CN104351204B - 一种戊唑醇和大蒜素的微囊悬浮剂 - Google Patents
一种戊唑醇和大蒜素的微囊悬浮剂 Download PDFInfo
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Abstract
本发明涉及一种戊唑醇和大蒜素的微囊悬浮剂，所述微囊悬浮剂中有效成分为戊唑醇和大蒜素；助剂为多官能团酰基卤二元醇、脂肪胺聚氧乙烯嘧、乙酸乙酯、C10‑20饱和脂肪酸类、山梨醇酐硬脂酸酯、山梨酸、氢氧化钠。本发明组合物对黄瓜白粉病具有非常好的防治效果，本发明利用戊唑醇和大蒜素的杀菌活性具有较好的协同作用，有效增强了对黄瓜白粉病的预防和治疗的作用，发病前期施药见效快，且持效期长，对非靶标作物无影响。
Description
技术领域
本发明涉及一种戊唑醇和大蒜素的微囊悬浮剂，具体涉及戊唑醇和大蒜素的微囊悬浮剂用于防治黄瓜白粉病，属于农药技术领域。
背景技术
戊唑醇属三唑类杀菌剂，是甾醇脱甲基抑制剂。戊唑醇是一种高效、广谱、内吸性三唑类杀菌剂，具有保护、治疗、铲除三大功能，杀菌谱广、持效期长。该品用于防治油菜菌核病，不仅防效好，而且具有抗倒伏，增产作用明显等特点。是用于重要经济作物的种子处理或面喷洒的高效杀菌剂，可有效地防治禾谷类作物的多种锈病、白粉病、网斑病、根腐病、赤霉病等。
大蒜素(Allicin)是从百合科葱属植物大蒜(Allium Sativum)的鳞茎(大蒜头)中提取的一种有机硫化合物，也存在于洋葱和其他葱属植物中。学名二烯丙基硫代亚磺酸酯。淡黄色油状液体。沸点80-85℃(0.2kPa)，相对密度1.112(20/4℃)，折光率1.561。溶于乙醇、氯仿或乙醚。水中溶解度2.5％(质量)(10℃)，其水溶液pH值为6.5，静置时有油状物沉淀物形成。与乙醇，乙醚及苯可互溶。对热碱不稳定，对酸稳定。由存在于百合科植物大蒜的鳞茎中，由存在的大蒜氨酸在大蒜酶作用下转化产生。也存在于葱的鳞茎中。具有强烈的大蒜臭，味辣。
目前植物病菌的防治难度越来越大，一方面，随着种植结构的改变，瓜果、蔬菜等经济作物种植面积逐步扩大，病害发生程度、发生数量均有所提高，在防治上难度加大；另一方面，病原菌的抗性在持续的药剂选择压力下逐年上升，单剂的防治效果越来越弱，植物病害防治面临重大挑战。
发明内容
针对上述问题，本发明提供了一种戊唑醇和大蒜素的微囊悬浮剂，本发明效果好、持效长，对非靶标作物安全。
本发明的技术方案如下：
一种戊唑醇和大蒜素的微囊悬浮剂，其中，有效成分为戊唑醇和大蒜素；助剂为多官能团酰基卤二元醇、脂肪胺聚氧乙烯醚、乙酸乙酯、C10-20饱和脂肪酸类、山梨醇酐硬脂酸酯、山梨酸、氢氧化钠。
进一步的，本发明组合物中各原料组分按重量百分数计：
戊唑醇1％-50％、大蒜素0.1％-1％、多官能团酰基卤二元醇5％-10％、脂肪胺聚氧乙烯醚5％-10％、乙酸乙酯5％-10％、C10-20饱和脂肪酸类0.1％-0.5％、山梨醇酐硬脂酸酯3％-9％、山梨酸0.1％-1％、氢氧化钠0.05％-0.3％、去离子水加至100％。
进一步的，本发明组合物中各原料组分按重量百分数计：
戊唑醇10％-40％、大蒜素0.1％-0.5％、多官能团酰基卤二元醇6％-9％、脂肪胺聚氧乙烯醚6％-9％、乙酸乙酯6％-9％、C10-20饱和脂肪酸类0.2％-0.4％、山梨醇酐硬脂酸酯4％-8％、山梨酸0.2％-0.8％、氢氧化钠0.1％-0.2％、去离子水加至100％。
更进一步的，本发明组合物中各原料组分按重量百分数计：
戊唑醇30％、大蒜素0.3％、多官能团酰基卤二元醇7％、脂肪胺聚氧乙烯醚8％、乙酸乙酯6％、C10-20饱和脂肪酸类0.3％、山梨醇酐硬脂酸酯5％、山梨酸0.5％、氢氧化钠0.2％、去离子水加至100％。
本发明用于防治黄瓜白粉病；施药方式为喷雾；施药时期为发病初期；每年施药次数为1或2次；本发明有效成分用药量为8克/公顷-15克/公顷，优选的，用药量为9.3克/公顷。
本发明组合物对黄瓜白粉病具有非常好的防治效果，本发明利用戊唑醇和大蒜素的杀菌活性具有较好的协同作用，有效增强了对黄瓜白粉病的预防和治疗的作用，发病前期施药见效快，且持效期长，对非靶标作物无影响。
具体实施方式
下面结合具体实施例来进一步描述本发明，本发明的优点和特点将会随着描述而更为清楚。但实施例仅是范例性的，并不对本发明的范围构成任何限制。本领域技术人员应该理解的是，在不偏离本发明的精神和范围下可以对本发明技术方案的细节和形式进行修改或替换，但这些修改和替换均落入本发明的保护范围内。
实施例1
30％戊唑醇和0.3％大蒜素微囊悬浮剂
各原料组分按重量百分数计：
戊唑醇30％、大蒜素0.3％、多官能团酰基卤二元醇7％、脂肪胺聚氧乙烯醚8％、乙酸乙酯6％、C10-20饱和脂肪酸类0.3％、山梨醇酐硬脂酸酯5％、山梨酸0.5％、氢氧化钠0.2％、去离子水加至100％。
将上述各成分应用常规农药加工技术，制成的适合农业上使用的微囊悬浮剂制品。本实施例中戊唑醇和大蒜素的共毒系数为221.54。
实施例2
40％戊唑醇和0.1％大蒜素微囊悬浮剂
各原料组分按重量百分数计：
戊唑醇40％、大蒜素0.1％、多官能团酰基卤二元醇6％、脂肪胺聚氧乙烯醚7％、乙酸乙酯6％、C10-20饱和脂肪酸类0.2％、山梨醇酐硬脂酸酯4％、山梨酸0.15％、氢氧化钠0.1％、去离子水加至100％。
将上述各成分应用常规农药加工技术，制成的适合农业上使用的微囊悬浮剂制品。本实施例中戊唑醇和大蒜素的共毒系数为188.95。
实施例3
10％戊唑醇和1％大蒜素微囊悬浮剂
各原料组分按重量百分数计：
戊唑醇10％、大蒜素1％、多官能团酰基卤二元醇8％、脂肪胺聚氧乙烯醚8％、乙酸乙酯6％、C10-20饱和脂肪酸类0.3％、山梨醇酐硬脂酸酯8％、山梨酸0.3％、氢氧化钠0.2％、去离子水加至100％。
将上述各成分应用常规农药加工技术，制成的适合农业上使用的微囊悬浮剂制品。本实施例中戊唑醇和大蒜素的共毒系数为175.64。
试验例1本发明对黄瓜白粉病的防治效果
1、试验方法
试验地点在山东省聊城市，供试作物为黄瓜，试验设每亩对照共10个处理，每处理重复4次，随机区组排列，小区面积为40平方米。
2、调查时间和次数
在施药前、第1次药后7天及第2次施药后7天、14天，每小区采用对角线5点取样，每点调查20株，逐叶分级调查发病程度，计算病指及防治效果。
分级标准如下：
0级：无病；
1级：病斑面积占整片叶面积的5％以下；
3级：病斑面积占整片叶面积的6％-15％；
5级：病斑面积占整片叶面积的16％-25％；
7级：病斑面积占整片叶面积的26％-50％；
9级：病斑面积占整片叶面积的50％以上。
3、药效计算方法
病叶率(％)＝病叶数/调查总叶数×100；
病情指数＝∑(各级病叶数×相对级数值)/(调查总叶数×9)×100
防治效果(％)＝[1-(空白对照区药前病情指数×处理区药后病情指数)/(空白对照区药后病情指数×处理区药前病情指数)]×100。
4、药害调查方法
施药后连续14d目测药剂对作物是否有药害。
5、试验结果及分析
各处理防治黄瓜白粉病的效果如表1所示：
表1 本发明微囊悬浮剂对黄瓜白粉病的防治效果
实验结果表明，本发明微囊悬浮剂对黄瓜白分病防治效果显著，且对非靶标作物无影响。
Claims (1)
1.一种戊唑醇和大蒜素的微囊悬浮剂，其特征在于，所述微囊悬浮剂中各原料组分按重量百分数计：
戊唑醇30％、大蒜素0.3％、多官能团酰基卤二元醇7％、脂肪胺聚氧乙烯醚8％、乙酸乙酯6％、C10-20饱和脂肪酸类0.3％、山梨醇酐硬脂酸酯5％、山梨酸0.5％、氢氧化钠0.2％、去离子水加至100％。
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Citations (3)
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|---|---|---|---|---|
| CN103250707A (zh) * | 2012-02-15 | 2013-08-21 | 陕西美邦农药有限公司 | 一种含烯丙苯噻唑与三唑类的农药组合物 |
| CN103355343A (zh) * | 2013-07-26 | 2013-10-23 | 海南正业中农高科股份有限公司 | 含有硫磺的农用组合物 |
| CN103651337A (zh) * | 2012-09-24 | 2014-03-26 | 宜德雅(北京)科技有限公司 | 一种杀菌增效悬浮剂组合物 |
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| CN103250707A (zh) * | 2012-02-15 | 2013-08-21 | 陕西美邦农药有限公司 | 一种含烯丙苯噻唑与三唑类的农药组合物 |
| CN103651337A (zh) * | 2012-09-24 | 2014-03-26 | 宜德雅(北京)科技有限公司 | 一种杀菌增效悬浮剂组合物 |
| CN103355343A (zh) * | 2013-07-26 | 2013-10-23 | 海南正业中农高科股份有限公司 | 含有硫磺的农用组合物 |
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