CN104311898B - The liberation footwear plasticating technology of calendering type black rubber foxing glue - Google Patents

The liberation footwear plasticating technology of calendering type black rubber foxing glue Download PDF

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Publication number
CN104311898B
CN104311898B CN201410595830.3A CN201410595830A CN104311898B CN 104311898 B CN104311898 B CN 104311898B CN 201410595830 A CN201410595830 A CN 201410595830A CN 104311898 B CN104311898 B CN 104311898B
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China
Prior art keywords
rubber
parts
glue
age resistor
type black
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CN201410595830.3A
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CN104311898A (en
Inventor
杜江
陈松雄
周川泉
晋齐怀
石银平
田吉
张世林
廖浦江
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Jihua Shoes Industry Co ltd
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Jihua 3537 Shoe Making Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00—Compositions of natural rubber
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B1/00—Footwear characterised by the material
    • A43B1/10—Footwear characterised by the material made of rubber
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00—Mixing; Kneading
    • B29B7/02—Mixing; Kneading non-continuous, with mechanical mixing or kneading devices, i.e. batch type
    • B29B7/22—Component parts, details or accessories; Auxiliary operations
    • B29B7/28—Component parts, details or accessories; Auxiliary operations for measuring, controlling or regulating, e.g. viscosity control
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)

Abstract

The invention discloses a kind of plasticating technology liberating footwear calendering type black rubber foxing glue, calculate in parts by weight, take butadiene-styrene rubber 6～8 parts, natural rubber 45～55 parts, age resistor CD 0.8～1.2 parts, age resistor KY 405L 0.2～0.4 part, and composite resin DS B 4～6 parts；Natural rubber is cut into the blob of viscose of 15 20 kilograms/block, in banbury, puts into natural rubber, butadiene-styrene rubber and the composite resin DS B cut, after banburying 3 minutes, add age resistor CD and age resistor KY 405L, then refine 4 minutes, discharge, it is thus achieved that banburying glue；Banburying glue is put into opening rubber mixing machine, under roll spacing is 5～6mm, lower machine of operating on turns refining 6～8 times, further according to needing to batch the packing element of predetermined weight level, sampling detection sizing material Wei Shi flexibility is 0.33～0.38, i.e. obtains the liberation footwear broken-down rubber of calendering type black rubber foxing glue.

Description

The liberation footwear plasticating technology of calendering type black rubber foxing glue
Technical field
The present invention relates to a kind of elastomeric material preparation field, a kind of plasticating technology liberating footwear calendering type black rubber foxing glue.
Background technology
The plasticating technology of current liberation footwear calendering type black rubber foxing glue uses opening rubber mixing machine and plasticates mode, first will just blob of viscose softened by baking in 40～60 DEG C of environment, again blob of viscose is crushed, then broken sizing material is put into roll spacing be 0.5-1mm, the opening rubber mixing machine of roller temperature 40～45 DEG C draws logical several times, make sizing material flexibility reach requirement.This plasticating technology there is problems of requiring that strict temperature controls, and needing substantial amounts of rubber mixing machine cooling water is that roller reduces the stability of temperature guarantee sizing material flexibility, higher work efficiency.There is also that hand labor intensity is big, degree of safety is low simultaneously, require that refining glue place is big, powder adds fashionable dust from flying in operation of plasticating and pollutes the weakness of environment, instability due to rubber mixing machine surface temperature, form sizing material flexibility unstable, finally cause processing performance unstable, age resistor age resistor KY-405L thus be difficult to sizing material formed homogeneous dispersion, and sizing material viscosifier RX-80 or composite resin DS-B etc. are because the elastomeric compound time is short, material dispersion inequality, form sizing material mass defect.
Summary of the invention
It is an object of the invention to: a kind of plasticating technology liberating footwear calendering type black rubber foxing glue is provided, it uses banbury replacement opening rubber mixing machine to carry out sizing material and plasticates, designed by rational feeding sequence, solve flexibility fluctuation big, labor intensity is big, the former opening rubber mixing machine plasticating technology weakness that degree of safety is low, reach dust from flying few, take up an area few, age resistor KY-405L, dispersed in sizing material of the materials such as composite resin DS B, the stay-in-grade technical problem of sizing material, achieve the technique effect that sizing material removing from mould processing performance is stable, owing to flexibility is in reasonable level, elastomeric compound hardness is made to meet decorative pattern requirement clearly, overcome the deficiencies in the prior art.
The present invention is achieved in that the plasticating technology of liberation footwear calendering type black rubber foxing glue, calculate in parts by weight, take butadiene-styrene rubber 6～8 parts, natural rubber 45～55 parts, age resistor CD 0.8～1.2 parts, age resistor KY-405L 0.2～0.4 part, and composite resin DS-B 4～6 parts；Natural rubber is cut into the blob of viscose of 15-20 kilogram/block, in banbury, puts into natural rubber, butadiene-styrene rubber and the composite resin DS-B cut, after banburying 3 minutes, add age resistor CD and age resistor KY-405L, then refine 4 minutes, discharge, it is thus achieved that banburying glue；Banburying glue is put into opening rubber mixing machine, under roll spacing is 5～6mm, lower machine of operating on turns refining 6～8 times, further according to needing to batch the packing element of predetermined weight level, sampling detection sizing material Wei Shi flexibility is 0.33～0.38, i.e. obtains the liberation footwear broken-down rubber of calendering type black rubber foxing glue.
The temperature of banbury is 80～85 DEG C.
The temperature of opening rubber mixing machine is 40～50 DEG C.
In order to verify the effect of the present invention further, carry out following experiment:
Upper table result shows, preferably: mill glue supplement refining rubber roll away from 5-6mm, turn refining 6-8 time.
Owing to have employed technique scheme, compared with prior art, the present invention solves the technical problem that, by rational feeding sequence, use banbury replacement opening rubber mixing machine to carry out sizing material to plasticate, solve the former open plasticating technology weakness that flexibility fluctuation is big, labor intensity is big, degree of safety is low, reach that dust from flying is few, take up an area less, the stable technical problem of compound quality, it is achieved that the technique effect that sizing material removing from mould processing performance is stable. this technological advantage is that production efficiency is high, energy consumption cost is low, constant product quality.
Detailed description of the invention
Embodiments of the invention 1: the liberation footwear plasticating technology of calendering type black rubber foxing glue, calculate in parts by weight, take butadiene-styrene rubber 7.5 kilograms, natural rubber 50 kilograms, age resistor CD 1 kilogram, age resistor KY-405L 0.3 kilogram, and composite resin DS-B 5 kilograms；Natural rubber (2# standard rubber) is cut into the blob of viscose of 15-20 kilogram/block, in the banbury that temperature is 80～85 DEG C, puts into natural rubber, butadiene-styrene rubber and the composite resin DS-B cut, after banburying 3 minutes, add age resistor CD and age resistor KY-405L, refine 4 minutes again, discharge, it is thus achieved that banburying glue；Banburying glue is put into opening rubber mixing machine, the temperature of opening rubber mixing machine is 40～50 DEG C, under roll spacing is 5～6mm, lower machine of operating on turns refining 6～8 times, further according to needing to batch the packing element of predetermined weight level, sampling detection sizing material Wei Shi flexibility is 0.33～0.38, i.e. obtains the liberation footwear broken-down rubber of calendering type black rubber foxing glue.
Embodiments of the invention 2: the liberation footwear plasticating technology of calendering type black rubber foxing glue, calculate in parts by weight, take butadiene-styrene rubber 6 kilograms, natural rubber 55 kilograms, age resistor CD 0.8 kilogram, age resistor KY-405L 0.4 kilogram, and composite resin DS-B 6 kilograms；Natural rubber is cut into the blob of viscose of 15-20 kilogram/block, in the banbury that temperature is 80～85 DEG C, puts into natural rubber, butadiene-styrene rubber and the composite resin DS-B cut, after banburying 3 minutes, add age resistor CD and age resistor KY-405L, refine 4 minutes again, discharge, it is thus achieved that banburying glue；Banburying glue is put into opening rubber mixing machine, the temperature of opening rubber mixing machine is 40～50 DEG C, under roll spacing is 5～6mm, lower machine of operating on turns refining 6～8 times, further according to needing to batch the packing element of predetermined weight level, sampling detection sizing material Wei Shi flexibility is 0.33～0.38, i.e. obtains the liberation footwear broken-down rubber of calendering type black rubber foxing glue.
Embodiments of the invention 3: the liberation footwear plasticating technology of calendering type black rubber foxing glue, calculate in parts by weight, take butadiene-styrene rubber 8 kilograms, natural rubber 45 kilograms, age resistor CD 1.2 kilograms, age resistor KY-405L 0.2 kilogram, and composite resin DS-B 4 kilograms；Natural rubber is cut into the blob of viscose of 15-20 kilogram/block, in the banbury that temperature is 80～85 DEG C, puts into natural rubber, butadiene-styrene rubber and the composite resin DS-B cut, after banburying 3 minutes, add age resistor CD and age resistor KY-405L, refine 4 minutes again, discharge, it is thus achieved that banburying glue；Banburying glue is put into opening rubber mixing machine, the temperature of opening rubber mixing machine is 40～50 DEG C, under roll spacing is 5～6mm, lower machine of operating on turns refining 6～8 times, further according to needing to batch the packing element of predetermined weight level, sampling detection sizing material Wei Shi flexibility is 0.33～0.38, i.e. obtains the liberation footwear broken-down rubber of calendering type black rubber foxing glue.

Claims (3)

1. the plasticating technology liberating footwear calendering type black rubber foxing glue, it is characterized in that: calculate in parts by weight, take butadiene-styrene rubber 6～8 parts, natural rubber 45～55 parts, age resistor CD 0.8～1.2 parts, age resistor KY-405L 0.2～0.4 part, and composite resin DS-B 4～6 parts；Natural rubber is cut into the blob of viscose of 15-20 kilogram/block, in banbury, puts into natural rubber, butadiene-styrene rubber and the composite resin DS-B cut, after banburying 3 minutes, add age resistor CD and age resistor KY-405L, then refine 4 minutes, discharge, it is thus achieved that banburying glue；Banburying glue is put into opening rubber mixing machine, under roll spacing is 5～6mm, lower machine of operating on turns refining 6～8 times, further according to needing to batch the packing element of predetermined weight level, sampling detection sizing material Wei Shi flexibility is 0.33～0.38, i.e. obtains the liberation footwear broken-down rubber of calendering type black rubber foxing glue.
The plasticating technology of liberation footwear calendering type black rubber foxing glue the most according to claim 1, it is characterised in that: the temperature of banbury is 80～85 DEG C.
The plasticating technology of liberation footwear calendering type black rubber foxing glue the most according to claim 1, it is characterised in that: the temperature of opening rubber mixing machine is 40～50 DEG C.
CN201410595830.3A 2014-10-30 2014-10-30 The liberation footwear plasticating technology of calendering type black rubber foxing glue Active CN104311898B (en)

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Publication number Priority date Publication date Assignee Title
CN105131364A (en) * 2015-10-09 2015-12-09 际华三五三七制鞋有限责任公司 Environment-friendly rolling type rubber natural-color covering strip glue for shoes and preparation method of environment-friendly rolling type rubber natural-color covering strip glue
CN105542675A (en) * 2016-01-29 2016-05-04 宁波吉象塑胶制品有限公司 Preparation method of wear-resistant adhesive tape

Citations (3)

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Publication number Priority date Publication date Assignee Title
CN101381487A (en) * 2008-10-20 2009-03-11 吴金林 Breathable rubber and use thereof
CN101955599A (en) * 2010-10-21 2011-01-26 际华三五三七制鞋有限责任公司 Formula for in situ preparing rolled high brightness shoe side rubber and preparation method thereof
CN103435859A (en) * 2013-08-31 2013-12-11 青岛承天伟业机械制造有限公司 High-efficiency oil-resistant wear-resistant rubber

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FR2894252B1 (en) * 2005-12-07 2013-01-04 Arkema RETICULATED COMPOSITION COMPRISING A BARK-HEATED COPOLYMER, METHOD FOR PRODUCING THE SAME AND USES THEREOF

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Publication number Priority date Publication date Assignee Title
CN101381487A (en) * 2008-10-20 2009-03-11 吴金林 Breathable rubber and use thereof
CN101955599A (en) * 2010-10-21 2011-01-26 际华三五三七制鞋有限责任公司 Formula for in situ preparing rolled high brightness shoe side rubber and preparation method thereof
CN103435859A (en) * 2013-08-31 2013-12-11 青岛承天伟业机械制造有限公司 High-efficiency oil-resistant wear-resistant rubber

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"纳米碳酸钙在解放鞋草绿围条中的应用";易岳雄等;《橡胶工业》;20121125;第59卷(第11期);第673-675页 *

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Address after: 550025 No. 1 Qingxi Road, Huaxi District, Guiyang City, Guizhou Province

Patentee after: Jihua 3537 Co.,Ltd.

Address before: 550025 No. 1 Qingxi Road, Huaxi District, Guiyang City, Guizhou Province

Patentee before: JIHUA 3537 SHOE-MAKING Co.,Ltd.

CP03 Change of name, title or address
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Address after: 550025 No. 1 Qingxi Road, Huaxi District, Guizhou, Guiyang

Patentee after: Jihua Shoes Industry Co.,Ltd.

Address before: No. 1, Qingxi Road, Huaxi District

Patentee before: Jihua 3537 Co.,Ltd.