CN104310723A - High-salinity wastewater resourceful treatment method - Google Patents
High-salinity wastewater resourceful treatment method Download PDFInfo
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- CN104310723A CN104310723A CN201410659045.XA CN201410659045A CN104310723A CN 104310723 A CN104310723 A CN 104310723A CN 201410659045 A CN201410659045 A CN 201410659045A CN 104310723 A CN104310723 A CN 104310723A
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Abstract
The invention discloses a high-salinity wastewater resourceful treatment method. After the water quality is adjusted through an adjusting tank, suspended matter in high-salinity wastewater is partially removed by being filtered through quartz sand and activated carbon, salt in the wastewater is removed through an electrodialyzer, the total salt content in the wastewater is reduced below the highest limiting value of the total salt content in inflow water of constructed wetland, the wastewater passes through the constructed wetland, the COD, the BOD, the total nitrogen, the total phosphorus, the suspended matter, the organic matter and the total salt of the wastewater are reduced so that the quality of the wastewater can be comprehensively improved, the final effluent quality meets the standards of farmland irrigation water or the standards of industrial reuse water, the purpose of resource utilization is achieved, and particularly, the construction cost and the maintenance cost of facilities for wastewater treatment are greatly reduced.
Description
Technical field
The present invention relates to technical field of waste water processing, specifically a kind of Resourceful treatment method for high-salinity wastewater.
Background technology
High-salt wastewater is a hang-up of water treatment field always, and simultaneously also containing in organic situation, common water treatment method cannot reach treatment effect especially.Generally, common process many employings biochemical treatment of wastewater treatment, traditional biochemical processing method cannot reach processing requirements for high concentration hard-degraded organic waste water, this mainly because, hardly degraded organic substance is more difficult realization for the oxidizing reaction of microorganism, its stable benzene ring structure, backbone, or there is more functional group, all hinder the oxidising process of microorganism, if containing higher salinity in waste water, so unaffordable especially for microorganism, salinity in waste water can anti-bacteria consumingly, the Growth and reproduction condition of bacterium cannot be reached, finally cause the collapse of biochemical treatment system.And adopting anaerobic biological technique, the organic waste water for process high-concentration hardly-degradable can not have good hydrolytic action, if when salinity is higher, methanogen cannot normal growth, and anaerobic reaction is also a greater impact.Therefore, the organic wastewater with difficult degradation thereby for high density high salinity is difficult to adopt biochemical processing process.
Time biochemical method cannot carry out, physics and chemistry technology is seeming especially applicable.For the organic waste water of high density high salinity, the technology of current internal and international employing mostly is method of evaporation, reverse osmosis membrane filtration method, advanced oxidation processes, extraction process etc.Method of evaporation, mainly by reducing the means such as saturated vapor pressure, heating, realizing the concentrated of Pollutants in Wastewater and being separated, in engineer applied, often occur scale problems; Osmosis filtration method overcomes osmotic pressure by increasing pressure at one section of organic membrane, realizes water and organism, being separated of salt, the problem often occurring fouling membrane He scrap in engineering; Extraction is separation and the enrichment that the dissolubility difference utilizing solute in different solvents carries out pollutent equally, the case of extraction process domestic application is less, mainly because the water yield of waste water is larger, extraction agent costly simultaneously, and the requirement of engineering to reaction conditions is higher, although these methods can make the separated from contaminants in waste water, water quality is purified, but pollutent itself is change not, after concentrated, be still difficult to process, form secondary pollution.
Summary of the invention
The object of the present invention is to provide a kind of Resourceful treatment method for high-salinity wastewater, make effluent quality reach field irrigation water quality standard or industrial reuse water quality standard, realize recycling.
For achieving the above object, the invention provides following technical scheme:
A kind of Resourceful treatment method for high-salinity wastewater, by removing a part of suspended substance through quartz sand, activated carbon filtration after equalizing tank regulating water quality, then by electrodialyzer desalination, below the most ceiling value total salt content of waste water being dropped to artificial swamp water inlet total salt content, reduce COD, the BOD of waste water, total nitrogen, total phosphorus, suspended substance, organism and total salt through artificial swamp again, make effluent quality reach field irrigation water quality standard or industrial reuse water quality standard.
As the further scheme of the present invention: the most ceiling value of described artificial swamp water inlet total salt content is 1.5-2%.
Compared with prior art, the invention has the beneficial effects as follows: by equalizing tank, quartz sand filtration, activated carbon filtration, electrodialysis, artificial swamp, high-salt wastewater is processed, effectively reduce the COD of waste water, BOD, total nitrogen, total phosphorus, suspended substance, organism and total salt, make effluent quality reach field irrigation water quality standard or industrial reuse water quality standard, achieve the object of recycling; Especially facility cost and the carrying cost of wastewater treatment is also greatly reduced.
Accompanying drawing explanation
Fig. 1 is the FB(flow block) of Resourceful treatment method for high-salinity wastewater.
Embodiment
Below in conjunction with the embodiment of the present invention and accompanying drawing, be clearly and completely described the technical scheme in the embodiment of the present invention, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
Refer to Fig. 1, in the embodiment of the present invention, a kind of Resourceful treatment method for high-salinity wastewater, by removing a part of suspended substance through quartz sand, activated carbon filtration after equalizing tank regulating water quality, then by electrodialyzer desalination, below the most ceiling value total salt content of waste water being dropped to artificial swamp water inlet total salt content, reduce COD, the BOD of waste water, total nitrogen, total phosphorus, suspended substance, organism and total salt through artificial swamp again, make effluent quality reach field irrigation water quality standard or industrial reuse water quality standard.
Embodiment 1
According to the feature of industrial park, Tuoketuo County high-salt wastewater, in Togtoh associating water utilities company limited, on-site has built 200m
2medium-sized facility, comprise tank, equalizing tank, quartz filter, activated charcoal filter, electrodialyzer, artificial swamp and millpond, the effect of each facility is as follows:
Tank: for hoarding waste water, avoids in waste water unprocessed just inflow living environment.
Equalizing tank: waste water is precipitated, dosing, mixing, neutralization, play the regulating effect of the water yield and water quality being carried out to pH, preaeration.
Strainer: strainer is indispensable a kind of device on delivery medium pipeline, plays while removing a part of impurity and larger molecular organics and plays again the effect preventing electrodialysis from blocking.
Electrodialyzer: utilize the selective penetrated property of semi-permeable membranes to be called electrodialysis to the method being separated different ions under electric field action.It is extensively used to seawater and brackish water desalination; Elementary desalination when preparing pure water and boiler, power-equipment are to fields such as water demineralizing are softening.But it to the removal of organism and nitrogen phosphorus without any effect.
Artificial swamp: the principle of artificial swamp waste water disposal facility is by manually building and controlling to run the ground similar with swampland, by waste water controlledly dosing on wetland, make waste water in wetland soil gap and the surperficial process flowed in a certain direction, utilize soil, artificial dielectric, plant, the physics of microorganism, chemistry, biological triple synergy, to a kind of technology that waste water processes.The mechanism of action of its ecosystem comprises absorption, delay, filtration, precipitation, microbial decomposition, conversion, redox, plant are covered, other effects etc. of residue accumulated, water transpiration and nutrition absorption and all kinds of animal.The pollutent that artificial swamp is removed is in extensive range, comprises N, P, S, organism, pathogenic agent etc.Under the condition that influent concentration is lower, the clearance of artificial swamp to biochemical oxygen demand (BOD) (Biochemical Oxygen Demand, BOD) can reach 60% ~ 85%, and the clearance of chemical oxygen demand (COD) (Chemical Oxygen Demand, COD) can reach more than 60%.
Millpond: after a series for the treatment of process, flow into millpond by artificial swamp, the water quality in millpond reaches discharge standard, directly can be used as farmland irrigating water or industrial reuse water.
Described Resourceful treatment method for high-salinity wastewater, comprises the steps:
(1) regulating water quality: waste water is introduced in equalizing tank by tank, by equalizing tank, waste water is precipitated, dosing, mixing, neutralization, play the regulating effect of the water yield and water quality being carried out to pH, preaeration;
(2) filter: comprise quartz sand filtration and activated carbon filtration, a part of impurity and larger molecular organics can be removed, can prevent again electrodialysis from blocking;
(3) electrodialysis: utilize the selective penetrated property of semi-permeable membranes to be separated different ions under electric field action, thus desalination, below the most ceiling value total salt content of waste water being dropped to artificial swamp water inlet total salt content;
(4) artificial wetland treatment: by waste water dosing on wetland, make waste water in wetland soil gap and the surperficial process flowed in a certain direction, utilize soil, artificial dielectric, plant, the physics of microorganism, chemistry, biological triple synergy, waste water is processed, the COD of waste water, BOD, total nitrogen, total phosphorus, suspended substance, organism and total salt etc. are improved comprehensively, and effluent quality reaches field irrigation water quality standard or industrial reuse water quality standard;
(5) after artificial wetland treatment, after the water quality for the treatment of and purification is sent into millpond, to be used.
Result shows: wastewater treatment cost of the present invention is well below traditional treatment process, and particularly, construction cost of the present invention is lower than 30% of waste water treatment plant, and standing charges of the present invention are also less than 20% of waste water treatment plant.
The present invention is processed high-salt wastewater by equalizing tank, quartz sand filtration, activated carbon filtration, electrodialysis, artificial swamp, effectively reduce the COD of waste water, BOD, total nitrogen, total phosphorus, suspended substance, organism and total salt, make effluent quality reach field irrigation water quality standard or industrial reuse water quality standard, achieve the object of recycling; Especially facility cost and the carrying cost of wastewater treatment is also greatly reduced.
To those skilled in the art, obviously the invention is not restricted to the details of above-mentioned one exemplary embodiment, and when not deviating from spirit of the present invention or essential characteristic, the present invention can be realized in other specific forms.Therefore, no matter from which point, all should embodiment be regarded as exemplary, and be nonrestrictive, scope of the present invention is limited by claims instead of above-mentioned explanation, and all changes be therefore intended in the implication of the equivalency by dropping on claim and scope are included in the present invention.
In addition, be to be understood that, although this specification sheets is described according to embodiment, but not each embodiment only comprises an independently technical scheme, this narrating mode of specification sheets is only for clarity sake, those skilled in the art should by specification sheets integrally, and the technical scheme in each embodiment also through appropriately combined, can form other embodiments that it will be appreciated by those skilled in the art that.
Claims (2)
1. a Resourceful treatment method for high-salinity wastewater, it is characterized in that, by removing a part of suspended substance through quartz sand, activated carbon filtration after equalizing tank regulating water quality, then by electrodialyzer desalination, below the most ceiling value total salt content of waste water being dropped to artificial swamp water inlet total salt content, reduce COD, the BOD of waste water, total nitrogen, total phosphorus, suspended substance, organism and total salt through artificial swamp again, make effluent quality reach field irrigation water quality standard or industrial reuse water quality standard.
2. Resourceful treatment method for high-salinity wastewater according to claim 1, is characterized in that, the most ceiling value of described artificial swamp water inlet total salt content is 1.5-2%.
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CN107162649A (en) * | 2017-05-27 | 2017-09-15 | 遵义盛林农业发展有限公司 | A kind of blueberry plantation irrigation water and its compound method |
CN108455795A (en) * | 2018-03-15 | 2018-08-28 | 金河生物科技股份有限公司 | A kind of fermentation regenerated water desalination method |
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