CN104355639A - Castable specially used for coal-injection ducts of cement kilns - Google Patents

Castable specially used for coal-injection ducts of cement kilns Download PDF

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Publication number
CN104355639A
CN104355639A CN201410709663.0A CN201410709663A CN104355639A CN 104355639 A CN104355639 A CN 104355639A CN 201410709663 A CN201410709663 A CN 201410709663A CN 104355639 A CN104355639 A CN 104355639A
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CN
China
Prior art keywords
powder
additional
injection pipe
coal injection
cement kiln
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Application number
CN201410709663.0A
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Chinese (zh)
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CN104355639B (en
Inventor
张婷
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Jincheng Shanshui India Cements Limited
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张婷
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Priority to CN201610160478.XA priority Critical patent/CN105837228B/en
Priority to CN201410709663.0A priority patent/CN104355639B/en
Publication of CN104355639A publication Critical patent/CN104355639A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/66Monolithic refractories or refractory mortars, including those whether or not containing clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements

Abstract

The invention aims to provide a castable specially used for coal-injection ducts of cement kilns. By adopting the castable, the problem of non-uniformity of tissue structures of current castables can be solved, the defects of poor constructability and castable segregation, more pores and non-uniformity of pore distribution caused by poor constructability are overcome, the phenomena of no wear resistance, spalling, no erosion resistance, and the like of kiln mouths can be effectively improved, and the service lives of the mouths of the cement kilns can be substantially prolonged.

Description

A kind of cement kiln coal injection pipe dedicated pouring material
Technical field
The present invention relates to building materials high-temperature material field, be specifically related to a kind of cement kiln coal injection pipe dedicated pouring material.
Background technology
Rapidly, cement production capacity is seriously superfluous for the new type nonaqueous cement production line development of current China.Therefore, cement production enterprise improves production of units efficiency, and reducing production cost, is generate profit maximized only way.And the operation factor improving cement producing line is the essential condition improving cement kiln production efficiency.But there is important impact the running period of the life-span of cement kiln coal injection pipe on whole production line.The coal injection pipe working conditions of cement kiln is severe, except bearing up to except high temperature in 1400 DEG C of kilns, also bear washing away of cement kiln clinker, the thermal stresses that the secondary air that grate-cooler comes causes, chlor-alkali corrodes the impact brought it, thus has higher requirement to the over-all properties of the mould material that cement kiln coal injection pipe uses.3 to 8 months work-ing life of current common coal injection pipe, not etc. such life-span still can not meet the demand of client.The major cause affecting its work-ing life is that current refractory castable wears no resistance, poor heat stability, properties is unstable, simultaneously the chemical erosion of cement kiln coal injection pipe also not water resistant mud kiln atmosphere, constrain the raising of cement kiln production line rate, have impact on the economic benefit of cement producer.
In addition, the shortcomings such as current coal injection pipe castable exists the defect of workability difference, and easily cause mould material segregation, pore is many, and gas cell distribution is uneven, thus also reduce the work-ing life of coal injection pipe.
Summary of the invention
The object of this invention is to provide a kind of coal injection pipe castable, the mould material segregation solving application property difference and come by application property difference band, pore is many, the defect that gas cell distribution is uneven.By above-mentioned measure, effectively can improve the not wear-resisting of coal injection pipe, fall block, the phenomenon such as anti-erosion, significantly can not extend the coal injection pipe work-ing life of cement kiln.
Above-mentioned technical purpose of the present invention is achieved by the following technical programs: a kind of cement kiln coal injection pipe dedicated pouring material, is characterized in that: described component comprises aluminium titanates, synthetic moissanite, Brown Alundum, strontium titanate powder, carbonic acid zirconium powder, andaluzite powder, silicic acid zinc powder, alumina powder, pure calcium aluminate cement, terbium sesquioxide.
As preferentially, described component also comprises C 5h 10n 6o 2, heat-resistant steel fiber, polyethers poly carboxylic acid.
Further, described component also comprises Sulfonated Copolymer of Styrene and Maleic Anhydride and Tc 2o 7one or both.
Preferential, described a kind of cement kiln coal injection pipe dedicated pouring material, is characterized in that: the weight percentage of described component is:
Aluminium titanates 15-25%
Synthetic moissanite 10-20%
Brown Alundum 25-30%
Strontium titanate powder 5-10%
Carbonic acid zirconium powder 5-8%
Andaluzite powder 1-3%
Zinc silicate 3-5%
Alumina powder 5-10%
Pure calcium aluminate cement 4-6%
Terbium sesquioxide 1-2%
Additional C 5h 10n 6o 20.2%
Additional heat-resistant steel fiber 0.5%
Additional polyethers poly carboxylic acid 0.1%
Additional Sulfonated Copolymer of Styrene and Maleic Anhydride add-on is 0.05%
Additional Tc 2o 7add-on be 0-0.05%.
Preferential, the weight percentage of described component is:
Aluminium titanates 15%
Synthetic moissanite 20%
Brown Alundum 30%
Strontium titanate powder 10%
Carbonic acid zirconium powder 8%
Andaluzite powder 2%
Zinc silicate 3%
Alumina powder 5%
Pure calcium aluminate cement 6%
Terbium sesquioxide 1%
Additional C 5h 10n 6o 20.2%
Additional heat-resistant steel fiber 0.5%
Additional polyethers poly carboxylic acid 0.1%
Additional Sulfonated Copolymer of Styrene and Maleic Anhydride add-on is 0.05%.
Preferential ,the weight percentage of described component is:
Aluminium titanates 20%
Synthetic moissanite 15%
Brown Alundum 30%
Strontium titanate powder 10%
Carbonic acid zirconium powder 8%
Andaluzite powder 2%
Zinc silicate 3%
Alumina powder 5%
Pure calcium aluminate cement 5%
Terbium sesquioxide 2%
Additional C 5h 10n 6o 20.2%
Additional heat-resistant steel fiber 0.5%
Additional polyethers poly carboxylic acid 0.1%
Additional Sulfonated Copolymer of Styrene and Maleic Anhydride add-on is 0.05%
Additional Tc 2o 7add-on be 0.05%.
Preferential, described a kind of cement kiln coal injection pipe dedicated pouring material, described component also comprises 0.3 part, Silica hydrogel powder.
As preferentially, described aluminium titanate content >=98%; Carborundum content >=97% of synthetic moissanite; Zirconium carbonate >=97%, the granularity of zirconium carbonate is≤10 μm; Zinc silicate content >=95%; Strontium titanate content >=95%; Andaluzite aluminium content >=57%; Terbium oxide content >=98%.
The technical indicator of cement kiln coal injection pipe dedicated pouring material of the present invention is as follows:
Compared with prior art, advantage of the present invention is: mould material is made up of the materials such as aluminium titanates, synthetic moissanite, Brown Alundum, strontium titanate powder, carbonic acid zirconium powder, andaluzite, zinc silicate, terbium sesquioxide, alumina powder and Extra Section, present invention improves the heat-shock resistance of cement kiln coal injection pipe, erosion-resisting characteristics, resistance to elevated temperatures, wear resisting property, obtain good workability, improve the erosion-resisting characteristics of mould material self, obtain a kind of mould material of good performance, the work-ing life of coal injection pipe prepared by mould material extends to more than 2 times.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail.This specific embodiment is only explanation of the invention; it is not the restriction to invention; those skilled in the art can make any amendment to the present embodiment as required after reading this specification sheets, as long as but be all subject to the protection of patent law in right of the present invention.
Embodiment 1
A kind of cement kiln coal injection pipe dedicated pouring material, the weight percentage of component contained by it is:
Aluminium titanates 25%
Synthetic moissanite 20%
Brown Alundum 25%
Strontium titanate powder 8%
Carbonic acid zirconium powder 5%
Andaluzite powder 1%
Zinc silicate 3%
Alumina powder 5%
Pure calcium aluminate cement 6%
Terbium sesquioxide 2%
C 5H 10N 6O 20.2%
Heat-resistant steel fiber 0.5%
Sulfonated Copolymer of Styrene and Maleic Anhydride 0.05%
Polyethers poly carboxylic acid 0.1%
Embodiment 2
A kind of cement kiln coal injection pipe dedicated pouring material, the weight percentage of component contained by it is:
Aluminium titanates 15%
Synthetic moissanite 20%
Brown Alundum 30%
Strontium titanate powder 10%
Carbonic acid zirconium powder 8%
Andaluzite powder 2%
Zinc silicate 3%
Alumina powder 5%
Pure calcium aluminate cement 6%
Terbium sesquioxide 1%
C 5H 10N 6O 20.2%
Heat-resistant steel fiber 0.5%
Sulfonated Copolymer of Styrene and Maleic Anhydride 0.05%
Polyethers poly carboxylic acid 0.1%.
Embodiment 3
A kind of cement kiln coal injection pipe dedicated pouring material, the weight percentage of component contained by it is:
Aluminium titanates 20%
Synthetic moissanite 15%
Brown Alundum 30%
Strontium titanate powder 10%
Carbonic acid zirconium powder 8%
Andaluzite powder 2%
Zinc silicate 3%
Alumina powder 5%
Pure calcium aluminate cement 5%
Terbium sesquioxide 2%
C 5H 10N 6O 20.2%
Heat-resistant steel fiber 0.5%
Sulfonated Copolymer of Styrene and Maleic Anhydride 0.05%
Polyethers poly carboxylic acid 0.1%
Tc 2O 70.05%。
Embodiment 4
A kind of cement kiln coal injection pipe dedicated pouring material, the weight percentage of component contained by it is:
Aluminium titanates 20%
Synthetic moissanite 15%
Brown Alundum 30%
Strontium titanate powder 10%
Carbonic acid zirconium powder 8%
Andaluzite powder 2%
Zinc silicate 3%
Alumina powder 5%
Pure calcium aluminate cement 5%
Terbium sesquioxide 2%
C 5H 10N 6O 20.2%
Heat-resistant steel fiber 0.5%
Sulfonated Copolymer of Styrene and Maleic Anhydride 0.05%
Polyethers poly carboxylic acid 0.1%
Tc 2O 70.05%
Silica hydrogel powder 0.3%
Each component used in above-described embodiment well known to a person skilled in the art product, commercially all can buy, wherein the interpolation of aluminium titanates, synthetic moissanite, strontium titanate, Brown Alundum, steel fiber, is conducive to the wear resistance of mould material, thermal shock resistance; Andaluzite has micro-expansibility; The introducing of zirconium carbonate makes mould material in use obtain good performance, zirconium carbonate is decomposed to form the oxide of high activity zirconium with superperformance, and the micropore formed in decomposition course, all be conducive to the heat-shock resistance improving material, improve resistance to fouling, the phenomenon such as avoid mould material to ftracture, to drop; Zinc silicate, alumina powder simultaneously, terbium sesquioxide, in use can progressively react, and generates performance good original position aluminium zinc spinel, improves the homogeneity of structure of mould material, improve the anti acid alkali performance energy of mould material, chemical resistance of concrete performance.The Tc added 2o 7, Sulfonated Copolymer of Styrene and Maleic Anhydride, polyethers poly carboxylic acid can improve the operable time of mould material, improves the distribution of pore when mould material is constructed, flowing property, different according to temperature, suitably can regulate add-on; The C added 5h 10n 6o 2produce the micro-pore be communicated with, the steam produced when making to toast easily is discharged, and the Silica hydrogel powder activity added is high, is easy to aluminum oxide and generates mullite of good performance.After adopting above-mentioned scheme, can obtain a kind of mould material of good performance, the work-ing life of coal injection pipe prepared by mould material extends to more than 2 times.
The cement kiln coal injection pipe dedicated pouring material of above-described embodiment 1-4 is prepared by the following method: by each component mixing and stirring, then adds appropriate water mixing strong stirring evenly, subsequently shaping use after conventional maintenance and baking.
The physical index of above-described embodiment 1-4 compares and sees the following form:

Claims (7)

1. a cement kiln coal injection pipe dedicated pouring material, is characterized in that: described component comprises aluminium titanates, synthetic moissanite, Brown Alundum, strontium titanate powder, carbonic acid zirconium powder, andaluzite powder, silicic acid zinc powder, alumina powder, pure calcium aluminate cement, terbium sesquioxide.
2. a kind of cement kiln coal injection pipe dedicated pouring material according to claim 1, is characterized in that: described component also comprises C 5h 10n 6o 2, heat-resistant steel fiber, polyethers poly carboxylic acid.
3. a kind of cement kiln coal injection pipe dedicated pouring material according to claim 2, is characterized in that: described component also comprises Sulfonated Copolymer of Styrene and Maleic Anhydride and Tc 2o 7one or both.
4. a kind of cement kiln coal injection pipe dedicated pouring material according to claim 3, is characterized in that: the weight percentage of described component is:
Aluminium titanates 15-25%
Synthetic moissanite 10-20%
Brown Alundum 25-30%
Strontium titanate powder 5-10%
Carbonic acid zirconium powder 5-8%
Andaluzite powder 1-3%
Zinc silicate 3-5%
Alumina powder 5-10%
Pure calcium aluminate cement 4-6%
Terbium sesquioxide 1-2%
Additional C 5h 10n 6o 20.2%
Additional heat-resistant steel fiber 0.5%
Additional polyethers poly carboxylic acid 0.1%
Additional Sulfonated Copolymer of Styrene and Maleic Anhydride 0.05%
Additional Tc 2o 70-0.05%.
5. a kind of cement kiln coal injection pipe dedicated pouring material according to claim 4, is characterized in that: the weight percentage of described component is:
Aluminium titanates 15%
Synthetic moissanite 20%
Brown Alundum 30%
Strontium titanate powder 10%
Carbonic acid zirconium powder 8%
Andaluzite powder 2%
Zinc silicate 3%
Alumina powder 5%
Pure calcium aluminate cement 6%
Terbium sesquioxide 1%
Additional C 5h 10n 6o 20.2%
Additional heat-resistant steel fiber 0.5%
Additional polyethers poly carboxylic acid 0.1%
Additional Sulfonated Copolymer of Styrene and Maleic Anhydride 0.05%.
6. a kind of cement kiln coal injection pipe dedicated pouring material according to claim 4, is characterized in that: the weight percentage of described component is:
Aluminium titanates 20%
Synthetic moissanite 15%
Brown Alundum 30%
Strontium titanate powder 10%
Carbonic acid zirconium powder 8%
Andaluzite powder 2%
Zinc silicate 3%
Alumina powder 5%
Pure calcium aluminate cement 5%
Terbium sesquioxide 2%
Additional C 5h 10n 6o 20.2%
Additional heat-resistant steel fiber 0.5%
Additional polyethers poly carboxylic acid 0.1%
Additional Sulfonated Copolymer of Styrene and Maleic Anhydride 0.05%
Additional Tc 2o 70.05%.
7. a kind of cement kiln coal injection pipe dedicated pouring material according to claim 4, is characterized in that: described component also comprises Silica hydrogel powder, and add-on is additional 0.3%.
CN201410709663.0A 2014-12-01 2014-12-01 A kind of cement kiln coal injection pipe dedicated pouring material Active CN104355639B (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201610160478.XA CN105837228B (en) 2014-12-01 2014-12-01 A kind of Special pouring material for coal injection pipe
CN201410709663.0A CN104355639B (en) 2014-12-01 2014-12-01 A kind of cement kiln coal injection pipe dedicated pouring material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410709663.0A CN104355639B (en) 2014-12-01 2014-12-01 A kind of cement kiln coal injection pipe dedicated pouring material

Related Child Applications (3)

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CN201610160478.XA Division CN105837228B (en) 2014-12-01 2014-12-01 A kind of Special pouring material for coal injection pipe
CN201610160423.9A Division CN105712722A (en) 2014-12-01 2014-12-01 Special castable for coal-injection duct
CN201610160424.3A Division CN105712723A (en) 2014-12-01 2014-12-01 Special castable for cement kiln coal-injection duct

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106083103A (en) * 2016-06-30 2016-11-09 万燕杰 A kind of cement kiln flashboard dedicated pouring material
CN106083098A (en) * 2016-06-30 2016-11-09 张婷 A kind of grate-cooler wall castable
CN106083105A (en) * 2016-06-30 2016-11-09 张婷 A kind of airduct flashboard castable

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101514109A (en) * 2009-01-23 2009-08-26 安徽宁火新材料有限公司 Cement kiln coal injection pipe castable
CN102584295A (en) * 2012-02-29 2012-07-18 浙江锦诚耐火材料有限公司 Special pouring material for coal injection pipe
CN103771889A (en) * 2014-02-16 2014-05-07 徐梅子 Special casting material for 12000D/T kilneye
CN103979949A (en) * 2014-06-06 2014-08-13 辽宁中镁控股股份有限公司 Castable for steel ladle cover and application thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101514109A (en) * 2009-01-23 2009-08-26 安徽宁火新材料有限公司 Cement kiln coal injection pipe castable
CN102584295A (en) * 2012-02-29 2012-07-18 浙江锦诚耐火材料有限公司 Special pouring material for coal injection pipe
CN103771889A (en) * 2014-02-16 2014-05-07 徐梅子 Special casting material for 12000D/T kilneye
CN103979949A (en) * 2014-06-06 2014-08-13 辽宁中镁控股股份有限公司 Castable for steel ladle cover and application thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106083103A (en) * 2016-06-30 2016-11-09 万燕杰 A kind of cement kiln flashboard dedicated pouring material
CN106083098A (en) * 2016-06-30 2016-11-09 张婷 A kind of grate-cooler wall castable
CN106083105A (en) * 2016-06-30 2016-11-09 张婷 A kind of airduct flashboard castable

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Publication number Publication date
CN105837228B (en) 2018-06-29
CN105837228A (en) 2016-08-10
CN104355639B (en) 2016-05-04

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Inventor after: Chen Zhiyuan

Inventor before: Zhang Ting

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Effective date of registration: 20160407

Address after: 362000 Shigu, Fujian, Yongchun County town of Phoenix Village, No.

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Address before: Stone bridge town Haining city Jiaxing city Zhejiang province 314400 No. 26

Applicant before: Zhang Ting

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Inventor after: Liu Naiyong

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Effective date of registration: 20170626

Address after: 048000, Shanxi, Jincheng province Zezhou County Town Village home village (tomb Road, Dan River, 350 meters east bridge)

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Address before: 362000 Shigu, Fujian, Yongchun County town of Phoenix Village, No.

Patentee before: Chen Zhiyuan