CN104340978A - Preparation method of graphene-based composite material - Google Patents
Preparation method of graphene-based composite material Download PDFInfo
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- CN104340978A CN104340978A CN201410565510.3A CN201410565510A CN104340978A CN 104340978 A CN104340978 A CN 104340978A CN 201410565510 A CN201410565510 A CN 201410565510A CN 104340978 A CN104340978 A CN 104340978A
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- graphene
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 57
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 54
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000002131 composite material Substances 0.000 title abstract description 10
- JQWHASGSAFIOCM-UHFFFAOYSA-M sodium periodate Chemical compound [Na+].[O-]I(=O)(=O)=O JQWHASGSAFIOCM-UHFFFAOYSA-M 0.000 claims abstract description 26
- 229920001661 Chitosan Polymers 0.000 claims abstract description 19
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000008367 deionised water Substances 0.000 claims abstract description 15
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000006243 chemical reaction Methods 0.000 claims abstract description 8
- 238000001035 drying Methods 0.000 claims abstract description 7
- 238000001027 hydrothermal synthesis Methods 0.000 claims abstract description 7
- 238000001816 cooling Methods 0.000 claims abstract description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 18
- 239000011159 matrix material Substances 0.000 claims description 18
- 229910052709 silver Inorganic materials 0.000 claims description 16
- 239000004332 silver Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 8
- 238000009413 insulation Methods 0.000 claims description 5
- 229910002804 graphite Inorganic materials 0.000 claims description 4
- 239000010439 graphite Substances 0.000 claims description 4
- 239000002356 single layer Substances 0.000 claims description 3
- 229910002651 NO3 Inorganic materials 0.000 claims description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 230000032798 delamination Effects 0.000 claims description 2
- YPNVIBVEFVRZPJ-UHFFFAOYSA-L silver sulfate Chemical compound [Ag+].[Ag+].[O-]S([O-])(=O)=O YPNVIBVEFVRZPJ-UHFFFAOYSA-L 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 8
- 239000002994 raw material Substances 0.000 abstract description 4
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- 239000004809 Teflon Substances 0.000 abstract 1
- 229920006362 Teflon® Polymers 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 235000019441 ethanol Nutrition 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 14
- 239000003795 chemical substances by application Substances 0.000 description 7
- 239000010410 layer Substances 0.000 description 6
- 230000002829 reductive effect Effects 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 4
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- 239000007864 aqueous solution Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
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- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- -1 bio-imaging Substances 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical class C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- 108010054033 Chitin deacetylase Proteins 0.000 description 1
- 241000238424 Crustacea Species 0.000 description 1
- 241000238557 Decapoda Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
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- 238000004043 dyeing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
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- 239000000835 fiber Substances 0.000 description 1
- 229910003472 fullerene Inorganic materials 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-N hydroperoxyl Chemical compound O[O] OUUQCZGPVNCOIJ-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000004377 microelectronic Methods 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000012279 sodium borohydride Substances 0.000 description 1
- 229910000033 sodium borohydride Inorganic materials 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
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Abstract
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Claims (6)
Priority Applications (1)
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CN201410565510.3A CN104340978B (en) | 2014-10-22 | 2014-10-22 | A kind of preparation method of graphene-based matrix material |
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CN201410565510.3A CN104340978B (en) | 2014-10-22 | 2014-10-22 | A kind of preparation method of graphene-based matrix material |
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CN104340978A true CN104340978A (en) | 2015-02-11 |
CN104340978B CN104340978B (en) | 2016-03-16 |
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CN201410565510.3A Expired - Fee Related CN104340978B (en) | 2014-10-22 | 2014-10-22 | A kind of preparation method of graphene-based matrix material |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107140623A (en) * | 2017-05-24 | 2017-09-08 | 郑州大学 | A kind of method for preparing graphene |
CN108529603A (en) * | 2018-06-26 | 2018-09-14 | 西南交通大学 | Alcohol heat-treats the method and graphene of graphene oxide |
CN108751179A (en) * | 2018-08-17 | 2018-11-06 | 佛山皖和新能源科技有限公司 | A kind of preparation method of transparent graphene conductive film |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102160998A (en) * | 2011-04-25 | 2011-08-24 | 北京航空航天大学 | Preparation method of graphene-silver nano particle composite material |
CN102698747A (en) * | 2012-06-14 | 2012-10-03 | 聊城大学 | Silver/graphene compound material and application |
CN103318877A (en) * | 2013-06-24 | 2013-09-25 | 华南理工大学 | Method for preparing graphene through water-soluble chitosan derivative |
CN103467620A (en) * | 2013-09-12 | 2013-12-25 | 深圳先进技术研究院 | Activity modification method for chitosan materials |
KR101359771B1 (en) * | 2012-02-17 | 2014-02-13 | 영남대학교 산학협력단 | Composites of graphene decorated with silver nanoparticles and preparation method thereof |
CN103787322A (en) * | 2014-01-25 | 2014-05-14 | 华南理工大学 | Graphene-carrying phyllosilicate nano composite material and preparation method thereof |
-
2014
- 2014-10-22 CN CN201410565510.3A patent/CN104340978B/en not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102160998A (en) * | 2011-04-25 | 2011-08-24 | 北京航空航天大学 | Preparation method of graphene-silver nano particle composite material |
KR101359771B1 (en) * | 2012-02-17 | 2014-02-13 | 영남대학교 산학협력단 | Composites of graphene decorated with silver nanoparticles and preparation method thereof |
CN102698747A (en) * | 2012-06-14 | 2012-10-03 | 聊城大学 | Silver/graphene compound material and application |
CN103318877A (en) * | 2013-06-24 | 2013-09-25 | 华南理工大学 | Method for preparing graphene through water-soluble chitosan derivative |
CN103467620A (en) * | 2013-09-12 | 2013-12-25 | 深圳先进技术研究院 | Activity modification method for chitosan materials |
CN103787322A (en) * | 2014-01-25 | 2014-05-14 | 华南理工大学 | Graphene-carrying phyllosilicate nano composite material and preparation method thereof |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107140623A (en) * | 2017-05-24 | 2017-09-08 | 郑州大学 | A kind of method for preparing graphene |
CN107140623B (en) * | 2017-05-24 | 2019-11-15 | 郑州大学 | A method of preparing graphene |
CN108529603A (en) * | 2018-06-26 | 2018-09-14 | 西南交通大学 | Alcohol heat-treats the method and graphene of graphene oxide |
CN108751179A (en) * | 2018-08-17 | 2018-11-06 | 佛山皖和新能源科技有限公司 | A kind of preparation method of transparent graphene conductive film |
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Publication number | Publication date |
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CN104340978B (en) | 2016-03-16 |
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Inventor after: Zhou Zhaohan Inventor before: Zhao Bing |
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Effective date of registration: 20170502 Address after: 515100, Guangdong, Shantou Province, the southern slope of the mountain street, Si Lian River Road, No. 15 Patentee after: SHANTOU CITY YITONG WEAVING Co.,Ltd. Address before: 215000 No. 2, Taishan Road, Suzhou hi tech Zone, Jiangsu, Suzhou Patentee before: SUZHOU ZHENGYECHANG INTELLIGENT TECHNOLOGY Co.,Ltd. |
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Address after: 515100 No. 15, Si Lianhe Road, Jiashan street, Chaonan District, Shantou, Guangdong Patentee after: GUANGDONG YITONG TEXTILE TECHNOLOGY Co.,Ltd. Address before: 515100 No. 15, Si Lianhe Road, Jiashan street, Chaonan District, Shantou, Guangdong Patentee before: SHANTOU CITY YITONG WEAVING Co.,Ltd. |
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CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160316 Termination date: 20211022 |