CN104370533B - A kind of low cost ceramic cutter material and preparation method thereof - Google Patents
A kind of low cost ceramic cutter material and preparation method thereof Download PDFInfo
- Publication number
- CN104370533B CN104370533B CN201410580581.0A CN201410580581A CN104370533B CN 104370533 B CN104370533 B CN 104370533B CN 201410580581 A CN201410580581 A CN 201410580581A CN 104370533 B CN104370533 B CN 104370533B
- Authority
- CN
- China
- Prior art keywords
- mesh sieves
- add
- pottery
- oxide
- minute
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000463 material Substances 0.000 title claims abstract description 19
- 239000000919 ceramic Substances 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 47
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 13
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 13
- -1 polyoxyethylene Polymers 0.000 claims abstract description 13
- 239000008367 deionised water Substances 0.000 claims abstract description 10
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 10
- 239000000843 powder Substances 0.000 claims abstract description 9
- 239000010453 quartz Substances 0.000 claims abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002699 waste material Substances 0.000 claims abstract description 9
- 229920002125 Sokalan® Polymers 0.000 claims abstract description 7
- 229910052810 boron oxide Inorganic materials 0.000 claims abstract description 7
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 7
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 7
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 7
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004584 polyacrylic acid Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 239000002245 particle Substances 0.000 claims description 15
- 238000000498 ball milling Methods 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 238000007731 hot pressing Methods 0.000 claims description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 6
- 239000005995 Aluminium silicate Substances 0.000 claims description 6
- 239000004160 Ammonium persulphate Substances 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- 235000012211 aluminium silicate Nutrition 0.000 claims description 6
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 6
- 235000019395 ammonium persulphate Nutrition 0.000 claims description 6
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 6
- 239000000292 calcium oxide Substances 0.000 claims description 6
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 6
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 6
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 6
- 239000000347 magnesium hydroxide Substances 0.000 claims description 6
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 6
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 102000004160 Phosphoric Monoester Hydrolases Human genes 0.000 claims description 3
- 108090000608 Phosphoric Monoester Hydrolases Proteins 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims description 3
- 239000002105 nanoparticle Substances 0.000 claims description 3
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 3
- 229910000166 zirconium phosphate Inorganic materials 0.000 claims description 3
- LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 claims description 3
- 229910004261 CaF 2 Inorganic materials 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 abstract description 3
- 229910001634 calcium fluoride Inorganic materials 0.000 abstract description 3
- 229910052594 sapphire Inorganic materials 0.000 abstract description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910003465 moissanite Inorganic materials 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/10—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/62204—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/632—Organic additives
- C04B35/634—Polymers
- C04B35/63404—Polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B35/63424—Polyacrylates; Polymethacrylates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/632—Organic additives
- C04B35/634—Polymers
- C04B35/63448—Polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B35/63488—Polyethers, e.g. alkylphenol polyglycolether, polyethylene glycol [PEG], polyethylene oxide [PEO]
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/38—Non-oxide ceramic constituents or additives
- C04B2235/3817—Carbides
- C04B2235/3826—Silicon carbides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/38—Non-oxide ceramic constituents or additives
- C04B2235/3817—Carbides
- C04B2235/3839—Refractory metal carbides
- C04B2235/3847—Tungsten carbides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
- C04B2235/9607—Thermal properties, e.g. thermal expansion coefficient
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
- C04B2235/963—Surface properties, e.g. surface roughness
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
Does is a kind of low cost ceramic cutter material, made up of the raw material of following weight part: water reducer 0.6-0.7, magnesium oxide 2.6-3, boron oxide 2-3, waste quartz crucible powder 10-15, α-Al2O3? 75-80, SiC6-8, WC3-4, CaF2? 2-3, deionized water are appropriate, polyacrylic acid 1-1.4, polyoxyethylene glycol 0.7-1.2, ethylene glycol are appropriate, antiwear assistant 3-4; Pottery of the present invention is by adding waste quartz crucible powder, while reducing cost, add the thermotolerance of pottery, by adding CaF2, add the oilness of pottery, this pottery possesses high antifriction and high-wear resistance, can be used for making cutting tool and anti-friction wear-resistant structure, cost is low, long service life; The antiwear assistant of the application of the invention, can increase the surface smoothness of pottery, wear resistance and thermotolerance.
Description
Technical field
The present invention relates to ceramic cutter material field, particularly relate to a kind of low cost ceramic cutter material and preparation method thereof.
Background technology
Ceramic cutting-tool has possessed high rigidity, high-density, high temperature resistant, the features such as diamagneticization, anti-oxidant, erosion resistance is strong, chemical stability is good, high-wearing feature, be the substitute that traditional cutting tools such as rapid steel are good, solve the problem of the scarcity of resources such as molybdenum, nickel.But it is higher that current ceramic cutting material still exists cost, the problems such as toughness is inadequate, fragility is large, hardness is uneven, poor radiation, self lubricity are bad, need to solve.
Summary of the invention
The object of the present invention is to provide a kind of low cost ceramic cutter material and preparation method thereof, this ceramic heat resistant is good, and oilness is good, possess high antifriction and high-wear resistance, can be used for making cutting tool and anti-friction wear-resistant structure, cost is low, long service life.
Technical scheme of the present invention is as follows:
A kind of low cost ceramic cutter material, is characterized in that being made up of the raw material of following weight part: water reducer 0.6-0.7, magnesium oxide 2.6-3, boron oxide 2-3, waste quartz crucible powder 10-15, α-Al2O375-80, SiC6-8, WC3-4, CaF22-3, deionized water is appropriate, polyacrylic acid 1-1.4, polyoxyethylene glycol 0.7-1.2, ethylene glycol are appropriate, antiwear assistant 3-4;
Described antiwear assistant is made up of the raw material of following weight part: nano-graphite 0.3-0.5, zirconium phosphate 1-1.3, nano zircite 1-1.3, calcium oxide 0.4-0.5, magnesium hydroxide 0.4-0.6, phosphatase 11-2, molybdenumdisulphide 1-2, aluminum oxide 2-3, kaolin 0.4-0.8, acrylate 1-2, ammonium persulphate 0.2-0.3, nano-sized carbon 0.7-0.9, water 10-12, polyoxyethylene glycol 0.4-0.6; Preparation method is: acrylate, polyoxyethylene glycol are added to the water, stir, then adds calcium oxide, magnesium hydroxide, phosphoric acid, aluminum oxide, kaolin, ammonium persulphate, be heated to 70-80 DEG C, stirring reaction 20-30 minute, then add other remaining components, stir 10-20 minute, ultrasonic disperse 6-8 minute, filter, dry, pulverize, cross 40 mesh sieves, under nitrogen atmosphere, at 1380-1440 DEG C, calcine 30-40 minute, pulverize, cross 40 mesh sieves, to obtain final product.
The preparation method of described low cost ceramic cutter material, is characterized in that comprising the following steps:
(1) by waste quartz crucible powder, magnesium oxide mixing, ball milling, crosses 300 mesh sieves, obtains particle;
(2) by boron oxide, α-Al2O3, SiC, WC mixing, ball milling, crosses 250 mesh sieves, obtains particle;
(3) water reducer, CaF are mixed with the particle that first two steps obtain, add the ethylene glycol of the deionized water of 23-28% weight part, 3-5% weight part, be mixed into pureed, send into ball milling 2-3 in ball mill individual hour, dry, send in calcining furnace, 1-2 hour is calcined at 800-900 DEG C, take out and pulverize, cross 200 mesh sieves, obtain particle;
(4) particle that (3) step obtains is mixed with other remaining components, get the deionized water of 3-4 times of weight part of mixing material, add polyacrylic acid, polyoxyethylene glycol, stir, add mixing material, ball milling 2-3 hour, dries at 110-120 DEG C, crosses 40 mesh sieves, hot pressing at 1680-1740 DEG C, hot pressing pressure is 25-30MPa, and hot pressing time is 40-45 minute, to obtain final product.
Beneficial effect of the present invention
Pottery of the present invention is by adding waste quartz crucible powder, while reducing cost, add the thermotolerance of pottery, by adding CaF2, add the oilness of pottery, this pottery possesses high antifriction and high-wear resistance, can be used for making cutting tool and anti-friction wear-resistant structure, cost is low, long service life; The antiwear assistant of the application of the invention, can increase the surface smoothness of pottery, wear resistance and thermotolerance.
Embodiment
A kind of low cost ceramic cutter material, is made up of the raw material of following weight part (kilogram): water reducer 0.6, magnesium oxide 2.8, boron oxide 2.5, waste quartz crucible powder 13, α-Al2O378, SiC7, WC3.5, CaF22.5, deionized water is appropriate, polyacrylic acid 1.2, polyoxyethylene glycol 0.9, ethylene glycol are appropriate, antiwear assistant 3.5;
Described antiwear assistant is made up of the raw material of following weight part (kilogram): nano-graphite 0.4, zirconium phosphate 1.2, nano zircite 1.2, calcium oxide 0.5, magnesium hydroxide 0.5, phosphatase 11 .5, molybdenumdisulphide 1.5, aluminum oxide 2.5, kaolin 0.6, acrylate 1.5, ammonium persulphate 0.2, nano-sized carbon 0.8, water 11, polyoxyethylene glycol 0.5; Preparation method is: acrylate, polyoxyethylene glycol are added to the water, stir, then adds calcium oxide, magnesium hydroxide, phosphoric acid, aluminum oxide, kaolin, ammonium persulphate, be heated to 75 DEG C, stirring reaction 25 minutes, then add other remaining components, stir 15 minutes, ultrasonic disperse 7 minutes, filter, dry, pulverize, cross 40 mesh sieves, under nitrogen atmosphere, calcine 35 minutes at 1400 DEG C, pulverize, cross 40 mesh sieves, to obtain final product.
The preparation method of described low cost ceramic cutter material, comprises the following steps:
(1) by waste quartz crucible powder, magnesium oxide mixing, ball milling, crosses 300 mesh sieves, obtains particle;
(2) by boron oxide, α-Al2O3, SiC, WC mixing, ball milling, crosses 250 mesh sieves, obtains particle;
(3) water reducer, CaF are mixed with the particle that first two steps obtain, add the ethylene glycol of the deionized water of 25% weight part, 4% weight part, be mixed into pureed, in feeding ball mill, ball milling 2.5 hours, dry, sends in calcining furnace, calcine 1.5 hours at 850 DEG C, take out and pulverize, cross 200 mesh sieves, obtain particle;
(4) particle that (3) step obtains is mixed with other remaining components, get the deionized water of 3.5 times of weight parts of mixing material, add polyacrylic acid, polyoxyethylene glycol, stir, add mixing material, ball milling 2.5 hours, dries at 115 DEG C, crosses 40 mesh sieves, hot pressing at 1700 DEG C, hot pressing pressure is 25MPa, and hot pressing time is 43 minutes, to obtain final product.
Experimental data:
The Vickers' hardness of this embodiment pottery is 90GPa, and bending strength is 1120MPa, and fracture toughness property is 12MPam
1/2.
Claims (2)
1. a low cost ceramic cutter material, is characterized in that being made up of the raw material of following weight part: water reducer 0.6-0.7, magnesium oxide 2.6-3, boron oxide 2-3, waste quartz crucible powder 10-15, α-Al
2o
375-80, SiC6-8, WC3-4, CaF
22-3, deionized water are appropriate, polyacrylic acid 1-1.4, polyoxyethylene glycol 0.7-1.2, ethylene glycol are appropriate, antiwear assistant 3-4;
Described antiwear assistant is made up of the raw material of following weight part: nano-graphite 0.3-0.5, zirconium phosphate 1-1.3, nano zircite 1-1.3, calcium oxide 0.4-0.5, magnesium hydroxide 0.4-0.6, phosphatase 11-2, molybdenumdisulphide 1-2, aluminum oxide 2-3, kaolin 0.4-0.8, acrylate 1-2, ammonium persulphate 0.2-0.3, nano-sized carbon 0.7-0.9, water 10-12, polyoxyethylene glycol 0.4-0.6; Preparation method is: acrylate, polyoxyethylene glycol are added to the water, stir, then adds calcium oxide, magnesium hydroxide, phosphoric acid, aluminum oxide, kaolin, ammonium persulphate, be heated to 70-80 DEG C, stirring reaction 20-30 minute, then add other remaining components, stir 10-20 minute, ultrasonic disperse 6-8 minute, filter, dry, pulverize, cross 40 mesh sieves, under nitrogen atmosphere, at 1380-1440 DEG C, calcine 30-40 minute, pulverize, cross 40 mesh sieves, to obtain final product.
2. the preparation method of low cost ceramic cutter material according to claim 1, is characterized in that comprising the following steps:
(1) by waste quartz crucible powder, magnesium oxide mixing, ball milling, crosses 300 mesh sieves, obtains particle;
(2) by boron oxide, α-Al
2o
3, SiC, WC mixing, ball milling, cross 250 mesh sieves, obtain particle;
(3) by water reducer, CaF
2mix with the particle that first two steps obtain, add deionized water that mass percent is 23-28%, mass percent is the ethylene glycol of 3-5%, be mixed into pureed, send into ball milling 2-3 in ball mill individual hour, dry, send in calcining furnace, 1-2 hour is calcined at 800-900 DEG C, take out and pulverize, cross 200 mesh sieves, obtain particle;
(4) particle that (3) step obtains is mixed with other remaining components, get the deionized water of 3-4 times of weight part of mixing material, add polyacrylic acid, polyoxyethylene glycol, stir, add mixing material, ball milling 2-3 hour, dries at 110-120 DEG C, crosses 40 mesh sieves, hot pressing at 1680-1740 DEG C, hot pressing pressure is 25-30MPa, and hot pressing time is 40-45 minute, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410580581.0A CN104370533B (en) | 2014-10-27 | 2014-10-27 | A kind of low cost ceramic cutter material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410580581.0A CN104370533B (en) | 2014-10-27 | 2014-10-27 | A kind of low cost ceramic cutter material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104370533A CN104370533A (en) | 2015-02-25 |
| CN104370533B true CN104370533B (en) | 2016-04-13 |
Family
ID=52549777
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410580581.0A Active CN104370533B (en) | 2014-10-27 | 2014-10-27 | A kind of low cost ceramic cutter material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104370533B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104498800B (en) * | 2014-12-03 | 2016-07-06 | 刘从祥 | Plastic bottle crusher high abrasion crushing knife |
| CN105110762A (en) * | 2015-08-03 | 2015-12-02 | 佛山蓝途科技有限公司 | Ceramic cutter material prepared from serpentine tailings and preparation method therefor |
| CN105174919A (en) * | 2015-09-02 | 2015-12-23 | 安徽万年针织有限公司 | High wear-resistance alumina ceramic eye added with graphite powder |
| CN106630969A (en) * | 2016-12-07 | 2017-05-10 | 苏州洛特兰新材料科技有限公司 | High hardness ceramic composite material for cutting tools and preparation method thereof |
| CN108706554A (en) * | 2018-07-03 | 2018-10-26 | 贵州大学 | A kind of technique of ardealite and red mud relieving haperacidity coproduction Machine press carbon-free lining brick for steel ladles |
| CN108706555A (en) * | 2018-07-03 | 2018-10-26 | 贵州大学 | A kind of technique of ardealite and low product bauxite ceramic cutting tool material coproduction acid |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85103011A (en) * | 1985-04-03 | 1986-09-10 | 国家建材局山东工业陶瓷研究所 | High toughness ceramice kuife material based on nitrided silicon and manufacture method thereof |
| BR9500993A (en) * | 1995-03-29 | 1997-05-06 | Ngk Brasil Ceram Velas Ignicao | Process for manufacturing ceramic sharpener |
| CN101269961A (en) * | 2008-05-07 | 2008-09-24 | 淄博博纳科技发展有限公司 | Antimicrobial ceramic cutting tool and its manufacturing method |
| CN103011784A (en) * | 2012-12-16 | 2013-04-03 | 山东轻工业学院 | High performance nano-composite aluminum oxide based self-lubricating cutter material and preparation method thereof |
| CN103058667A (en) * | 2013-01-17 | 2013-04-24 | 山东轻工业学院 | Nano solid lubricant and nano ceramic grain composite modified cutter material and preparation method thereof |
-
2014
- 2014-10-27 CN CN201410580581.0A patent/CN104370533B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85103011A (en) * | 1985-04-03 | 1986-09-10 | 国家建材局山东工业陶瓷研究所 | High toughness ceramice kuife material based on nitrided silicon and manufacture method thereof |
| BR9500993A (en) * | 1995-03-29 | 1997-05-06 | Ngk Brasil Ceram Velas Ignicao | Process for manufacturing ceramic sharpener |
| CN101269961A (en) * | 2008-05-07 | 2008-09-24 | 淄博博纳科技发展有限公司 | Antimicrobial ceramic cutting tool and its manufacturing method |
| CN103011784A (en) * | 2012-12-16 | 2013-04-03 | 山东轻工业学院 | High performance nano-composite aluminum oxide based self-lubricating cutter material and preparation method thereof |
| CN103058667A (en) * | 2013-01-17 | 2013-04-24 | 山东轻工业学院 | Nano solid lubricant and nano ceramic grain composite modified cutter material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104370533A (en) | 2015-02-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104370533B (en) | A kind of low cost ceramic cutter material and preparation method thereof | |
| CN104370550B (en) | A kind of high tenacity Stupalox material and preparation method thereof | |
| CN104387032B (en) | A kind of cutting tool pottery and its preparation method | |
| CN104355652A (en) | Ceramic with good abrasion resistance for cutting tools and preparation method of ceramic | |
| CN104370548B (en) | A kind of rapid steel cutting tool stupalith and preparation method thereof | |
| CN103691929A (en) | Industrial powder metallurgy tool and manufacturing method thereof | |
| CN104370542B (en) | A kind of zirconia-based ceramics cutter material and preparation method thereof | |
| CN104402454B (en) | A kind of heat-stable ceramic and preparation method thereof for cutting tool | |
| CN104370534B (en) | A kind of cutting tool wear-resistant special cermacis and preparation method thereof | |
| CN104355615B (en) | A kind of high-hardness ceramic cutter material and preparation method thereof | |
| CN104402485A (en) | High-strength silicon carbide crystal whisker reinforcing ceramic and preparation method thereof | |
| CN105884388A (en) | Modified silicon carbide crystal whisker reinforced ceramic material and preparing method thereof | |
| CN104387071A (en) | Self-lubricating wear-resistant ceramic for cutting tools and preparation method thereof | |
| CN104402412B (en) | A kind of thermal shock resistance pottery and preparation method thereof for cutting tool | |
| CN104370555B (en) | A kind of ceramice kuife material based on nitrided silicon and preparation method thereof | |
| CN106278254B (en) | A kind of high-strength and high ductility ceramic composite and its application in manufacture cutter | |
| CN104446488A (en) | Silicon carbide cutting ceramic material and preparation method thereof | |
| CN104402442B (en) | A kind of cutting tool high wear-resistant pottery and preparation method thereof | |
| CN104402420A (en) | High toughness ceramic material for cutting tools and preparation method thereof | |
| CN104355619B (en) | A kind of cutting blade pottery and preparation method thereof | |
| CN104387083A (en) | Aluminum-nitride-base ceramic for cutting tools and preparation method thereof | |
| CN104402453B (en) | A kind of ceramic cutter material and preparation method thereof | |
| CN104387041A (en) | Aluminum oxide ceramic for self-lubricated cutter and preparation method of aluminum oxide ceramic | |
| CN103695750A (en) | Powder metallurgy alloy cutting tool and preparation method thereof | |
| CN104355625A (en) | Special ceramic material for cutter and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Liu Huilian Inventor before: Xi Shaofei |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20170907 Address after: Qinhuangdao City, Hebei province 066000 Harbor District Tianyang Metro 9 Building 1 unit 402 Patentee after: Liu Huilian Address before: 231602, No. 68, Zhong Xiang Road, Hefei Town, Feidong County, Anhui Patentee before: HEFEI DONGLU MACHINERY MANUFACTURING CO., LTD. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20191204 Address after: 313000 1-C, building 1, No. 656, Qixing Road, high tech Zone, Wuxing District, Huzhou City, Zhejiang Province Patentee after: Huzhou xinbeilian Network Technology Co., Ltd Address before: 066000 402 1 unit 9, Tianyang new town, seaport, Qinhuangdao, Hebei Patentee before: Liu Huilian |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20191220 Address after: 246001 Anqing wancaqianmu Agricultural Technology Co., Ltd., Changqing Industrial Park, Yingjiang District, Anqing City, Anhui Province Patentee after: Wang Zhao Address before: 313000 1-C, building 1, No. 656, Qixing Road, high tech Zone, Wuxing District, Huzhou City, Zhejiang Province Patentee before: Huzhou xinbeilian Network Technology Co., Ltd |
|
| CP02 | Change in the address of a patent holder | ||
| CP02 | Change in the address of a patent holder |
Address after: 221300 Guozhuang Industrial Park, yanzibu Town, Pizhou City, Xuzhou City, Jiangsu Province Patentee after: Wang Zhao Address before: 246001 Anqing wancaoqianmu Agricultural Technology Co., Ltd., Changqing Industrial Park, Yingjiang District, Anqing City, Anhui Province Patentee before: Wang Zhao |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20220412 Address after: 239000 northeast of the intersection of Liuzhou Road and Xin'anjiang Road, Zhongxin Suchu high tech Industrial Development Zone, Chuzhou City, Anhui Province Patentee after: Chuzhou yongpu New Material Technology Co.,Ltd. Address before: 221300 Guozhuang Industrial Park, yanzibu Town, Pizhou City, Xuzhou City, Jiangsu Province Patentee before: Wang Zhao |