CN104312166A - Bra component material and manufacturing method thereof as well as bra component manufacturing method - Google Patents
Bra component material and manufacturing method thereof as well as bra component manufacturing method Download PDFInfo
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- CN104312166A CN104312166A CN201410532736.3A CN201410532736A CN104312166A CN 104312166 A CN104312166 A CN 104312166A CN 201410532736 A CN201410532736 A CN 201410532736A CN 104312166 A CN104312166 A CN 104312166A
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Abstract
The invention discloses a bra component material and a manufacturing method thereof as well as a bra component manufacturing method. The bra component material is prepared by performing hybrid reaction on dimethyl vinyl (siloxane and poly-siloxane), nanosilicon dioxide, hydroxyl silicone oil, sulfide bridging agents, dimethicone, natural nanometer anion powder, natural radium stone powder, anti-microbial powder, an antioxidant and slipping agents; the bra component material is high in elongation rate and tear-resistant performance, has a natural energy function and wide market prospect, and can be used for effectively promoting breast development and shaping of girls, guaranteeing smooth blood circulation of female breast and realizing health-care functions of fighting bacterium and diminishing inflammation, activating breast cells, relaxing blood vessels, promoting metabolism and increasing lymphocinesia; moreover, the existing bra manufacturing material is innovated.
Description
Technical field
The present invention relates to underwear material technical field, relate to making material and the making method of the cup of energy brassiere in underwear, shoulder belt, setting band, snap-fastener etc. more specifically.
Background technology
Existing women underwear pursuit comfort level while, gradually towards health care future development.Underwear component mainly carries the effect such as connection, support of underwear, as cup, shoulder belt, qualitative band etc., in prior art, the making material of this underwear component mainly contains two kinds, a kind of is fabric, one is silicon rubber, the former elasticity, retractility are poor, cause underwear degree of comfort decreased, the latter because of its there is good elasticity, tearing retractility is widely used in the making of underwear component gradually.But the subject matter that existing silicon rubber underwear component exists is that toughness, tearing are still lower, rate of generally stretching is about 400%, limit the high-comfort of underwear, also have existing underwear component there is no the health care characteristics such as ir radiation, sterilization, the growth requirement of modern underwear cannot be met.
Summary of the invention
The present invention is based on above-mentioned prior art problem, a kind of brand-new underwear construction material of proposition of innovation and preparation method thereof, and underwear structure manufacture method, described underwear construction material adds natural nano negative ion powder by innovating in the fusion of the materials such as dimethyl ethenyl (siloxanes and polysiloxane) and silicon-dioxide, the materials such as natural radium stone flour and antibacterial powder, make provided underwear make material except having and excellent stretch rate, anti-tearly draw outside performance, also there is natural energy effect simultaneously, can effectively promote girl breast grow and moulding, health care adult female breast blood is smooth, reach antisepsis and anti-inflammation, activation mammary cell, vasodilator, enhance metabolism, strengthen the health effects such as lymphokinesis, innovate existing underwear and make material, there are market outlook widely.
It is as follows that the present invention solves the problems of the technologies described above taked technology:
A kind of underwear member material, by the dimethyl ethenyl (siloxanes and polysiloxane) of 73-79 weight part, the nano silicon of 15-20 weight part, the hydroxy silicon oil of 0.5-3.2 weight part, the sulfuration bridging agent of 2-4 weight part, the dimethyl silicone oil of 1-4 weight part, the natural nano negative ion powder of 3-5 weight part, the natural radium stone flour of 1-3 weight part, the antibacterial powder of 1-2 weight part, the antioxidant of 0.5-1 weight part and the slipping agent hybrid reaction of 0.8-1.2 weight part obtain, wherein hydroxy-end capped in dimethyl ethenyl (siloxanes and polysiloxane) dimethyl ethenyl (siloxanes and polysiloxane) accounts for the weight ratio of 2.1-2.6%, wherein said natural nano negative ion powder comprises the following powder component of nanometer particle size: SiO
2, B
2o
3, Al
2o
3, Fe
2o
3, ZrO, MnO, MgO, Na
2o and Li
2o.
Further according to underwear member material of the present invention, the particle diameter of wherein said nano silicon is between 10-20nm and purity reaches 99.9%, and described hydroxy silicon oil is that at 25 DEG C, oil viscosity was less than or equal to for 25 milli handkerchief seconds, specific refractory power is in 1.44-1.46, ring body content at 23-25%, hydroxy radical content at the hydroxy silicon oil of 7.5-9.5% at 25 DEG C.
Further according to underwear member material of the present invention, wherein said sulfuration bridging agent is by the peroxidation two (2 of 25-30%, 4-dichloro-benzoyl), the dicumyl peroxide (DCP) of 15-18%, the silicone oil hydrogen content of 16 ~ 20% be 1.2% ~ 1.5% high containing hydrogen silicone oil, the white carbon black of 15-25%, the vinyltriethoxysilane of 8-12% and 3-5% potassium silicate composition, each per-cent is mass percent.
Further according to underwear member material of the present invention, wherein said natural nano negative ion powder is by the Nano-meter SiO_2 of 38-42 weight part
2, 9-10 weight part nanometer B
2o
3, 15-16 weight part nanometer Al
2o
3, 3-3.5 weight part nanometer Fe
2o
3, the nanometer MnO of 1-1.5 weight part, the nano-MgO of 1.8-2.2 weight part, the nanometer Na of 1.5-2 weight part
2the nanometer Li of O, 0.5-1 weight part
2nanometer Rb below the nanometer ZrO of O, 30-35 weight part, 0.1 weight part
2nanometer CaO below O, 0.1 weight part and the nano-TiO below 0.1 weight part
2composition.
Further according to underwear member material of the present invention, wherein said antibacterial powder is made up of the nano-calcium carbonate of the nano titanium oxide of the nano silicon of 40-50 weight part, 10-15 weight part, the nanometer silver of 3-10 weight part, the nano zine oxide of 1-3 weight part and 40-60 weight part.
Further according to underwear member material of the present invention, wherein said antioxidant is selected from oxidation inhibitor-264, dihydroxyphenyl propane, triphenyl phosphite, oxidation inhibitor-1010, antioxidant 1076 or tris phosphite, and described slipping agent is selected from the one in erucicamide, stearylamide, Zinic stearas or amine hydroxybenzene.
Further according to underwear member material of the present invention, the expansion and contraction of wherein said underwear member material reaches more than 850%, pull apart tensile strength reaches more than 15Mpa, and tear strength reaches 8 × 10
4more than N/m, radiation infrared wavelength concentrates within the scope of 8-11 μm, and ir radiant power density reaches 0.09W/cm
2above, negative-ion energy burst size reaches 10000/cm
3above; Described underwear component comprises cup, shoulder belt, setting band, snap-fastener.
A making method for underwear member material of the present invention, comprises the following steps:
Step one: dissolved in the machine of beginning to pratise by the above-mentioned dimethyl ethenyl (siloxanes and polysiloxane) of 73-79 weight part and stir preheating 5-10 minute, temperature controls between 150-220 degree Celsius;
Step 2: the above-mentioned nano silicon adding 15-20 weight part to above-mentioned mill carries out stirring time white silk about 10 minutes, makes dimethyl ethenyl (siloxanes and polysiloxane) even with nano silicon two kinds of mixing of materials, plays filling effect;
Step 3: add the above-mentioned hydroxy silicon oil of 0.5-3.2 weight part and the above-mentioned dimethyl silicone oil of 1-4 weight part, carry out kneading 3-5 minute, allows viscous consistency, adds the above-mentioned natural nano negative ion powder of 1-2 weight part simultaneously and stirs;
Step 4: add the above-mentioned sulfuration bridging agent of 2-4 weight part and fully stir more than 20 minutes, promote that dimethyl ethenyl (siloxanes and polysiloxane) and silicon-dioxide are mixing, control temperature is at 200-280 degree Celsius;
Step 5: add the above-mentioned slipping agent of the above-mentioned natural nano negative ion powder of remaining 2-3 weight part, the above-mentioned natural radium stone flour of 1-3 weight part, the above-mentioned antibacterial powder of 1-2 weight part, the above-mentioned antioxidant of 0.5-1 weight part and 0.8-1.2 weight part and stir, the virgin rubber material of semi-solid is practiced in described mill, then room temperature is naturally cooled to, obtained described underwear member material.
A kind of underwear structure manufacture method, comprises the following steps: (1), startup sulfuration machine, about temperature being adjusted to 180-200 degree; (2), underwear element mold is put into board heat, when thermostatic to 190 is spent, open mould; (3), by the materials weight of underwear component specification size, underwear member material of the present invention is cut into strip, puts into underwear element mold and to heat 5-8 minute, make formed product; (4), open underwear element mold, take out shaping after underwear component product.
Further according to underwear structure manufacture method of the present invention, wherein said underwear component comprises cup, shoulder belt, setting band and snap-fastener.
At least following technique effect can be reached by technical scheme of the present invention:
1), the present invention is by innovation choice dimethyl ethenyl (siloxanes and polysiloxane), nano silicon, hydroxy silicon oil, sulfuration bridging agent, dimethyl-silicon wet goods raw material and content thereof, make obtained underwear construction material have good elasticity, retractility, anti-tear drawing property, ensure that the comfort level of underwear;
2), the present invention adds the materials such as natural nano negative ion powder, natural radium stone flour and antibacterial powder by innovation in the fusion of silicon rubber, make provided underwear make material and there is natural energy effect, can effectively promote girl breast grow and moulding, health care adult female breast blood is smooth, reach antisepsis and anti-inflammation, activation mammary cell, vasodilator, enhance metabolism, strengthen the health effects such as lymphokinesis, meet modern underwear health-care growth requirement;
3), underwear provided by the present invention makes virgin rubber material and can pass through the shaping various underwear component of mold cure easily, simplifies underwear structure manufacture technique, can be widely used in the making of all kinds of underwear, wide market.
Embodiment
Below technical scheme of the present invention is described in detail, to enable those skilled in the art's understanding the solution of the present invention clearly, but does not therefore limit the scope of the invention.
A kind of underwear of proposition of the present invention's innovation makes material, the interpolation natural nano negative ion powder that described material is innovated in the polyreaction of the materials such as dimethyl ethenyl (siloxanes and polysiloxane) and silicon-dioxide, the materials such as natural radium stone flour and antibacterial powder, make provided underwear make material and there is natural energy effect, can effectively promote girl breast grow and moulding, health care adult female breast blood is smooth, reach antisepsis and anti-inflammation, activation mammary cell, vasodilator, enhance metabolism, strengthen the health effects such as lymphokinesis, innovate existing underwear and make material, make the underwear by utilizing material of the present invention to make have good health properties simultaneously, reform modern underwear and make material.Underwear material of the present invention is especially suitable for use in the internals of underwear, as underwear components such as cup, shoulder belt, setting band, snap-fasteners, these manufactured underwear components not only have good strength and toughness, and there is good antibiotic health effect, significantly improve the health-care effect of underwear to skin, meet the development trend of modern underwear.
The making material of concrete underwear component of the present invention comprises following component according to the mass fraction:
In the dimethyl ethenyl (siloxanes and polysiloxane) of wherein above-mentioned 73-79 weight part, preferably hydroxy-end capped dimethyl ethenyl (siloxanes and polysiloxane) accounts for 2.1-2.6% weight ratio.
The nano silicon of above-mentioned 15-20 weight part be preferably particle diameter between 10-20nm, purity reach 99.9% nano silicon and thermal silica.
The hydroxy silicon oil of above-mentioned 0.5-3.2 weight part, preferred oil viscosity is less than or equal to the hydroxy silicon oil of 25 millis handkerchief second (25 DEG C), specific refractory power 1.44-1.46 (25 DEG C), ring body content 23-25%, hydroxy radical content 7.5-9.5%.
The sulfuration bridging agent of above-mentioned 2-4 weight part, specifically consist of (mass percent by forming sulfuration bridging agent self): the peroxidation two (2 of 25-30%, 4-dichloro-benzoyl), the dicumyl peroxide (DCP) of 15-18%, the silicone oil hydrogen content of 16 ~ 20% is the high containing hydrogen silicone oil of 1.2% ~ 1.5%, the white carbon black of 15-25%, the vinyltriethoxysilane of 8-12% and the potassium silicate of 3-5%, by adding high containing hydrogen silicone oil in described sulfuration bridging agent, vinyltriethoxysilane, make the large enhancing of anti-yellowing change effect of sulfuration bridging agent, obtained underwear component outward appearance is more transparent, add product aesthetic feeling, accelerate vulcanization rate simultaneously, reduce raw materials cost.
The dimethyl silicone oil of above-mentioned 1-4 weight part can adopt currently available products.
The natural nano negative ion powder of above-mentioned 3-5 weight part, belong to one of key component innovating interpolation in material of the present invention, applicant obtains the radiation infrared wavelength of the natural nano negative ion powder of following composition within the scope of 2-18 μm through the Test Summary of several times, especially near 9.5um, radiosity reaches more than 0.09W/cm2, and negative-ion energy release reaches 10000/more than CM3, can play well and promote that blood is smooth, vasodilator, enhance metabolism, strengthen the health effects such as lymphokinesis, meet natural energy effect of health-care underclothes, the composition of concrete described natural nano negative ion powder comprises mixed uniformly following component (mass fraction by self composition):
| Composition | SiO 2 | B 2O 3 | Al 2O 3 | Fe 2O 3 | MnO | MgO |
| Content | 38-42 | 9-10 | 15-16 | 3-3.5 | 1-1.5 | 1.8-2.2 |
| Composition | Na 2O | Li 2O | Rb 2O | ZrO | GaO | TiO 2 |
| Content | 1.5-2 | 0.5-1 | ≤0.1 | 30-35 | ≤0.1 | ≤0.1 |
。
Natural nano negative ion powder of the present invention configures each composition according to above-mentioned mass fraction, and each composition is ground to nanometer particle size, then Homogeneous phase mixing is carried out, the natural nano negative ion powder obtained is through test generation negative aeroion that can be permanent and radiation infrared, can play and strengthen the health-care effect such as blood circulation, antibiotic and sterilizing, activation histocyte, one of innovation of the present invention be namely this add in the underwear construction material of direct body contact this through testing the natural nano negative ion powder providing best health-care effect determined.
The natural radium stone flour of above-mentioned 1-3 weight part, preferably adopt 2500-4000 object radium stone flour, the same with described negative ion powder, described radium stone flour also can play expansion capillary vessel, strengthens blood circulation, and the health-care effect such as enhance metabolism.
Specifically consisting of (mass fraction by self composition) of the antibacterial powder of above-mentioned 1-2 weight part: nano silicon 40-50 weight part, nano titanium oxide 10-15 weight part, nanometer silver 3-10 weight part, nano zine oxide 1-3 weight part and nano-calcium carbonate 40-60 weight part, described antibacterial powder is by after fully mixing above-mentioned component, be placed in heating vessel at 800-1000 degree Celsius of lower calcination 2-3 hour, then grind and cross 1000 mesh sieves after cooling, namely extracting screen underflow obtains described antibacterial powder, and described antibacterial powder is through test and described natural nano negative ion powder, natural radium stone flour can be good at cooperation and plays antibiotic health effect.
The antioxidant of above-mentioned 0.5-1 weight part, is selected from oxidation inhibitor-264, dihydroxyphenyl propane, triphenyl phosphite, oxidation inhibitor-1010, antioxidant 1076 or tris phosphite;
The slipping agent of above-mentioned 0.1-0.5 weight part, is selected from the one in erucicamide, stearylamide, Zinic stearas or amine hydroxybenzene.
The procedure adopting above-mentioned component materials to make underwear component basic material of the present invention comprises the following steps:
Step one: dissolved in the machine of beginning to pratise by the semisolid dimethyl ethenyl (siloxanes and polysiloxane) of 73-79 weight part and carry out stirring preheating more than 5 minutes, temperature controls between 150-220 degree Celsius;
Step 2: the nano silicon adding 15-20 weight part to above-mentioned mill carries out stirring time white silk about 10 minutes, makes dimethyl ethenyl (siloxanes and polysiloxane) even with nano silicon two kinds of mixing of materials, plays filling effect;
Step 3: add the hydroxy silicon oil of 0.5-3.2 weight part and the dimethyl silicone oil of 1-4 weight part, carries out mediating about 5 minutes, allows viscous consistency, adds the natural nano negative ion powder of a small half of 1-2 weight part simultaneously and stirs;
Step 4: add the sulfuration bridging agent of 2-4 weight part and fully stir more than 20 minutes, promote that dimethyl ethenyl (siloxanes and polysiloxane) and silicon-dioxide are mixing, control temperature is at 200-280 degree Celsius;
Step 5: then add the slipping agent of remaining (2-3 weight part) natural nano negative ion powder, the natural radium stone flour of 1-3 weight part, the antibacterial powder of 1-2 weight part, the antioxidant of 0.5-1 weight part and 0.8-1.2 weight part and stir, in described mill, practice into semisolid virgin rubber material, naturally cool to room temperature;
Step 6: adjustment virgin rubber material thickness is 8-10mm, prepares to expect that pipe carries out rewinding and goes out finished product, the obtained underwear component virgin rubber material with natural energy effect of the present invention.
The underwear component virgin rubber material that the method for the invention obtains after tested expansion and contraction can reach 850%, and pull apart tensile strength and reach 15Mpa, tear strength reaches 8 × 10
4n/m, radiation infrared wavelength concentrates within the scope of 8-11 μm, and maximum radiated power density reaches 0.09W/cm
2above, and negative-ion energy release reach 10000/cm
3above, not only meet the anti-tear strength and toughness requirement of drawing of component such as underwear shoulder belt, setting band, and there is good health-care effect.
Described underwear component virgin rubber material is heated to the compression molding of 180-200 degree by vulcanizer, namely can be made into the bra cup of various style and different hardness different colours, shoulder belt, setting band, snap-fastener work in-process and finished product, specifically provide below and utilize described above-mentioned underwear component virgin rubber material specifically to make the procedure of the underwear components such as cup, shoulder belt, setting band, snap-fastener.
One, make underwear and cup bra to comprise the following steps:
Step one: start sulfuration machine, about temperature being adjusted to 180-200 degree;
Step 2: cup mould is put into board and heats, when thermostatic to 190 is spent, opens mould;
Step 3: by the materials weight of cup specification size, is cut into strip by above-mentioned obtained underwear component virgin rubber material, and puts into cup mould and to heat 5-8 minute, makes formed product;
Step 4: open cup mould, get shaping after cup product;
Step 5: the quality confirming the hardness of cup, size, color.
Two, make underwear shoulder belt to comprise the following steps:
Step one: start sulfuration machine, about temperature being adjusted to 180-200 degree;
Step 2: the mould of shoulder belt is put in board and heats, when thermostatic to 190 is spent, open mould;
Step 3: by the materials weight of shoulder belt specification size, after above-mentioned obtained underwear component virgin rubber material is cut into strip, puts into shoulder belt mould and to heat 3-5 minute, make formed product;
Step 4: open mould, get shaping after shoulder belt product;
Step 5: the quality confirming the hardness of shoulder belt, size, color.
Three, make setting band to comprise the following steps:
Step one: start sulfuration machine, about temperature being adjusted to 180-200 degree;
Step 2: the mould of setting band is put in board and heats, when thermostatic to 190 is spent, open mould;
Step 3: by the materials weight of setting band specification size, after above-mentioned obtained underwear component virgin rubber material is cut into strip, puts into mould and to heat 4-6 minute, make formed product;
Step 4: open mould, get shaping after setting carries product;
Step 5: the quality confirming the hardness of setting band, size, color.
Four, make underwear snap-fastener to comprise the following steps:
Step one: start sulfuration machine, about temperature being adjusted to 180-200 degree;
Step 2: the mould of snap-fastener is put in board and heats, when thermostatic to 190 is spent, open mould;
Step 3: by the materials weight of snap-fastener specification size, after above-mentioned obtained underwear component virgin rubber material is cut into strip, puts into mould and to heat 8-12 minute, make formed product;
Step 4: open mould, get shaping after by buckle product;
Step 5: the quality confirming the hardness of setting band, size, color.
The underwear and cup bra that the present invention obtains, shoulder belt, setting band, snap-fastener, the performance of its material is completely different from the common underwear component of commercial type, the present invention is from the selection of underwear component raw material, focus on the health care characteristics of underwear component raw material, it is main for researching and developing around women's health, replace the Health hazard that traditional sponge and steel ring underwear bring to female breast, the underwear structure manufacture sizing material provided has health-care effect, various underwear component can be made easily, facilitate the development of health-care underclothes, there is stronger market popularization value.
Below provide specific embodiment.
Embodiment 1
Make the underwear and cup bra with natural energy effect, comprise the following steps:
Step one: the semisolid dimethyl ethenyl (siloxanes and polysiloxane) of 73 weight parts is dissolved in the machine of beginning to pratise and carries out stirring preheating 5 minutes, wherein hydroxy-end capped dimethyl ethenyl (siloxanes and polysiloxane) accounts for 2.1%, and temperature controls between 150-220 degree Celsius;
Step 2: the nano silicon adding 15 weight parts to above-mentioned mill carries out stirring time white silk about 10 minutes, makes dimethyl ethenyl (siloxanes and polysiloxane) even with nano silicon two kinds of mixing of materials, plays filling effect;
Step 3: add the hydroxy silicon oil of 0.5 weight part and the dimethyl silicone oil of 1 weight part, carries out mediating about 5 minutes, allows viscous consistency, adds the natural nano negative ion powder of 1 weight part simultaneously and stirs;
Step 4: add the sulfuration bridging agent of 2 weight parts and fully stir more than 20 minutes, promote that dimethyl ethenyl (siloxanes and polysiloxane) and silicon-dioxide are mixing, control temperature is at 200-280 degree Celsius, and bis(2，4-dichlorobenzoyl)peroxide, the dicumyl peroxide (DCP) of 15%, the silicone oil hydrogen content of 20% that described sulfuration bridging agent is configured to 25% be 1.2% high containing hydrogen silicone oil, the white carbon black of 25%, the vinyltriethoxysilane of 10% and 5% potassium silicate;
Step 5: then add the slipping agent of 2 weight part natural nano negative ion powders, the natural radium stone flour of 1 weight part, the antibacterial powder of 1 weight part, the antioxidant of 0.5 weight part and 0.1 weight part and stir, in described mill, practice into semisolid virgin rubber material, naturally cool to room temperature; Wherein said natural negative ion powder composed as follows:
| Composition | SiO 2 | B 2O 3 | Al 2O 3 | Fe 2O 3 | MnO | M gO |
| Content | 38 | 9 | 15 | 3 | 1 | 1.8 |
| Composition | Na 2O | Li 2O | Rb 2O | ZrO | CaO | TiO 2 |
| Content | 1.5 | 0.5 | 0.05 | 30 | 0.05 | 0.05 |
Wherein specifically the consisting of of antibacterial powder: nano silicon 40 weight part, nano titanium oxide 10 weight part, nanometer silver 3 weight part, nano zine oxide 1 weight part and nano-calcium carbonate 40 weight part, described slipping agent is selected from erucicamide, and described antioxidant is selected from oxidation inhibitor-264;
Step 6: adjustment virgin rubber material thickness is 8-10mm, prepares to expect that pipe carries out rewinding and goes out finished product, the obtained underwear component virgin rubber material with natural energy effect;
Step 7: start sulfuration machine, temperature is adjusted to about 190 degree;
Step 8: cup mould is put into board and heats, when thermostatic to 190 is spent, opens mould;
Step 9: by the materials weight of cup specification size, is cut into strip by above-mentioned obtained underwear component virgin rubber material, and puts into cup mould and heat 5 minutes, makes formed product;
Step 10: open cup mould, get shaping after cup product;
Step 11: the quality confirming the hardness of cup, size, color, obtains the underwear and cup bra of natural energy effect.
Embodiment 2
Make the underwear shoulder belt with natural energy effect, comprise the following steps:
Step one: the semisolid dimethyl ethenyl (siloxanes and polysiloxane) of 79 weight parts is dissolved in the machine of beginning to pratise and carries out stirring preheating 5 minutes, wherein hydroxy-end capped dimethyl ethenyl (siloxanes and polysiloxane) accounts for 2.6%, and temperature controls between 150-220 degree Celsius;
Step 2: the nano silicon adding 20 weight parts to above-mentioned mill carries out stirring time white silk about 10 minutes, makes dimethyl ethenyl (siloxanes and polysiloxane) even with nano silicon two kinds of mixing of materials, plays filling effect;
Step 3: add the hydroxy silicon oil of 3.2 weight parts and the dimethyl silicone oil of 4 weight parts, carries out mediating about 5 minutes, allows viscous consistency, adds the natural nano negative ion powder of 2 weight parts simultaneously and stirs;
Step 4: add the sulfuration bridging agent of 4 weight parts and fully stir more than 20 minutes, promote that dimethyl ethenyl (siloxanes and polysiloxane) and silicon-dioxide are mixing, control temperature is at 200-280 degree Celsius, and bis(2，4-dichlorobenzoyl)peroxide, the dicumyl peroxide (DCP) of 18%, the silicone oil hydrogen content of 18% that described sulfuration bridging agent is configured to 30% be 1.5% high containing hydrogen silicone oil, the white carbon black of 20%, the vinyltriethoxysilane of 10% and 4% potassium silicate;
Step 5: then add the slipping agent of 3 weight part natural nano negative ion powders, the natural radium stone flour of 3 weight parts, the antibacterial powder of 2 weight parts, the antioxidant of 1 weight part and 0.5 weight part and stir, in described mill, practice into semisolid virgin rubber material, naturally cool to room temperature; Wherein said natural negative ion powder composed as follows:
| Composition | SiO 2 | B 2O 3 | Al 2O 3 | Fe 2O 3 | MnO | M gO |
| Content | 42 | 10 | 16 | 3.5 | 1.5 | 2.2 |
| Composition | Na 2O | Li 2O | Rb 2O | ZrO | CaO | TiO 2 |
| Content | 2 | 1 | 0.1 | 35 | 0.1 | 0.1 |
Wherein specifically the consisting of of antibacterial powder: nano silicon 50 weight part, nano titanium oxide 15 weight part, nanometer silver 10 weight part, nano zine oxide 3 weight part and nano-calcium carbonate 60 weight part, described slipping agent is selected from stearylamide, and described antioxidant is selected from dihydroxyphenyl propane;
Step 6: adjustment virgin rubber material thickness is 8-10mm, prepares to expect that pipe carries out rewinding and goes out finished product, the obtained underwear component virgin rubber material with natural energy effect;
Step 7: start sulfuration machine, temperature is adjusted to about 190 degree;
Step 8: shoulder belt mould is put into board and heats, when thermostatic to 190 is spent, opens mould;
Step 9: by the materials weight of shoulder belt specification size, is cut into strip by above-mentioned obtained underwear component virgin rubber material, and puts into shoulder belt mould and heat 4 minutes, makes formed product;
Step 10: open shoulder belt mould, get shaping after cup product;
Step 11: the quality confirming the hardness of shoulder belt, size, color, obtains the underwear shoulder belt of natural energy effect.
Embodiment 3
Make the underwear setting band with natural energy effect, comprise the following steps:
Step one: the semisolid dimethyl ethenyl (siloxanes and polysiloxane) of 75 weight parts is dissolved in the machine of beginning to pratise and carries out stirring preheating 5 minutes, wherein hydroxy-end capped dimethyl ethenyl (siloxanes and polysiloxane) accounts for 2.3%, and temperature controls between 150-220 degree Celsius;
Step 2: the nano silicon adding 18 weight parts to above-mentioned mill carries out stirring time white silk about 10 minutes, makes dimethyl ethenyl (siloxanes and polysiloxane) even with nano silicon two kinds of mixing of materials, plays filling effect;
Step 3: add the hydroxy silicon oil of 2.2 weight parts and the dimethyl silicone oil of 2 weight parts, carries out mediating about 5 minutes, allows viscous consistency, adds the natural nano negative ion powder of 1.5 weight parts simultaneously and stirs;
Step 4: add the sulfuration bridging agent of 3 weight parts and fully stir more than 20 minutes, promote that dimethyl ethenyl (siloxanes and polysiloxane) and silicon-dioxide are mixing, control temperature is at 200-280 degree Celsius, and bis(2，4-dichlorobenzoyl)peroxide, the dicumyl peroxide (DCP) of 16%, the silicone oil hydrogen content of 18% that described sulfuration bridging agent is configured to 30% be 1.5% high containing hydrogen silicone oil, the white carbon black of 22%, the vinyltriethoxysilane of 10% and 4% potassium silicate;
Step 5: then add the slipping agent of 2 weight part natural nano negative ion powders, the natural radium stone flour of 2 weight parts, the antibacterial powder of 1.5 weight parts, the antioxidant of 0.8 weight part and 0.3 weight part and stir, in described mill, practice into semisolid virgin rubber material, naturally cool to room temperature; Wherein said natural negative ion powder composed as follows:
| Composition | SiO 2 | B 2O 3 | Al 2O 3 | Fe 2O 3 | MnO | M gO |
| Content | 40 | 9.5 | 15.5 | 3.2 | 1.2 | 2 |
| Composition | Na 2O | Li 2O | Rb 2O | ZrO | CaO | TiO 2 |
| Content | 1.9 | 0.8 | 0.1 | 32 | 0.1 | 0.1 |
Wherein specifically the consisting of of antibacterial powder: nano silicon 45 weight part, nano titanium oxide 12 weight part, nanometer silver 8 weight part, nano zine oxide 2 weight part and nano-calcium carbonate 50 weight part, described slipping agent is selected from Zinic stearas, and described antioxidant is selected from triphenyl phosphite;
Step 6: adjustment virgin rubber material thickness is 8-10mm, prepares to expect that pipe carries out rewinding and goes out finished product, the obtained underwear component virgin rubber material with natural energy effect;
Step 7: start sulfuration machine, temperature is adjusted to about 190 degree;
Step 8: setting band mould is put into board and heats, when thermostatic to 190 is spent, open mould;
Step 9: by the materials weight of setting band specification size, above-mentioned obtained underwear component virgin rubber material is cut into strip, and put into setting band mould and heat 4 minutes, make formed product;
Step 10: opening setting band mould, get shaping after setting carries product;
Step 11: the quality confirming the hardness of setting band, size, color, obtains the underwear setting band of natural energy effect.
Embodiment 4
Make the underwear snap-fastener with natural energy effect, comprise the following steps:
Step one: the semisolid dimethyl ethenyl (siloxanes and polysiloxane) of 76 weight parts is dissolved in the machine of beginning to pratise and carries out stirring preheating 5 minutes, wherein hydroxy-end capped dimethyl ethenyl (siloxanes and polysiloxane) accounts for 2.4%, and temperature controls between 150-220 degree Celsius;
Step 2: the nano silicon adding 17 weight parts to above-mentioned mill carries out stirring time white silk about 10 minutes, makes dimethyl ethenyl (siloxanes and polysiloxane) even with nano silicon two kinds of mixing of materials, plays filling effect;
Step 3: add the hydroxy silicon oil of 2.8 weight parts and the dimethyl silicone oil of 3 weight parts, carries out mediating about 5 minutes, allows viscous consistency, adds the natural nano negative ion powder of 1.8 weight parts simultaneously and stirs;
Step 4: add the sulfuration bridging agent of 4 weight parts and fully stir more than 20 minutes, promote that dimethyl ethenyl (siloxanes and polysiloxane) and silicon-dioxide are mixing, control temperature is at 200-280 degree Celsius, and bis(2，4-dichlorobenzoyl)peroxide, the dicumyl peroxide (DCP) of 15%, the silicone oil hydrogen content of 20% that described sulfuration bridging agent is configured to 30% be 1.5% high containing hydrogen silicone oil, the white carbon black of 24%, the vinyltriethoxysilane of 8% and 3% potassium silicate;
Step 5: then add the slipping agent of 2.2 weight part natural nano negative ion powders, the natural radium stone flour of 2.2 weight parts, the antibacterial powder of 1.8 weight parts, the antioxidant of 0.6 weight part and 0.4 weight part and stir, in described mill, practice into semisolid virgin rubber material, naturally cool to room temperature; Wherein said natural negative ion powder composed as follows:
| Composition | SiO 2 | B 2O 3 | Al 2O 3 | Fe 2O 3 | MnO | M gO |
| Content | 41 | 9.5 | 15.8 | 3.2 | 1.2 | 2.1 |
| Composition | Na 2O | Li 2O | Rb 2O | ZrO | CaO | TiO 2 |
| Content | 1.6 | 0.6 | 0.05 | 33 | 0.1 | 0.1 |
Wherein specifically the consisting of of antibacterial powder: nano silicon 48 weight part, nano titanium oxide 12 weight part, nanometer silver 10 weight part, nano zine oxide 2 weight part and nano-calcium carbonate 40 weight part, described slipping agent is selected from amine hydroxybenzene, and described antioxidant is selected from tris phosphite;
Step 6: adjustment virgin rubber material thickness is 8-10mm, prepares to expect that pipe carries out rewinding and goes out finished product, the obtained underwear component virgin rubber material with natural energy effect;
Step 7: start sulfuration machine, temperature is adjusted to about 190 degree;
Step 8: snap-fastener mould is put into board and heats, when thermostatic to 190 is spent, opens mould;
Step 9: by the materials weight of snap-fastener specification size, is cut into strip by above-mentioned obtained underwear component virgin rubber material, and puts into snap-fastener mould and heat 4 minutes, makes formed product;
Step 10: open snap-fastener mould, get shaping after by buckle product;
Step 11: the quality confirming the hardness of snap-fastener, size, color, obtains the underwear snap-fastener of natural energy effect.
Underwear component obtained by the various embodiments described above there is good expansion performance after tested and anti-tearly to draw, anti tear characteristic, and be machined in after in underwear and make underwear entirety have good health-care effect, facilitate the development of modern health underwear.
Below be only that the preferred embodiment of the present invention is described; technical scheme of the present invention is not limited to this; the any known distortion that those skilled in the art do on the basis that major technique of the present invention is conceived all belongs to the claimed technology category of the present invention, and the concrete protection domain of the present invention is as the criterion with the record of claims.
Claims (10)
1. a underwear member material, it is characterized in that, by the dimethyl ethenyl (siloxanes and polysiloxane) of 73-79 weight part, the nano silicon of 15-20 weight part, the hydroxy silicon oil of 0.5-3.2 weight part, the sulfuration bridging agent of 2-4 weight part, the dimethyl silicone oil of 1-4 weight part, the natural nano negative ion powder of 3-5 weight part, the natural radium stone flour of 1-3 weight part, the antibacterial powder of 1-2 weight part, the antioxidant of 0.5-1 weight part and the slipping agent hybrid reaction of 0.8-1.2 weight part obtain, wherein hydroxy-end capped in dimethyl ethenyl (siloxanes and polysiloxane) dimethyl ethenyl (siloxanes and polysiloxane) accounts for the weight ratio of 2.1-2.6%, wherein said natural nano negative ion powder comprises the following powder component of nanometer particle size: SiO
2, B
2o
3, Al
2o
3, Fe
2o
3, ZrO, MnO, MgO, Na
2o and Li
2o.
2. underwear member material according to claim 1, it is characterized in that, the particle diameter of wherein said nano silicon is between 10-20nm and purity reaches 99.9%, and described hydroxy silicon oil is that at 25 DEG C, oil viscosity was less than or equal to for 25 milli handkerchief seconds, specific refractory power is in 1.44-1.46, ring body content at 23-25%, hydroxy radical content at the hydroxy silicon oil of 7.5-9.5% at 25 DEG C.
3. the underwear member material according to any one of claim 1-2, it is characterized in that, wherein said sulfuration bridging agent is by the peroxidation two (2 of 25-30%, 4-dichloro-benzoyl), the dicumyl peroxide (DCP) of 15-18%, the silicone oil hydrogen content of 16 ~ 20% be 1.2% ~ 1.5% high containing hydrogen silicone oil, the white carbon black of 15-25%, the vinyltriethoxysilane of 8-12% and 3-5% potassium silicate composition, each per-cent is mass percent.
4. the underwear member material according to any one of claim 1-3, is characterized in that, wherein said natural nano negative ion powder is by the Nano-meter SiO_2 of 38-42 weight part
2, 9-10 weight part nanometer B
2o
3, 15-16 weight part nanometer Al
2o
3, 3-3.5 weight part nanometer Fe
2o
3, the nanometer MnO of 1-1.5 weight part, the nano-MgO of 1.8-2.2 weight part, the nanometer Na of 1.5-2 weight part
2the nanometer Li of O, 0.5-1 weight part
2nanometer Rb below the nanometer ZrO of O, 30-35 weight part, 0.1 weight part
2nanometer CaO below O, 0.1 weight part and the nano-TiO below 0.1 weight part
2composition.
5. the underwear member material according to any one of claim 1-4, it is characterized in that, wherein said antibacterial powder is made up of the nano-calcium carbonate of the nano titanium oxide of the nano silicon of 40-50 weight part, 10-15 weight part, the nanometer silver of 3-10 weight part, the nano zine oxide of 1-3 weight part and 40-60 weight part.
6. the underwear member material according to any one of claim 1-5, it is characterized in that, wherein said antioxidant is selected from the one in oxidation inhibitor-264, dihydroxyphenyl propane, triphenyl phosphite, oxidation inhibitor-1010, antioxidant 1076 or tris phosphite, and described slipping agent is selected from the one in erucicamide, stearylamide, Zinic stearas or amine hydroxybenzene.
7. the underwear member material according to any one of claim 1-6, is characterized in that, the expansion and contraction of described underwear member material reaches more than 850%, and pull apart tensile strength and reach more than 15Mpa, tear strength reaches 8 × 10
4more than N/m, radiation infrared wavelength concentrates within the scope of 8-11 μm, and ir radiant power density reaches 0.09W/cm
2above, negative-ion energy burst size reaches 10000/cm
3above; Described underwear component comprises cup, shoulder belt, setting band, snap-fastener.
8. a making method for underwear member material described in any one of claim 1-7, is characterized in that, comprise the following steps:
Step one: dissolved in the machine of beginning to pratise by the above-mentioned dimethyl ethenyl (siloxanes and polysiloxane) of 73-79 weight part and stir preheating 5-10 minute, temperature controls between 150-220 degree Celsius;
Step 2: the above-mentioned nano silicon adding 15-20 weight part to above-mentioned mill carries out stirring time white silk about 10 minutes, makes dimethyl ethenyl (siloxanes and polysiloxane) and nano silicon two kinds of mixing of materials even;
Step 3: add the above-mentioned hydroxy silicon oil of 0.5-3.2 weight part and the above-mentioned dimethyl silicone oil of 1-4 weight part, carry out kneading 3-5 minute, allows viscous consistency, adds the above-mentioned natural nano negative ion powder of 1-2 weight part simultaneously and stirs;
Step 4: add the above-mentioned sulfuration bridging agent of 2-4 weight part and fully stir more than 20 minutes, promote that dimethyl ethenyl (siloxanes and polysiloxane) and silicon-dioxide are mixing, and control temperature is at 200-280 degree Celsius;
Step 5: add the above-mentioned slipping agent of the above-mentioned natural nano negative ion powder of remaining 2-3 weight part, the above-mentioned natural radium stone flour of 1-3 weight part, the above-mentioned antibacterial powder of 1-2 weight part, the above-mentioned antioxidant of 0.5-1 weight part and 0.8-1.2 weight part and stir, the virgin rubber material of semi-solid is practiced in described mill, then room temperature is naturally cooled to, obtained described underwear member material.
9. a underwear structure manufacture method, is characterized in that, comprises the following steps: (1), startup sulfuration machine, about temperature being adjusted to 180-200 degree; (2), underwear element mold is put into board heat, when thermostatic to 190 is spent, open mould; (3), by the materials weight of underwear component specification size, the underwear member material that making method described in underwear member material described in any one of claim 1-7 or claim 8 is obtained is cut into strip, put into underwear element mold to heat 5-8 minute, make formed product; (4), open underwear element mold, take out shaping after underwear component product.
10. underwear structure manufacture method according to claim 9, is characterized in that, described underwear component comprises cup, shoulder belt, setting band and snap-fastener.
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| CN106633893A (en) * | 2016-11-30 | 2017-05-10 | 海宁久久胶塑有限公司 | Negative-oxygen-ion silica gel as well as production process and application thereof |
| CN106700763A (en) * | 2016-11-24 | 2017-05-24 | 河北晨阳工贸集团有限公司 | Eyesight-improving interior wall water paint and preparation method thereof |
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| CN1900180A (en) * | 2005-07-22 | 2007-01-24 | Sar控股国际有限公司 | Negative ion silica-gel composition, its preparing method and its product |
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| CN1542054A (en) * | 2003-07-14 | 2004-11-03 | 黎俊廷 | Nanometer silicon rubber product and method for preparing the same |
| CN1740217A (en) * | 2004-08-27 | 2006-03-01 | 株式会社东星硅树脂 | Silicon rubber foam and producing method and use thereof |
| CN1900180A (en) * | 2005-07-22 | 2007-01-24 | Sar控股国际有限公司 | Negative ion silica-gel composition, its preparing method and its product |
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| CN106700763A (en) * | 2016-11-24 | 2017-05-24 | 河北晨阳工贸集团有限公司 | Eyesight-improving interior wall water paint and preparation method thereof |
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