CN104313320B - The strong acid saturated crystallization separation method of zinc-magnesium in a kind of zinc electrolyte - Google Patents

The strong acid saturated crystallization separation method of zinc-magnesium in a kind of zinc electrolyte Download PDF

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CN104313320B
CN104313320B CN201410567990.7A CN201410567990A CN104313320B CN 104313320 B CN104313320 B CN 104313320B CN 201410567990 A CN201410567990 A CN 201410567990A CN 104313320 B CN104313320 B CN 104313320B
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zinc
magnesium
electrolyte
strong acid
zinc electrolyte
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CN104313320A (en
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岳峰
何振华
沈振岳
费怀道
何双力
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Yunnan YuQi Environmental Protection Technology Co., Ltd
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Yunnan Yuqi Environmental Protection Technology Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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Abstract

The invention discloses in a kind of zinc electrolyte zinc-magnesium strong acid saturated crystallization separation method, including the step such as strong acid allotment, stirring eddy flow, precipitate and separate and separator reuse.The phenomenon that the present invention quickly can be separated out in specific high temperature peracid condition in a large number using zinc sulfate and magnesium sulfate, zinc-magnesium in zinc electrolyte is separated, whole production process does not introduce any impurity, discharge without waste water and dregs, sulphuric acid in flow process can all reclaim use, realize the whole of electrolysis waste solution to recycle without outer row, saved the consumption of waste water, the expenses of environmental protection of Solid state fermentation and additive in traditional neutralization precipitation method, can effectively reduce power consumption.Present invention process simplicity, short, easy to operate flow process, reduced investment, consumption are low, and additive and the electrolysis waste solution after process all can be recycled, and fully achieve the reasonable utilization and maximizing the benefits of ERM, have preferable economic benefit and social benefit.

Description

The strong acid saturated crystallization separation method of zinc-magnesium in a kind of zinc electrolyte
Technical field
The invention belongs to the electrolytic zinc technical field of hydrometallurgy industry, and in particular in a kind of zinc electrolyte, zinc-magnesium is strong Sour saturated crystallization separation method.
Background technology
It is in zinc electrolysis production process, inevitably containing foreign metals such as lead, nickel, copper, magnesium in raw material zinc ore, right Electrolytic zinc quality affects very big, the current efficiency and electrolysis zinc product when wherein the magnesium elements in zinc liquid can have a strong impact on electrolysis Purity.With constantly carrying out for electrolytic process, the Zn content in electrolyte constantly will be reduced, and sulfuric acid content is continuously increased, In order to keep stablizing for electrolytic condition, need from a waste liquid extraction part for electrolysis to return in sulphuric leachate, at this moment, contain The anolyte of magnesium ion and sulphuric acid is used to soak ore deposit together, and in leaching and purification process, the magnesium ion in waste liquid can not be by Effectively remove, then, in recycling, magnesium ion is progressively enriched with electrolytic zinc anolyte so that electrolytic process energy consumption significantly increases Plus.For reducing energy consumption, generally opened a way using electrolyte, daily the electrolyte in discharge once electrolytic groove, this part of discharge In electrolyte, sulphuric acid, zinc, content of magnesium are all higher, to avoid environmental pollution and waste, the typically electrolyte to discharging from first using hydrogen Then plus sulfide precipitation is filtered calcium oxide is neutralized, and, precipitate returns pyrometallurgical smelting, outer after wastewater treatment to arrange.Although the method Simply, implement easy, but directly neutralize, however it remains problems with:1., due to acid concentration height in waste liquid, needs add big Amount calcium hydroxide is neutralized, and can produce a large amount of waste residues, while being also a kind of waste to sour resource;2., precipitation process with the addition of Sulfide, easily causes secondary pollution after the hydrogen sulfide emission of generation, the emission treatment cost of investment in later stage is higher;3., generate Slag in zinc recovering using relatively costly, waste water is difficult to direct reuse and needs discharge, and enterprise's production capacity is high, resource circulation utilization Rate is low.
The content of the invention
In order to solve problem present in background technology, it is an object of the invention to provide one kind can have from zinc electrolyte Effect separating magnesium sulphate, realizes zero generation of wastewater zero discharge and solid waste while electrolytic zinc power consumption is reduced, and energy-conserving and environment-protective, invests into The zinc-magnesium strong acid saturated crystallization separation method of this low, achievable resource circulation utilization.
The object of the present invention is achieved like this, and the separation method is comprised the following steps that:
1., strong acid allotment:Pending zinc electrolyte is placed in agitator tank, is slowly added into tank after opening agitating device Concentration is 98% concentrated sulphuric acid, and zinc electrolyte is 1 with the new volume ratio for adding concentrated sulphuric acid:0.8~0.9;
2., stir eddy flow:Accelerate stirring when mixeding liquid temperature reaches 110~120 DEG C, form eddy flow, speed of agitator is 1000~1200 revs/min, mixing time is 3~5 minutes;
3., precipitate and separate:Mixed liquor is imported after the completion of stirring and staticly settled in sedimentation tank, mixed liquor is separated into and is deposited in The zinc-magnesium solidfied material of downside and the supernatant for floating over upside;
4., separator reuse:Transparent limpid supernatant pump is returned into wet method electrolysis Zn system reuse, bottom is deposited in Zinc-magnesium solidfied material send dispensing in pyrometallurgical smelting fuming furnace to smelt to reclaim zinc, magnesium become slag making element water it is broken after be used as cement raw Material.
The research of Jing lot of experiments finds that the zinc sulfate and magnesium sulfate in zinc electrolyte can be big at specific temperature and acidity Amount is quick to be separated out, and the present invention formulates technique using the characteristic and the zinc-magnesium in zinc electrolyte is separated, and whole production process does not have There is introducing any impurity, discharge without waste water and dregs, the sulphuric acid in flow process can all reclaim use, realize the whole of electrolysis waste solution Recycle without outer row, saved the consumption of waste water, the expenses of environmental protection of Solid state fermentation and additive in traditional neutralization precipitation method, can Power consumption is reduced effectively.Present invention process simplicity, short, easy to operate flow process, reduced investment, consumption are low, and additive and the electricity after process Liquid waste solution all can be recycled, and fully achieve the reasonable utilization and maximizing the benefits of ERM, have preferable economy Benefit and social benefit.
Description of the drawings
Fig. 1 is the process chart of the present invention.
Specific embodiment
With reference to embodiment and accompanying drawing, the present invention is further illustrated, but never in any form to the present invention in addition Limit, based on present invention teach that any conversion for being made or replacement, belong to protection scope of the present invention.
Embodiment 1:
It is the zinc electrolyte of 24.5g/L that 1000L Zn contents are taken for 51g/L, content of magnesium, is carried out point by the method for the invention From.
1., strong acid allotment:Pending zinc electrolyte is placed in agitator tank, is slowly added into tank after opening agitating device Concentration is 98% concentrated sulphuric acid, and the speed of agitator of agitating device is 800 revs/min, solution mix homogeneously, temperature stabilization is increased, Do not occur it is quick-fried splash, zinc electrolyte is 1 with the new volume ratio for adding concentrated sulphuric acid:0.8;
2., stir eddy flow:Accelerate stirring when mixeding liquid temperature reaches 110 DEG C, form eddy flow, speed of agitator is 1200 Rev/min, mixing time is 5 minutes;
3., precipitate and separate:Mixed liquor is imported after the completion of stirring and staticly settled in sedimentation tank, the time for staticly settling is 90 Minute, mixed liquor is separated into the zinc-magnesium solidfied material for being deposited in downside and the supernatant for floating over upside;
4., separator reuse:Transparent limpid supernatant pump is returned into wet method electrolysis Zn system reuse, bottom is deposited in Zinc-magnesium solidfied material send dispensing in pyrometallurgical smelting fuming furnace to smelt to reclaim zinc, magnesium become slag making element water it is broken after be used as cement raw Material.
In the present embodiment, after testing, in the supernatant after precipitate and separate Zn content be 1.96g/L, content of magnesium be 7.28g/ L, up to 96%, the separation rate of magnesium solves industry conventional difficulties up to 70% to the separation rate of zinc, meets current energy-conserving and environment-protective, resource and follows Ring such as utilizes at the social development in science and technology theme, with preferable economic benefit and social benefit.
Embodiment 2:
It is the zinc electrolyte of 24.5g/L that 1000L Zn contents are taken for 51g/L, content of magnesium, is carried out point by the method for the invention From.
1., pretreatment:In pending zinc electrolyte, add the concentration that percent by volume is 1% to be 98% concentrated sulphuric acid and stir Mix uniform, make the temperature of zinc electrolyte be increased to 36 DEG C;
2., strong acid allotment:Pending zinc electrolyte is placed in agitator tank, is slowly added into tank after opening agitating device Concentration is 98% concentrated sulphuric acid, and the speed of agitator of agitating device is 900 revs/min, solution mix homogeneously, temperature stabilization is increased, Do not occur it is quick-fried splash, zinc electrolyte is 1 with the new volume ratio for adding concentrated sulphuric acid:0.85;
3., stir eddy flow:Accelerate stirring when mixeding liquid temperature reaches 115 DEG C, form eddy flow, speed of agitator is 1100 Rev/min, mixing time is 4 minutes;
4., precipitate and separate:Mixed liquor is imported after the completion of stirring and staticly settled in sedimentation tank, the time for staticly settling is 60 Minute, mixed liquor is separated into the zinc-magnesium solidfied material for being deposited in downside and the supernatant for floating over upside;
5., separator reuse:Transparent limpid supernatant pump is returned into wet method electrolysis Zn system reuse, bottom is deposited in Zinc-magnesium solidfied material send dispensing in pyrometallurgical smelting fuming furnace to smelt to reclaim zinc, magnesium become slag making element water it is broken after be used as cement raw Material.
In the present embodiment, after testing, in the supernatant after precipitate and separate Zn content be 2g/L, content of magnesium be 4.3g/L, zinc Separation rate up to 96%, the separation rate of magnesium solves industry conventional difficulties up to 82%, meet current energy-conserving and environment-protective, resources circulation profit With social development in science and technology theme is waited, with preferable economic benefit and social benefit.
Embodiment 3:
It is the zinc electrolyte of 24.5g/L that 1000L Zn contents are taken for 51g/L, content of magnesium, is carried out point by the method for the invention From.
1., pretreatment:The concentrated sulphuric acid that the concentration that percent by volume is 0.5% is 98% is added in pending zinc electrolyte simultaneously Stir, make the temperature of zinc electrolyte be increased to 34 DEG C;
2., strong acid allotment:Pending zinc electrolyte is placed in agitator tank, is slowly added into tank after opening agitating device Concentration is 98% concentrated sulphuric acid, and the speed of agitator of agitating device is 1000 revs/min, makes solution mix homogeneously, on temperature stabilization Rise, do not occur it is quick-fried splash, zinc electrolyte is 1 with the new volume ratio for adding concentrated sulphuric acid: 0.9;
3., stir eddy flow:Accelerate stirring when mixeding liquid temperature reaches 120 DEG C, form eddy flow, speed of agitator is 1000 Rev/min, mixing time is 3 minutes;
4., precipitate and separate:Mixed liquor is imported after the completion of stirring and staticly settled in sedimentation tank, the time for staticly settling is 40 Minute, mixed liquor is separated into the zinc-magnesium solidfied material for being deposited in downside and the supernatant for floating over upside;
5., separator reuse:Transparent limpid supernatant pump is returned into wet method electrolysis Zn system reuse, bottom is deposited in Zinc-magnesium solidfied material send dispensing in pyrometallurgical smelting fuming furnace to smelt to reclaim zinc, magnesium become slag making element water it is broken after be used as cement raw Material.
In the present embodiment, after testing, in the supernatant after precipitate and separate Zn content be 1.9g/L, content of magnesium be 5.8g/L, Up to 96%, the separation rate of magnesium solves industry conventional difficulties up to 76% to the separation rate of zinc, meets current energy-conserving and environment-protective, resources circulation The social development in science and technology theme such as utilize, with preferable economic benefit and social benefit.

Claims (3)

1. in a kind of zinc electrolyte zinc-magnesium strong acid saturated crystallization separation method, it is characterised in that comprise the following steps that:
1., strong acid allotment:Pending zinc electrolyte is placed in agitator tank, first volume basis is added in pending zinc electrolyte Than concentrated sulphuric acid that the concentration for 0.5~2% is 98% and stir, make the temperature of zinc electrolyte be increased to 34~36 DEG C;Then The concentrated sulphuric acid that concentration is 98%, zinc electrolyte and the new volume for adding concentrated sulphuric acid are slowly added after agitating device is opened into tank Than for 1:0.8~0.9;
2., stir eddy flow:Accelerate stirring when mixeding liquid temperature reaches 110~120 DEG C, form eddy flow, speed of agitator is 1000 ~1200 revs/min, mixing time is 3~5 minutes;
3., precipitate and separate:Mixed liquor is imported after the completion of stirring and staticly settled in sedimentation tank, mixed liquor is separated into and is deposited in downside Zinc-magnesium solidfied material and float over upside supernatant;
4., separator reuse:Transparent limpid supernatant pump is returned into wet method electrolysis Zn system reuse, the zinc of bottom is deposited in During magnesium hardener thing send pyrometallurgical smelting fuming furnace, dispensing smelts recovery zinc, and magnesium is used as cement raw material after becoming slag making element water quenching.
2. according to claim 1 in a kind of zinc electrolyte zinc-magnesium strong acid saturated crystallization separation method, it is characterised in that:Step The speed of agitator of rapid 1. middle agitating device is 800~1000 revs/min.
3. according to claim 1 in a kind of zinc electrolyte zinc-magnesium strong acid saturated crystallization separation method, it is characterised in that:Step It is rapid 3. in time for staticly settling be 40~90 minutes.
CN201410567990.7A 2014-10-23 2014-10-23 The strong acid saturated crystallization separation method of zinc-magnesium in a kind of zinc electrolyte Active CN104313320B (en)

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CN104630471B (en) * 2015-03-01 2017-06-27 云南驰宏锌锗股份有限公司 A kind of method and its device of the removing solution of zinc sulfate magnesium ion that pressurizes
CN104630469B (en) * 2015-03-01 2017-03-08 云南驰宏锌锗股份有限公司 A kind of combine the method for Organic substance and magnesium ion and its device in removing solution of zinc sulfate

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