CN104311584A - Synthesis and application of cadmium metal organic complex second-order nonlinear optical material - Google Patents
Synthesis and application of cadmium metal organic complex second-order nonlinear optical material Download PDFInfo
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- CN104311584A CN104311584A CN201410526497.0A CN201410526497A CN104311584A CN 104311584 A CN104311584 A CN 104311584A CN 201410526497 A CN201410526497 A CN 201410526497A CN 104311584 A CN104311584 A CN 104311584A
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- nonlinear optical
- order nonlinear
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- dioctyl phthalate
- cadmium
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- 230000003287 optical effect Effects 0.000 title claims abstract description 29
- 239000000463 material Substances 0.000 title claims abstract description 14
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 title abstract description 10
- 230000015572 biosynthetic process Effects 0.000 title abstract description 7
- 238000003786 synthesis reaction Methods 0.000 title abstract description 6
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims abstract description 15
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000013078 crystal Substances 0.000 claims abstract description 10
- 238000006243 chemical reaction Methods 0.000 claims abstract description 7
- YKYOUMDCQGMQQO-UHFFFAOYSA-L cadmium dichloride Chemical compound Cl[Cd]Cl YKYOUMDCQGMQQO-UHFFFAOYSA-L 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000007810 chemical reaction solvent Substances 0.000 claims abstract description 5
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 230000004044 response Effects 0.000 claims description 15
- 150000001875 compounds Chemical class 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 12
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 9
- -1 pyrazoles dioctyl phthalate Chemical class 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 5
- 238000002425 crystallisation Methods 0.000 claims description 3
- 230000008025 crystallization Effects 0.000 claims description 3
- 235000006408 oxalic acid Nutrition 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 125000006850 spacer group Chemical group 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 2
- 239000000376 reactant Substances 0.000 claims description 2
- 229910052793 cadmium Inorganic materials 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 150000004696 coordination complex Chemical class 0.000 abstract description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 abstract 2
- 235000019796 monopotassium phosphate Nutrition 0.000 abstract 2
- 239000011259 mixed solution Substances 0.000 abstract 1
- 229910000402 monopotassium phosphate Inorganic materials 0.000 abstract 1
- GNSKLFRGEWLPPA-UHFFFAOYSA-M potassium dihydrogen phosphate Chemical compound [K+].OP(O)([O-])=O GNSKLFRGEWLPPA-UHFFFAOYSA-M 0.000 abstract 1
- LWIHDJKSTIGBAC-UHFFFAOYSA-K potassium phosphate Substances [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 abstract 1
- 230000002194 synthesizing effect Effects 0.000 abstract 1
- 229910021645 metal ion Inorganic materials 0.000 description 6
- 238000011160 research Methods 0.000 description 6
- 230000008859 change Effects 0.000 description 4
- 239000013110 organic ligand Substances 0.000 description 4
- 230000006854 communication Effects 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- WLZRMCYVCSSEQC-UHFFFAOYSA-N cadmium(2+) Chemical compound [Cd+2] WLZRMCYVCSSEQC-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000010365 information processing Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000005281 excited state Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000005283 ground state Effects 0.000 description 1
- ZHUXMBYIONRQQX-UHFFFAOYSA-N hydroxidodioxidocarbon(.) Chemical compound [O]C(O)=O ZHUXMBYIONRQQX-UHFFFAOYSA-N 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 150000001455 metallic ions Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000000644 propagated effect Effects 0.000 description 1
- 150000003217 pyrazoles Chemical class 0.000 description 1
- 125000003226 pyrazolyl group Chemical group 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 238000001338 self-assembly Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/08—Cadmium compounds
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/35—Non-linear optics
- G02F1/355—Non-linear optics characterised by the materials used
- G02F1/361—Organic materials
- G02F1/3611—Organic materials containing Nitrogen
- G02F1/3612—Heterocycles having N as heteroatom
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F2202/00—Materials and properties
- G02F2202/02—Materials and properties organic material
- G02F2202/021—Materials and properties organic material low molecular weight
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- Physics & Mathematics (AREA)
- Nonlinear Science (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Optical Modulation, Optical Deflection, Nonlinear Optics, Optical Demodulation, Optical Logic Elements (AREA)
Abstract
The invention relates to a cadmium metal organic complex second-order nonlinear optical material and synthesis and application thereof. The invention aims at synthesizing a second-order nonlinear optical responsive metal complex of cadmium in non-centrosymmetry by selecting a 3, 5-pyrazol dioctyl phthalate in centrosymmetry. By using cadmium chloride and 3, 5-pyrazol dioctyl phthalate as reaction raw materials and a mixed solution of acetonitrile and water as a reaction solvent, a single crystal of the complex (H3O)[Cd3(Hpada)2(pada)(H2O) under a solvothermal condition is obtained. The single crystal of the complex is flaky and easy to prepare by a device. The second-order nonlinear optical responsive strength is about 1/2 of KDP (monopotassium phosphate) in phase match and can be used for manufacturing a nonlinear optical device.
Description
Technical field
The present invention relates to a kind of second nonlinear optic response metal complexes, particularly relate to cadmium metal organic coordination compound second-order non-linear optical materials (H
3o) [Cd
3(Hpada)
2(pada) (H
2o) synthesis] and application, wherein H
3pada=3,5 pyrazoles dioctyl phthalate.
Background technology
Organometallic complex passes through metal ion, as the compounds that transition metal, rare earth ion and organic ligand generate by forming coordinate bond, select various because of metal ion and organic ligand and can arrange in pairs or groups flexibly, make the structure of metal complex very abundant and can regulate and control to a certain extent, these features of metal complexes make it play an important role in fields such as optical, electrical device and the energy, thus cause the dense research interest of scientists.Wherein, the research of the second-order nonlinear optical property of metal complexes receives the attention of more and more investigator.
Before laser occurs, the understanding of the mankind to optical phenomena only rests on " linear optics " stage.So-called linear optics refers to when low light level bundle is propagated in media as well, the major optical parameter such as specific refractory power, uptake factor of medium and the intensity of incident light have nothing to do, namely these significant parameters can not change with the change of the intensity of light, and the frequency of light also can not change in communication process.But along with the discovery of laser, linear optics cannot explain some new optical phenomenas, as launched the light beam of a branch of new frequency after medium when beam of laser.Therefore, nonlinear optics is arisen at the historic moment as an emerging optics subject, correspondingly, become to the research of nonlinear optics particularly second-order non-linear optical materials the research topic that has scientific value very much, the prepared material with excellent second nonlinear optic response to calculate and there is important application in the field such as dynamic imaging at optical Information Processing, laser frequency conversion, photoelectric communication, unicircuit, photon.Compared with inorganic with pure or pure organic second-order non-linear optical material, a metal-organic complex has good Charger transfer, more transition energy, the diversity of atoms metal and the moment of dipole change advantage such as obvious between ground state and excited state, becomes study hotspot and the forward position in current second-order non-linear optical materials field.
A kind of molecule or material will have its structure of second-order nonlinear optical property requirement must be non-centrosymmetrical and crystallization in non-centrosymmetrical spacer.The molecular structure typically with Nonlinear Second order Optical Properties also meets " Donor-π-Acceptor " configuration.Linked together by conjugated structure between electron donor(ED) (Donor) and acceptor (Acceptor).Electron donor(ED) produces second order nonlinear optical effect transfer transport to electron acceptor(EA) by conjugated bridge.In traditional sense, a metal-organic complex constructing second nonlinear optic response is the part and the metallic ion coordination that utilize non-centrosymmetrical or even chirality.But as long as nearest research shows that metal ion and organic ligand take a kind of asymmetric coordination mode, and complex molecule piles up the non-heart title complex also can constructing out second nonlinear optic response in crystal in asymmetric mode.So, the quantity with the non-centrosymmetry compound of second nonlinear optic response will increase greatly.But because up to the present also there is no enough practical experiences and synthesis strategy, so the non-heart title complex utilizing centrosymmetric part to construct second nonlinear optic response remains challenging something; Correspondingly, associated materials synthesis and report also less.
3,5 pyrazoles dioctyl phthalate contain a pyrazole ring and two carboxyls, are centrosymmetric molecules.Pyrazoles is five-ring electron-conjugated system; Itself and carboxyl all have stronger and various coordination ability, can construct zero to three-dimensional structure-rich and the metal complexes of novelty with metal ion.Therefore, by regulation and control reaction conditions, prepare based on 3, the non-centrosymmetry metal complexes of 5 pyrazoles dioctyl phthalate parts, can the experience that provides of the research in field for this reason; The compound with excellent second-order nonlinear optical property simultaneously obtained, the making that can be second nonlinear optic device provides potential material.
Summary of the invention
Object of the present invention is just the metal complexes (H being synthesized a kind of second nonlinear optic response cadmium by centrosymmetric 3,5 pyrazoles dioctyl phthalate parts
3o) [Cd
3(Hpada)
2(pada) (H
2o)].
The present invention includes following technical scheme
1. a second-order non-linear optical crystal material (H
3o) [Cd
3(Hpada)
2(pada) (H
2o)], H
3pada=3,5 pyrazoles dioctyl phthalate, is characterized in that: this compound is oblique system, and crystallization in polarity spacer is
pc, cell parameter is
a=8.84 (3),
b=12.78 (5),
c=12.21 (4),
α=
γ=90 o,
β=100.06 (7) o,
z=2, unit-cell volume V=1358.85 (17).
2. a preparation method with second nonlinear optic response title complex for claim 1, is characterized in that:
Reactant Cadmium chloride fine powder, 3,5 pyrazoles dioctyl phthalate, oxalic acid is as reaction raw materials, and its mol ratio is 3:3:1, and adopt the mixed liquid of acetonitrile and water as reaction solvent, be warming up to 150 DEG C, constant temperature 3 days, is then down to room temperature.
3. a purposes for the second nonlinear optic response metal complexes of item 1, is characterized in that: its second-order nonlinear optical property can be utilized for making device for non-linear optical.
Embodiment
We select CdCl
22.5H
2o, 3,5 pyrazoles dioctyl phthalate and H
2c
2o
42H
2o is reaction raw materials, adopts the mixing solutions of acetonitrile and water as reaction solvent, obtains cadmium metal complex (H under solvent thermal condition
3o) [Cd
3(Hpada)
2(pada) (H
2o) colorless plate monocrystalline].We record molecular structure and the crystalline structure of this Metal cadmium complex.3,5 pyrazoles dioctyl phthalate parts carry out chelating ligands with carboxyl oxygen and pyrazolyl nitrogen-atoms and cadmium metal ion, take the mode of octahedral coordination for one in three cadmium ions, all the other two cadmium ions take the mode of seven coordinations, a final formation three-dimensional anionic framework structure.
Second nonlinear light optic response metal complexes provided by the present invention adopts cadmium metal ion and organic ligand self-assembly under the acidity of oxalic acid regulates to obtain, and reaction solvent is the mixing solutions of acetonitrile and water; Product is tabular crystal, is easy to element manufacturing; Material preparation method is simple, easy to operate; Sufficient raw, low production cost.
Second nonlinear optic response metal complexes Clock Multiplier Factor prepared by this invention is 0.5 times of potassium primary phosphate, and there is the feature of phase matched, its performance can be utilized for making optical Information Processing, laser frequency conversion, photoelectric communication, unicircuit, photon calculating, Laser Devices.
Embodiment 1
The preparation of compound
Take CdCl
22.5H
2o (0.3 mmol), H
3pada (0.3 mmol), H
2c
2o
42H
2o (0.1 mmol), adds the distilled water of 2 mL acetonitriles and 2 mL, loads in the reactor of 25 airtight mL, and adopt solvent process for thermosynthesizing, be warming up to 150 DEG C, constant temperature 3 days, is cooled to room temperature subsequently, just can obtain crystal.Analyze through X-ray single crystal diffraction, determine that this crystal is (H
3o) [Cd
3(Hpada)
2(pada) (H
2o)], wherein H
3pada=3,5 pyrazoles dioctyl phthalate.
Second-order nonlinear optical property is tested
The crystal prototype of preparation is ground, sieve the sample (30 – 50,50 – 75,75 – 100,100 – 150,150 – 200,200 – 300 μm) obtaining six kinds of different-grain diameter scopes.From development second-order nonlinear optical test system on testing, result show, second nonlinear optic response intensity is about KDP(potassium primary phosphate) 1/2; And be phase matched.
Accompanying drawing explanation.
Fig. 1 is the powder diffraction experiment value (b curve) of the compound of embodiment 1 and the comparison diagram of the analogue value (a curve), and interpret sample purity is higher.
Fig. 2 is the infrared spectrogram of the compound of embodiment 1, determines the organic constituent in sample.
Fig. 3 is second nonlinear optic response (a curve) and the KDP(KH of the compound of embodiment 1
2pO
4) comparison diagram of standard specimen (b curve).
Fig. 4 is the second nonlinear phase matched figure of the compound of embodiment 1.
Claims (3)
1. a second-order non-linear optical crystal material (H
3o) [Cd
3(Hpada)
2(pada) (H
2o)], H
3pada=3,5 pyrazoles dioctyl phthalate, is characterized in that: this compound is oblique system, and crystallization in polarity spacer is
pc, cell parameter is
a=8.84 (3),
b=12.78 (5),
c=12.21 (4),
α=
γ=90 o,
β=100.06 (7) o,
z=2, unit-cell volume V=1358.85 (17).
2. a preparation method with second nonlinear optic response title complex for claim 1, is characterized in that:
Reactant Cadmium chloride fine powder, 3,5 pyrazoles dioctyl phthalate, oxalic acid is as reaction raw materials, and its mol ratio is 3:3:1, and adopt the mixed liquid of acetonitrile and water as reaction solvent, be warming up to 150 DEG C, constant temperature 3 days, is then down to room temperature.
3. a purposes for the second nonlinear optic response metal complexes of item 1, is characterized in that: its second-order nonlinear optical property can be utilized for making device for non-linear optical.
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|---|---|
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Family
ID=52366920
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105820347A (en) * | 2016-04-28 | 2016-08-03 | 河南大学 | Three-dimensional coordination polymer nonlinear optical material and preparation method thereof |
| CN106319623A (en) * | 2016-09-18 | 2017-01-11 | 济南大学 | Silver iodine based hybrid second-order nonlinear optical material and synthesis and application thereof |
| CN106432325A (en) * | 2016-09-22 | 2017-02-22 | 济南大学 | Yellow photoluminescence nonlinear optical crystal material and preparation and application thereof |
| CN111518282A (en) * | 2020-06-24 | 2020-08-11 | 江苏理工学院 | Hydroxypyrazole cadmium carboxylate coordination polymer for visible light catalytic degradation of organic dye and preparation and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03284734A (en) * | 1990-03-31 | 1991-12-16 | Toshiba Corp | Organic nonlinear optical material |
| CN101798319A (en) * | 2009-12-10 | 2010-08-11 | 郑州轻工业学院 | 2, 3, 4, 5-tetrahydrofuran tetracarboxylic acid and 3-(2-pyridyl) pyrazol-mixed cadmium composition, as well as preparation method and application thereof |
| CN102053449A (en) * | 2009-10-28 | 2011-05-11 | 中国科学院福建物质结构研究所 | Glutamic acid-derived chiral metal-organic nonlinear optical material |
| CN102532173A (en) * | 2011-12-09 | 2012-07-04 | 天津工业大学 | Pyrazole diacid-bridged lutecium complex and preparation method thereof |
| CN102644118A (en) * | 2012-04-27 | 2012-08-22 | 中国科学院福建物质结构研究所 | Benzene three acid calcium cadmium dissimilar metal complexes and synthesis and application thereof |
-
2014
- 2014-10-09 CN CN201410526497.0A patent/CN104311584A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03284734A (en) * | 1990-03-31 | 1991-12-16 | Toshiba Corp | Organic nonlinear optical material |
| CN102053449A (en) * | 2009-10-28 | 2011-05-11 | 中国科学院福建物质结构研究所 | Glutamic acid-derived chiral metal-organic nonlinear optical material |
| CN101798319A (en) * | 2009-12-10 | 2010-08-11 | 郑州轻工业学院 | 2, 3, 4, 5-tetrahydrofuran tetracarboxylic acid and 3-(2-pyridyl) pyrazol-mixed cadmium composition, as well as preparation method and application thereof |
| CN102532173A (en) * | 2011-12-09 | 2012-07-04 | 天津工业大学 | Pyrazole diacid-bridged lutecium complex and preparation method thereof |
| CN102644118A (en) * | 2012-04-27 | 2012-08-22 | 中国科学院福建物质结构研究所 | Benzene three acid calcium cadmium dissimilar metal complexes and synthesis and application thereof |
Non-Patent Citations (4)
| Title |
|---|
| LONG PAN,ET AL.: "A Reversible Structural Interconversion Involving [M(H2pdc)2(H2O)2]•2H2O (M＝Mn, Fe, Co, Ni, Zn, H3pdc＝3,5-pyrazoledicarboxylic acid) and the Role of A Reactive Intermediate [Co(H2pdc)2]", 《CHEM. EUR. J.》 * |
| LONG PAN,ET AL.: "A Reversible Structural Interconversion Involving [M(H2pdc)2(H2O)2]•2H2O (M＝Mn, Fe, Co, Ni, Zn, H3pdc＝3,5-pyrazoledicarboxylic acid) and the Role of A Reactive Intermediate [Co(H2pdc)2]", 《CHEM. EUR. J.》, vol. 7, 5 October 2001 (2001-10-05), pages 4431 - 4437 * |
| LONG PAN,ET AL.: "Assembly of New Coordination Frameworks in a pH-Controlled Medium: Syntheses, Structures, and Properties of 3∞[Cd(Hpdc)(H2O)] and 3∞[Cd3(pdc)2(H2O)2]", 《JOURNAL OF SOLID STATE CHEMISTRY》 * |
| PASCAL ROUSSEL，ET AL.: "Thermal evolution and crystal structures of the 3,5-pyrazole dicarboxylic acid (hydrated form and anhydrous): Ligations with nickel II and barium II", 《JOURNAL OF MOLECULAR STRUCTURE》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105820347A (en) * | 2016-04-28 | 2016-08-03 | 河南大学 | Three-dimensional coordination polymer nonlinear optical material and preparation method thereof |
| CN105820347B (en) * | 2016-04-28 | 2018-11-23 | 河南大学 | A kind of three-dimensional coordination polymer nonlinear optical material and preparation method thereof |
| CN106319623A (en) * | 2016-09-18 | 2017-01-11 | 济南大学 | Silver iodine based hybrid second-order nonlinear optical material and synthesis and application thereof |
| CN106432325A (en) * | 2016-09-22 | 2017-02-22 | 济南大学 | Yellow photoluminescence nonlinear optical crystal material and preparation and application thereof |
| CN106432325B (en) * | 2016-09-22 | 2019-01-04 | 济南大学 | A kind of non-linear optical crystal material of yellow photoluminescence and its preparation and application |
| CN111518282A (en) * | 2020-06-24 | 2020-08-11 | 江苏理工学院 | Hydroxypyrazole cadmium carboxylate coordination polymer for visible light catalytic degradation of organic dye and preparation and application thereof |
| CN111518282B (en) * | 2020-06-24 | 2022-03-04 | 江苏理工学院 | Hydroxypyrazole cadmium carboxylate coordination polymer for visible light catalytic degradation of organic dye and preparation and application thereof |
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Application publication date: 20150128 |