CN104322536A - High-efficient pesticide containing imidacloprid, bifenthrin, flubendiamide and dinotefuran - Google Patents
High-efficient pesticide containing imidacloprid, bifenthrin, flubendiamide and dinotefuran Download PDFInfo
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- CN104322536A CN104322536A CN201410521273.0A CN201410521273A CN104322536A CN 104322536 A CN104322536 A CN 104322536A CN 201410521273 A CN201410521273 A CN 201410521273A CN 104322536 A CN104322536 A CN 104322536A
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- 239000000575 pesticide Substances 0.000 title claims abstract description 26
- OMFRMAHOUUJSGP-IRHGGOMRSA-N bifenthrin Chemical compound C1=CC=C(C=2C=CC=CC=2)C(C)=C1COC(=O)[C@@H]1[C@H](\C=C(/Cl)C(F)(F)F)C1(C)C OMFRMAHOUUJSGP-IRHGGOMRSA-N 0.000 title claims abstract description 24
- 239000005906 Imidacloprid Substances 0.000 title claims abstract description 22
- 229940056881 imidacloprid Drugs 0.000 title claims abstract description 22
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 239000005874 Bifenthrin Substances 0.000 title abstract description 3
- 239000005901 Flubendiamide Substances 0.000 title abstract description 3
- YKBZOVFACRVRJN-UHFFFAOYSA-N dinotefuran Chemical compound [O-][N+](=O)\N=C(/NC)NCC1CCOC1 YKBZOVFACRVRJN-UHFFFAOYSA-N 0.000 title abstract description 3
- ZGNITFSDLCMLGI-UHFFFAOYSA-N flubendiamide Chemical compound CC1=CC(C(F)(C(F)(F)F)C(F)(F)F)=CC=C1NC(=O)C1=CC=CC(I)=C1C(=O)NC(C)(C)CS(C)(=O)=O ZGNITFSDLCMLGI-UHFFFAOYSA-N 0.000 title abstract description 3
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 29
- 239000000203 mixture Substances 0.000 claims abstract description 23
- 230000002147 killing effect Effects 0.000 claims abstract description 15
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- ZOCSXAVNDGMNBV-UHFFFAOYSA-N 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile Chemical compound NC1=C(S(=O)C(F)(F)F)C(C#N)=NN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl ZOCSXAVNDGMNBV-UHFFFAOYSA-N 0.000 claims description 20
- 239000005899 Fipronil Substances 0.000 claims description 20
- 229940013764 fipronil Drugs 0.000 claims description 20
- FTQWRYSLUYAIRQ-UHFFFAOYSA-N n-[(octadecanoylamino)methyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCNC(=O)CCCCCCCCCCCCCCCCC FTQWRYSLUYAIRQ-UHFFFAOYSA-N 0.000 claims description 20
- 241000238631 Hexapoda Species 0.000 claims description 12
- 210000004894 snout Anatomy 0.000 claims description 6
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- KLEYVGWAORGTIT-UHFFFAOYSA-N 2-chlorothiazole Chemical compound ClC1=NC=CS1 KLEYVGWAORGTIT-UHFFFAOYSA-N 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a high-efficient pesticide composition which is composed of following components, by weight, 30-60 parts of imidacloprid, 10-40 parts of bifenthrin, 10-50 parts of flubendiamide and 20-40 parts of dinotefuran. The pesticide composition is broad-spectrum, high-efficient, low-toxic and low-residue, is not liable to generate resistance in pests, is safe to human, livestock, plants and natural enemies, has a significant synergistic effect, can reduce a use amount of effective components and a use cost, can delay generation of the resistance in the pests, can effectively reduce environmental pollution and pesticide residue, is free of pesticide hazard and low-toxic in human and other mammals, is free of chronic toxin, and has significant killing effects on chilo supperssalis, lerodea eufala, homoptera piercing-sucking mouthpart pests, mainly including plant hoppers and aphids.
Description
Technical field
The present invention relates to the field of pesticides for agricultural insect pests control, particularly a kind of efficient pesticides containing Imidacloprid, Biphenthrin, fipronil bisamide and MTI-446.
Background technology
Insecticide residues and the toxicity problem to animal in agricultural product are the focuses that people pay close attention to always.
Imidacloprid:
Chemical name: 1-(6-chloro-3-pyridyl ylmethyl)-4,5-dihydro-N-Nitroimidazoline-2-base amine
Molecular formula: C
9h
10clN
5o
2
Molecular weight: 255.661
Structural formula:
Imidacloprid is nicotinoids super-high-efficient insecticide, and have wide spectrum, efficient, low toxicity, low-residual, insect not easily produces resistance, to features such as people, animal, plant and natural enemies securities, and have tag, the multiple action such as stomach toxicity and interior suction.After contacting pests medicament, nervous centralis normal conduction is obstructed, and makes it benumb death.Product quick-acting is good, and within after medicine 1 day, namely have higher preventive effect, residual life reaches about 25 days.Drug effect and temperature are proportionate, temperature is high, good disinsection effect, be mainly used in control sucking pest and resistant strain thereof, chloro nicotine insecticide of new generation, nitro-methylene-type systemic insecticide, be the acting body of nicotinic acetylcholine esterase acceptor, it is malfunctioning that interference pest movements nervous system makes chemical signal transmit, without cross resistance problem.
Biphenthrin:
Chinese another name: Uranus, the spirit of worm mite, Bi Fenning
English name: Bifenthrin
Molecular formula: C
46h
44c
l2f
6o
4
Molecular weight: 845.7356
Structural formula:
Biphenthrin is very high to fish toxicity, is 0.00015mg/L to rainbow trout LC50 (96 hours), water flea LC50 (48 hours) 0.00016mg/L.But because this medicament has very high affinity interaction in soil, and it is water-soluble low again, therefore actual influence is less.This agent is medium to honeybee toxicity, to the high poison of silkworm.Insecticidal activity is very high, is mainly and tags and stomach poison function, without interior suction and fumigation activity.Rapidly, the lasting period is long, and insecticidal spectrum is wide in its effect.
Biphenthrin is a kind of efficient pyrethroid Insecticidal and acaricidal agent.Have tag, stomach poison function, without interior suction, fumigation action.Insecticidal spectrum is wide, also has favorable effect to mite.Effect rapidly.Do not move in soil, safer to environment, the longevity of residure is long.
Applicable crops has banana, barley, cotton, lettuce, tea, apple, wheat, tomato, pea, beanpod, white lupin, clover, green soya bean, pears, sugarcane, dry red pepper, muskmelon, potato, verdant, Chinese cabbage, red pepper, mango, eggplant, cauliflower, grape, peanut, watermelon, tobacco, corn, cocoa, asparagus, shallot.Each Species of Lepidopterous Larvae, aleyrodid, aphid, phytophagy tetranychid can be prevented and treated.
Using method (1) aleyrodid at aleyrodid initial stage of origination, (about 2/strain) dispenser when insect density is low.With 2.5% Uranus missible oil 2000-2500 times of liquid, spraying.2.5% Uranus missible oil, 4000 times of liquid and 25% buprofezin wetting powder 1500 times of liquid can be selected when insect pest situation is serious mixed.(2) aphid is in initial stage of origination 2.5% Uranus missible oil 2500-3000 times of liquid, spraying, about the 15 days longevity of residure.Same dose also can prevent and treat multiple defoliator.(3) if two spotted spider mite is in one-tenth mite emergence period dispenser.With 2.5% Uranus missible oil, 2000 times of liquid, spraying, can effectively control them in 10 days and cause harm.
Fipronil bisamide:
Chinese another name: N-[[(4-chlorphenyl) is amino] carbonyl]-2,6-difluorobenzene acid amides
English name: Flubendiamide
Molecular formula: C
23h
22f
7iN
2o
4s
Structural formula:
Fipronil bisamide good activity, all has good control effects to nearly all Lepidoptera class pest, has excellent activity to adult and larva, particularly to the activity of rice-stem borer and leaf roll snout moth's larva.
The nicotinic insecticide that MTI-446 (dinotefuran) is researched and developed for Mitsui company.The chemical constitution of itself and existing nicotinic insecticide is far from each other, and its tetrahydrofuran base instead of former chloro-pyridine base, chloro-thiazole base, not containing halogen.Meanwhile, also different with nicotine at aspect of performance, so current people are referred to as " furans nicotine ".
Chemical name: 1-methyl-2-nitro-3-(tetrahydrochysene-3-furfuryl) guanidine; (EZ)-(RS)-1-methyl-2-nitro-3-(tetrahydrochysene-3-furfuryl) guanidine; N-methyl-N'-nitro-N "-[(tetrahydrochysene-3-furans) methyl] guanidine
Molecular formula: C
7h
14n
4o
3
Molecular weight: 202.2111
Structural formula:
Toxicity: MTI-446 is fool proof to mammal, its acute oral LD50 is male rat 2450mg/kg, female rats 2275mg/kg; Male mice 2840mg/kg, female mice 2000mg/kg.To rat acute through skin LD50>2000mg/kg (female, male).Without teratogenesis, carcinogenic and mutagenicity.MTI-446 is also fool proof to aquatile.Ichthyotoxin test show, MTI-446 to carp nm (48h) >1000mg/L, to water flea >1000mg/L.Equally, MTI-446 is also very low to birds toxicity, to quail acute oral LD50>1000mg/kg.Through learning honeybee test, MTI-446 to honeybee safety, and does not affect honeybee producting honey.
This medicament has the features such as tag, strong, the quick-acting height of absorption in stomach toxicity and root, long 3-4 week lasting period (theoretical lasting effect 43 days), insecticidal spectrum are wide, and have excellent preventive effect to sucking insect, and namely show very high insecticidal activity at very low dosage.Be mainly used in the aphid in the various crop such as control wheat, paddy rice, cotton, vegetables, fruit tree, tobacco leaf, leafhopper, plant hopper, thrips, aleyrodid and resistant strain thereof, have efficiently coleoptera, diptera and Lepidoptera, diptera, beetle order and total wing order insect simultaneously, and to blattaria, have efficiently from the sanitary insect pest such as ant, housefly.It was introduced in 1993 in Japan, had been that the countries in Asia of representative, this country and European Countries obtain and register with Korea S later.
The insecticidal spectrum of MTI-446:
Rice grub
Efficient: brown planthopper, white-backed planthopper, small brown rice planthopper, rice leafhopper, rice spider rafter stinkbug, star stinkbug, green rice bug resemble, red must fleahopper, the negative mixed worm of rice, rice cylinder water snout moth's larva.
Effective: striped rice borer, oryza chinensis class.
Veterinary antibiotics insect
Efficient: aleyrodid class, a red-spotted lizard class, unaspis shield kuwana, the green stinkbug of Zhu, peach fruit borer, tangerine lyonetid, the thin moth of tea, striped flea-beetle, beans are dived fly, tea lesser leafhopper.
Effective: Phytophthira, the cured a red-spotted lizard in angle, diamond-back moth, two secret notes are chrysomelid, Scirothrips dorsalis, onion thrips, golden thistle horse, oranges and tangerines golden thistle horse, soybean pod gall-midge, tomato Liriomyza.
MTI-446 has very wide insecticidal spectrum, and fool proof again to crop, people and animals and environment, then is equipped with the using method of various uses, and this agricultural chemicals is expected to the large-scale agricultural chemicals that becomes international.
Summary of the invention
For the defect existed in prior art, the object of the present invention is to provide a kind of efficient pesticides containing Imidacloprid, Biphenthrin, fipronil bisamide and MTI-446.
For reaching above object, the technical scheme that the present invention takes is:
For killing an efficient pesticides composition for pest, be made up of according to parts by weight following component:
Imidacloprid: 30-60 part; Biphenthrin: 10-40 part; Fipronil bisamide: 10-50 part; MTI-446: 20-40 part.
On the basis of such scheme, a kind of efficient pesticides composition for killing pest, is made up of according to parts by weight following component:
Imidacloprid: 40-50 part; Biphenthrin: 15-35 part; Fipronil bisamide: 15-45 part; MTI-446: 25-35 part.
On the basis of such scheme, a kind of efficient pesticides composition for killing pest, is made up of according to parts by weight following component:
Imidacloprid: 45 parts; Biphenthrin: 25 parts; Fipronil bisamide: 30 parts; MTI-446: 30 parts.
The above-mentioned efficient pesticides composition for killing pest, the formulation that can prepare is missible oil, suspending agent, wetting powder, water dispersible granules, aqueous emulsion or microemulsion.
The above-mentioned efficient pesticides composition for killing pest, is mainly used in control lepidopterous insects and Homoptera sucking pest.
The above-mentioned efficient pesticides composition for killing pest is mainly the larva of rice-stem borer and leaf roll snout moth's larva for the lepidopterous insects prevented and treated, Homoptera sucking pest is mainly plant hopper, aphid.
Advantage of the present invention: Pesticidal combination of the present invention has obvious synergistic effect, effective ingredient consumption can be reduced, reduce use cost, delay the generation of pest resistance to insecticide, effective minimizing environmental pollution and residue of pesticide, without poisoning to people and mammal low toxicity, without chronic toxicity, to rice-stem borer and leaf roll snout moth's larva, Homoptera sucking pest is mainly plant hopper, aphid has remarkable result.
Embodiment
Below the present invention is described in further detail.
Embodiment 1
The present invention contains the cream preparation of the efficient pesticides of Imidacloprid, Biphenthrin, fipronil bisamide and MTI-446, concrete constituent following (every part of 1000g):
Imidacloprid: 30 parts; Biphenthrin: 15 parts; Fipronil bisamide: 15 parts; MTI-446: 25 parts.
The concrete production stage of this cream preparation dissolves completely for first active ingredient Imidacloprid, Biphenthrin, fipronil bisamide, MTI-446 being added in solvent according to this area conventional steps, add emulsifier again, synergist becomes transparent and homogeneous oily liquids after stirring, filling, namely can be made into the cream preparation of the present composition.
Embodiment 2
The present invention contains the suspending agent of the efficient pesticides of Imidacloprid, Biphenthrin, fipronil bisamide and MTI-446, concrete constituent following (every part of 1000g):
Imidacloprid: 50 parts; Biphenthrin: 35 parts; Fipronil bisamide: 45 parts; MTI-446: 35 parts; Ethyl pleocidin: 35 parts.
The concrete production stage of this suspending agent is the Conventional suspending agents preparation method of this area, first other auxiliary agents (dispersant, antifreezing agent, thickener, defoamer, penetrating agent and pH value regulator) are mixed, mix through high speed shear, add active ingredient Imidacloprid, Biphenthrin, fipronil bisamide and MTI-446, abrading-ball 2 ~ 4 hours in ball crusher, make a diameter all at below 5mm, namely can be made into the aqueous suspension formulations of the present composition.
Embodiment 3
The present invention contains the water dispersible granules of the efficient pesticides of Imidacloprid, Biphenthrin, fipronil bisamide and MTI-446, concrete constituent following (every part of 1000g):
Imidacloprid: 45 parts; Biphenthrin: 25 parts; Fipronil bisamide: 30 parts; MTI-446: 30 parts.
The concrete production stage of this water dispersible granules is the customary preparation methods of the water dispersible granules of this area: active ingredient Imidacloprid, Biphenthrin, fipronil bisamide and MTI-446 dispersant, wetting agent, disintegrant and filler are mixed by above-mentioned formula, pulverize with micro jet, through mediating, then add in fluidized-bed granulation dryer and to carry out after granulation, drying, screening, through sample analysis, namely can be made into the water dispersible granules of the present composition.
Medicine prepared by embodiment of the present invention 1-3, carry out field experiment, after medicine, it is all better than existing medicament to the control efficiency of leaf roll snout moth's larva, and medicine effect of the present invention is fast, and efficiency time is long, and control efficiency is good.After medicine, the insecticidal effect of 10 days reaches 77.2% respectively, 86.4%, 94.9 %.
Above-mentioned detailed description of the present invention being carried out with reference to embodiment; illustrative instead of determinate; several embodiments can be listed according to institute's limited range, therefore in the change do not departed under general plotting of the present invention and amendment, all belong within protection scope of the present invention.
Claims (6)
1., for killing an efficient pesticides composition for pest, it is characterized in that being made up of according to parts by weight following component:
Imidacloprid: 30-60 part; Biphenthrin: 10-40 part; Fipronil bisamide: 10-50 part; MTI-446: 20-40 part.
2. a kind of efficient pesticides composition for killing pest according to claim 1, is characterized in that being made up of according to parts by weight following component:
Imidacloprid: 40-50 part; Biphenthrin: 15-35 part; Fipronil bisamide: 15-45 part; MTI-446: 25-35 part.
3. a kind of efficient pesticides composition for killing pest according to claim 2, is characterized in that being made up of according to parts by weight following component:
Imidacloprid: 45 parts; Biphenthrin: 25 parts; Fipronil bisamide: 30 parts; MTI-446: 30 parts.
4. the efficient pesticides composition for killing pest according to any one of claim 1-3, is characterized in that: the present invention is missible oil, suspending agent, wetting powder, water dispersible granules, aqueous emulsion or microemulsion for the formulation that the efficient pesticides composition killing pest can be prepared.
5. the efficient pesticides composition for killing pest according to any one of claim 1-3, is characterized in that: Pesticidal combination of the present invention is mainly used in preventing and treating lepidopterous insects.
6. the efficient pesticides composition for killing pest according to claim 5, it is characterized in that: the efficient pesticides composition for killing pest of the present invention is mainly the larva of rice-stem borer and leaf roll snout moth's larva for the lepidopterous insects prevented and treated, Homoptera sucking pest is mainly plant hopper, aphid.
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| WO2020012310A1 (en) * | 2018-07-10 | 2020-01-16 | Upl Ltd | Novel agrochemical combinations |
| WO2024121865A1 (en) * | 2022-12-07 | 2024-06-13 | Mikusu India Private Limited | Synergistic agrochemical insecticidal composition |
| US12161117B2 (en) | 2018-07-10 | 2024-12-10 | Upl Ltd | Agrochemical combinations |
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| US12161117B2 (en) | 2018-07-10 | 2024-12-10 | Upl Ltd | Agrochemical combinations |
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Application publication date: 20150204 |