CN104341697A - High-folding-resistance PVC sole material and preparation method thereof - Google Patents
High-folding-resistance PVC sole material and preparation method thereof Download PDFInfo
- Publication number
- CN104341697A CN104341697A CN201410567351.0A CN201410567351A CN104341697A CN 104341697 A CN104341697 A CN 104341697A CN 201410567351 A CN201410567351 A CN 201410567351A CN 104341697 A CN104341697 A CN 104341697A
- Authority
- CN
- China
- Prior art keywords
- sole material
- pvc
- pvc sole
- folding
- coupling agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a high-folding-resistance PVC sole material. The high-folding-resistance PVC sole material is prepared from the following ingredients in parts by weight: 60-75 parts of PVC, 1-10 parts of nano-silica, 0.5-2 parts of coupling agent, 0.3-5 parts of polyvinyl alcohol, 2-5 parts of thermal stabilizer, 1-3 parts of lubricant, 5-10 parts of epoxidized soybean oil and 2-5 parts of ACR. The invention further discloses a preparation method of the high-folding-resistance PVC sole material. The PVC sole material provided by the invention has the advantage that the folding resistance is very good.
Description
Technical field:
The present invention relates to a kind of material for sole of shoe, particularly relate to a kind of PVC sole material and manufacture method thereof of high folding.
Background technology:
The kind of material for sole of shoe is a lot, is broadly divided into natural class bed material and synthesis class bed material two kinds.Natural class bed material comprises natural bottom leather, bamboo and wood material etc., and synthesis class bed material comprises rubber, plastics, rubber and plastic suitable materials, regenerated leather, elasticity fiber board etc.PVC has excellent mechanical property, the advantage such as easy to process, with low cost, still occupy larger proportion, but its folding quality is poor in low and middle-grade material for sole of shoe market, there is the hidden danger of fracture in winter.
Summary of the invention:
The technical problem to be solved in the present invention is to provide a kind of PVC sole material of high folding, and its folding quality is very good.
For solving the problems of the technologies described above, technical scheme of the present invention is:
A PVC sole material for high folding, its weight part consists of:
Preferably, coupling agent of the present invention is Silane coupling agent KH550 or silane coupling agent KH560.
Preferably, thermo-stabilizer of the present invention is lead sulfate tribasic.
Preferably, lubricant of the present invention is stearic acid, calcium stearate or polyethylene wax.
Another technical problem that the present invention will solve is to provide the manufacture method of the PVC sole material of above-mentioned high folding.
For solving the problems of the technologies described above, technical scheme is:
A manufacture method for the PVC sole material of high folding, comprises the following steps:
(1) coupling agent is dissolved in acetone soln, adds nano silicon, through ultra-sonic oscillation process, dry and slough solvent, obtain modified manometer silicon dioxide;
(2) other components in PVC, formula are mediated in high-speed kneading machine high speed, discharging when 110 degree, more blended on two roller together with modified manometer silicon dioxide, obtain compound;
(3) compound that step (2) obtains is added extruding pelletization in forcing machine, obtain the PVC sole material of high folding.
Therefore compared with prior art, the present invention has following beneficial effect:
Nano silicon bounding force is strong, specific surface area large, good mechanical performance, can improve its tensile yield strength, elongation at break, yield strength, make it have good folding quality after adding PVC; Due to nano silicon and PVC consistency poor, be difficult to be dispersed in PVC, so the present invention carries out surface modification by coupling agent and ultrasonic wave to it, solve the agglomeration of nano silicon in PVC well, can be dispersed in PVC, improve its folding quality.
Embodiment:
Describe the present invention in detail below in conjunction with specific embodiment, be used for explaining the present invention in this illustrative examples of the present invention and explanation, but not as a limitation of the invention.
Embodiment 1
A PVC sole material for high folding, its weight part consists of:
Its manufacture method comprises the following steps:
(1) coupling agent is dissolved in acetone soln, adds nano silicon, through ultra-sonic oscillation process, dry and slough solvent, obtain modified manometer silicon dioxide;
(2) other components in PVC, formula are mediated in high-speed kneading machine high speed, discharging when 110 degree, more blended on two roller together with modified manometer silicon dioxide, obtain compound;
(3) compound that step (2) obtains is added extruding pelletization in forcing machine, obtain the PVC sole material of high folding.
Embodiment 2
A PVC sole material for high folding, its weight part consists of:
Its manufacture method comprises the following steps:
(1) coupling agent is dissolved in acetone soln, adds nano silicon, through ultra-sonic oscillation process, dry and slough solvent, obtain modified manometer silicon dioxide;
(2) other components in PVC, formula are mediated in high-speed kneading machine high speed, discharging when 110 degree, more blended on two roller together with modified manometer silicon dioxide, obtain compound;
(3) compound that step (2) obtains is added extruding pelletization in forcing machine, obtain the PVC sole material of high folding.
Embodiment 3
A PVC sole material for high folding, its weight part consists of:
Its manufacture method comprises the following steps:
(1) coupling agent is dissolved in acetone soln, adds nano silicon, through ultra-sonic oscillation process, dry and slough solvent, obtain modified manometer silicon dioxide;
(2) other components in PVC, formula are mediated in high-speed kneading machine high speed, discharging when 110 degree, more blended on two roller together with modified manometer silicon dioxide, obtain compound;
(3) compound that step (2) obtains is added extruding pelletization in forcing machine, obtain the PVC sole material of high folding.
Embodiment 4
A PVC sole material for high folding, its weight part consists of:
Its manufacture method comprises the following steps:
(1) coupling agent is dissolved in acetone soln, adds nano silicon, through ultra-sonic oscillation process, dry and slough solvent, obtain modified manometer silicon dioxide;
(2) other components in PVC, formula are mediated in high-speed kneading machine high speed, discharging when 110 degree, more blended on two roller together with modified manometer silicon dioxide, obtain compound;
(3) compound that step (2) obtains is added extruding pelletization in forcing machine, obtain the PVC sole material of high folding.
Embodiment 5
A PVC sole material for high folding, its weight part consists of:
Its manufacture method comprises the following steps:
(1) coupling agent is dissolved in acetone soln, adds nano silicon, through ultra-sonic oscillation process, dry and slough solvent, obtain modified manometer silicon dioxide;
(2) other components in PVC, formula are mediated in high-speed kneading machine high speed, discharging when 110 degree, more blended on two roller together with modified manometer silicon dioxide, obtain compound;
(3) compound that step (2) obtains is added extruding pelletization in forcing machine, obtain the PVC sole material of high folding.
Embodiment 6
A PVC sole material for high folding, its weight part consists of:
Its manufacture method comprises the following steps:
(1) coupling agent is dissolved in acetone soln, adds nano silicon, through ultra-sonic oscillation process, dry and slough solvent, obtain modified manometer silicon dioxide;
(2) other components in PVC, formula are mediated in high-speed kneading machine high speed, discharging when 110 degree, more blended on two roller together with modified manometer silicon dioxide, obtain compound;
(3) compound that step (2) obtains is added extruding pelletization in forcing machine, obtain the PVC sole material of high folding.
Above-described embodiment is illustrative principle of the present invention and effect thereof only, but not for limiting the present invention.Any person skilled in the art scholar all without prejudice under spirit of the present invention and category, can modify above-described embodiment or changes.Therefore, such as have in art usually know the knowledgeable do not depart from complete under disclosed spirit and technological thought all equivalence modify or change, must be contained by claim of the present invention.
Claims (5)
1. a PVC sole material for high folding, is characterized in that: its weight part consists of:
2. the PVC sole material of a kind of high folding according to claim 1, is characterized in that: described coupling agent is Silane coupling agent KH550 or silane coupling agent KH560.
3. the PVC sole material of a kind of high folding according to claim 1, is characterized in that: described thermo-stabilizer is lead sulfate tribasic.
4. the PVC sole material of a kind of high folding according to claim 1, is characterized in that: described lubricant is stearic acid, calcium stearate or polyethylene wax.
5. the manufacture method of the PVC sole material of a kind of high folding according to Claims 1 to 4 any one, is characterized in that: comprise the following steps:
(1) coupling agent is dissolved in acetone soln, adds nano silicon, through ultra-sonic oscillation process, dry and slough solvent, obtain modified manometer silicon dioxide;
(2) other components in PVC, formula are mediated in high-speed kneading machine high speed, discharging when 110 degree, more blended on two roller together with modified manometer silicon dioxide, obtain compound;
(3) compound that step (2) obtains is added extruding pelletization in forcing machine, obtain the PVC sole material of high folding.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410567351.0A CN104341697A (en) | 2014-10-22 | 2014-10-22 | High-folding-resistance PVC sole material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410567351.0A CN104341697A (en) | 2014-10-22 | 2014-10-22 | High-folding-resistance PVC sole material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104341697A true CN104341697A (en) | 2015-02-11 |
Family
ID=52498203
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410567351.0A Pending CN104341697A (en) | 2014-10-22 | 2014-10-22 | High-folding-resistance PVC sole material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104341697A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104672716A (en) * | 2015-03-06 | 2015-06-03 | 苏州市景荣科技有限公司 | Novel PVC/CPVC (polyvinyl chloride/chlorinated polyvinyl chloride) sole composite material and preparation method thereof |
| CN105295247A (en) * | 2015-11-18 | 2016-02-03 | 安徽华塑股份有限公司 | Hydrotalcite-lanthanum stearate composite environmental protection stabilizer for PVC, and preparation method thereof |
| CN109762273A (en) * | 2019-01-16 | 2019-05-17 | 江苏瑞文新材料科技有限公司 | A kind of high-temperature resistant high flame retardant polyvinyl chloride insulated cable material and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102786747A (en) * | 2012-07-10 | 2012-11-21 | 苏州宝津塑业有限公司 | PVC strengthening plasticizing nano-material |
| CN103304919A (en) * | 2013-05-31 | 2013-09-18 | 苏州市景荣科技有限公司 | Fold resisting PVC (Polyvinyl Chloride) foaming sole material |
-
2014
- 2014-10-22 CN CN201410567351.0A patent/CN104341697A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102786747A (en) * | 2012-07-10 | 2012-11-21 | 苏州宝津塑业有限公司 | PVC strengthening plasticizing nano-material |
| CN103304919A (en) * | 2013-05-31 | 2013-09-18 | 苏州市景荣科技有限公司 | Fold resisting PVC (Polyvinyl Chloride) foaming sole material |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104672716A (en) * | 2015-03-06 | 2015-06-03 | 苏州市景荣科技有限公司 | Novel PVC/CPVC (polyvinyl chloride/chlorinated polyvinyl chloride) sole composite material and preparation method thereof |
| CN105295247A (en) * | 2015-11-18 | 2016-02-03 | 安徽华塑股份有限公司 | Hydrotalcite-lanthanum stearate composite environmental protection stabilizer for PVC, and preparation method thereof |
| CN109762273A (en) * | 2019-01-16 | 2019-05-17 | 江苏瑞文新材料科技有限公司 | A kind of high-temperature resistant high flame retardant polyvinyl chloride insulated cable material and preparation method thereof |
| CN109762273B (en) * | 2019-01-16 | 2021-02-05 | 江苏瑞文新材料科技有限公司 | High-temperature-resistance high-flame-retardant polyvinyl chloride insulated cable material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103772745B (en) | A kind of sodium alginate/18 alcohol surface modified calcium carbonate powder | |
| CN104341697A (en) | High-folding-resistance PVC sole material and preparation method thereof | |
| CN103881340A (en) | Preparation method and application for biomass fibre-aliphatic polyester composite material macromolecular coupling agent | |
| CN105733220B (en) | Biodegradable plastic containing biogas residue and preparation method thereof | |
| CN105176098A (en) | Silicon rubber compound added with modified nano calcium carbonate and preparing method thereof | |
| CN104497637A (en) | Modified calcium carbonate and preparation method thereof | |
| CN104177700B (en) | A kind of enhanced polypropylene and preparation method thereof | |
| CN104558945A (en) | Low-temperature-brittleness-resistant PVC pipe material and preparation method thereof | |
| CN105273238A (en) | Multi-functional plastic auxiliary agent | |
| CN106589690A (en) | High-impact-strength transparent PVC/MBS alloy material and preparation method thereof | |
| CN106977847A (en) | A kind of polyvinyl chloride pipe | |
| CN103613712B (en) | A kind of High-hydrophilia polyvinyl chloride and preparation method thereof | |
| CN103408869B (en) | A kind of flexible PVC of resistance to migration preparation method | |
| CN105733271A (en) | Polymer material used for 3D printing and preparation method thereof | |
| CN104387699A (en) | Medical PVC paste material and preparation method thereof | |
| CN103319630A (en) | Low-temperature-resistant latex yarn | |
| CN107207625A (en) | Converted starch derivative is used as purposes of the elastic composition with delayed reduction additive | |
| CN103665434A (en) | Plastic additive and preparation method thereof | |
| JP5794842B2 (en) | Plasticizer formulation with good gelling properties | |
| CN109608789A (en) | A kind of high tenacity PVC foam plate and preparation method thereof | |
| CN104262825A (en) | PVC (polyvinyl chloride) foamed shoe sole material with high folding resistance and manufacturing method thereof | |
| CN106854377A (en) | Plastic formula | |
| Schmitt et al. | Processing and Mechanical Behaviour of Halloysite Filled Starch Based Nanocomposites | |
| CN107216626B (en) | A kind of preparation method of polycaprolactone and starch nano crystal composite material | |
| CN102993593A (en) | Method for preparing PVC (polyvinyl chloride) using modified calcium carbonate |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150211 |
|
| RJ01 | Rejection of invention patent application after publication |