CN104342928A - Bamboo-fiber gridding cloth containing environment-friendly bonding agent - Google Patents
Bamboo-fiber gridding cloth containing environment-friendly bonding agent Download PDFInfo
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- CN104342928A CN104342928A CN201410533381.XA CN201410533381A CN104342928A CN 104342928 A CN104342928 A CN 104342928A CN 201410533381 A CN201410533381 A CN 201410533381A CN 104342928 A CN104342928 A CN 104342928A
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Abstract
The invention relates to a textile and particularly relates to bamboo-fiber gridding cloth containing an environment-friendly bonding agent. The bamboo-fiber gridding cloth is prepared by the following steps: preparation of bamboo fiber; preparation of gridding cloth, namely, turning the cloth, cutting weft yarns, sewing ends, singeing on single surface, retreating, cooking, bleaching, mercerizing, dyeing, straightening wefts, impregnating and stentering; and the impregnation comprises the following steps: impregnating the cloth after weft straightening into an environment-friendly bonding agent for 18-25 minutes, and then draining gum for 5-8 minutes, wherein the environment-friendly bonding agent comprises the following materials in parts by weight: phthalic anhydride, furfuryl alcohol extracted from natural plants, triethylene glycol, glutaric acid, butantriol, zinc oxide, magnesium oxide, chloroprene rubber, 70-95 parts of elastic rubber, 2-3 parts of softening oil, dimethyl carbonate, benzoyl peroxide, acetic ether, emulsifying agent, 20-30 parts of flour, 5*10<-5>-9*10<-5> and flame retardant; and the elastic rubber comprises first elastic rubber and second elastic rubber which are mixed according to the weight ratio of (1-3):1. The bamboo-fiber gridding cloth prepared by the invention is good in softness and antibacterial property.
Description
Technical field
The present invention relates to a kind of textiles, particularly relate to a kind of bamboo fibre grid cloth containing environmental protection binding agent.
Background technology
Bamboo fibre in the market has following two classes: one is the regenerated fiber produced by bamboo pulp, is commonly referred to bamboo pulp fiber; Two is the fibers directly extracted from bamboo through special process, is called bamboo fiber.Because bamboo fiber has more superior performance in hygroscopicity, gas permeability, spinnability etc., therefore study spinnability bamboo fiber and there is obvious economic benefit and good social benefit.
China's bamboo fiber manufacture method has many patents of invention in recent years, CN11078520C announces and a kind ofly former bamboo is opened bar, kicker, the manufacture method of formation bamboo fiber bundle goods, CN1261290C have announced a kind of method former bamboo bamboo chip being adopted pure physics, by boiling sub-wire, desaccharification, degrease, protein, after starch process, through mechanical impact, tear, shredding becomes bamboo fibre.CN1185086C has announced by operations such as cold rolling, poach leaching, dehydration and comb fibers processed, and the fiber of acquisition is mainly for the production of bamboo fiberboard.CN1217038 has announced a kind of preparation method of bamboo fiber from bamboo, and this preparation method is prepared by sample, soften, wash, roll, wash, urinate oxygen process, washing, alkali lye kiering, washing, Urea bleaching, pickling, dewater, shake up, the step sequence such as to dry can obtain bamboo fibre.
But said method production stage is loaded down with trivial details, the processing time is long, and the fineness of bamboo fiber products and pliability need to improve.
In addition, although bamboo fiber products itself has certain biocidal property, but still can produce mildew after repeated use, affect perception and use.
Summary of the invention
The object of this invention is to provide the bamboo fibre grid cloth containing environmental protection binding agent that a kind of pliability and the good bamboo fibre of biocidal property are made.
Above-mentioned technical purpose of the present invention is achieved by the following technical programs:
A bamboo fibre grid cloth containing environmental protection binding agent, it is prepared from by following steps:
(1) bamboo fibre preparation: comprise and select materials, flatten, flood flame treatment, softening, fibrillation, boiling, pickling, bamboo vinegar process and micro-wave vacuum;
Described bamboo vinegar process comprises a bamboo vinegar process and the process of secondary bamboo vinegar, a bamboo vinegar process is 20-40min in bamboo vinegar treatment fluid bamboo fibre being immersed in 40-50 DEG C, the process of secondary bamboo vinegar is 10-30min in secondary bamboo vinegar treatment fluid bamboo fibre being immersed in 55-80 DEG C, a described bamboo vinegar treatment fluid is the bamboo vinegar aqueous solution of 20-30g/L, and described secondary bamboo vinegar treatment fluid is the mixed solution of the bamboo vinegar of weight ratio 1:0.1-0.2:60-100, ethylenediamine tetra-acetic acid and water composition;
(2) grid cloth preparation: comprise step: turn over cloth, sanction opened by weft yarn, margin to seam, one side are singed, move back and boil drift, mercerising, dyeing, whole latitude, impregnation and tentering;
Described impregnation comprises in the immersion of the cloth after by whole latitude environmental protection binding agent and keeps 18-25min, then drop glue 5-8min;
Described environmental protection binding agent is made up of the raw material of following parts by weight:
Phthalic anhydride 25-35 part, the furfuryl alcohol 7-11 part of extracting from natural plants, triethylene glycol 10-12 part, glutaric acid 15-18 part, butantriol 8-10 part, Zinc Oxide 5-7 part, magnesia 3-5 part, neoprene 15-25 part, elastic plastic 70-95 part, softening oil 2-3 part, dimethyl carbonate 15-20 part, benzoyl peroxide 1-3 part, ethyl acetate 4-8 part, emulsifying agent 1-4 part, flour 20-30 part, Nano Silver 5 × 10
-5-9 × 10
-5part, fire retardant 1-3 part;
Described emulsifying agent is one or more in OPEO, sulfonated castor oil, lauryl sodium sulfate, neopelex;
Described elastic plastic comprises the first elastic plastic and the second elastic plastic that mix by weight 1-3:1;
The solids content that described first elastic plastic comprises 10-35 part weight is the emulsion acrylic resin of 60-75%, 10-15 part aqueous polyurethane, the acrylic resin powder of 5-8 part weight, the solids content of 2-6 part weight are the EVA emulsion of 20-35% and the chlorinated polypropylene of 1-4 part weight;
The preparation method of described emulsion acrylic resin is: the acrylate monomer mixed liquor of preparation 80-110 part weight is stand-by, then the emulsifying agent of 5-7 part weight of several compositions in OPEO, sulfonated castor oil, lauryl sodium sulfate, neopelex, the sodium bicarbonate of 0.3-0.7 part weight and deionized water are joined in reactor, add the 1/3 acrylate monomer mixed liquor prepared again wherein, be warming up to 50-90 DEG C, fully stir 20-40min; Be warming up to 60-100 DEG C, drip remaining 2/3 acrylate monomer mixed liquor and ammonium persulfate solution initator, time for adding controls, for 1-4h, to ensure that monomer drips prior to initiator solution; Dropwise rear insulation 1-4h, after cooling, regulate ph value of emulsion to about 7;
The preparation method of described second elastic plastic is: be that the polyvinyl alcohol water solution of 30-45% and the aqueous polyurethane aqueous solution of 5-10% are heated to 60-80 DEG C by mass concentration, be cooled to 30-50 DEG C and add acrylate 10-15%, then add potassium hydroxide 0.1-0.2% and be warming up to 100-110 DEG C, then the plant phenols 2-4% adding sclerotin albumen 5-8%, rosin fat 6-9%, extract from natural plants; React and be cooled to 45-55 DEG C in 3-5 hour, then add Sodium Benzoate 0.06-0.08%, di-tert-butyl peroxide 0.01-0.02% and ethyl acetate 0.1-0.3%, stir 1-1.5 hour, cooling, obtained described second elastic plastic;
Described Nano Silver is prepared from according to following steps:
A. sodium dodecyl sulfate solution, water polyacrylic acid and hydrazine hydrate solution are added in silver nitrate aqueous solution and obtain mixed liquor, the mol ratio of described dodecyl sodium sulfate and silver nitrate is 4-6:1; The mol ratio of described water polyacrylic acid and silver nitrate is 0.4-0.6:1; ; The mol ratio of described hydrazine hydrate and silver nitrate is 0.2-0.3:1;
B. in described mixed liquor, add crown ether and sodium metaphosphate, the mol ratio of described crown ether and silver nitrate is 3-5:1; The mol ratio of described sodium metaphosphate and silver nitrate is 0.8-1.3:1, and control ph is 8-9, obtains Nano Silver.
Advantage of the present invention is:
1. environmental protection binding agent composition of the present invention environmental protection, while the larger adhesive force of imparting bamboo fiber products, can prevent binding agent from coming off, and increases bactericidal properties and the mildew resistance of bamboo fiber products;
2. the second elastic plastic not only environmental protection, water-fast, mildew-resistant, and bonding strength is high, with the first elastic plastic in proportion combination matching in environmental protection binding agent, some performance of binding agent can be improved simultaneously with the combination matching of Nano Silver, furfuryl alcohol, benzoyl peroxide and elastic plastic, and make it have very strong sterilizing ability, stability, dispersive property and bond properties simultaneously;
3. crown ether have hydrophobic external skeletal and hydrophilic can with the inner chamber of metal ion Cheng Jian, stable complex can be formed with alkali metal ion.Meanwhile, the present invention is engaged in follow-up reduction reaction and adds sodium metaphosphate, makes on the one hand free in reaction system or exposed reduction anion have higher reactivity; Meanwhile, after alkali metal and crown ether generation ligand complex, alkali metal cation is coated in inner chamber by crown ether, just pulls open the distance in Nano Silver system between positive and negative charge thus, make Nano Silver can stable dispersion in the aqueous solution, not easily reunite;
4., by each raw material of binding agent and the particular combination of Nano Silver, can not occur to reunite and particle growth in depositing, and can not be oxidized, stability and good dispersion;
5. the bamboo fibre grid cloth prepared by the inventive method also has more excellent pliability, bulking intensity and smooth feeling concurrently simultaneously, and feel is better.
As preferably, sanction opened by weft yarn time prepared by described step (2) grid cloth is cut apart with a knife or scissors by weft yarn by fabric; Described margin to seam is that margin to seam between board, between fabric is carried out the parallel margin to seam of weft yarn;
Described moving back is boiled drift and is comprised moving back and boil and oxygen bleaching, adopts and boils drift combined production line, after adopting six lattice adverse current open washings, carry out roll compacting to control moisture content for 45-55%, then directly pad liquid lime chloride and fabric decatize is bleached fabric;
Making fabric contain damp rate during described mercerising controls at 25-35%, carries out half wet mercerising in the mercerising solution comprising 265-300g/L sodium hydroxide, 5-8g/L alkylol sulfuric ester sodium salt;
Described tentering passes through with speed of a motor vehicle 45-50m/min, and aftertreatment fluid comprises antistatic additive SN, and the concentration of described antistatic additive SN in aftertreatment fluid is 0.5-2g/L;
In described whole latitude process, the speed of a motor vehicle is 90-120m/min, detects weft yarn latitude shifting state by photovoltaic, passes to automatic weft yarn reorganizer give the arrangement of high accuracy weft yarn to fabric weft yarn by computer calculating, then carry out correcting and showing, weft yarn latitude is moved within 1CM/150CM.
Adopt method of the present invention the to prepare weft yarn latitude amount of moving that grid cloth can control cloth grid more exactly.
As preferably, described emulsion acrylic resin is synthesized as monomer and emulsifying agent, ammonium persulfate initiator, sodium bicarbonate and deionized water by any one or a few in any one or a few in methyl methacrylate, ethyl methacrylate, butyl methacrylate, butyl acrylate, isobutyl methacrylate, dodecylacrylate, octadecyl acrylate and methacrylic acid, acrylic acid, acrylamide, acrylonitrile, Methacrylamide, styrene.
As preferably, described mixed liquor is heated to 45-55 DEG C add crown ether and sodium metaphosphate in described mixed liquor before by described step B; Described step B is heated to 70-85 DEG C add crown ether and sodium metaphosphate in described mixed liquor after, Keep agitation 5-8min.
As preferably, described step B carries out under microwave vacuum condition, and be specifically evacuated to vacuum for-0.02MPa ~-0.001MPa, then carry out microwave treatment, microwave frequency is 100MHz ~ 230MHz, and microwave treatment time is 3 ~ 7s.
As preferably, containing catalyst 0.8-2.5 part in described environmental protection binding agent.
More preferably, described catalyst is NaOH.
As preferably, described crown ether is bicyclohexane also-18-hat-6
As preferably, the described furfuryl alcohol extracted from natural plants is selected from the furfuryl alcohol extracted from the wheat bran or bamboo wood chip of the core slag of corncob, oat or wheat.
More preferably, the described plant phenols extracted from natural plants is eugenol or anacardol.
As preferably, described one side singeing specifically gas singeing, singes twice, speed of a motor vehicle 80-85m/min in two burner fronts.
In sum, the present invention has following beneficial effect:
1, the bamboo fibre grid cloth that prepared by the present invention has good pliability, bulking intensity and smooth feeling, and feel is better;
2, the bamboo fibre grid cloth biocidal property prepared of the present invention is good.
Detailed description of the invention
Embodiment one
The preparation of Nano Silver:
A. sodium dodecyl sulfate solution, water polyacrylic acid and hydrazine hydrate solution are added in silver nitrate aqueous solution and obtain mixed liquor, the mol ratio of dodecyl sodium sulfate and silver nitrate is 4:1; The mol ratio of water polyacrylic acid and silver nitrate is 0.4:1; The mol ratio of hydrazine hydrate and silver nitrate is 0.2:1;
B. in mixed liquor, add bicyclohexane also-18-hat-6 and sodium metaphosphate, bicyclohexane also-18-hat-6 is 3:1 with the mol ratio of silver nitrate; The mol ratio of sodium metaphosphate and silver nitrate is 0.8:1, and control ph is 8-9, obtains Nano Silver.
Composition and ratio for the environmental protection binding agent of bamboo fiber products:
Phthalic anhydride 25 parts, the furfuryl alcohol 7 parts extracted from the core slag of corncob, triethylene glycol 10 parts, glutaric acid 15 parts, butantriol 8 parts, Zinc Oxide 5 parts, 3 parts, magnesia, neoprene 15 parts, elastic plastic 70 parts, softening oil 2 parts, dimethyl carbonate 15 parts, benzoyl peroxide 1 part, ethyl acetate 4 parts, emulsifying agent 1 part, 20 parts, flour, Nano Silver 5 × 10
-5, fire retardant 3 parts;
Fire retardant is counted composed of the following components by weight: ammonium low polyphosphate 20 parts, 10 parts, ammonium phosphate, ammonium pyrophosphate 6 parts, 5 parts, ammonium sulfate, boric acid 5 parts, 25 parts, water.
Emulsifying agent is OPEO;
Elastic plastic comprises the first elastic plastic and the second elastic plastic that mix by weight 1:1;
The solids content that first elastic plastic comprises 10 parts of weight is the emulsion acrylic resin of 60-75%, 10 parts of aqueous polyurethanes, the acrylic resin powder of 5 parts of weight, the solids content of 2 parts of weight are the EVA emulsion of 20% and the chlorinated polypropylene of 1 part of weight;
The preparation of emulsion acrylic resin:
4.63 parts of OPEOs (OP-10), 1.67 parts of lauryl sodium sulfate, 0.6 part of sodium bicarbonate are dissolved in 70 parts of deionized waters, then add in reactor, are warming up to about 70 DEG C; Take 1.3 parts of methyl methacrylates, 2.14 parts of styrene, 50.9 parts of butyl acrylates, 29.08 parts of Isooctyl acrylate monomers, 2.45 parts of butyl methacrylates, 1.8 parts of acrylonitrile, 0.8 part of acrylic acid and 1.44 parts of methacrylic acids make mix monomer; 1/3 part of mix monomer is added in reactor, at 85 DEG C of pre-emulsification 30min; Then 0.45 part of initiator ammonium persulfate (APS) joined and make solution in 50 parts of deionized waters and drop to gradually in reactor, drip residual monomer, about 3h dropwises simultaneously, controls mix monomer and drips prior to initiator solution; After dropwising, after insulation 1h, namely can be made into stand-by emulsion;
The preparation of acrylic resin powder: 3 parts of BPO are dissolved in 13.3 parts of methyl methacrylates, 61 parts of styrene, 21.4 parts of n-butyl acrylates and 4.3 parts of acrylic acid mix monomers; The mix monomer being dissolved with initator is joined and is dissolved with in 500 parts of deionized waters of 7.5 parts of protecting colloids, high-speed stirred, in 30min, be warming up to 85 DEG C simultaneously; Product is collected after insulation reaction 4h; Product is dried after pulverizing, make acrylic resin powder with 200 eye mesh screens filtrations stand-by.
The preparation method of the second elastic plastic is: be that the polyvinyl alcohol water solution of 30% and the aqueous polyurethane aqueous solution of 5% are heated to 60 DEG C by mass concentration, be cooled to 30 DEG C and add acrylate 10%, then add potassium hydroxide 0.1% and be warming up to 100 DEG C, then add sclerotin albumen 5%, rosin fat 6%, eugenol 2%; React and be cooled to 45 DEG C in 3 hours, then add Sodium Benzoate 0.06%, di-tert-butyl peroxide 0.01% and ethyl acetate 0.1%, stir 1 hour, cooling, obtained second elastic plastic.
Bamboo fibre grid cloth containing environmental protection binding agent, it comprises the following steps successively:
(1) bamboo fibre preparation: comprise and select materials, flatten, flood flame treatment, softening, fibrillation, boiling, pickling, bamboo vinegar process and micro-wave vacuum;
Described bamboo vinegar process comprises a bamboo vinegar process and the process of secondary bamboo vinegar, a bamboo vinegar process is 20min in bamboo vinegar treatment fluid bamboo fibre being immersed in 40 DEG C, the process of secondary bamboo vinegar is 10min in secondary bamboo vinegar treatment fluid bamboo fibre being immersed in 55 DEG C, a described bamboo vinegar treatment fluid is the bamboo vinegar aqueous solution of 20g/L, and described secondary bamboo vinegar treatment fluid is the mixed solution of the bamboo vinegar of weight ratio 1:0.1:60, ethylenediamine tetra-acetic acid and water composition;
(2) grid cloth preparation: comprise step: turn over cloth, sanction opened by weft yarn, margin to seam, one side are singed, move back and boil drift, mercerising, dyeing, whole latitude, impregnation and tentering;
Described impregnation comprises in the immersion of the cloth after by whole latitude environmental protection binding agent and keeps 18min, then drop glue 5min.
Sanction opened by weft yarn is cut apart with a knife or scissors by weft yarn by fabric; Described margin to seam is that margin to seam between board, between fabric is carried out the parallel margin to seam of weft yarn;
One side singeing specifically gas singeing, singes twice, speed of a motor vehicle 83m/min in two burner fronts;
Move back and boil drift and comprise moving back and boil and oxygen bleaching, adopt and boil drift combined production line, after adopting six lattice adverse current open washings, roll compacting is carried out to control moisture content for 45% to fabric, then directly pads liquid lime chloride and fabric decatize is bleached;
Making fabric contain damp rate during mercerising controls 25%, carries out half wet mercerising in the mercerising solution comprising 265g/L sodium hydroxide, 5g/L alkylol sulfuric ester sodium salt;
Described tentering passes through with speed of a motor vehicle 45m/min, and aftertreatment fluid comprises antistatic additive SN, and the concentration of described antistatic additive SN in aftertreatment fluid is 0.5g/L;
In whole latitude process, the speed of a motor vehicle is 90m/min, detects weft yarn latitude shifting state by photovoltaic, passes to automatic weft yarn reorganizer give the arrangement of high accuracy weft yarn to fabric weft yarn by computer calculating, then carry out correcting and showing, weft yarn latitude is moved within 1CM/150CM.
Embodiment two
The preparation of Nano Silver:
A. sodium dodecyl sulfate solution, water polyacrylic acid and hydrazine hydrate solution are added in silver nitrate aqueous solution and obtain mixed liquor, the mol ratio of dodecyl sodium sulfate and silver nitrate is 6:1; The mol ratio of water polyacrylic acid and silver nitrate is 0.6:1; ; The mol ratio of hydrazine hydrate and silver nitrate is 0.3:1;
B. in mixed liquor, add bicyclohexane also-18-hat-6 and sodium metaphosphate, bicyclohexane also-18-hat-6 is 5:1 with the mol ratio of silver nitrate; The mol ratio of sodium metaphosphate and silver nitrate is 1.3:1, and control ph is 8-9, obtains Nano Silver.
Composition and ratio for the environmental protection binding agent of bamboo fiber products:
Phthalic anhydride 35 parts, the furfuryl alcohol 11 parts, triethylene glycol 12 parts, glutaric acid 18 parts, butantriol 10 parts, Zinc Oxide 7 parts, 5 parts, magnesia, neoprene 25 parts, elastic plastic 95 parts, softening oil 3 parts, dimethyl carbonate 20 parts, benzoyl peroxide 3 parts, ethyl acetate 8 parts, emulsifying agent 4 parts, 30 parts, flour, the Nano Silver 5 × 10 that extract from the wheat bran of oat or wheat
-5-9 × 10
-5, fire retardant 1 part;
Fire retardant is counted composed of the following components by weight: ammonium low polyphosphate 50 parts, 25 parts, ammonium phosphate, ammonium pyrophosphate 12 parts, 20 parts, ammonium sulfate, boric acid 10 parts, 10 parts, water.
Emulsifying agent is lauryl sodium sulfate;
Elastic plastic comprises the first elastic plastic and the second elastic plastic that mix by weight 3:1;
The solids content that first elastic plastic comprises 35 parts of weight is the emulsion acrylic resin of 75%, 15 parts of aqueous polyurethanes, the acrylic resin powder of 8 parts of weight, the solids content of 6 parts of weight are the EVA emulsion of 35% and the chlorinated polypropylene of 4 parts of weight;
The preparation of emulsion acrylic resin: 5.28 parts of sulfonated castor oils, 1.84 parts of lauryl sodium sulfate, 0.66 part of sodium bicarbonate are dissolved in 70 parts of deionized waters, then join in reactor, are warming up to about 70 DEG C; Take 6.12 parts of methyl methacrylates, 62.78 parts of butyl acrylates, 11.58 parts of styrene, 7.35 parts of butyl methacrylates, 0.88 part of acrylic acid, 1.58 parts of methacrylic acids, 8.7 parts of Isooctyl acrylate monomers make mix monomer; 1/3 part of mix monomer is added in reactor, at 85 DEG C of pre-emulsification 30min; Then joined by 0.5 part of initiator A PS and make solution in 50 parts of deionized waters and drop to gradually in reactor, drip residual monomer, about 3h dropwises simultaneously, controls mix monomer and drips prior to initiator solution; After dropwising, after insulation 1h, namely can be made into stand-by emulsion;
The preparation of acrylic resin powder: 4 parts of BPO are dissolved in 15.96 parts of methyl methacrylates, 65 parts of styrene, 23.54 parts of n-butyl acrylates, 4.3 parts of acrylic acid mix monomers; The mix monomer being dissolved with initator is joined and is dissolved with in 600 parts of deionized waters of 8 parts of protecting colloids, high-speed stirred, in 30min, be warming up to 85 DEG C simultaneously; Product is collected after insulation reaction 4h; Product is dried after pulverizing, make acrylic resin powder with 200 eye mesh screens filtrations stand-by.
The preparation method of the second elastic plastic is: be that the polyvinyl alcohol water solution of 38% and the aqueous polyurethane aqueous solution of 9% are heated to 80 DEG C by mass concentration, be cooled to 50 DEG C and add acrylate 15%, then add potassium hydroxide 0.2% and be warming up to 110 DEG C, then add sclerotin albumen 8%, rosin fat 9%, anacardol 2-4%; React and be cooled to 55 DEG C in 5 hours, then add Sodium Benzoate 0.08%, di-tert-butyl peroxide 0.02% and ethyl acetate 0.3%, stir 1.5 hours, cooling, obtained second elastic plastic.
Bamboo fibre grid cloth containing environmental protection binding agent, it comprises the following steps successively:
(1) bamboo fibre preparation: comprise and select materials, flatten, flood flame treatment, softening, fibrillation, boiling, pickling, bamboo vinegar process and micro-wave vacuum;
Described bamboo vinegar process comprises a bamboo vinegar process and the process of secondary bamboo vinegar, a bamboo vinegar process is 40min in bamboo vinegar treatment fluid bamboo fibre being immersed in 50 DEG C, the process of secondary bamboo vinegar is 30min in secondary bamboo vinegar treatment fluid bamboo fibre being immersed in 80 DEG C, a described bamboo vinegar treatment fluid is the bamboo vinegar aqueous solution of 30g/L, and described secondary bamboo vinegar treatment fluid is the mixed solution of the bamboo vinegar of weight ratio 1:0.2:100, ethylenediamine tetra-acetic acid and water composition;
(2) grid cloth preparation: comprise step: turn over cloth, sanction opened by weft yarn, margin to seam, one side are singed, move back and boil drift, mercerising, dyeing, whole latitude, impregnation and tentering;
Turn over cloth requirement unanimously positive and negative, margin to seam is straight, requires flat, straight, neat, firm, and pin is close at 40-45 pin/15cm, and both sides are encrypted to 4-6 pin/cm, prevents from dyeing and printing process, produce wrinkle bar, skew of weft, crimping
Sanction opened by weft yarn is cut apart with a knife or scissors by weft yarn by fabric; Described margin to seam is that margin to seam between board, between fabric is carried out the parallel margin to seam of weft yarn;
One side singeing specifically gas singeing, singes twice, speed of a motor vehicle 80m/min in two burner fronts;
Move back and boil drift and comprise moving back and boil and oxygen bleaching, adopt and boil drift combined production line, after adopting six lattice adverse current open washings, roll compacting is carried out to control moisture content for 55% to fabric, then directly pads liquid lime chloride and fabric decatize is bleached;
Making fabric contain damp rate during mercerising controls 35%, carries out half wet mercerising in the mercerising solution comprising 300g/L sodium hydroxide, 8g/L alkylol sulfuric ester sodium salt;
In whole latitude process, the speed of a motor vehicle is 120m/min, detects weft yarn latitude shifting state by photovoltaic, passes to automatic weft yarn reorganizer give the arrangement of high accuracy weft yarn to fabric weft yarn by computer calculating, then carry out correcting and showing, make weft yarn latitude move within 1CM/150CM;
Impregnation comprises in the immersion of the cloth after by whole latitude environmental protection binding agent and keeps 18-25min, then drop glue 8min;
Described tentering passes through with speed of a motor vehicle 50m/min, and aftertreatment fluid comprises antistatic additive SN, and the concentration of described antistatic additive SN in aftertreatment fluid is 2g/L.
Embodiment three
The preparation of Nano Silver:
A. sodium dodecyl sulfate solution, water polyacrylic acid and hydrazine hydrate solution are added in silver nitrate aqueous solution and obtain mixed liquor, the mol ratio of dodecyl sodium sulfate and silver nitrate is 5:1; The mol ratio of water polyacrylic acid and silver nitrate is 0.5:1; ; The mol ratio of hydrazine hydrate and silver nitrate is 0.25:1;
B. in mixed liquor, add bicyclohexane also-18-hat-6 and sodium metaphosphate, bicyclohexane also-18-hat-6 is 4:1 with the mol ratio of silver nitrate; The mol ratio of sodium metaphosphate and silver nitrate is 1:1, and control ph is 8-9, obtains Nano Silver.
Composition and ratio for the environmental protection binding agent of bamboo fiber products:
Phthalic anhydride 30 parts, the furfuryl alcohol 7-11 part extracted from bamboo wood chip, triethylene glycol 11 parts, glutaric acid 16 parts, butantriol 9 parts, Zinc Oxide 6 parts, 4 parts, magnesia, neoprene 19 parts, elastic plastic 85 parts, softening oil 2.5 parts, dimethyl carbonate 18 parts, benzoyl peroxide 2 parts, ethyl acetate 7 parts, emulsifying agent 3 parts, 27 parts, flour, Nano Silver 6 × 10
-5, fire retardant 2 parts;
Fire retardant is counted composed of the following components by weight: ammonium low polyphosphate 30 parts, 15 parts, ammonium phosphate, ammonium pyrophosphate 8 parts, 15 parts, ammonium sulfate, boric acid 8 parts, 18 parts, water.
Emulsifying agent is one or more in OPEO, sulfonated castor oil, lauryl sodium sulfate, neopelex;
Elastic plastic comprises the first elastic plastic and the second elastic plastic that mix by weight 2:1;
The solids content that first elastic plastic comprises 25 parts of weight is the emulsion acrylic resin of 65%, 12 parts of aqueous polyurethanes, the acrylic resin powder of 7 parts of weight, the solids content of 5 parts of weight are the EVA emulsion of 28% and the chlorinated polypropylene of 3 parts of weight;
The preparation of emulsion acrylic resin: 4.5 parts of OP-10,1.62 parts of lauryl sodium sulfate, 0.55 part of sodium bicarbonate are dissolved in 70 parts of deionized waters, then join in reactor, are warming up to about 70 DEG C; Take 5.42 parts of methyl methacrylates, 54.79 parts of butyl acrylates, 10.11 parts of styrene, 6.55 parts of butyl methacrylates, 0.76 part of acrylic acid, 1.41 parts of methacrylic acids, 7.83 parts of Isooctyl acrylate monomers make mix monomer; 1/3 part of mix monomer is added in reactor, at 85 DEG C of pre-emulsification 30min; Then joined by 0.42 part of initiator A PS and make solution in 50 parts of deionized waters and drop to gradually in reactor, drip residual monomer, about 3h dropwises simultaneously, controls mix monomer and drips prior to initiator solution; After dropwising, after insulation 1h, namely can be made into stand-by emulsion;
The preparation of acrylic resin powder: 2.7 parts of BPO are dissolved in 11.97 parts of methyl methacrylates, 57.95 parts of styrene, 19.26 parts of n-butyl acrylates, 4.1 parts of acrylic acid mix monomers; The mix monomer being dissolved with initator is joined and is dissolved with in 420 parts of deionized waters of 6 parts of protecting colloids, high-speed stirred, in 30min, be warming up to 85 DEG C simultaneously; Product is collected after insulation reaction 4h; Product is dried after pulverizing, make acrylic resin powder with 200 eye mesh screens filtrations stand-by;
The preparation method of the second elastic plastic is: be that the polyvinyl alcohol water solution of 35% and the aqueous polyurethane aqueous solution of 8% are heated to 69 DEG C by mass concentration, be cooled to 40 DEG C and add acrylate 13%, then add potassium hydroxide 0.15% and be warming up to 105 DEG C, then add sclerotin albumen 6%, rosin fat 8%, eugenol or anacardol 3%; React and be cooled to 50 DEG C in 4 hours, then add Sodium Benzoate 0.07%, di-tert-butyl peroxide 0.015% and ethyl acetate 0.2%, stir 1.2 hours, cooling, obtained second elastic plastic.
Bamboo fibre grid cloth containing environmental protection binding agent, it comprises the following steps successively:
(1) bamboo fibre preparation: comprise and select materials, flatten, flood flame treatment, softening, fibrillation, boiling, pickling, bamboo vinegar process and micro-wave vacuum;
Described bamboo vinegar process comprises a bamboo vinegar process and the process of secondary bamboo vinegar, a bamboo vinegar process is 28min in bamboo vinegar treatment fluid bamboo fibre being immersed in 45 DEG C, the process of secondary bamboo vinegar is 20min in secondary bamboo vinegar treatment fluid bamboo fibre being immersed in 70 DEG C, a described bamboo vinegar treatment fluid is the bamboo vinegar aqueous solution of 25g/L, and described secondary bamboo vinegar treatment fluid is the mixed solution of the bamboo vinegar of weight ratio 1:0.15:70, ethylenediamine tetra-acetic acid and water composition;
(2) grid cloth preparation: comprise step: turn over cloth, sanction opened by weft yarn, margin to seam, one side are singed, move back and boil drift, mercerising, dyeing, whole latitude, impregnation and tentering;
Described impregnation comprises in the immersion of the cloth after by whole latitude environmental protection binding agent and keeps 20min, then drop glue 6min.
Sanction opened by weft yarn is cut apart with a knife or scissors by weft yarn by fabric; Described margin to seam is that margin to seam between board, between fabric is carried out the parallel margin to seam of weft yarn;
One side singeing specifically gas singeing, singes twice, speed of a motor vehicle 85m/min in two burner fronts;
Move back and boil drift and comprise moving back and boil and oxygen bleaching, adopt and boil drift combined production line, after adopting six lattice adverse current open washings, roll compacting is carried out to control moisture content for 48% to fabric, then directly pads liquid lime chloride and fabric decatize is bleached;
Making fabric contain damp rate during mercerising controls 28%, carries out half wet mercerising in the mercerising solution comprising 280g/L sodium hydroxide, 6g/L alkylol sulfuric ester sodium salt;
Described tentering passes through with speed of a motor vehicle 48m/min, and aftertreatment fluid comprises antistatic additive SN, and the concentration of described antistatic additive SN in aftertreatment fluid is 1.5g/L;
In whole latitude process, the speed of a motor vehicle is 100m/min, detects weft yarn latitude shifting state by photovoltaic, passes to automatic weft yarn reorganizer give the arrangement of high accuracy weft yarn to fabric weft yarn by computer calculating, then carry out correcting and showing, weft yarn latitude is moved within 1CM/150CM.
Embodiment four
With embodiment one, also contain sodium hydroxide catalyst 0.8 part unlike in environmental protection binding agent.Before Nano Silver preparation process B adds crown ether and sodium metaphosphate in mixed liquor, mixed liquor is heated to 45 DEG C; 70 DEG C are heated to, Keep agitation 5min add crown ether and sodium metaphosphate in mixed liquor after.Nano Silver preparation process B carries out under microwave vacuum condition, and be specifically evacuated to vacuum for-0.02MPa, then carry out microwave treatment, microwave frequency is 100MHz, and microwave treatment time is 3s.
Embodiment five
With embodiment two, also contain sodium hydroxide catalyst 2.5 parts unlike in environmental protection binding agent.Before Nano Silver preparation process B adds crown ether and sodium metaphosphate in mixed liquor, mixed liquor is heated to 55 DEG C; 85 DEG C are heated to, Keep agitation 8min add crown ether and sodium metaphosphate in mixed liquor after.Nano Silver preparation process B carries out under microwave vacuum condition, and be specifically evacuated to vacuum for-0.001MPa, then carry out microwave treatment, microwave frequency is 230MHz, and microwave treatment time is 7s.
Embodiment six
With embodiment three, also contain sodium hydroxide catalyst 1.5 parts unlike in environmental protection binding agent.Before Nano Silver preparation process B adds crown ether and sodium metaphosphate in mixed liquor, mixed liquor is heated to 48 DEG C; 78 DEG C are heated to, Keep agitation 6min add crown ether and sodium metaphosphate in mixed liquor after.Nano Silver preparation process B carries out under microwave vacuum condition, and be specifically evacuated to vacuum for-0.01MPa, then carry out microwave treatment, microwave frequency is 180MHz, and microwave treatment time is 5s.
Comparative example one
With embodiment one, unlike the furfuryl alcohol extracted from natural plants 14 parts, triethylene glycol 13 parts, elastic plastic 60 parts, softening oil 4 parts, emulsifying agent 6 parts; Not containing benzoyl peroxide, ethyl acetate;
Elastic plastic comprises the first elastic plastic and the second elastic plastic that mix by weight 4:1.
Comparative example two
With embodiment two, be prepared from according to following steps unlike Nano Silver:
A. sodium dodecyl sulfate solution and hydrazine hydrate solution are added in silver nitrate aqueous solution and obtain mixed liquor, the mol ratio of dodecyl sodium sulfate and silver nitrate is 3:1; The mol ratio of described hydrazine hydrate and silver nitrate is 0.2:1;
B. in mixed liquor, add crown ether and sodium metaphosphate, the mol ratio of described crown ether and silver nitrate is 6:1; The mol ratio of sodium metaphosphate and silver nitrate is 0.8:1, and control ph is 8-9, obtains Nano Silver.
Embodiment 1-6 and comparative example are left standstill, observe the dispersity of the Nano Silver of adhesive system after 1 month and 6 months containing Nano Silver respectively, observed result is in table 1.
The dispersity of table 1 containing Nano Silver in the binder system of Nano Silver
The Binder Properties contrast of table 2 embodiment and comparative example
In two steps, the first step is evaluation feel style in pliability evaluation, comprises flexibility, fluffy, smooth, elasticity, the performance such as active; Second step is rating, and feel grading is divided into 5 grades, and 1 grade the poorest, and 5 grades best, and evaluation result is averaged.
The bamboo fibre grid cloth performance comparison of table 3 embodiment and comparative example
This specific embodiment is only explanation of the invention; it is not limitation of the present invention; those skilled in the art can make to the present embodiment the amendment not having creative contribution as required after reading this description, as long as but be all subject to the protection of Patent Law in right of the present invention.
Claims (10)
1. the bamboo fibre grid cloth containing environmental protection binding agent, is characterized in that it is prepared from by following steps:
(1) bamboo fibre preparation: comprise and select materials, flatten, flood flame treatment, softening, fibrillation, boiling, pickling, bamboo vinegar process and micro-wave vacuum;
Described bamboo vinegar process comprises a bamboo vinegar process and the process of secondary bamboo vinegar, a bamboo vinegar process is 20-40min in bamboo vinegar treatment fluid bamboo fibre being immersed in 40-50 DEG C, the process of secondary bamboo vinegar is 10-30min in secondary bamboo vinegar treatment fluid bamboo fibre being immersed in 55-80 DEG C, a described bamboo vinegar treatment fluid is the bamboo vinegar aqueous solution of 20-30g/L, and described secondary bamboo vinegar treatment fluid is the mixed solution of the bamboo vinegar of weight ratio 1:0.1-0.2:60-100, ethylenediamine tetra-acetic acid and water composition;
(2) grid cloth preparation: comprise step: turn over cloth, sanction opened by weft yarn, margin to seam, one side are singed, move back and boil drift, mercerising, dyeing, whole latitude, impregnation and tentering;
Described impregnation comprises in the immersion of the cloth after by whole latitude environmental protection binding agent and keeps 18-25min, then drop glue 5-8min;
Described environmental protection binding agent is made up of the raw material of following parts by weight:
Phthalic anhydride 25-35 part, the furfuryl alcohol 7-11 part of extracting from natural plants, triethylene glycol 10-12 part, glutaric acid 15-18 part, butantriol 8-10 part, Zinc Oxide 5-7 part, magnesia 3-5 part, neoprene 15-25 part, elastic plastic 70-95 part, softening oil 2-3 part, dimethyl carbonate 15-20 part, benzoyl peroxide 1-3 part, ethyl acetate 4-8 part, emulsifying agent 1-4 part, flour 20-30 part, Nano Silver 5 × 10
-5-9 × 10
-5part, fire retardant 1-3 part;
Described emulsifying agent is one or more in OPEO, sulfonated castor oil, lauryl sodium sulfate, neopelex;
Described elastic plastic comprises the first elastic plastic and the second elastic plastic that mix by weight 1-3:1;
The solids content that described first elastic plastic comprises 10-35 part weight is the emulsion acrylic resin of 60-75%, 10-15 part aqueous polyurethane, the acrylic resin powder of 5-8 part weight, the solids content of 2-6 part weight are the EVA emulsion of 20-35% and the chlorinated polypropylene of 1-4 part weight;
The preparation method of described emulsion acrylic resin is: the acrylate monomer mixed liquor of preparation 80-110 part weight is stand-by, then the emulsifying agent of 5-7 part weight of several compositions in OPEO, sulfonated castor oil, lauryl sodium sulfate, neopelex, the sodium bicarbonate of 0.3-0.7 part weight and deionized water are joined in reactor, add the 1/3 acrylate monomer mixed liquor prepared again wherein, be warming up to 50-90 DEG C, fully stir 20-40min; Be warming up to 60-100 DEG C, drip remaining 2/3 acrylate monomer mixed liquor and ammonium persulfate solution initator, time for adding controls, for 1-4h, to ensure that monomer drips prior to initiator solution; Dropwise rear insulation 1-4h, after cooling, regulate ph value of emulsion to about 7;
The preparation method of described second elastic plastic is: be that the polyvinyl alcohol water solution of 30-45% and the aqueous polyurethane aqueous solution of 5-10% are heated to 60-80 DEG C by mass concentration, be cooled to 30-50 DEG C and add acrylate 10-15%, then add potassium hydroxide 0.1-0.2% and be warming up to 100-110 DEG C, then the plant phenols 2-4% adding sclerotin albumen 5-8%, rosin fat 6-9%, extract from natural plants; React and be cooled to 45-55 DEG C in 3-5 hour, then add Sodium Benzoate 0.06-0.08%, di-tert-butyl peroxide 0.01-0.02% and ethyl acetate 0.1-0.3%, stir 1-1.5 hour, cooling, obtained described second elastic plastic;
Described Nano Silver is prepared from according to following steps:
A. sodium dodecyl sulfate solution, water polyacrylic acid and hydrazine hydrate solution are added in silver nitrate aqueous solution and obtain mixed liquor, the mol ratio of described dodecyl sodium sulfate and silver nitrate is 4-6:1; The mol ratio of described water polyacrylic acid and silver nitrate is 0.4-0.6:1; ; The mol ratio of described hydrazine hydrate and silver nitrate is 0.2-0.3:1;
B. in described mixed liquor, add crown ether and sodium metaphosphate, the mol ratio of described crown ether and silver nitrate is 3-5:1; The mol ratio of described sodium metaphosphate and silver nitrate is 0.8-1.3:1, and control ph is 8-9, obtains Nano Silver.
2. a kind of bamboo fibre grid cloth containing environmental protection binding agent according to claim 1, is characterized in that: sanction opened by weft yarn time prepared by described step (2) grid cloth is cut apart with a knife or scissors by weft yarn by fabric; Described margin to seam is that margin to seam between board, between fabric is carried out the parallel margin to seam of weft yarn;
Described moving back is boiled drift and is comprised moving back and boil and oxygen bleaching, adopts and boils drift combined production line, after adopting six lattice adverse current open washings, carry out roll compacting to control moisture content for 45-55%, then directly pad liquid lime chloride and fabric decatize is bleached fabric;
Making fabric contain damp rate during described mercerising controls at 25-35%, carries out half wet mercerising in the mercerising solution comprising 265-300g/L sodium hydroxide, 5-8g/L alkylol sulfuric ester sodium salt;
Described tentering passes through with speed of a motor vehicle 45-50m/min, and aftertreatment fluid comprises antistatic additive SN, and the concentration of described antistatic additive SN in aftertreatment fluid is 0.5-2g/L;
In described whole latitude process, the speed of a motor vehicle is 90-120m/min, detects weft yarn latitude shifting state by photovoltaic, passes to automatic weft yarn reorganizer give the arrangement of high accuracy weft yarn to fabric weft yarn by computer calculating, then carry out correcting and showing, weft yarn latitude is moved within 1CM/150CM.
3. a kind of bamboo fibre grid cloth containing environmental protection binding agent according to claim 2, is characterized in that: described mixed liquor is heated to 45-55 DEG C add crown ether and sodium metaphosphate in described mixed liquor before by described step B; Described step B is heated to 70-85 DEG C add crown ether and sodium metaphosphate in described mixed liquor after, Keep agitation 5-8min.
4. a kind of bamboo fibre grid cloth containing environmental protection binding agent according to claim 3, is characterized in that: described crown ether is bicyclohexane also-18-hat-6.
5. a kind of bamboo fibre grid cloth containing environmental protection binding agent according to claim 4, it is characterized in that: described step B carries out under microwave vacuum condition, specifically be evacuated to vacuum for-0.02MPa ~-0.001MPa, then carry out microwave treatment, microwave frequency is 100MHz ~ 230MHz.
6. a kind of bamboo fibre grid cloth containing environmental protection binding agent according to claim 5, is characterized in that: containing catalyst 0.8-2.5 part in described environmental protection binding agent.
7. a kind of bamboo fibre grid cloth containing environmental protection binding agent according to claim 6, is characterized in that: described catalyst is NaOH.
8. a kind of bamboo fibre grid cloth containing environmental protection binding agent according to any one of claim 1-7, is characterized in that: described one side singeing specifically gas singeing, singes twice, speed of a motor vehicle 80-85m/min in two burner fronts.
9. a kind of bamboo fibre grid cloth containing environmental protection binding agent according to claim 8, is characterized in that: the described furfuryl alcohol extracted from natural plants is selected from the furfuryl alcohol extracted from the wheat bran or bamboo wood chip of the core slag of corncob, oat or wheat.
10. a kind of bamboo fibre grid cloth containing environmental protection binding agent according to claim 9, is characterized in that: the described plant phenols extracted from natural plants is eugenol or anacardol.
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| CN102995139A (en) * | 2012-10-25 | 2013-03-27 | 郭荣才 | Bamboo fiber material for shirt |
| CN102995141A (en) * | 2012-10-25 | 2013-03-27 | 郭荣才 | Bamboo fiber |
| CN103015084A (en) * | 2011-09-22 | 2013-04-03 | 保定宁信新型材料有限公司 | Automatic warp beaming and weft straightening setting method of glass fiber gridding cloth |
| KR20130119673A (en) * | 2012-04-24 | 2013-11-01 | (주)대길산업 | Environmental friedly textile fabrics of engineering for preventing growth of weeds |
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|---|---|---|---|---|
| CN1789540A (en) * | 2005-12-26 | 2006-06-21 | 管昆明 | Gum dipping, stentering forming method of earthwork grid cloth |
| EP2426253A1 (en) * | 2009-04-28 | 2012-03-07 | Bridgestone Corporation | Adhesive composition for organic fiber cords, rubber-reinforcing material using same, tire and bonding method |
| CN103015084A (en) * | 2011-09-22 | 2013-04-03 | 保定宁信新型材料有限公司 | Automatic warp beaming and weft straightening setting method of glass fiber gridding cloth |
| KR20130119673A (en) * | 2012-04-24 | 2013-11-01 | (주)대길산업 | Environmental friedly textile fabrics of engineering for preventing growth of weeds |
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Effective date of registration: 20230718 Address after: 313000 Wujiatang, Maji Village, Tianhuangping Town, Anji County, Huzhou, Zhejiang Province Patentee after: Anji Bamboo Impression Home Furnishings Co.,Ltd. Address before: 313000 Wujiatang Anji Dengguan Bamboo and Wood Development Co., Ltd., Maji Village, Tianhuangping Town, Anji County, Huzhou, Zhejiang Province Patentee before: ANJI DENGGUAN BAMBOO & WOOD DEVELOP CO.,LTD. |