CN104371290A - Environment-friendly composite biological high polymer material and preparation method thereof - Google Patents
Environment-friendly composite biological high polymer material and preparation method thereof Download PDFInfo
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- CN104371290A CN104371290A CN201410641250.3A CN201410641250A CN104371290A CN 104371290 A CN104371290 A CN 104371290A CN 201410641250 A CN201410641250 A CN 201410641250A CN 104371290 A CN104371290 A CN 104371290A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- 239000002861 polymer material Substances 0.000 title abstract description 14
- 239000002131 composite material Substances 0.000 title abstract description 4
- 239000000463 material Substances 0.000 claims abstract description 53
- 229920002472 Starch Polymers 0.000 claims abstract description 23
- 239000008107 starch Substances 0.000 claims abstract description 23
- 235000019698 starch Nutrition 0.000 claims abstract description 23
- 108010039918 Polylysine Proteins 0.000 claims abstract description 22
- 229920000858 Cyclodextrin Polymers 0.000 claims abstract description 21
- 239000001116 FEMA 4028 Substances 0.000 claims abstract description 21
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 21
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 claims abstract description 21
- 235000011175 beta-cyclodextrine Nutrition 0.000 claims abstract description 21
- 229960004853 betadex Drugs 0.000 claims abstract description 21
- 229920000747 poly(lactic acid) Polymers 0.000 claims abstract description 21
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 21
- 229920001221 xylan Polymers 0.000 claims abstract description 21
- 150000004823 xylans Chemical class 0.000 claims abstract description 21
- 238000003756 stirring Methods 0.000 claims abstract description 18
- 239000000203 mixture Substances 0.000 claims abstract description 15
- -1 Poly(lactic acid) Polymers 0.000 claims description 58
- 150000001875 compounds Chemical class 0.000 claims description 47
- 238000002156 mixing Methods 0.000 claims description 20
- OBNCKNCVKJNDBV-UHFFFAOYSA-N ethyl butyrate Chemical compound CCCC(=O)OCC OBNCKNCVKJNDBV-UHFFFAOYSA-N 0.000 claims description 19
- GUOCOOQWZHQBJI-UHFFFAOYSA-N 4-oct-7-enoxy-4-oxobutanoic acid Chemical compound OC(=O)CCC(=O)OCCCCCCC=C GUOCOOQWZHQBJI-UHFFFAOYSA-N 0.000 abstract 2
- 229920001612 Hydroxyethyl starch Polymers 0.000 abstract 2
- 229940050526 hydroxyethylstarch Drugs 0.000 abstract 2
- 239000004626 polylactic acid Substances 0.000 abstract 2
- 238000001125 extrusion Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 5
- 229920002988 biodegradable polymer Polymers 0.000 description 3
- 239000004621 biodegradable polymer Substances 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 2
- 230000000875 corresponding effect Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 229920002101 Chitin Polymers 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000012620 biological material Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000003248 secreting effect Effects 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Biological Depolymerization Polymers (AREA)
Abstract
Description
The degradable time (my god) | Tensile strength (MPa) | Elongation at break (%) | |
Embodiment 1 | 53 | 25.1 | 202 |
Embodiment 2 | 53 | 23.5 | 193 |
Embodiment 3 | 48 | 29.6 | 225 |
Embodiment 4 | 49 | 30.4 | 211 |
Embodiment 5 | 45 | 39.5 | 274 |
Comparative example | 56 | 14.1 | 167 |
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410641250.3A CN104371290B (en) | 2014-11-14 | 2014-11-14 | A kind of environment-friendly type compound bio macromolecular material and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410641250.3A CN104371290B (en) | 2014-11-14 | 2014-11-14 | A kind of environment-friendly type compound bio macromolecular material and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104371290A true CN104371290A (en) | 2015-02-25 |
CN104371290B CN104371290B (en) | 2016-08-17 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201410641250.3A Expired - Fee Related CN104371290B (en) | 2014-11-14 | 2014-11-14 | A kind of environment-friendly type compound bio macromolecular material and preparation method thereof |
Country Status (1)
Country | Link |
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CN (1) | CN104371290B (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103756273A (en) * | 2013-12-27 | 2014-04-30 | 吴江市东泰电力特种开关有限公司 | Environment-friendly and degradable dust-proof thin film and preparation method thereof |
CN106280342A (en) * | 2016-08-30 | 2017-01-04 | 胡何辉 | A kind of PP composite material being applicable to medical infusion bags and preparation method thereof |
CN106496848A (en) * | 2016-11-01 | 2017-03-15 | 金福兴 | A kind of composite resin medical infusion bags material and preparation method thereof |
CN107236153A (en) * | 2017-06-29 | 2017-10-10 | 苏州凌科特新材料有限公司 | A kind of high-strength biodegradable starch-resin and preparation method thereof |
CN107266927A (en) * | 2017-05-06 | 2017-10-20 | 北京敬科技有限公司 | High degradable type high polymer material of a kind of mechanical performance and preparation method thereof |
CN112048102A (en) * | 2020-09-14 | 2020-12-08 | 谢强 | Environment-friendly food packaging plastic and preparation method thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100119417A1 (en) * | 2008-11-10 | 2010-05-13 | Biotix, Inc. | Degradable fluid handling devices |
CN101948598A (en) * | 2010-02-02 | 2011-01-19 | 广东上九生物降解塑料有限公司 | Method for preparing biodegradable membrane |
CN102219933A (en) * | 2011-05-10 | 2011-10-19 | 黄姜 | Process for manufacturing dining-table ornaments by starch based fully-degradable plastics |
CN102516605A (en) * | 2011-12-02 | 2012-06-27 | 李哲 | Antibacterial degradable film and manufacturing method and application thereof |
CN103951919A (en) * | 2014-04-09 | 2014-07-30 | 中国科学院宁波材料技术与工程研究所 | Polyvinyl alcohol composite master batch and preparation method thereof |
-
2014
- 2014-11-14 CN CN201410641250.3A patent/CN104371290B/en not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100119417A1 (en) * | 2008-11-10 | 2010-05-13 | Biotix, Inc. | Degradable fluid handling devices |
CN101948598A (en) * | 2010-02-02 | 2011-01-19 | 广东上九生物降解塑料有限公司 | Method for preparing biodegradable membrane |
CN102219933A (en) * | 2011-05-10 | 2011-10-19 | 黄姜 | Process for manufacturing dining-table ornaments by starch based fully-degradable plastics |
CN102516605A (en) * | 2011-12-02 | 2012-06-27 | 李哲 | Antibacterial degradable film and manufacturing method and application thereof |
CN103951919A (en) * | 2014-04-09 | 2014-07-30 | 中国科学院宁波材料技术与工程研究所 | Polyvinyl alcohol composite master batch and preparation method thereof |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103756273A (en) * | 2013-12-27 | 2014-04-30 | 吴江市东泰电力特种开关有限公司 | Environment-friendly and degradable dust-proof thin film and preparation method thereof |
CN103756273B (en) * | 2013-12-27 | 2016-03-23 | 吴江市东泰电力特种开关有限公司 | A kind of environment-friendly degradable antirust film and preparation method thereof |
CN106280342A (en) * | 2016-08-30 | 2017-01-04 | 胡何辉 | A kind of PP composite material being applicable to medical infusion bags and preparation method thereof |
CN106496848A (en) * | 2016-11-01 | 2017-03-15 | 金福兴 | A kind of composite resin medical infusion bags material and preparation method thereof |
CN107266927A (en) * | 2017-05-06 | 2017-10-20 | 北京敬科技有限公司 | High degradable type high polymer material of a kind of mechanical performance and preparation method thereof |
CN107236153A (en) * | 2017-06-29 | 2017-10-10 | 苏州凌科特新材料有限公司 | A kind of high-strength biodegradable starch-resin and preparation method thereof |
CN112048102A (en) * | 2020-09-14 | 2020-12-08 | 谢强 | Environment-friendly food packaging plastic and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
CN104371290B (en) | 2016-08-17 |
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C41 | Transfer of patent application or patent right or utility model | ||
CB03 | Change of inventor or designer information |
Inventor after: Li Qinqin Inventor before: Jin Zhongen Inventor before: Quan Chunlan Inventor before: Zhang Fan |
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COR | Change of bibliographic data | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20160307 Address after: 510640 Tianhe District, Guangzhou, No. five mountain road, 371-1, building No. 715, unit Applicant after: Guangdong Huabo Enterprise Management Consulting Co., Ltd. Address before: 215163 Suzhou province high tech Zone Longshan Road, No. 10, Jiangsu Applicant before: Suzhou Koumei New Material Co., Ltd. |
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C41 | Transfer of patent application or patent right or utility model | ||
CB03 | Change of inventor or designer information |
Inventor after: Lin Yumao Inventor before: Li Qinqin |
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TA01 | Transfer of patent application right |
Effective date of registration: 20160630 Address after: 518133 Guangdong city of Shenzhen province Baoan District City West Coast Garden District 48 Plaza Pavilion 4-7B Applicant after: Lin Yumao Address before: 510640 Tianhe District, Guangzhou, No. five mountain road, 371-1, building No. 715, unit Applicant before: Guangdong Huabo Enterprise Management Consulting Co., Ltd. |
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CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160817 Termination date: 20171114 |
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CF01 | Termination of patent right due to non-payment of annual fee |