CN104369305A - Technology for in-mold decoration with chromium-plated appearance effect - Google Patents

Technology for in-mold decoration with chromium-plated appearance effect Download PDF

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Publication number
CN104369305A
CN104369305A CN201410117937.7A CN201410117937A CN104369305A CN 104369305 A CN104369305 A CN 104369305A CN 201410117937 A CN201410117937 A CN 201410117937A CN 104369305 A CN104369305 A CN 104369305A
Authority
CN
China
Prior art keywords
substrate
product
mould injection
preparing product
method adopting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410117937.7A
Other languages
Chinese (zh)
Inventor
刁振新
朱浩
马克
邱志阳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
INESA ELECTRON CO Ltd
SHANGHAI YIDIAN ELECTRONIC PRINTING TECHNOLOGY Co Ltd
Original Assignee
INESA ELECTRON CO Ltd
SHANGHAI YIDIAN ELECTRONIC PRINTING TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by INESA ELECTRON CO Ltd, SHANGHAI YIDIAN ELECTRONIC PRINTING TECHNOLOGY Co Ltd filed Critical INESA ELECTRON CO Ltd
Priority to CN201410117937.7A priority Critical patent/CN104369305A/en
Publication of CN104369305A publication Critical patent/CN104369305A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B29C45/1418Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles the inserts being deformed or preformed, e.g. by the injection pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B29C45/14311Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles using means for bonding the coating to the articles

Abstract

The invention relates to the field of machine manufacturing, and especially relates to a technology for in-mold decoration with chromium-plated appearance effect. The metal chromium-plated appearance effect is reappeared by employing silk-screen printing, and the technology helps to effectively improve the characteristics of a conventional chromium plating technology that the product is high in cost and high in reject ratio, and products are bad in adaptability and easily damage natural environment and human body health because of multiple mutually-influenced processes, and the like.

Description

A kind of process of in-mold decoration of chrome look effect
Technical field
The present invention relates to mechanical manufacturing field, particularly relate to a kind of process of in-mold decoration of chrome look effect.
Background technology
Electrodeposited chromium coating technology is a kind of material surface engineering technolog, the industries such as its extensive use and automobile, machinery, oil, Aero-Space, weaving, food processing, what adopt due to its electroplated coating is crome metal, and crome metal has strong mutagenicity and potential carcinogenicity, particularly Cr VI is the carcinogenic substance of International Contre research center and U.S.'s toxicology organisations publish, has obvious carcinogenesis.
Due to the specific needs of electrodeposited chromium coating technology production technology, be fixed as long as chromium is not converted to product, become insoluble form, will chromium ion be become, and chromium ion chance water is instant, can be transformed into the extremely strong Cr VI of toxicity very soon.
Chromium slag is producing the industrial residue produced in crome metal and chromic salts process, and toxicity own is powerful.If chromium slag is by air storage, drench leaching by sleet, contained Cr VI will be dissolved and permeates the ground water or enter contaminated environment in river, lake, easily causes large-scale environmental hazard.
Chinese patent (CN102080239A) describes a kind of environment-friendly type chromium plating liquid.Contained each composition is by ratio of weight and the number of copies: CrO 2120 ~ 210 parts, NF1 ~ 5 part, KBrO 30.5 ~ 3.2 part, 98%H 2sO 40.2 ~ 1.2 part; CF-2012 ~ 7 part; Its environment-friendly type chromium plating liquid one that to be anode material be in Pb/Sn or Pb/Sb.
The method of this invention decreases the chromium content in the waste material produced in chrome-plated process, reduces pollution.But the utilization of its process program still to crome metal, does not have to remain chromium in the solution chrome-plated process of essence in waste material to the harm of environment.
Chinese patent (CN101760721A) describes a kind of method for plating chromium on surface of plastic material.The present invention is achieved by the following technical programs: a kind of method for plating chromium on surface of plastic material, pre-treatment step that it comprises successively (1); (2) prime coat step is prepared; (3) crome metal plating steps is prepared; (4) face plating steps is prepared; (5) check; (6) pack.
The method of this invention solves the method adding plating chromium at frosting, improves the aesthetic appearance of metallic article, but does not solve in chrome-plated process process, because causing the problem of environmental pollution containing chromium in the discarded object produced.
Summary of the invention
In view of the above problems, this invention describes a kind of process of in-mold decoration of chrome look effect, to overcome the problem of environmental pollution caused because adopting chrome-plated process in prior art.
For achieving the above object, the technical scheme that technical solution problem of the present invention adopts is:
Step S1 a: substrate is provided, and at least one side of this substrate is non-hardened face;
Step S2: after printing one has the ink layer of metallic luster on a non-hardened surface of described substrate, carry out moulding process and clicking technique successively, forms the reeded product blank of back side tool;
Step S3: after carrying out Shooting Technique to described groove, forms product component;
Wherein, described ink layer covers the front face surface of described product blank.
The method of described employing in-mould injection technique preparing product, wherein, described method also comprises:
After pre-firing processes is carried out to described substrate, then in this substrate non-hardened face printing described in there is the ink layer of metallic luster.
The method of described employing in-mould injection technique preparing product, wherein, the material of described ink layer has high-temperature stability.
The method of described employing in-mould injection technique preparing product, wherein, described method also comprises:
After the described ink layer of printing, in the environment temperature of 60-90 DEG C, described substrate is carried out to the baking process of 1-2 hour, and continue described moulding process.
The method of described employing in-mould injection technique preparing product, wherein, after described baking process, carries out nature process for cooling to described substrate, and continues described moulding process.
The method of described employing in-mould injection technique preparing product, wherein, when carrying out nature process for cooling to described substrate, described substrate and an electrostatic dispel equipment connection.
The method of described employing in-mould injection technique preparing product, wherein, described method also comprises:
After the inner surface of described groove is prepared an adhesive phase, in remaining groove, fill injection moulding particle, to complete described Shooting Technique.
The method of described employing in-mould injection technique preparing product, wherein, the material of described injection moulding particle is one or more in PC, ABS or PMMA.
The method of described employing in-mould injection technique preparing product, wherein, described moulding process is for carry out mould punching to described substrate.
The method of described employing in-mould injection technique preparing product, wherein, described clicking technique, to the substrate completing described moulding process, uses punch press to remove described substrate and does not carry out formed in mould part.
Technique scheme tool has the following advantages or beneficial effect:
The present invention adopts screen printing technique, crome metal is replaced with the coating technology not containing Cr VI metal, thus reach the appearance of electrodeposited chromium, metallic aluminium, then in-mould injection IMF (Insert Molding by Sliced-film) is carried out to the diaphragm printed, the application of its IMF technique can by original split framework, replaced by integration, not only save manually, also facility brought to assembling, Parts Purchasing, production management.By the appearance adopting the method for in-mould injection technique preparing product to reproduce plated metal chromium, it is large that this technology has ink film thickness, color reproducibility is good, resistance to illumination, high temperature resistant, resistance to high humidity, chemically-resistant solvent, ROHS) expense is lower, meet parliament of European Union and EU Council " electrically, in electronic equipment restriction use some Hazardous Substances Directive ", and (the Restriction of the use of certain hazardous substances inelectrical and electronic equipment is called for short: the feature such as.Technically carry out in-mould injection technique at it, the structure member with certain mechanical strength can be formed, and then the industries such as communication, household electrical appliances electronics, automobile, instrument, instrument, medicine equipment, toy and aerospace field can be widely used in.
Accompanying drawing explanation
With reference to appended accompanying drawing, to describe embodiments of the invention more fully.But, appended accompanying drawing only for illustration of and elaboration, do not form limitation of the scope of the invention.
Fig. 1 is the process flow diagram of the embodiment of the present invention;
Fig. 2-7 is the device architecture schematic diagrames corresponding to each step in the technological process in Fig. 1.
Detailed description of the invention
Below in conjunction with accompanying drawing and specific embodiment, the present invention is further illustrated, but not as limiting to the invention.
Core concept of the present invention is by utilizing serigraphy to have metallic luster ink at device surface, to realize the appearance with metallic luster, and thus replaces chrome faced technology mode of the prior art.And utilize IMF technique, become structure member.
Below in conjunction with accompanying drawing, technical scheme of the present invention is described in detail.
Step S1, one substrate 11 is provided, and at least one side of this substrate 11 is non-hardened face, as shown in Figure 2, and prebake conditions is carried out to substrate 11, the moisture in substrate 11 is evaporated, and makes the free convergent-divergent of material, thus ensure that the flatness of substrate 11 in subsequent technique process, and then improve the yield of final products.
In above-mentioned technique, the material of substrate 11 can be preferably the plastic material that PC or PET etc. is easy to printed, and the time of prebake conditions and temperature have selected material behavior to determine.
Step S2, prints the upper surface of substrate 11, and printing ink used need have metallic luster, and be Surface Creation one deck ink layer 12 of substrate 11, its structure as shown in Figure 3.
If it is noted that substrate 11 exists hardened face and non-hardened face in this technical process, then ink layer 12 needs to be printed on the non-hardened face of substrate 11.
Preferably, print ink used and need have resistant to elevated temperatures characteristic, ensure that ink layer 12 is in the high-temperature process of subsequent technique, and the change of outward appearance and character does not occur, ensure the presentation quality of final products.
Step S3, carries out baking process to the substrate 11 completing described typography, makes ink layer 12 dry, prevents from subsequent technique, produce red ink phenomenon, ensure the even of ink layer, and then makes the final product appearance obtained neat and artistic.
Preferably, in the baking process of step S3, the temperature process parameter adopted be 60-90 DEG C (such as 65 DEG C, 70 DEG C or 80 DEG C etc.), the time technological parameter adopted be 1-2 hour (such as 1 hour 20 minutes, 1 hour 30 minutes or 1 hour 45 minutes etc.) certainly, also can according to process requirements, suitable increase or reduce above-mentioned two technological parameters, and then prepare the ink layer 21 of uniform in color, stable performance, to meet the demand of technique.
Finally, cool the substrate 11 completing baking, the type of cooling is preferably nature cooling, makes the natural convergent-divergent of substrate 11, avoids effect of stress to make substrate 11 and ink layer 12 that stress deformation occur, the final product appearance obtained of impact.
Simultaneously, preferred further, need electrostatic is set in cooling procedure and dispels equipment, electrostatic is dispelled equipment and is connected with substrate 11, prevent substrate 11 because of Electrostatic Absorption dust, and affect follow-up Shooting Technique, cause coming off because dust two bonds loosely between substrate and injection moulding, and then reduce product yield.
Step S4, carries out moulding process to the substrate completing described baking process, preferably by the mode using Sheet Metal Forming Technology, makes the substrate of plane become original blank 21.As shown in Figure 4, wherein, fresh oil layer of ink 22 covers the front face surface of original blank 21 to its structure.
Re-use clicking technique, the outer sideline judge being Pressing Deformation by original blank 21 goes, and forms the reeded product blank of back side tool, and as shown in Figure 5, product blank 31 and the shaping ink layer 32 of reservation are the shell mechanism of injection molding part.
Step S5, arranges one deck adhesive layer 13 on the concave surface of substrate completing above-mentioned moulding process and clicking technique, to ensure that the moulding that product blank 31 and follow-up Shooting Technique generate can be bonded in one piece securely.
Wherein, the injection moulding particulate material character that the material of adhesive layer 13 is selected by follow-up Shooting Technique determines.
Then, carry out Shooting Technique in the groove of product blank 31, make it form final product, its structure as shown in Figure 7.
Preferably, the injection moulding particulate material that Shooting Technique is selected is PC, ABS, PMMA, PC & ABS.
Step S6, carries out quality inspection to final product.
In sum, in the present invention, adopt serigraphy to reproduce the appearance of plated metal chromium, effectively improve the product cost existed in existing chromium plating technology high, fraction defective is high, influence each other between multiple working procedure and cause the adaptation of product poor, easily the feature such as harm natural environment and human body health, and this technology to have ink film thickness large, color reproducibility is good, resistance to illumination, high temperature resistant, resistance to high humidity, chemically-resistant solvent, expense is lower, meet the features such as parliament of European Union and ROHS.Technically carry out in-mould injection technique at it, the structure member with certain mechanical strength can be formed, and then communication, household electrical appliances electronics, automobile, instrument can be widely used in, instrument, the industry such as medicine equipment and toy.
It should be appreciated by those skilled in the art that those skilled in the art are realizing described change case in conjunction with prior art and above-described embodiment, do not repeat at this.Such change case does not affect flesh and blood of the present invention, does not repeat them here.
Above preferred embodiment of the present invention is described.It is to be appreciated that the present invention is not limited to above-mentioned particular implementation, the equipment wherein do not described in detail to the greatest extent and structure are construed as to be implemented with the common mode in this area; Any those of ordinary skill in the art, do not departing under technical solution of the present invention ambit, the Method and Technology content of above-mentioned announcement all can be utilized to make many possible variations and modification to technical solution of the present invention, or being revised as the Equivalent embodiments of equivalent variations, this does not affect flesh and blood of the present invention.Therefore, every content not departing from technical solution of the present invention, according to technical spirit of the present invention to any simple modification made for any of the above embodiments, equivalent variations and modification, all still belongs in the scope of technical solution of the present invention protection.

Claims (10)

1. adopt a method for in-mould injection technique preparing product, it is characterized in that, described technique comprises the following steps:
Step S1 a: substrate is provided, and at least one side of this substrate is non-hardened face;
Step S2: after printing one has the ink layer of metallic luster on a non-hardened surface of described substrate, carry out moulding process and clicking technique successively, forms the reeded product blank of back side tool;
Step S3: after carrying out Shooting Technique to described groove, forms product component;
Wherein, described ink layer covers the front face surface of described product blank.
2. the method adopting in-mould injection technique preparing product as claimed in claim 1, it is characterized in that, described method also comprises:
After pre-firing processes is carried out to described substrate, then in this substrate non-hardened face printing described in there is the ink layer of metallic luster.
3. the method adopting in-mould injection technique preparing product as claimed in claim 1, it is characterized in that, the material of described ink layer has high-temperature stability.
4. the method adopting in-mould injection technique preparing product as claimed in claim 1, it is characterized in that, described method also comprises:
After the described ink layer of printing, in the environment temperature of 60-90 DEG C, described substrate is carried out to the baking process of 1-2 hour, and continue described moulding process.
5. the method adopting in-mould injection technique preparing product as claimed in claim 4, is characterized in that, after described baking process, carry out nature process for cooling to described substrate, and continue described moulding process.
6. the method adopting in-mould injection technique preparing product as claimed in claim 5, it is characterized in that, when carrying out nature process for cooling to described substrate, described substrate and an electrostatic dispel equipment connection.
7. the method adopting in-mould injection technique preparing product as claimed in claim 1, it is characterized in that, described method also comprises:
After the inner surface of described groove is prepared an adhesive phase, in remaining groove, fill injection moulding particle, to complete described Shooting Technique.
8. the as claimed in claim 7 method adopting in-mould injection technique preparing product, is characterized in that, the material of described injection moulding particle is one or more in PC, ABS or PMMA.
9. the method adopting in-mould injection technique preparing product as claimed in claim 1, it is characterized in that, described moulding process is for carry out mould punching to described substrate.
10. the method adopting in-mould injection technique preparing product as claimed in claim 1, is characterized in that, described clicking technique, to the substrate completing described moulding process, uses punch press to remove described substrate and do not carry out formed in mould part.
CN201410117937.7A 2014-03-26 2014-03-26 Technology for in-mold decoration with chromium-plated appearance effect Pending CN104369305A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410117937.7A CN104369305A (en) 2014-03-26 2014-03-26 Technology for in-mold decoration with chromium-plated appearance effect

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410117937.7A CN104369305A (en) 2014-03-26 2014-03-26 Technology for in-mold decoration with chromium-plated appearance effect

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106113380A (en) * 2016-06-28 2016-11-16 长春华涛汽车塑料饰件有限公司 A kind of imitative woven design automotive upholstery processing method

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1411982A (en) * 2001-10-19 2003-04-23 帝国印刷油墨制造株式会社 Resin forming article with metal glossy surface
US20040179347A1 (en) * 2003-03-10 2004-09-16 Denso Corporation Circuit board
CN101045332A (en) * 2006-03-28 2007-10-03 德尔斐韩国株式会社 Emblem of automobile part and method of manufacturing the same
CN101327632A (en) * 2008-08-01 2008-12-24 华硕电脑股份有限公司 In-mold thin film transfer device
CN102431120A (en) * 2011-11-10 2012-05-02 郭传滨 Method for manufacturing intramode injection-molded automobile caution plates and decoration strips
CN102700053A (en) * 2012-06-26 2012-10-03 东莞劲胜精密组件股份有限公司 In-mold labeling process
CN103419518A (en) * 2012-05-22 2013-12-04 上海百嘉电子有限公司 Method for preparing field type display back electrode plate of electronic ink

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1411982A (en) * 2001-10-19 2003-04-23 帝国印刷油墨制造株式会社 Resin forming article with metal glossy surface
US20040179347A1 (en) * 2003-03-10 2004-09-16 Denso Corporation Circuit board
CN101045332A (en) * 2006-03-28 2007-10-03 德尔斐韩国株式会社 Emblem of automobile part and method of manufacturing the same
CN101327632A (en) * 2008-08-01 2008-12-24 华硕电脑股份有限公司 In-mold thin film transfer device
CN102431120A (en) * 2011-11-10 2012-05-02 郭传滨 Method for manufacturing intramode injection-molded automobile caution plates and decoration strips
CN103419518A (en) * 2012-05-22 2013-12-04 上海百嘉电子有限公司 Method for preparing field type display back electrode plate of electronic ink
CN102700053A (en) * 2012-06-26 2012-10-03 东莞劲胜精密组件股份有限公司 In-mold labeling process

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106113380A (en) * 2016-06-28 2016-11-16 长春华涛汽车塑料饰件有限公司 A kind of imitative woven design automotive upholstery processing method

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