CN104354646B - Full-sized car liquid crystal glareproof mirror - Google Patents

Full-sized car liquid crystal glareproof mirror Download PDF

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Publication number
CN104354646B
CN104354646B CN201410624113.9A CN201410624113A CN104354646B CN 104354646 B CN104354646 B CN 104354646B CN 201410624113 A CN201410624113 A CN 201410624113A CN 104354646 B CN104354646 B CN 104354646B
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liquid crystal
glass substrate
conducting glass
ito conducting
dichroic dye
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CN104354646A (en
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张健
张国敏
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Gao Hui (tianjin) Technology Co Ltd
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Gao Hui (tianjin) Technology Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60RVEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R1/00Optical viewing arrangements; Real-time viewing arrangements for drivers or passengers using optical image capturing systems, e.g. cameras or video systems specially adapted for use in or on vehicles
    • B60R1/02Rear-view mirror arrangements
    • B60R1/08Rear-view mirror arrangements involving special optical features, e.g. avoiding blind spots, e.g. convex mirrors; Side-by-side associations of rear-view and other mirrors
    • B60R1/083Anti-glare mirrors, e.g. "day-night" mirrors
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00Liquid crystal materials
    • C09K19/04Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06Non-steroidal liquid crystal compounds
    • C09K19/08Non-steroidal liquid crystal compounds containing at least two non-condensed rings
    • C09K19/30Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00Liquid crystal materials
    • C09K19/52Liquid crystal materials characterised by components which are not liquid crystals, e.g. additives with special physical aspect: solvents, solid particles
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/137Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells characterised by the electro-optical or magneto-optical effect, e.g. field-induced phase transition, orientation effect, guest-host interaction or dynamic scattering
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/137Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells characterised by the electro-optical or magneto-optical effect, e.g. field-induced phase transition, orientation effect, guest-host interaction or dynamic scattering
    • G02F1/13712Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells characterised by the electro-optical or magneto-optical effect, e.g. field-induced phase transition, orientation effect, guest-host interaction or dynamic scattering the liquid crystal having negative dielectric anisotropy

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Nonlinear Science (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Multimedia (AREA)
  • Mechanical Engineering (AREA)
  • Liquid Crystal (AREA)

Abstract

The present invention relates to car light manufacturing technology field, particularly relate to a kind of full-sized car liquid crystal glareproof mirror and include LCDs, described LCDs is mainly made up of an ITO conducting glass substrate and the 2nd ITO conducting glass substrate, and a described ITO conducting glass substrate is coated with one layer of polyimide insulative layer and alignment agent;Aluminize on described 2nd ITO conducting glass substrate or argentum reflecting layer and alignment agent;Separate with the interval insulant of 5 μ~18 μ between a described ITO conducting glass substrate and the 2nd ITO conducting glass substrate plate, make liquid crystal cell, under vacuo green liquid-crystal mixture, blue liquid crystal mixture and black liquid crystal compound are poured into respectively sealing after in each liquid crystal cell, is respectively prepared display screen.The present invention uses the cyclohexanes the completeest to ultraviolet and fluoro liquid crystals monomer, makes the nematic crystal mixing material of the negative dielectric anisotropic to UV stable, substantially increases the rearview mirror stability to ultraviolet.

Description

Full-sized car liquid crystal glareproof mirror
Technical field
The present invention relates to car light manufacturing technology field, particularly relate to a kind of full-sized car liquid crystal glareproof mirror.
Background technology
The auto industry in modern age, each parts is all along with the progressive continuous renewal of science and technology, successfully research and development and industrialization It is applied to glareproof mirror in saloon car.But heavy type transport vehicle, Medium Truck, minibus, touring car and bus etc. still make With traditional rearview mirror, when night, there was strong illumination at rear, through the reflection of rearview mirror, the eyes dizziness of driver, cause raw friendship Interpreter's event.
Electricity look rearview mirror is plating last layer electric material on transparent electrically-conductive backing plate, and the albedo of light is passed through by mirror Electrochemical process is controlled by, and makes the electrochrome optical property in electricity look mirror change by applying voltage, thus weakens rearview mirror Albedo to light.
GENTEX company of the U.S. is that the world mainly produces glareproof mirror manufacturer.Electricity look mirror is slow by bright dimmed conversion speed, Large scale rearview mirror can not be manufactured for oversize vehicle.
United States Patent (USP) U.S.Patent 3,597, the 044 a kind of technology disclosed, be liquid crystal and dyestuff are clipped in Between reflecting plate and ito glass, use the nematic crystal of positive dielectric anisotrop, under electric field action, present on state of.1988 Year Deutsche Bundespatent GB2,205,075 are disclosed that aluminium film is placed in the outer surface of bottom glass as reflecting surface, by liquid crystal and list Automobile rearview mirror made by look dyestuff.Above-described liquid crystal rearview mirror uses positive dielectric anisotropic liquid crystals to mix with dichroic dye Compound pours in liquid crystal cell.Being dark-state when no power, become on state of after energising, even if by day, rearview mirror also must be opened Electric-control system.
The quick liquid crystal rearview mirror with an automatic light meter (Chinese invention patent CN 1278887C) that discloses of state in 2004, uses negative The property nematic crystal of dielectric anisotropy, vertical orientated material, dichroic dye and relevant chemical material, make liquid crystal Show device, tie line and shell, form liquid crystal rearview mirror with an automatic light meter.This rearview mirror and with positive dielectric anisotrop to Row type liquid crystal is contrary, when daytime uses, is not required to connect power supply, and minute surface presents on state of, and its back vision function is as conventional mirror.Night The chien shih used time, when there is strong illumination at rear, photosensor triggers Circuits System, makes circuit open, and minute surface is the most dimmed, now rearview mirror Lower the albedo to light, make light not stimulate eyes, it is ensured that night safe travels.
In sum, electricity look and liquid crystal glareproof mirror, oneself is applied to little saloon car, is arranged in car.The biggest Type transport vehicle, Medium Truck, minibus, touring car and bus car external application glareproof mirror.Main cause is: anti-dazzle back vision Mirror is arranged on the outer both sides of car, and display area is big, and electricity look mirror is slow by bright dimmed conversion speed, can not manufacture large scale rearview mirror and supply Oversize vehicle uses.Liquid crystal glareproof mirror is made up of the material such as liquid crystal and dichroic dye, and these materials are to UV stable Property poor, when strong illumination, ultraviolet damage liquid crystal and dye molecule, the display screen life-span is short, in the winter time temperature be less than-20C liquid The series of problems such as brilliant material cisco unity malfunction.
Summary of the invention
It is an object of the invention to overcome the deficiency of above-mentioned technology, and a kind of full-sized car liquid crystal glareproof mirror be provided, Fast to electric field response, visual angle width, contrast is high, and range is wide, and what energy was safe is applied to heavy type transport vehicle, Medium Truck, face Hired car, touring car and bus are waited for bus.
The present invention for achieving the above object, by the following technical solutions: a kind of full-sized car liquid crystal glareproof mirror, including LCDs, current converter circuit, automatically controlled display circuit, automatically controlled heater circuit, electronic rotation control device, light-sensitive device and Housing forms.
Described LCDs is mainly made up of an ITO conducting glass substrate and the 2nd ITO conducting glass substrate, described One layer of polyimide insulative layer and alignment agent it is coated with on oneth ITO conducting glass substrate;On described 2nd ITO conducting glass substrate Aluminize or argentum reflecting layer and alignment agent;Between a described ITO conducting glass substrate and the 2nd ITO conducting glass substrate plate with 5 μ~ The interval insulant of 18 μ separates, and makes liquid crystal cell, under vacuo by liquid crystal compound, dichroic dye, ultra-violet absorber mixing Thing pours in liquid crystal cell, and LCDs is made in sealing.
Described LCDs dorsal part is provided with described electric heating circuit, and described electric heating circuit is connected with electro-hot regulator, Described LCDs dorsal part is also connected with photosensitive adjuster, and described photosensitive adjuster is connected with photosensitive tube, described LCDs Control box with rotary electric switch respectively by circuit and electronic integration block is connected.
Described liquid crystal compound is a kind of nematic crystal with negative dielectric anisotropic, is made up of 12 class liquid crystal monomers GH-LC mixed liquid crystal: it includes 3.16g CCH301,3.22g CCH501,25.5g CCN35,29.0g CCN55,2.0g CH33,2.0g CH35,2.0g CH43,2.0g CH45,3.0g PCH32,13.8g CCP502FF,6.7g CBC53F,8.0g CBC55F。
Described dichroic dye includes: JZ-01, and green dichromatism dyestuff is: aryl-1,5-diaminourea-4,8-dihydroxy Anthraquinone dye and 2-aryl, 5-dihydroxy-4-arylamino anthraquinone dye anthraquinone analog compound and JZ-02, blue dichromatism dye Material is: 1,4-diaminourea-2-(decahydro-2-fears epoxide) carbonyl Anthraquinone.
Described UV-absorber mixture is hydroxy-phenyl benzotriazole class ultra-violet absorber.
Described GH-LC mixed liquid crystal preparation method is: be separately added into 3.16g in equipped with the reaction bulb of agitator CCH301,3.22g CCH501,25.5g CCN35,29.0g CCN55,2.0g CH33,2.0g CH35,2.0g CH43, 2.0g CH45,3.0g PCH32,13.8g CCP502FF, 6.7g CBC53F, 8.0g CBC55F liquid crystal compound is under agitation It is heated to limpid, is cooled to room temperature, with 0.45 micron filter membrane filtration.
Prepare green liquid-crystal mixture: add in equipped with the reaction bulb of agitator 94,5g GH-LC mixed liquid crystal and 2.0g JZ-01 green dichroic dye, 1,0g JZ-03 ultraviolet absorber, 1.5g CB15 chiral liquid crystal mixture is under agitation It is heated to limpid, is cooled to room temperature, filter with 0.45 micron filter;Wherein, JZ-01 green dichroic dye is-aryl-1, 5-diaminourea-4,8-dihydroxy anthraquinone dyestuff, 2-aryl-5-dihydroxy-4-arylamino anthraquinone dye.
Prepare blue liquid crystal mixture: add in equipped with the reaction bulb of agitator 94,5g GH-LC mixed liquid crystal and 2.0g JZ-02 blueness dichroic dye, 1.0g JZ-03 ultraviolet absorber, 1.5g CB15, mixture is under agitation heated to Limpid, stir 15 minutes, be cooled to room temperature, with 0.45 Mm filter membrane filtration;Wherein, JZ-02 blueness dichroic dye is-1, 4-diaminourea-2-(decahydro-2-fears epoxide) carbonyl fears quinone dyes;
Prepare black liquid crystal compound: add in equipped with the reaction bulb of agitator 94,5g GH-LC mixed liquid crystal and 0.031g G168,0.093g G165,0.586g LCD-121,0.412g SI 252,0.206gG2540,206g G254, 0.298g M361,0.213g M570,0.213g LCD-117,1,0g LCD119 dichroic dye, 1.5g CB15 chirality liquid Brilliant mixture, 1.5g JZ-03 ultraviolet absorber, mixture is under agitation heated to 80 DEG C, stirs about 30 minutes, is cooled to Room temperature, crosses membrane filtration with 0.45-5 micron;Wherein, JZ-03 ultraviolet absorber is hydroxy-phenyl benzotriazole class ultra-violet absorber.
The LCDs photoelectric control circuit system of described rearview mirror, automatic control heating device, electro-motor backsight Mirror swiveling device, converting direct-current power into alternating-current power device and light-sensitive device and two kinds of modes of electric-controlled switch control display device.
The invention has the beneficial effects as follows: the present invention uses the cyclohexanes the completeest to ultraviolet and fluoro liquid crystals monomer, Make the nematic crystal mixing material of the negative dielectric anisotropic to UV stable, substantially increase rearview mirror to ultraviolet Stability.The present invention uses novel negative dielectric anisotropy nematic crystal, dichroic dye, vertical orientated material, anti-purple Outside material is made display screen and uses automatically controlled display, automatically controlled heating, electronic rotation to control device and housing composition, has excellence Optical characteristics, when apply voltage, display screen is 20-35% to the reflectivity of light, in dark-state, when being not added with voltage, rearview mirror Reflectivity to light is 65-70%, and on state of, brightness and darkness are automatically controlled by light-sensitive device, make rearview mirror manifest splendid Optics and visual effect, and can work at negative below-30C, fast to electric field response, visual angle width, contrast is high, range Extensively, can be applied to heavy type transport vehicle, Medium Truck, minibus, touring car and the bus of safety wait for bus external application anti-dazzle back vision Mirror.Benzotriazole Ultraviolet Stabilizer, has an outstanding photostability, high solubility and to liquid crystal compound intermiscibility Good.Adding this kind of material and effectively filter out the ultraviolet given off in sunshine and artificial light sources, filter ultraviolet coefficient reaches 99.9%, transparency reaches 99.9%, improves resistance to ultraviolet ability.
Accompanying drawing explanation
Fig. 1 is the display general principle structural representation of the present invention;
Fig. 2 is the structure chart of glareproof mirror.
Detailed description of the invention
Below in conjunction with the accompanying drawings and preferred embodiment describe in detail the present invention detailed description of the invention, the invention provides one Full-sized car liquid crystal glareproof mirror,
(1) main associated materials
1, liquid crystal material
The present invention uses the cyclohexanes the completeest to ultraviolet and fluoro liquid crystals monomer, makes and bears UV stable The nematic crystal mixing material of dielectric anisotropy, substantially increases the rearview mirror stability to ultraviolet.
Described plurality of liquid crystals comprises following 12 kinds of liquid crystal monocrystalline:
2, dichroic dye
UV stable is feared oxyketone dye by present invention application, including:
JZ-01 green dichroic dye: aryl-1,5-diaminourea-4,8-dihydroxy anthraquinone dyestuff, 2-aryl-5-dihydroxy Base-4-arylamino anthraquinone dye.
JZ-02 blue dichroic dye: 1,4-diaminourea-2-(decahydro-2-fears epoxide) carbonyl fears quinone dyes.These dyes Material has good dichroism, high contrast, excellent photochemical stability.
3, JZ-03 ultraviolet absorber
Present invention application hydroxy-phenyl benzotriazole class ultraviolet absorber, Benzotriazole Ultraviolet Stabilizer, have outstanding Photostability, high solubility and good to liquid crystal compound intermiscibility.Add this kind of material and effectively filter out sunshine and artificial The ultraviolet given off in light source, filter ultraviolet coefficient reaches 99.9%, and transparency reaches 99.9%, improves resistance to ultraviolet ability.
Experiment 1
The preparation of GH-LC mixed liquid crystal
3.16g CCH301,3.22g CCH501,25.5g CCN35 it is separately added in equipped with the reaction bulb of agitator, 29.0g CCN55,2.0g CH33,2.0g CH35,2.0g CH43,2.0g CH45,3.0g PCH32,13.8g CCP502FF, 6.7g CBC53F, 8.0g CBC55F liquid crystal compound is under agitation heated to limpid, is cooled to room temperature, uses 0.45 micron filter membrane filtration.
Experiment 2
The preparation of green liquid-crystal mixture
94,5g GH-LC mixed liquid crystal and 2.0g JZ-01 green dichroism dye is added in equipped with the reaction bulb of agitator Material, 1,0g JZ-03 ultraviolet absorber, 1.5g CB15 chiral liquid crystal mixture, mixture is under agitation heated to limpid, cooling To room temperature, filter with 0.45 micron filter.
Experiment 3
The preparation of blue liquid crystal compound
94,5g GH-LC mixed liquid crystal and 2.0g JZ-02 blue dichroism dye is added in equipped with the reaction bulb of agitator Material, 1.0g JZ-03 ultraviolet absorber, 1.5g CB15, mixture is under agitation heated to limpid, stirs 15 minutes, is cooled to Room temperature, with 0.45 Mm filter membrane filtration.
Experiment 4
The preparation of black liquid crystal compound
94,5g GH-LC mixed liquid crystal and 0.031g G168,0.093g is added in equipped with the reaction bulb of agitator G165,0.586g LCD-121,0.412g SI 252,0.206g G2540,206g G254,0.298g M361,0.213g The dichroic dyes such as M570,0.213 LCD-117,1,0g LCD119,1.5g CB15,1.5g JZ-3 ultraviolet absorber, mixing Thing is under agitation heated to 80 DEG C, stirs about 30 minutes, is cooled to room temperature, crosses membrane filtration with 0.45-5 micron.
(2) structure of glareproof mirror
1, LCDs
Fig. 1. for liquid-crystal displaying screen structure schematic diagram: display is by upper and lower two panels transparent ITO conducting glass substrate group Become, be respectively as follows: an ITO conducting glass substrate 1, ito glass is coated with one layer of polyimide insulative layer and alignment agent 2;The Two ITO conducting glass substrates 3, on ITO electro-conductive glass, aluminize or argentum reflecting layer and alignment agent 4;Oneth ITO electro-conductive glass base Separate with the interval insulant of 5 μ~18 μ between plate and the 2nd ITO conducting glass substrate, make liquid crystal cell 5.Under vacuo by green liquid Brilliant mixture;Blue liquid crystal compound and black liquid crystal compound pour into sealing after in each liquid crystal cell respectively, make green liquid crystal Display screen;Blue LCDs and black LCDs.The structure of glareproof mirror.
Fig. 2 is that the structure chart of glareproof mirror includes with lower component:
(1) two, left and right LCDs;
(2) D+, D-are to automatically control liquid crystal display circuit system;
(3) H+, GND are to automatically control heater circuit;
(4) electro-motor is rearview mirror whirligig;
(5) 12V converting direct-current power into alternating-current power device;
(6) control display on state of by light-sensitive device and two kinds of modes of electric-controlled switch and dark-state is changed;
(7) by temperature-sensitive device electro-hot regulator.
Transport vehicle rearview mirror includes: two, left and right LCDs, and standard size is 7 " x16 ", straight with 12 volts by automobile Stream electricity conversion electric power, is provided with switchgear box, has electronic and manual two kinds of methods and show;Automatically controlled heating, electronic rotation control Device and housing, be combined into liquid crystal glareproof mirror.
In figure exist two kinds of reflective mirrors, one is to be served only for light mirror, and one is to be served only for electronic mirror, on electronic mirror with Motor, can cross rotation, and the surface of two kinds of eyeglasses is all with electric heating system, it is possible to heat minute surface, it is therefore an objective to solve- The idle problem of this device in the case of 30 DEG C, electric heating system is connected with electro-hot regulator by wire, electro-hot regulator energy Enough regulate the temperature of electric heating system.This device is additionally provided with photosensitive adjuster, and it has photosensitive tube, it is possible to regulate the sense of this device Luminous intensity.This device is additionally provided with the switch control box of electronic rotation, and for being controlled whole circuit, the inside is provided with left and right Motor switch, display switch and some interfaces.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For Yuan, under the premise without departing from the principles of the invention, it is also possible to make some improvements and modifications, these improvements and modifications also should It is considered as protection scope of the present invention.

Claims (2)

1. a full-sized car liquid crystal glareproof mirror, it is characterised in that: include LCDs, current converter circuit, automatically controlled Display circuit, automatically controlled heater circuit, electronic rotation control device, light-sensitive device and housing composition;Described LCDs is main It is made up of an ITO conducting glass substrate and the 2nd ITO conducting glass substrate, a described ITO conducting glass substrate is coated with One layer of polyimide insulative layer and alignment agent;Aluminize on described 2nd ITO conducting glass substrate or argentum reflecting layer and alignment agent;Institute State and separate with the interval insulant of 5 μm~18 μm between an ITO conducting glass substrate and the 2nd ITO conducting glass substrate, make liquid Brilliant box, pours in liquid crystal cell by liquid crystal compound, dichroic dye, UV-absorber mixture under vacuo, and sealing is made LCDs;Described liquid crystal compound is a kind of nematic crystal with negative dielectric anisotropic, by 12 class liquid crystal monomers The GH-LC mixed liquid crystal of composition:
Comprising:
Described dichroic dye includes: green dichroic dye and blue dichroic dye, and described green dichroic dye is: virtue Base-1,5-diaminourea-4,8-dihydroxy anthraquinone dyestuff and 2-aryl-5-dihydroxy-4-arylamino anthraquinone dye, described blueness Dichroic dye is: 1,4-diaminourea-2-(decahydro-2-anthracene epoxide)-carbonyl anthraquinone analog compound;Described ultra-violet absorber mixes Compound is hydroxy-phenyl benzotriazole class ultra-violet absorber.
Full-sized car liquid crystal glareproof mirror the most according to claim 1, it is characterised in that: described GH-LC mixed liquid crystal system Preparation Method is: be separately added in equipped with the reaction bulb of agitator
Liquid crystal compound is under agitation heated to limpid, is cooled to room temperature, with 0.45 micron filter membrane filtration.
CN201410624113.9A 2014-11-07 2014-11-07 Full-sized car liquid crystal glareproof mirror Active CN104354646B (en)

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Publication number Priority date Publication date Assignee Title
CN104656294B (en) 2015-03-03 2017-05-31 京东方科技集团股份有限公司 Rearview mirror
CN107924097A (en) * 2015-05-29 2018-04-17 夏普株式会社 Liquid crystal display device
CN106627376A (en) * 2016-08-11 2017-05-10 桂林电子科技大学 Car rearview mirror device capable of automatically adjusting brightness
CN108117873A (en) * 2016-11-29 2018-06-05 京东方科技集团股份有限公司 Oriented material composition, liquid crystal display panel and preparation method thereof, display device
CN109172138A (en) * 2018-11-12 2019-01-11 江苏美信光电科技有限公司 A kind of light-operated welding mask of intelligent solar auxiliary heating liquid crystal
CN116661201B (en) * 2023-06-01 2023-11-17 莆田市佳阳电子有限公司 Anti-glare structure and rearview mirror

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030169500A1 (en) * 2002-03-06 2003-09-11 Cutaia Christopher C. Automatic glare reduction side-mirror for trucks, truck cabs and sports utility vehicles
CN1278887C (en) * 2003-10-27 2006-10-11 张国敏 Rearview mirror with light being adjusted by liquid crystal display automatically
CN202923508U (en) * 2012-11-28 2013-05-08 浙江奥尔峰光电科技有限公司 Liquid crystal display screen for automobile rearview mirror
CN203232223U (en) * 2013-04-23 2013-10-09 江西合力泰科技股份有限公司 Liquid crystal display module capable of working at low temperature
CN103242861B (en) * 2013-05-22 2014-08-20 北京市金讯阳光电子材料科技有限公司 Liquid crystal composition and application thereof

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