensor is extensive not as semi-conductor and stupalith, and be mainly used in mechanical pick-up device and electromagnetic sensor, the material used has platinum, copper, aluminium, gold and silver, cobalt-base alloy etc.; Organic materials is used for sensor and is also in the development phase, the sensors such as the power that is mainly used in is quick, humidity, gas, ion, organic molecule, and material therefor has polymer electrolyte, moisture-absorption resin, polymeric membrane, organic semiconductor polyimidazole, enzyme membrane etc.Water quality monitoring (WQM) sensor material be a kind of very important can only material, there is the dual-use function of sensing and transmission, but existing water quality monitoring (WQM) sensor material erosion resistance and ageing resistance poor.
Therefore how to overcome the deficiencies in the prior art and become existing field technical barrier urgently to be resolved hurrily.
Summary of the invention
The object of the invention is to solve the deficiencies in the prior art, a kind of water quality monitoring (WQM) sensor matrix material and preparation method thereof is provided, this matrix material machinery superior performance, corrosion-resistant ageing-resistant.
The technical solution used in the present invention is as follows:
Water quality monitoring (WQM) sensor matrix material, comprises the following raw material according to mass fraction meter: PC 20-30 part, PET 12-25 part, SBS 8-15 part, butyl acrylate 15-26 part, molybdenumdisulphide 5-12 part, maleic anhydride 6-18 part, nano zine oxide 14-26 part, polytetrafluorethylepowder powder 6-15 part, sodium laurate 2-10 part, triethylene diamine 3-10 part.
Described water quality monitoring (WQM) sensor matrix material, comprises the following raw material according to mass fraction meter: PC 22-28 part, PET 14-21 part, SBS 9-13 part, butyl acrylate 18-23 part, molybdenumdisulphide 8-11 part, maleic anhydride 7-14 part, nano zine oxide 16-24 part, polytetrafluorethylepowder powder 8-13 part, sodium laurate 4-8 part, triethylene diamine 4-8 part.
Described water quality monitoring (WQM) sensor matrix material, comprises the following raw material according to mass fraction meter: PC 24-26 part, PET 16-19 part, SBS 10-11 part, butyl acrylate 20-21 part, molybdenumdisulphide 9-10 part, maleic anhydride 9-12 part, nano zine oxide 18-22 part, polytetrafluorethylepowder powder 9-11 part, sodium laurate 5-7 part, triethylene diamine 5-7 part.
Described water quality monitoring (WQM) sensor matrix material, comprises the following raw material according to mass fraction meter: PC 22 parts, PET 14 parts, SBS 9 parts, butyl acrylate 18 parts, molybdenumdisulphide 8 parts, maleic anhydride 7 parts, nano zine oxide 16 parts, polytetrafluorethylepowder powder 8 parts, sodium laurate 4 parts, triethylene diamine 4 parts.
Described water quality monitoring (WQM) sensor matrix material, comprises the following raw material according to mass fraction meter: PC 28 parts, PET 21 parts, SBS 13 parts, butyl acrylate 23 parts, molybdenumdisulphide 11 parts, maleic anhydride 14 parts, nano zine oxide 24 parts, polytetrafluorethylepowder powder 13 parts, sodium laurate 8 parts, triethylene diamine 8 parts.
Described water quality monitoring (WQM) sensor matrix material, comprises the following raw material according to mass fraction meter: PC 24 parts, PET 16 parts, SBS 10 parts, butyl acrylate 20 parts, molybdenumdisulphide 9 parts, maleic anhydride 9 parts, nano zine oxide 18 parts, polytetrafluorethylepowder powder 9 parts, sodium laurate 5 parts, triethylene diamine 5 parts.
Described water quality monitoring (WQM) sensor matrix material, comprises the following raw material according to mass fraction meter: PC 26 parts, PET 19 parts, SBS 11 parts, butyl acrylate 21 parts, molybdenumdisulphide 10 parts, maleic anhydride 12 parts, nano zine oxide 22 parts, polytetrafluorethylepowder powder 11 parts, sodium laurate 7 parts, triethylene diamine 7 parts.
The preparation method of described water quality monitoring (WQM) sensor matrix material, comprise the steps: according to quality proportioning, PC, PET, SBS, butyl acrylate, molybdenumdisulphide, maleic anhydride, nano zine oxide, polytetrafluorethylepowder powder, sodium laurate and triethylene diamine are mixed, be placed in forcing machine, extruding pelletization at 190-210 DEG C, obtains described water quality monitoring (WQM) sensor matrix material.
compared with prior art, its beneficial effect is in the present invention:
Matrix material of the present invention has excellent mechanical property, and has excellent ageing-resistant performance and corrosion resistance nature; In addition, the present invention compared with traditional sensor material, Environmental Safety, environmentally friendly; Preparation method of the present invention is simple, easy and simple to handle, can promote the use of on a large scale.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail, the raw material used in the present invention unless otherwise noted, all by commercial acquisition.
embodiment 1
Water quality monitoring (WQM) sensor matrix material, comprises the following raw material according to mass fraction meter: PC 20 parts, PET 12 parts, SBS 8 parts, butyl acrylate 15 parts, molybdenumdisulphide 5 parts, maleic anhydride 6 parts, nano zine oxide 14 parts, polytetrafluorethylepowder powder 6 parts, sodium laurate 2 parts, triethylene diamine 3 parts.
The preparation method of described water quality monitoring (WQM) sensor matrix material, comprise the steps: according to quality proportioning, PC, PET, SBS, butyl acrylate, molybdenumdisulphide, maleic anhydride, nano zine oxide, polytetrafluorethylepowder powder, sodium laurate and triethylene diamine are mixed, be placed in forcing machine, extruding pelletization at 190 DEG C, obtains described water quality monitoring (WQM) sensor matrix material.
embodiment 2
Water quality monitoring (WQM) sensor matrix material, comprises the following raw material according to mass fraction meter: PC 30 parts, PET 25 parts, SBS 15 parts, butyl acrylate 26 parts, molybdenumdisulphide 12 parts, maleic anhydride 18 parts, nano zine oxide 26 parts, polytetrafluorethylepowder powder 15 parts, sodium laurate 10 parts, triethylene diamine 10 parts.
The preparation method of described water quality monitoring (WQM) sensor matrix material, comprise the steps: according to quality proportioning, PC, PET, SBS, butyl acrylate, molybdenumdisulphide, maleic anhydride, nano zine oxide, polytetrafluorethylepowder powder, sodium laurate and triethylene diamine are mixed, be placed in forcing machine, extruding pelletization at 210 DEG C, obtains described water quality monitoring (WQM) sensor matrix material.
embodiment 3
Water quality monitoring (WQM) sensor matrix material, comprises the following raw material according to mass fraction meter: PC 22 parts, PET 14 parts, SBS 9 parts, butyl acrylate 18 parts, molybdenumdisulphide 8 parts, maleic anhydride 7 parts, nano zine oxide 16 parts, polytetrafluorethylepowder powder 8 parts, sodium laurate 4 parts, triethylene diamine 4 parts.
The preparation method of described water quality monitoring (WQM) sensor matrix material, comprise the steps: according to quality proportioning, PC, PET, SBS, butyl acrylate, molybdenumdisulphide, maleic anhydride, nano zine oxide, polytetrafluorethylepowder powder, sodium laurate and triethylene diamine are mixed, be placed in forcing machine, extruding pelletization at 200 DEG C, obtains described water quality monitoring (WQM) sensor matrix material.
embodiment 4
Water quality monitoring (WQM) sensor matrix material, comprises the following raw material according to mass fraction meter: PC 28 parts, PET 21 parts, SBS 13 parts, butyl acrylate 23 parts, molybdenumdisulphide 11 parts, maleic anhydride 14 parts, nano zine oxide 24 parts, polytetrafluorethylepowder powder 13 parts, sodium laurate 8 parts, triethylene diamine 8 parts.
The preparation method of described water quality monitoring (WQM) sensor matrix material, comprise the steps: according to quality proportioning, PC, PET, SBS, butyl acrylate, molybdenumdisulphide, maleic anhydride, nano zine oxide, polytetrafluorethylepowder powder, sodium laurate and triethylene diamine are mixed, be placed in forcing machine, extruding pelletization at 195 DEG C, obtains described water quality monitoring (WQM) sensor matrix material.
embodiment 5
Water quality monitoring (WQM) sensor matrix material, comprises the following raw material according to mass fraction meter: PC 24 parts, PET 16 parts, SBS 10 parts, butyl acrylate 20 parts, molybdenumdisulphide 9 parts, maleic anhydride 9 parts, nano zine oxide 18 parts, polytetrafluorethylepowder powder 9 parts, sodium laurate 5 parts, triethylene diamine 5 parts.
The preparation method of described water quality monitoring (WQM) sensor matrix material, comprise the steps: according to quality proportioning, PC, PET, SBS, butyl acrylate, molybdenumdisulphide, maleic anhydride, nano zine oxide, polytetrafluorethylepowder powder, sodium laurate and triethylene diamine are mixed, be placed in forcing machine, extruding pelletization at 205 DEG C, obtains described water quality monitoring (WQM) sensor matrix material.
embodiment 6
Water quality monitoring (WQM) sensor matrix material, comprises the following raw material according to mass fraction meter: PC 26 parts, PET 19 parts, SBS 11 parts, butyl acrylate 21 parts, molybdenumdisulphide 10 parts, maleic anhydride 12 parts, nano zine oxide 22 parts, polytetrafluorethylepowder powder 11 parts, sodium laurate 7 parts, triethylene diamine 7 parts.
The preparation method of described water quality monitoring (WQM) sensor matrix material, comprise the steps: according to quality proportioning, PC, PET, SBS, butyl acrylate, molybdenumdisulphide, maleic anhydride, nano zine oxide, polytetrafluorethylepowder powder, sodium laurate and triethylene diamine are mixed, be placed in forcing machine, extruding pelletization at 208 DEG C, obtains described water quality monitoring (WQM) sensor matrix material.
reference examples 1
Water quality monitoring (WQM) sensor matrix material, comprises the following raw material according to mass fraction meter: PC 22 parts, PET 14 parts, SBS 9 parts, butyl acrylate 18 parts, molybdenumdisulphide 8 parts, maleic anhydride 7 parts, nano zine oxide 16 parts, sodium laurate 4 parts, triethylene diamine 4 parts.
The preparation method of described water quality monitoring (WQM) sensor matrix material, comprise the steps: according to quality proportioning, PC, PET, SBS, butyl acrylate, molybdenumdisulphide, maleic anhydride, nano zine oxide, sodium laurate and triethylene diamine are mixed, be placed in forcing machine, extruding pelletization at 200 DEG C, obtains described water quality monitoring (WQM) sensor matrix material.
reference examples 2
Water quality monitoring (WQM) sensor matrix material, comprises the following raw material according to mass fraction meter: PC 22 parts, PET 14 parts, butyl acrylate 18 parts, molybdenumdisulphide 8 parts, maleic anhydride 7 parts, nano zine oxide 16 parts, polytetrafluorethylepowder powder 8 parts, sodium laurate 4 parts, triethylene diamine 4 parts.
The preparation method of described water quality monitoring (WQM) sensor matrix material, comprise the steps: according to quality proportioning, PC, PET, butyl acrylate, molybdenumdisulphide, maleic anhydride, nano zine oxide, polytetrafluorethylepowder powder, sodium laurate and triethylene diamine are mixed, be placed in forcing machine, extruding pelletization at 200 DEG C, obtains described water quality monitoring (WQM) sensor matrix material.
performance test
The test embodiment of the present invention 1 to 6 and reference examples 1 to 2 products obtained therefrom, test result sees the following form 1.
Table 1 product performance test data
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Reference examples 1 | Reference examples 2 | |
| Heat-drawn wire (1.8MPa), DEG C | 198 | 200 | 205 | 203 | 202 | 199 | 100 | 105 |
| Flexural strength, MPa | 150 | 152 | 155 | 154 | 153 | 153 | 60 | 70 |
| Erosion resistance | Excellent | Excellent | Excellent | Excellent | Excellent | Excellent | Difference | Difference |
| Ageing resistance | Excellent | Excellent | Excellent | Excellent | Excellent | Excellent | Difference | Difference |
| Tensile strength, MPa | 326 | 335 | 336 | 328 | 329 | 328 | 124 | 123 |
The embodiment of the present invention 1 to 6 gained finished product all has excellent performance, and wherein, embodiment 3 can be considered most preferred embodiment.
Claims (8)
1. water quality monitoring (WQM) sensor matrix material, it is characterized in that, comprise the following raw material according to mass fraction meter: PC 20-30 part, PET 12-25 part, SBS 8-15 part, butyl acrylate 15-26 part, molybdenumdisulphide 5-12 part, maleic anhydride 6-18 part, nano zine oxide 14-26 part, polytetrafluorethylepowder powder 6-15 part, sodium laurate 2-10 part, triethylene diamine 3-10 part.
2. the water quality monitoring (WQM) sensor matrix material according to claims 1, it is characterized in that, comprise the following raw material according to mass fraction meter: PC 22-28 part, PET 14-21 part, SBS 9-13 part, butyl acrylate 18-23 part, molybdenumdisulphide 8-11 part, maleic anhydride 7-14 part, nano zine oxide 16-24 part, polytetrafluorethylepowder powder 8-13 part, sodium laurate 4-8 part, triethylene diamine 4-8 part.
3. the water quality monitoring (WQM) sensor matrix material according to claims 1, it is characterized in that, comprise the following raw material according to mass fraction meter: PC 24-26 part, PET 16-19 part, SBS 10-11 part, butyl acrylate 20-21 part, molybdenumdisulphide 9-10 part, maleic anhydride 9-12 part, nano zine oxide 18-22 part, polytetrafluorethylepowder powder 9-11 part, sodium laurate 5-7 part, triethylene diamine 5-7 part.
4. the water quality monitoring (WQM) sensor matrix material according to claims 1, it is characterized in that, comprise the following raw material according to mass fraction meter: PC 22 parts, PET 14 parts, SBS 9 parts, butyl acrylate 18 parts, molybdenumdisulphide 8 parts, maleic anhydride 7 parts, nano zine oxide 16 parts, polytetrafluorethylepowder powder 8 parts, sodium laurate 4 parts, triethylene diamine 4 parts.
5. the water quality monitoring (WQM) sensor matrix material according to claims 1, it is characterized in that, comprise the following raw material according to mass fraction meter: PC 28 parts, PET 21 parts, SBS 13 parts, butyl acrylate 23 parts, molybdenumdisulphide 11 parts, maleic anhydride 14 parts, nano zine oxide 24 parts, polytetrafluorethylepowder powder 13 parts, sodium laurate 8 parts, triethylene diamine 8 parts.
6. the water quality monitoring (WQM) sensor matrix material according to claims 1, it is characterized in that, comprise the following raw material according to mass fraction meter: PC 24 parts, PET 16 parts, SBS 10 parts, butyl acrylate 20 parts, molybdenumdisulphide 9 parts, maleic anhydride 9 parts, nano zine oxide 18 parts, polytetrafluorethylepowder powder 9 parts, sodium laurate 5 parts, triethylene diamine 5 parts.
7. the water quality monitoring (WQM) sensor matrix material according to claims 1, it is characterized in that, comprise the following raw material according to mass fraction meter: PC 26 parts, PET 19 parts, SBS 11 parts, butyl acrylate 21 parts, molybdenumdisulphide 10 parts, maleic anhydride 12 parts, nano zine oxide 22 parts, polytetrafluorethylepowder powder 11 parts, sodium laurate 7 parts, triethylene diamine 7 parts.
8. the preparation method of the water quality monitoring (WQM) sensor matrix material described in claims 1, it is characterized in that, comprise the steps: according to quality proportioning, PC, PET, SBS, butyl acrylate, molybdenumdisulphide, maleic anhydride, nano zine oxide, polytetrafluorethylepowder powder, sodium laurate and triethylene diamine are mixed, be placed in forcing machine, extruding pelletization at 190-210 DEG C, obtains described water quality monitoring (WQM) sensor matrix material.
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| CN201410662943.0A CN104371297B (en) | 2014-11-19 | 2014-11-19 | Water quality monitoring sensor composite and preparation method thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101160356A (en) * | 2005-04-14 | 2008-04-09 | 通用电气公司 | Thermoplastic blends and articles made therefrom |
| CN101245160A (en) * | 2008-03-11 | 2008-08-20 | 四川大学 | Fire retardant thermoplastic resin composition and manufacture method thereof |
| CN102352095A (en) * | 2003-12-30 | 2012-02-15 | 沙伯基础创新塑料知识产权有限公司 | Polymer compositions, method of manufacture, and articles formed therefrom |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102352095A (en) * | 2003-12-30 | 2012-02-15 | 沙伯基础创新塑料知识产权有限公司 | Polymer compositions, method of manufacture, and articles formed therefrom |
| CN101160356A (en) * | 2005-04-14 | 2008-04-09 | 通用电气公司 | Thermoplastic blends and articles made therefrom |
| CN101245160A (en) * | 2008-03-11 | 2008-08-20 | 四川大学 | Fire retardant thermoplastic resin composition and manufacture method thereof |
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