CN104312272A - Rustproof type special conductive printing ink and preparation method thereof - Google Patents
Rustproof type special conductive printing ink and preparation method thereof Download PDFInfo
- Publication number
- CN104312272A CN104312272A CN201410627481.9A CN201410627481A CN104312272A CN 104312272 A CN104312272 A CN 104312272A CN 201410627481 A CN201410627481 A CN 201410627481A CN 104312272 A CN104312272 A CN 104312272A
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- parts
- printing ink
- preparation
- ferrocene
- starch
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/52—Electrically conductive inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to a special printing ink and particularly relates to a rustproof type special conductive printing ink and a preparation method thereof. The printing ink comprises the following raw materials in parts by weight: 2 to 3 parts of inositol hexaphosphate, 3 to 4 parts of azone, 20 to 30 parts of a 400-mesh stannic oxide powder, 3 to 5 parts of ferrocene, 50 to 60 parts of epoxy acrylic resin, 12 to 18 parts of a DBE solvent, 10 to 12 parts of ethyl alcohol, 1 to 2 parts of ethylene glycol monophenyl ether, 16 to 20 parts of vinegar naphtha, 1 to 2 parts of 2,5-ditert-butylhydroquinone and 2 to 4 parts of an additive. The printing ink provided by the invention takes the epoxy acrylic resin as a connecting material, and adopts the environment-friendly and low-toxicity solvent, the ferrocene and the tin oxide in the raw materials are excellent in electric conductivity and have high thermal stability, the prepared printing ink is stable and uniform in electric conductivity and also has a certain rustproof property, and has a good adhesive power to a metal base material, the material surface seepage force is strong, the curing speed is fast, and the special printing ink is particularly suitable for being used for materials such as printed circuits, electric plates, electroplated bottom layers and the like.
Description
Technical field
The present invention relates to a kind of special printing inks, be specifically related to extraordinary electrically conductive ink of a kind of rust-proof type and preparation method thereof.
Background technology
Special printing inks is a class to adapt to different printing materials and in order to reach the ink that different printing effects is developed, special ink kind is more, common comprises luminescent ink, sterilizing ink, anti-forgery ink, magnetic ink, fragrant printing ink, electrically conductive ink etc., adopt toluene in the formula of current special ink more, dimethylbenzene etc. all have the volatile solvent of higher hazardness, the potential safety hazard used is very big, and adopt water not fully up to expectations as the use properties of the water color ink of primary solvent, therefore, be badly in need of researching and developing low toxicity and the special printing inks with good use properties.
Summary of the invention
The object of the invention is to, provide extraordinary electrically conductive ink of a kind of rust-proof type and preparation method thereof, to achieve these goals, the technical solution used in the present invention is as follows:
Extraordinary electrically conductive ink of a kind of rust-proof type and preparation method thereof, it is characterized in that, this ink is made up of the raw material of following weight part: myo-Inositol hexaphosphate 2-3, azone 3-4,400 order putty powder 20-30, ferrocene 3-5, epoxy acrylic resin 50-60, DBE solvent 12-18, ethanol 10-12, ethyleneglycol monophenylether 1-2, ethyl acetate 16-20,2,5-ditert-butylhydro quinone 1-2, auxiliary agent 2-4;
Described auxiliary agent is made up of the raw material of following weight part: polyvinyl butyral acetal 2-4, silane coupling agent KH560 1-2, phosphoric acid propylene diamine 0.2-0.4, polyamide wax 2-3, silicone antifoam agent 1-3, diethylene glycol ether acetic ester 12-15, nano-starch 4-6, preparation method is: first nano-starch and silane coupling agent KH560 mixed grinding are disperseed 20-30min, obtain surface-modified nano starch for subsequent use, again other leftover materials are mixed subsequently, after stirring 30-40min, mixing solutions is heated to 60-80 DEG C, and drop into surperficial modified nano-starch, dispersed with stirring is evenly incubated and ultrasonic disperse 4-5h afterwards, obtain.
Extraordinary electrically conductive ink of described a kind of rust-proof type and preparation method thereof, its preparation method is:
(1) first dropped into by ferrocene in the hot ethanol of 50-60 DEG C, airtight mix and blend, after ferrocene dissolves completely, add 400 order putty powders, after mixing, by mixture grinding distribution 40-50min, gained material is for subsequent use;
(2) other leftover materials are dropped in batch can, be uniformly mixed 40-50min, add step (1) gained material subsequently, after continuing mix and blend 30-40min, grinding distribution in three-roller sent into by gained slurry, to particle diameter≤25 μm of gained slurry, through packing and get product after the assay was approved.
The advantage of special ink prepared by the present invention is: using epoxy acrylic resin as binder, and adopt environmental protection low poison solvent, greatly improve the feature of environmental protection of ink, ferrocene in raw material, stannic oxide have the thermostability of good conductivity and height, and stronger through the bonding force of pretreated powder and the composition such as binder, pigment, the ink conductivity stable and uniform prepared; In addition, ink prepared by the present invention also has certain rustless property, has good sticking power with metal base, strong at material surface seepage force, and solidification fast, is especially applicable to being applied to the materials such as printed wiring, electroplax, plating bottom.
Embodiment
Embodiment
The ink of the present embodiment is made up of the raw material of following weight part: myo-Inositol hexaphosphate 3, azone 4,400 order putty powder 25, ferrocene 4, epoxy acrylic resin 55, DBE solvent 16, ethanol 12, ethyleneglycol monophenylether 2, ethyl acetate 20,2,5-ditert-butylhydro quinone 2, auxiliary agent 4.
Wherein auxiliary agent is made up of the raw material of following weight part: polyvinyl butyral acetal 4, silane coupling agent KH560 2, phosphoric acid propylene diamine 0.3, polyamide wax 3, silicone antifoam agent 2, diethylene glycol ether acetic ester 15, nano-starch 6, preparation method is: first nano-starch and silane coupling agent KH560 mixed grinding are disperseed 30min, obtain surface-modified nano starch for subsequent use, again other leftover materials are mixed subsequently, after stirring 40min, mixing solutions is heated to 60-80 DEG C, and drop into surperficial modified nano-starch, dispersed with stirring is evenly incubated and ultrasonic disperse 5h afterwards, obtain.
The preparation method of this printing-ink is:
(1) first dropped into by ferrocene in the hot ethanol of 50-60 DEG C, airtight mix and blend, after ferrocene dissolves completely, add 400 order putty powders, after mixing, by mixture grinding distribution 45min, gained material is for subsequent use;
(2) other leftover materials are dropped in batch can, be uniformly mixed 50min, add step (1) gained material subsequently, after continuing mix and blend 40min, grinding distribution in three-roller sent into by gained slurry, to particle diameter≤25 μm of gained slurry, through packing and get product after the assay was approved.
By the ink printing obtained by the present embodiment on base material, after its complete drying, according to corresponding national examination criteria, the performance test results of this ink coating is:
Claims (2)
1. extraordinary electrically conductive ink of rust-proof type and preparation method thereof, it is characterized in that, this printing-ink is made up of the raw material of following weight part: myo-Inositol hexaphosphate 2-3, azone 3-4,400 order putty powder 20-30, ferrocene 3-5, epoxy acrylic resin 50-60, DBE solvent 12-18, ethanol 10-12, ethyleneglycol monophenylether 1-2, ethyl acetate 16-20,2,5-ditert-butylhydro quinone 1-2, auxiliary agent 2-4;
Described auxiliary agent is made up of the raw material of following weight part: polyvinyl butyral acetal 2-4, silane coupling agent KH560 1-2, phosphoric acid propylene diamine 0.2-0.4, polyamide wax 2-3, silicone antifoam agent 1-3, diethylene glycol ether acetic ester 12-15, nano-starch 4-6, preparation method is: first nano-starch and silane coupling agent KH560 mixed grinding are disperseed 20-30min, obtain surface-modified nano starch for subsequent use, again other leftover materials are mixed subsequently, after stirring 30-40min, mixing solutions is heated to 60-80 DEG C, and drop into surperficial modified nano-starch, dispersed with stirring is evenly incubated and ultrasonic disperse 4-5h afterwards, obtain.
2. extraordinary electrically conductive ink of a kind of rust-proof type as claimed in claim 1 and preparation method thereof, its preparation method is:
(1) first dropped into by ferrocene in the hot ethanol of 50-60 DEG C, airtight mix and blend, after ferrocene dissolves completely, add 400 order putty powders, after mixing, by mixture grinding distribution 40-50min, gained material is for subsequent use;
(2) other leftover materials are dropped in batch can, be uniformly mixed 40-50min, add step (1) gained material subsequently, after continuing mix and blend 30-40min, grinding distribution in three-roller sent into by gained slurry, to particle diameter≤25 μm of gained slurry, through packing and get product after the assay was approved.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410627481.9A CN104312272A (en) | 2014-11-10 | 2014-11-10 | Rustproof type special conductive printing ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410627481.9A CN104312272A (en) | 2014-11-10 | 2014-11-10 | Rustproof type special conductive printing ink and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104312272A true CN104312272A (en) | 2015-01-28 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410627481.9A Pending CN104312272A (en) | 2014-11-10 | 2014-11-10 | Rustproof type special conductive printing ink and preparation method thereof |
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| CN (1) | CN104312272A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020101284A1 (en) * | 2018-11-12 | 2020-05-22 | 주식회사 포스코 | Organic-inorganic composite coating composition, and zinc-plated steel sheet surface-treated using same |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1693385A (en) * | 2005-05-11 | 2005-11-09 | 中国乐凯胶片集团公司 | UV photocureable magnetic offset lithography printing ink |
-
2014
- 2014-11-10 CN CN201410627481.9A patent/CN104312272A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1693385A (en) * | 2005-05-11 | 2005-11-09 | 中国乐凯胶片集团公司 | UV photocureable magnetic offset lithography printing ink |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020101284A1 (en) * | 2018-11-12 | 2020-05-22 | 주식회사 포스코 | Organic-inorganic composite coating composition, and zinc-plated steel sheet surface-treated using same |
| CN113015770A (en) * | 2018-11-12 | 2021-06-22 | Posco公司 | Organic-inorganic composite coating composition and galvanized steel sheet surface-treated with the same |
| EP3882318A4 (en) * | 2018-11-12 | 2022-01-05 | Posco | Organic-inorganic composite coating composition, and zinc-plated steel sheet surface-treated using same |
| JP2022509926A (en) * | 2018-11-12 | 2022-01-25 | ポスコ | Organic / inorganic composite coating composition and galvanized steel sheet surface-treated using it |
| JP7216355B2 (en) | 2018-11-12 | 2023-02-01 | ポスコホールディングス インコーポレーティッド | Organic/inorganic composite coating composition and galvanized steel sheet surface-treated using the same |
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Application publication date: 20150128 |
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