CN104319382A - Multicomponent alloy LiCo1-xTixO2 electrode material and preparation method thereof - Google Patents

Multicomponent alloy LiCo1-xTixO2 electrode material and preparation method thereof Download PDF

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CN104319382A
CN104319382A CN201410477466.0A CN201410477466A CN104319382A CN 104319382 A CN104319382 A CN 104319382A CN 201410477466 A CN201410477466 A CN 201410477466A CN 104319382 A CN104319382 A CN 104319382A
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solution
preparation
electrode material
multicomponent alloy
precipitation
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不公告发明人
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/366—Composites as layered products
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

The invention discloses a multicomponent alloy LiCo1-xTixO2 electrode material and a preparation method thereof. The method comprises the steps of dissolving raw materials LiNO3, Co(NO3)2 and TiCl2 at a molar ratio of 1:(1-x):x in an ethanol solution by a coprecipitation method preparation technology, dropwise adding the solution to an NaOH ethanol solution at 1 drop/s, filtering the solution and separating precipitate after a reaction is sufficient and no precipitate is generated, spreading out the separated precipitate, drying the separated precipitate for 10h at 80 DEG C, calcinating the separated precipitate in air at 400-800 DEG C, and finally grinding the separated precipitate to obtain a final product. The method has the advantages of accurate quantity relative ratio control, high product purity, lower calcination temperature, uniform synthetic product component, easy condition control, simple operation and the like.

Description

A kind of multicomponent alloy LiCo 1-xti xo 2electrode material and preparation method thereof
Technical field
The present invention relates to a kind of anode material for lithium-ion batteries and preparation method thereof, particularly a kind of stratiform multi-element transition metal oxides combination electrode material and preparation method thereof.
Background technology
At occurring in nature, elemental lithium is the lightest metal, and its atomic weight is 6.94g/mol, ρ=0.53g/cm 3, electrochemical equivalent is minimum, is 0.26 gAh -1standard electrode potential is the most negative, for-3.045 V, it is a kind of material with very high-energy-density that these features of elemental lithium determine it, lithium ion battery is exactly this characteristic utilizing elemental lithium, lithium ion battery is a kind of rechargeable battery, and main dependence lithium ion between a positive electrode and a negative electrode movement carrys out work.In charge and discharge process, Li +come and go between two electrodes and embed and deintercalation, during rechargable battery, Li +from positive pole deintercalation, embed negative pole through electrolyte, negative pole is in rich lithium state; Then contrary during electric discharge.Lithium ion battery gains great popularity because of advantages such as its voltage are high, energy density is high, have extended cycle life, environmental pollution is little, but along with the fast development of electronic information technology, it is also proposed higher requirement to the performance of lithium ion battery.
The selection of material is the first element affecting performance of lithium ion battery.From material angle, cycle performance factor the further developing restriction lithium battery of material, in the cyclic process of battery, may be on the one hand that changes in crystal structure is too fast thus cannot continue embedding lithium and take off lithium in cyclic process, may be that the SEI film that cannot generate dense uniform due to active material and corresponding electrolyte causes active material and electrolyte too early side reaction to occur and make the too fast consumption of electrolyte and then affect to circulate on the one hand.Therefore developing high performance electrode material is the key improving battery performance.
Anode material for lithium-ion batteries common at present mainly contains cobalt acid lithium, the LiMn2O4 of spinel structure and the LiFePO4 of olivine structural of layer structure.Business-like lithium ion battery mainly adopts LiCoO 2as positive electrode, LiCoO 2there is fail safe and overcharge resistance performance problem, Co belongs to scarce resource, expensive, and metallic cobalt is easily to environment, its development space is restricted, decrease the scope of application of boring series lithium ion battery to a great extent, therefore the features such as the good cycle performance of cobalt acid lithium are fully utilized, fully by the composite lithium-inserting oxide that the method synthesis multielements such as molecular level mixing, doping, coated and finishing are collaborative, the content of electrode material Co can be reduced, and adopt doped with metal elements, can to LiCoO 2lattice structure play certain support and stabilization, effectively suppress the phase transformation of cell configuration in charge and discharge process and subside, to reach the object of the safety of raising material, cycle performance and discharge platform, the therefore LiCo of doped Ti 1-xti xo 2electrode material has better development prospect.
Summary of the invention
The object of this invention is to provide a kind of anode material for lithium-ion batteries and preparation method thereof.
For realizing this purpose, the present invention is achieved through the following technical solutions:
Adopt coprecipitation legal system for a kind of multicomponent alloy LiCo 1-xti xo 2electrode material.
A kind of multicomponent alloy LiCo 1-xti xo 2electrode material preparation method, comprises the steps:
(1) with LiNO 3, Co (NO 3) 2and TiCl 2for raw material is by 1:(1-x): the mol ratio of x is dissolved in ethanolic solution, does not stop to shake up;
(2) getting appropriate NaOH pressed powder is dissolved in another part of ethanolic solution, does not stop to shake up;
(3) the solution of joining in is (1) added drop-wise to the speed of 1 drop/sec in the NaOH ethanolic solution (2), and constantly stirs and react fully;
(4), until (3) middle solution is not when producing precipitation, stopping instills;
(5) static a period of time, the solution in (4) by filtering to isolate precipitation;
Will (5) in isolated precipitation to spread out and at 80 DEG C of dry 10h;
(7) drier postprecipitation in is (6) placed in air 400-800 DEG C of calcining;
(8) namely gained solid abrasive after calcining is obtained final products.
The present invention has following advantages and characteristic;
(1) amount is than can accurately control, and product purity is high;
(2) gained presoma particle diameter is little, and mixes;
(3) calcining heat is lower, and synthetic product component is even;
(4) favorable reproducibility, condition easily controls, simple to operate.
Embodiment
Embodiment one:
Get a certain amount of LiNO respectively 3, Co (NO 3) 2and TiCl 2powder, is dissolved in ethanolic solution by the mol ratio of 1:0.3:0.7, is mixed with the solution that metal ion concentration is 3mol/L; Separately getting appropriate NaOH pressed powder is dissolved in another part of ethanolic solution, be made into the NaOH ethanolic solution of 3mol/L, joined solion is added drop-wise in NaOH ethanolic solution with the speed of 1 drop/sec, and constantly stirring reacts fully, mixing speed is 60r/min again; Until solution not when producing precipitation, stop instillation and static a period of time, solution is filtered to isolate precipitation, and isolated precipitation is spread out and at 80 DEG C of dry 10h, is placed in air again 400 DEG C of calcinings after drying; Namely gained solid abrasive after calcining is obtained final products.
Embodiment two:
Get a certain amount of LiNO respectively 3, Co (NO 3) 2and TiCl 2powder, is dissolved in ethanolic solution by the mol ratio of 1:0.5:0.5, is mixed with the solution that metal ion concentration is 3mol/L; Separately getting appropriate NaOH pressed powder is dissolved in another part of ethanolic solution, be made into the NaOH ethanolic solution of 3mol/L, joined solion is added drop-wise in NaOH ethanolic solution with the speed of 1 drop/sec, and constantly stirring reacts fully, mixing speed is 80r/min again; Until solution not when producing precipitation, stop instillation and static a period of time, solution is filtered to isolate precipitation, and isolated precipitation is spread out and at 80 DEG C of dry 10h, is placed in air again 600 DEG C of calcinings after drying; Namely gained solid abrasive after calcining is obtained final products.
Embodiment three:
Get a certain amount of LiNO respectively 3, Co (NO 3) 2and TiCl 2powder, is dissolved in ethanolic solution by the mol ratio of 1:0.7:0.3, is mixed with the solution that metal ion concentration is 3mol/L; Separately getting appropriate NaOH pressed powder is dissolved in another part of ethanolic solution, be made into the NaOH ethanolic solution of 3mol/L, joined solion is added drop-wise in NaOH ethanolic solution with the speed of 1 drop/sec, and constantly stirring reacts fully, mixing speed is 100r/min again; Until solution not when producing precipitation, stop instillation and static a period of time, solution is filtered to isolate precipitation, and isolated precipitation is spread out and at 80 DEG C of dry 10h, is placed in air again 800 DEG C of calcinings after drying; Namely gained solid abrasive after calcining is obtained final products.

Claims (4)

1. a multicomponent alloy LiCo 1-xti xo 2electrode material and preparation method thereof, is characterized in that, this preparation method carries out according to the following steps:
(1) with LiNO 3, Co (NO 3) 2and TiCl 2for raw material is by 1:(1-x): the mol ratio of x is dissolved in ethanolic solution, does not stop to shake up;
(2) getting appropriate NaOH pressed powder is dissolved in another part of ethanolic solution, does not stop to shake up;
(3) the solution of joining in is (1) added drop-wise to the speed of 1 drop/sec in the NaOH ethanolic solution (2), and constantly stirs and react fully;
(4), until (3) middle solution is not when producing precipitation, stopping instills;
(5) static a period of time, the solution in (4) by filtering to isolate precipitation;
(6) incite somebody to action isolated precipitation (5) to spread out at 80 DEG C of dry 10h.
(7) more dried precipitation in is (6) placed in air to calcine;
(8) namely gained solid abrasive after calcining is obtained final products.
2. a kind of multicomponent alloy LiCo according to claim 1 1-xti xo 2electrode material and preparation method thereof, is characterized in that, step (1) in X value scope be 0.3≤X≤0.7.
3. a kind of multicomponent alloy LiCo according to claim 1 1-xti xo 2electrode material and preparation method thereof, is characterized in that, step (3) in adopt agitating mode to be mechanical agitation, mixing speed is 60-100 r/min.
4. a kind of multicomponent alloy LiCo according to claim 1 1-xti xo 2electrode material and preparation method thereof, is characterized in that, step (7) in institute calcining heat control within the scope of 400-800 DEG C.
CN201410477466.0A 2014-09-18 2014-09-18 Multicomponent alloy LiCo1-xTixO2 electrode material and preparation method thereof Pending CN104319382A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020164528A1 (en) * 2001-02-23 2002-11-07 Takuya Sunagawa Lithium secondary battery
CN1417874A (en) * 2002-11-28 2003-05-14 清华大学 Prepn of high-rate lithium ion battery cathode material
CN101188296A (en) * 2006-11-20 2008-05-28 三星Sdi株式会社 Negative active material for rechargeable lithium battery, method of preparing the same, and rechargeable lithium battery including the same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020164528A1 (en) * 2001-02-23 2002-11-07 Takuya Sunagawa Lithium secondary battery
CN1417874A (en) * 2002-11-28 2003-05-14 清华大学 Prepn of high-rate lithium ion battery cathode material
CN101188296A (en) * 2006-11-20 2008-05-28 三星Sdi株式会社 Negative active material for rechargeable lithium battery, method of preparing the same, and rechargeable lithium battery including the same

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Application publication date: 20150128