CN104370357A - Stone-slab production wastewater treatment process - Google Patents
Stone-slab production wastewater treatment process Download PDFInfo
- Publication number
- CN104370357A CN104370357A CN201410717381.5A CN201410717381A CN104370357A CN 104370357 A CN104370357 A CN 104370357A CN 201410717381 A CN201410717381 A CN 201410717381A CN 104370357 A CN104370357 A CN 104370357A
- Authority
- CN
- China
- Prior art keywords
- magnetic
- stone slab
- production wastewater
- wastewater treatment
- slab production
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C1/00—Magnetic separation
- B03C1/02—Magnetic separation acting directly on the substance being separated
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/56—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
- C02F11/121—Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
- C02F11/123—Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering using belt or band filters
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
Abstract
The invention relates to a stone-slab production wastewater treatment process. The stone-slab production wastewater treatment process includes adding to-be-treated stone-slab production wastewater into a coagulation reactor, and feeding magnetic seeds, coagulant aids and coagulants into the coagulation reactor to perform coagulation reaction; guiding mixed liquid obtained after coagulation reaction into a super-magnetic separator to perform super-magnetic separation, directly discharging or reusing water obtained from separation, subjecting micro-magnetic floccules obtained from separation to separation of the magnetic seeds and non-magnetic sludges by a magnetic recovery system, returning the magnetic seeds to the coagulation reactor for coagulation reaction, and enabling the sludges to enter a sludge treatment system for treatment. The stone-slab production wastewater treatment process has the advantages that the stone-slab production wastewater is treated by a super-magnetic separation water purification technology, and the treatment process is further optimized and adjusted, so that the point source and non-point source pollution control requirements of the stone slab industry are met.
Description
Technical field
The present invention relates to technical field of sewage, is a kind of stone slab production wastewater treatment technique specifically.
Background technology
Luoyuan County processing of stone industry Present Situation on Pollution Control: material mine exploitation soil erosion, stone material are ingressed sewage, the stacking of waste residue waste material, spoil area sewage, ground, manufacturing district dust, the watershed streams such as the sewage treatment facility accidental discharge of indivedual enterprise are polluted very serious, the particularly rainwash that formed along with early-stage rainwater of rainy day, cause streams severe contamination, define " milk stream ".Through monitoring streams, water turbidity can reach about 500NTU, particularly affects water turbidity by early-stage rainwater and reaches as high as 2500NTU (province, municipal government require that streams water turbidity is less than 60NTU).
It is pollution of area source problem that Luoyuan County sheet material industry is polluted, and controlling area-source pollution technology must be adopted can to solve " milk stream " problem.In domestic, heavy rain early-stage rainwater amount can reach 2800m
3/ km
2the Dryweather flow such as h, Lan Shuixi, garden small stream, starting small stream on average reaches more than ten thousand stere every day 2, and general non-point source pollution control technique is difficult to meet Environmental capacity needs.
Summary of the invention
In order to overcome the defect of above-mentioned prior art, technical problem to be solved by this invention is to provide a kind of stone slab production wastewater treatment technique being applicable to stone slab industry point source and pollution of area source control.
In order to solve the problems of the technologies described above, the technical solution used in the present invention is:
A kind of stone slab production wastewater treatment technique, comprising:
Step 1, pending stone slab factory effluent is added in coagulation reactor, in coagulation reactor, add magnetic kind, coagulant aids and coagulating agent, carry out coagulating;
Step 2, the mixed solution after coagulating imported in super magnetic separator and carries out super Magneto separate, the water separated directly discharges or reuse, the micro-magnetic floc sedimentation separated carries out being separated of magnetic kind and non magnetic mud through magnetic recovery system, magnetic kind returns in coagulation reactor carries out coagulating, and mud enters sludge treating system and processes.
Beneficial effect of the present invention is:
1, can be difficult to the suspended substance of sedimentation in high efficiency separation stone slab factory effluent, effluent quality is good, and COD value is less than 5mg/L, and suspended substance (SS) value is less than 0.5mg/L, and turbidity can reach about 20NTU, can reach the process water requirement of stone slab processing district;
2, technical process is short, and processing efficiency is high, and whole process (micro-magnetic flocculation+mud-water separation) only needs about 3 minutes;
3, treatment capacity is large, can process the stone slab factory effluent of more than 20000 cubic metres every day, can meet stone slab industry point source and pollution of area source control overflow completely;
4, required equipment and raw material few, cost of investment is low, and processing costs is low, and production energy consumption is low;
5, magnetic kind can be recycled repeatedly, and the rate of recovery is up to 98%, and performance remains unchanged substantially;
6, spoil disposal water ratio is low, spoil disposal water ratio <15%;
7, routine maintenance is convenient, and without the need to backwash, level of automation is high, does not need human attendance.
Accompanying drawing explanation
Figure 1 shows that the equipment flowsheet schematic diagram of the embodiment of the present invention.
Label declaration:
1-coagulation reactor; 2-surpasses magnetic separator; 3-Magneto separate drum unit; 4-magnetic kind pump; 5-sludge sump; 6-sludge pump; 7-belt type dewaterer; 8-PAM chemicals dosing plant; 9-PAC chemicals dosing plant.
Embodiment
By describing technology contents of the present invention in detail, realized object and effect, accompanying drawing is coordinated to be explained below in conjunction with embodiment.
The design of most critical of the present invention is: utilize super Magneto separate water body purification technical finesse stone slab factory effluent, and optimize and revise further treatment process, thus meet stone slab industry point source and pollution of area source control overflow.
Please refer to shown in Fig. 1, the stone slab production wastewater treatment technique of present embodiment, comprising:
Step 1, pending stone slab factory effluent is added in coagulation reactor 1, in coagulation reactor 1, add magnetic kind, coagulant aids and coagulating agent, carry out coagulating;
Step 2, the mixed solution after coagulating imported in super magnetic separator 2 and carries out super Magneto separate, the water separated directly discharges or reuse, the micro-magnetic floc sedimentation separated carries out being separated of magnetic kind and non magnetic mud through magnetic recovery system, magnetic kind returns in coagulation reactor 1 carries out coagulating, and mud enters sludge treating system and processes.
Further, before step 1, also comprise the step of pending stone slab factory effluent through sedimentation filtration process.
Further, in step 1, the speed that adds of pending stone slab factory effluent is 20 ~ 30m
3/ min.
Further, described magnetic kind is the Fe that surface growth has the organic film of band active group
3o
4, particle diameter is 2 ~ 10 μm, and add-on is 150 ~ 200g/m by the gauge of pending stone slab factory effluent
3.
Further, described coagulant aids is PAM (polyacrylamide, English Polyacrylamide by name), and molecular-weight average is 1500 ~ 2,000 ten thousand, and concentration is 2 ‰, and add-on is 0.75 ~ 0.90g/m by the gauge of pending stone slab factory effluent
3.
Further, described coagulating agent is liquid PAC (polymerize aluminum chloride), and aluminum chloride content is 8 ~ 15wt%, and add-on is 3 ~ 6g/m by the gauge of pending stone slab factory effluent
3.
Further, in step 1, first in coagulation reactor 1, add magnetic kind, stir 1 ~ 2min with the rotating speed of 450 ~ 500r/min, then reduce rotating speed to 70 ~ 250r/min, add coagulant aids and coagulating agent, stir 1 ~ 2min.
Further, in step 2, the strength of current of super magnetic separator 2 is 8 ~ 10A, and stainless steel velvet filling ratio is 1.0 ~ 1.2%.
Further, described magnetic recovery system comprises Magneto separate drum unit 3 and magnetic kind pump 4, the micro-magnetic floc sedimentation separated carries out being separated of magnetic kind and non magnetic mud through Magneto separate drum unit 3, and the magnetic kind separated is returned in coagulation reactor 1 by magnetic kind pump 4 carries out coagulating.
Further, described sludge treating system comprises sludge sump 5, sludge pump 6 and belt type dewaterer 7, and mud is successively by discharge after sludge sump 5, sludge pump 6 and belt type dewaterer 7.
Embodiment 1
1, pending stone slab factory effluent is pressed 20m
3the speed of/min adds in coagulation reactor 1, and in coagulation reactor 1, adding magnetic kind, (surface growth has the Fe of the organic film of band active group
3o
4, particle diameter is 2 ~ 10 μm, and add-on is 150g/m by the gauge of pending stone slab factory effluent
3), stir 1min with the rotating speed of 450r/min, then reduce rotating speed to 70r/min, (molecular-weight average is 1500 ~ 2,000 ten thousand in coagulation reactor 1, to add coagulant aids PAM by PAM chemicals dosing plant 8, concentration is 2 ‰, and add-on is 0.75g/m by the gauge of pending stone slab factory effluent
3), by PAC chemicals dosing plant 9, to dosing coagulant PAC in coagulation reactor 1, (aluminum chloride content is 8wt%, and add-on is 3g/m by the gauge of pending stone slab factory effluent
3), stir 1min and carry out coagulating;
2, super Magneto separate is carried out by the super magnetic separator 2 of mixed solution importing after coagulating, the strength of current of super magnetic separator 2 is 8A, stainless steel velvet filling ratio is 1.0%, the water separated directly discharges or reuse, the micro-magnetic floc sedimentation separated carries out being separated of magnetic kind and non magnetic mud through Magneto separate drum unit 3, the magnetic kind separated is returned in coagulation reactor 1 by magnetic kind pump 4 carries out coagulating, and mud is successively by discharge after sludge sump 5, sludge pump 6 and belt type dewaterer 7.
After tested, the COD value of super Magneto separate water is out 4.5mg/L, and suspended substance (SS) value is 0.49mg/L, and turbidity can reach 20NTU; The rate of recovery of magnetic kind is 98%, and performance remains unchanged substantially; The water ratio of spoil disposal is 10%.
Embodiment 2
1, pending stone slab factory effluent is pressed 30m
3the speed of/min adds in coagulation reactor 1, and in coagulation reactor 1, adding magnetic kind, (surface growth has the Fe of the organic film of band active group
3o
4, particle diameter is 2 ~ 10 μm, and add-on is 200g/m by the gauge of pending stone slab factory effluent
3), 2min is stirred with the rotating speed of 500r/min, reduce rotating speed again to 250r/min, (molecular-weight average is 1500 ~ 2,000 ten thousand in coagulation reactor 1, to add coagulant aids PAM by PAM chemicals dosing plant 8, concentration is 2 ‰, and add-on is 0.90g/m by the gauge of pending stone slab factory effluent
3), by PAC chemicals dosing plant 9, to dosing coagulant PAC in coagulation reactor 1, (aluminum chloride content is 15wt%, and add-on is 6g/m by the gauge of pending stone slab factory effluent
3), stir 2min and carry out coagulating;
2, super Magneto separate is carried out by the super magnetic separator 2 of mixed solution importing after coagulating, the strength of current of super magnetic separator 2 is 10A, stainless steel velvet filling ratio is 1.2%, the water separated directly discharges or reuse, the micro-magnetic floc sedimentation separated carries out being separated of magnetic kind and non magnetic mud through Magneto separate drum unit 3, the magnetic kind separated is returned in coagulation reactor 1 by magnetic kind pump 4 carries out coagulating, and mud is successively by discharge after sludge sump 5, sludge pump 6 and belt type dewaterer 7.
After tested, the COD value of super Magneto separate water is out 4.0mg/L, and suspended substance (SS) value is 0.45mg/L, and turbidity can reach 20NTU; The rate of recovery of magnetic kind is 98%, and performance remains unchanged substantially; The water ratio of spoil disposal is 12%.
Embodiment 3
1, pending stone slab factory effluent is pressed 25m
3the speed of/min adds in coagulation reactor 1, and in coagulation reactor 1, adding magnetic kind, (surface growth has the Fe of the organic film of band active group
3o
4, particle diameter is 2 ~ 10 μm, and add-on is 180g/m by the gauge of pending stone slab factory effluent
3), 1.5min is stirred with the rotating speed of 480r/min, reduce rotating speed again to 100r/min, (molecular-weight average is 1500 ~ 2,000 ten thousand in coagulation reactor 1, to add coagulant aids PAM by PAM chemicals dosing plant 8, concentration is 2 ‰, and add-on is 0.80g/m by the gauge of pending stone slab factory effluent
3), by PAC chemicals dosing plant 9, to dosing coagulant PAC in coagulation reactor 1, (aluminum chloride content is 10wt%, and add-on is 5g/m by the gauge of pending stone slab factory effluent
3), stir 1.5min and carry out coagulating;
2, super Magneto separate is carried out by the super magnetic separator 2 of mixed solution importing after coagulating, the strength of current of super magnetic separator 2 is 9A, stainless steel velvet filling ratio is 1.1%, the water separated directly discharges or reuse, the micro-magnetic floc sedimentation separated carries out being separated of magnetic kind and non magnetic mud through Magneto separate drum unit 3, the magnetic kind separated is returned in coagulation reactor 1 by magnetic kind pump 4 carries out coagulating, and mud is successively by discharge after sludge sump 5, sludge pump 6 and belt type dewaterer 7.
After tested, the COD value of super Magneto separate water is out 4.4mg/L, and suspended substance (SS) value is 0.48mg/L, and turbidity can reach 20NTU; The rate of recovery of magnetic kind is 98%, and performance remains unchanged substantially; The water ratio of spoil disposal is 13%.
In sum, stone slab production wastewater treatment technique provided by the invention, beneficial effect is:
1, can be difficult to the suspended substance of sedimentation in high efficiency separation stone slab factory effluent, effluent quality is good, and COD value is less than 5mg/L, and suspended substance (SS) value is less than 0.5mg/L, and turbidity can reach about 20NTU, can reach the process water requirement of stone slab processing district;
2, technical process is short, and processing efficiency is high, and whole process (micro-magnetic flocculation+mud-water separation) only needs about 3 minutes;
3, treatment capacity is large, can process the stone slab factory effluent of more than 20000 cubic metres every day, can meet stone slab industry point source and pollution of area source control overflow completely;
4, required equipment and raw material few, cost of investment is low, and processing costs is low, and production energy consumption is low;
5, magnetic kind can be recycled repeatedly, and the rate of recovery is up to 98%, and performance remains unchanged substantially;
6, spoil disposal water ratio is low, spoil disposal water ratio <15%;
7, routine maintenance is convenient, and without the need to backwash, level of automation is high, does not need human attendance.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every equivalents utilizing specification sheets of the present invention and accompanying drawing content to do, or be directly or indirectly used in relevant technical field, be all in like manner included in scope of patent protection of the present invention.
Claims (10)
1. a stone slab production wastewater treatment technique, is characterized in that, comprising:
Step 1, pending stone slab factory effluent is added in coagulation reactor, in coagulation reactor, add magnetic kind, coagulant aids and coagulating agent, carry out coagulating;
Step 2, the mixed solution after coagulating imported in super magnetic separator and carries out super Magneto separate, the water separated directly discharges or reuse, the micro-magnetic floc sedimentation separated carries out being separated of magnetic kind and non magnetic mud through magnetic recovery system, magnetic kind returns in coagulation reactor carries out coagulating, and mud enters sludge treating system and processes.
2. stone slab production wastewater treatment technique according to claim 1, is characterized in that: before step 1, also comprises the step of pending stone slab factory effluent through sedimentation filtration process.
3. stone slab production wastewater treatment technique according to claim 1, is characterized in that: in step 1, and the speed that adds of pending stone slab factory effluent is 20 ~ 30m
3/ min.
4. stone slab production wastewater treatment technique according to claim 1, is characterized in that: described magnetic kind is the Fe that surface growth has the organic film of band active group
3o
4, particle diameter is 2 ~ 10 μm, and add-on is 150 ~ 200g/m by the gauge of pending stone slab factory effluent
3.
5. stone slab production wastewater treatment technique according to claim 1, is characterized in that: described coagulant aids is PAM, molecular-weight average is 1500 ~ 2,000 ten thousand, and concentration is 2 ‰, and add-on is 0.75 ~ 0.90g/m by the gauge of pending stone slab factory effluent
3.
6. stone slab production wastewater treatment technique according to claim 1, it is characterized in that: described coagulating agent is liquid PAC, aluminum chloride content is 8 ~ 15wt%, and add-on is 3 ~ 6g/m by the gauge of pending stone slab factory effluent
3.
7. stone slab production wastewater treatment technique according to claim 1, it is characterized in that: in step 1, first in coagulation reactor, add magnetic kind, 1 ~ 2min is stirred with the rotating speed of 450 ~ 500r/min, reduce rotating speed to 70 ~ 250r/min again, add coagulant aids and coagulating agent, stir 1 ~ 2min.
8. stone slab production wastewater treatment technique according to claim 1, is characterized in that: in step 2, and the strength of current of super magnetic separator is 8 ~ 10A, and stainless steel velvet filling ratio is 1.0 ~ 1.2%.
9. stone slab production wastewater treatment technique according to claim 1, it is characterized in that: described magnetic recovery system comprises Magneto separate drum unit and magnetic kind pump, the micro-magnetic floc sedimentation separated carries out being separated of magnetic kind and non magnetic mud through Magneto separate drum unit, and the magnetic kind separated is returned in coagulation reactor by magnetic kind pump carries out coagulating.
10. stone slab production wastewater treatment technique according to claim 1, is characterized in that: described sludge treating system comprises sludge sump, sludge pump and belt type dewaterer, and mud is successively by discharging after sludge sump, sludge pump and belt type dewaterer.
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105217695A (en) * | 2015-08-28 | 2016-01-06 | 南京大学 | The methods and applications of a kind of novel magnetic nano magnetic kind and process industrial biochemistry tail water thereof |
CN105366869A (en) * | 2015-12-14 | 2016-03-02 | 江苏源泰恒环境工程有限公司 | Mobile magnetic separation water purification equipment |
CN106186553A (en) * | 2016-08-26 | 2016-12-07 | 薛强 | A kind of black smelly muddy water mobile emergency processing system and method |
CN106673373A (en) * | 2017-01-19 | 2017-05-17 | 西藏神州瑞霖环保科技股份有限公司 | Sustainable and efficient sewage treatment system |
CN106698851A (en) * | 2017-01-18 | 2017-05-24 | 杭州问源环保科技股份有限公司 | Wastewater treatment process based on combination of super magnetic separation and SBR (Styrene Butadiene Rubber) technique |
CN107540143A (en) * | 2016-06-24 | 2018-01-05 | 江苏天鑫中冶环保设备有限公司 | A kind of New Magnetic Field Controlled loading water body purification station |
CN110577318A (en) * | 2019-10-17 | 2019-12-17 | 辽阳博仕流体设备有限公司 | Sewage treatment supermagnetic separation device |
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CN102531235A (en) * | 2011-12-27 | 2012-07-04 | 福州绿明环保工程有限公司 | Technology for deeply treating stone processing wastewater |
CN104163536A (en) * | 2013-05-17 | 2014-11-26 | 北京中力信达环保工程有限公司 | Magnetic coagulation mine water underground purification technology |
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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JP4465336B2 (en) * | 2006-08-23 | 2010-05-19 | 株式会社原田 | Waste leachate treatment system |
CN102531235A (en) * | 2011-12-27 | 2012-07-04 | 福州绿明环保工程有限公司 | Technology for deeply treating stone processing wastewater |
CN104163536A (en) * | 2013-05-17 | 2014-11-26 | 北京中力信达环保工程有限公司 | Magnetic coagulation mine water underground purification technology |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105217695A (en) * | 2015-08-28 | 2016-01-06 | 南京大学 | The methods and applications of a kind of novel magnetic nano magnetic kind and process industrial biochemistry tail water thereof |
CN105366869A (en) * | 2015-12-14 | 2016-03-02 | 江苏源泰恒环境工程有限公司 | Mobile magnetic separation water purification equipment |
CN107540143A (en) * | 2016-06-24 | 2018-01-05 | 江苏天鑫中冶环保设备有限公司 | A kind of New Magnetic Field Controlled loading water body purification station |
CN106186553A (en) * | 2016-08-26 | 2016-12-07 | 薛强 | A kind of black smelly muddy water mobile emergency processing system and method |
CN106698851A (en) * | 2017-01-18 | 2017-05-24 | 杭州问源环保科技股份有限公司 | Wastewater treatment process based on combination of super magnetic separation and SBR (Styrene Butadiene Rubber) technique |
CN106673373A (en) * | 2017-01-19 | 2017-05-17 | 西藏神州瑞霖环保科技股份有限公司 | Sustainable and efficient sewage treatment system |
CN110577318A (en) * | 2019-10-17 | 2019-12-17 | 辽阳博仕流体设备有限公司 | Sewage treatment supermagnetic separation device |
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