CN104310644A - Treatment method of cutting fluid wastewater - Google Patents

Treatment method of cutting fluid wastewater Download PDF

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Publication number
CN104310644A
CN104310644A CN201410569606.7A CN201410569606A CN104310644A CN 104310644 A CN104310644 A CN 104310644A CN 201410569606 A CN201410569606 A CN 201410569606A CN 104310644 A CN104310644 A CN 104310644A
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CN
China
Prior art keywords
cutting liquid
treatment
liquid wastewater
time
treatment process
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410569606.7A
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Chinese (zh)
Inventor
邵建军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Baoma Numerical Control Equipment Co Ltd
Original Assignee
Suzhou Baoma Numerical Control Equipment Co Ltd
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Filing date
Publication date
Application filed by Suzhou Baoma Numerical Control Equipment Co Ltd filed Critical Suzhou Baoma Numerical Control Equipment Co Ltd
Priority to CN201410569606.7A priority Critical patent/CN104310644A/en
Publication of CN104310644A publication Critical patent/CN104310644A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • C02F1/5245Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/722Oxidation by peroxides
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/725Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/02Specific form of oxidant
    • C02F2305/026Fenton's reagent
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/10Photocatalysts

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

The invention provides a treatment method of cutting fluid wastewater. The treatment method comprises the following steps: a) demulsification treatment; b) coagulation treatment; and c) photo-catalytic oxidation treatment. The invention discloses the treatment method of cutting fluid wastewater. The treatment method is simple to operate, low in treatment cost and good in separating effect. The COD (chemical oxygen demand) removal rate can reach 99% and the treatment method has a relatively good promotional and application values.

Description

A kind for the treatment of process of Cutting Liquid Wastewater
Technical field
The present invention relates to a kind of cutting fluid, particularly relate to a kind for the treatment of process of Cutting Liquid Wastewater, belong to cutting fluid technical field.
Background technology
Cutting fluid is that one is used in metal cutting, the mill course of processing, is used for the industrial type fluid of Cooling and Lubricator cutter and workpiece, and it is formed through science compound compatibility by several functions auxiliary agent.As a kind of important complementary supplementary material of metal cutting process, metal working fluid can extend the work-ing life of cutter and grinding tool, improves the smooth finish of workpiece, reduces cutting, grinding force, and its Main Function comprises cooling, lubrication, antirust and cleaning four aspects.Cutting fluid mainly oil base and water base two classes of general use, in recent years, water-base cutting fluid has outstanding feature and is able to apply more and more widely in cooling, cleaning, rust-preventing characteristic, oilness etc., and water-base cutting fluid can be divided into micro-emulsion type, oil-in-water type and complete synthesis type.Along with the requirement of harsh new complete processing and novel material in mechanized equipment manufacture, add continually developing of new type water-solubility additive, water-base cutting fluid is developed rapidly.
At present, there is a relatively more outstanding environmental problem in the application of cutting fluid, due to cutting fluid recycle after can go bad, lost efficacy, become Cutting Liquid Wastewater, and the emulsification degree of Cutting Liquid Wastewater is high, stable chemical nature, biodegradability are poor.The organic waste water of this high density, difficult degradation, once wantonly be discharged, will cause great pollution to environment, therefore need carry out necessary process to Cutting Liquid Wastewater, realize the zero release of waste water.In current art, chemical method, electrolytic process, ultrafiltration process etc. are mainly contained to the treatment process of Cutting Liquid Wastewater.Chemical method has less investment, easy-operating advantage, but treatment effect is not fine; Though electrolytic process, ultrafiltration process can realize good treatment effect, the investment of its required equipment is comparatively large, and cost is very high, and application is subject to certain restrictions.
Summary of the invention
For the demand, the invention provides a kind for the treatment of process of Cutting Liquid Wastewater, this treatment process be simple to operate, processing cost is low, good separating effect, its COD clearance can reach 99%, has good application value.
The present invention is a kind for the treatment of process of Cutting Liquid Wastewater, and described treatment process comprises the steps: a) breakdown of emulsion process, b) coagulating treatment, c) Treatment by Photocatalysis Oxidation.
In a preferred embodiment of the present invention, in described step a), breakdown of emulsion process comprises the steps: 1) hydrochloric acid to be added adjust ph in Cutting Liquid Wastewater be 3; 2) emulsion splitter nitric acid is added in Cutting Liquid Wastewater and carry out breakdown of emulsion process by the demulsification technology condition of setting.
In a preferred embodiment of the present invention, described demulsification technology condition is: stirring velocity 120r/min, churning time 2min for the first time; Second time stirring velocity 30r/min, churning time 5min; Time of repose 2h.
In a preferred embodiment of the present invention, in described step b), coagulating treatment comprises the steps: 1) calcium hydroxide is added breakdown of emulsion process after used cutting liquid in adjust ph be 7.5; 2) composite flocculation agent is added in used cutting liquid and carry out coagulating treatment by the coagulation process condition of setting.
In a preferred embodiment of the present invention, described composite flocculation agent by bodied ferric sulfate and polyacrylamide in mass ratio 60:1 mix, its add-on is 1500mg/L.
In a preferred embodiment of the present invention, described coagulation process condition is: stirring velocity 120r/min, churning time 2min for the first time; Second time stirring velocity 30r/min, churning time 5min; Time of repose 2h.
In a preferred embodiment of the present invention, in described step c), Treatment by Photocatalysis Oxidation comprises the steps: 1) hydrochloric acid to be added adjust ph in the used cutting liquid after coagulating treatment be 3; 2) hydrogen peroxide, iron vitriol are added in used cutting liquid carry out Treatment by Photocatalysis Oxidation by the photochemical catalytic oxidation processing condition of setting.
In a preferred embodiment of the present invention, described hydrogen peroxide add-on is 60mg/L, and iron vitriol add-on is 700mg/L.
In a preferred embodiment of the present invention, described photochemical catalytic oxidation processing condition are: ultraviolet light irradiation degree 50uW/cm 2, ultraviolet lighting time 7h.
Present invention is disclosed a kind for the treatment of process of Cutting Liquid Wastewater, this treatment process be simple to operate, processing cost is low, good separating effect, its COD clearance can reach 99%, has good application value.
Accompanying drawing explanation
Below in conjunction with the drawings and specific embodiments, the present invention is further detailed explanation:
Fig. 1 is the process figure of embodiment of the present invention cutting fluid waste water treatment method.
Embodiment
Below in conjunction with accompanying drawing, preferred embodiment of the present invention is described in detail, can be easier to make advantages and features of the invention be readily appreciated by one skilled in the art, thus more explicit defining is made to protection scope of the present invention.
Fig. 1 is the process figure of embodiment of the present invention cutting fluid waste water treatment method; This treatment process comprises the steps: a) breakdown of emulsion process, b) coagulating treatment, c) Treatment by Photocatalysis Oxidation.
Embodiment
Concrete treatment process is as follows:
A) breakdown of emulsion process, concrete treating processes is: by 1L Cutting Liquid Wastewater, first Cutting Liquid Wastewater is put into stirred vessel, then appropriate hydrochloric acid is added in 1L Cutting Liquid Wastewater, and adjust ph is 3; Then in Cutting Liquid Wastewater, add 30ml emulsion splitter nitric acid, first stir 2min with the rotating speed of 120r/min, then stir 5min with the rotating speed of 30r/min; Finally leave standstill 2h, obtain the used cutting liquid after breakdown of emulsion process.
B) coagulating treatment, concrete treating processes is: by the used cutting liquid after the process of 1L breakdown of emulsion, first the used cutting liquid after breakdown of emulsion process is put into stirred vessel, then adds in 1L used cutting liquid by appropriate calcium hydroxide, and adjust ph is 7.5; Then in 1L used cutting liquid, add 1500mg composite flocculation agent, first stir 2min with the rotating speed of 120r/min, then stir 5min with the rotating speed of 30r/min, wherein, composite flocculation agent by bodied ferric sulfate and polyacrylamide in mass ratio 60:1 mix; Finally leave standstill 2h, obtain the used cutting liquid after coagulating treatment.
C) Treatment by Photocatalysis Oxidation, concrete treating processes is: by the used cutting liquid after 1L coagulating treatment, first used cutting liquid is put into reaction vessel, then appropriate hydrochloric acid is added in 1L Cutting Liquid Wastewater, and adjust ph is 3; Then in 1L used cutting liquid, 24mg hydrogen peroxide is added, 700mg iron vitriol, at ultraviolet light irradiation degree 50uW/cm 2uV-irradiation oxidizing reaction is carried out under condition, in reactor, 12 mg hydrogen peroxide are added after question response 1h, in reactor, 12 mg hydrogen peroxide are added after question response 2h, in reactor, 12 mg hydrogen peroxide are added after question response 3h, can oxidizing reaction be terminated after question response 7h, reach optimal light catalytic oxidation effect.Through practical measurement, this Cutting Liquid Wastewater is after breakdown of emulsion, coagulation and Treatment by Photocatalysis Oxidation, and its COD clearance can reach 99%, meets growth requirement and the environmental requirement of manufacturing enterprise completely.
Present invention is disclosed a kind for the treatment of process of Cutting Liquid Wastewater, this treatment process be simple to operate, processing cost is low, good separating effect, its COD clearance can reach 99%, has good application value.
The above; be only the specific embodiment of the present invention; but protection scope of the present invention is not limited thereto; any those of ordinary skill in the art are in the technical scope disclosed by the present invention; the change can expected without creative work or replacement, all should be encompassed within protection scope of the present invention.Therefore, the protection domain that protection scope of the present invention should limit with claims is as the criterion.

Claims (9)

1. a treatment process for Cutting Liquid Wastewater, is characterized in that, described treatment process comprises the steps: a) breakdown of emulsion process, b) coagulating treatment, c) Treatment by Photocatalysis Oxidation.
2. the treatment process of Cutting Liquid Wastewater according to claim 1, is characterized in that, in described step a), breakdown of emulsion process comprises the steps: 1) hydrochloric acid to be added adjust ph in Cutting Liquid Wastewater be 3; 2) emulsion splitter nitric acid is added in Cutting Liquid Wastewater and carry out breakdown of emulsion process by the demulsification technology condition of setting.
3. the treatment process of Cutting Liquid Wastewater according to claim 2, is characterized in that, described demulsification technology condition is: stirring velocity 120r/min, churning time 2min for the first time; Second time stirring velocity 30r/min, churning time 5min; Time of repose 2h.
4. the treatment process of Cutting Liquid Wastewater according to claim 1, is characterized in that, in described step b), coagulating treatment comprises the steps: 1) calcium hydroxide is added breakdown of emulsion process after used cutting liquid in adjust ph be 7.5; 2) composite flocculation agent is added in used cutting liquid and carry out coagulating treatment by the coagulation process condition of setting.
5. the treatment process of Cutting Liquid Wastewater according to claim 4, is characterized in that, described composite flocculation agent by bodied ferric sulfate and polyacrylamide in mass ratio 60:1 mix, its add-on is 1500mg/L.
6. the treatment process of Cutting Liquid Wastewater according to claim 4, is characterized in that, described coagulation process condition is: stirring velocity 120r/min, churning time 2min for the first time; Second time stirring velocity 30r/min, churning time 5min; Time of repose 2h.
7. the treatment process of Cutting Liquid Wastewater according to claim 1, is characterized in that, in described step c), Treatment by Photocatalysis Oxidation comprises the steps: 1) hydrochloric acid to be added adjust ph in the used cutting liquid after coagulating treatment be 3; 2) hydrogen peroxide, iron vitriol are added in used cutting liquid carry out Treatment by Photocatalysis Oxidation by the photochemical catalytic oxidation processing condition of setting.
8. the treatment process of Cutting Liquid Wastewater according to claim 7, is characterized in that, described hydrogen peroxide add-on is 60mg/L, and iron vitriol add-on is 700mg/L.
9. the treatment process of Cutting Liquid Wastewater according to claim 7, is characterized in that, described photochemical catalytic oxidation processing condition are: ultraviolet light irradiation degree 50uW/cm 2, ultraviolet lighting time 7h.
CN201410569606.7A 2014-10-23 2014-10-23 Treatment method of cutting fluid wastewater Pending CN104310644A (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104944631A (en) * 2015-06-03 2015-09-30 安徽新天环保科技有限公司 Pretreatment method of high-concentration cutting fluid sewage
CN105439327A (en) * 2015-12-30 2016-03-30 北京清大国华环境股份有限公司 Method and device for demulsifying multiple mixed waste emulsions
CN105923861A (en) * 2016-05-10 2016-09-07 上海电力学院 Method for efficiently treating alkaline washing wastewater
CN107619141A (en) * 2017-11-10 2018-01-23 徐州华瑞机械锻造有限公司 A kind of processing method of used cutting liquid
CN108675490A (en) * 2018-05-16 2018-10-19 孟静 A kind of industrial wastewater catalytic reactor
CN108689536A (en) * 2018-07-17 2018-10-23 苏州方舟环保科技有限公司 A kind of emulsion low-pressure treatment device
CN110540341A (en) * 2019-08-29 2019-12-06 四川拓璞环保科技有限公司 waste cutting emulsion wastewater treatment system and method
CN112960838A (en) * 2021-04-06 2021-06-15 江苏科技大学 Reduction treatment system and treatment method for machining emulsified waste liquid

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CN101792239A (en) * 2010-03-31 2010-08-04 成都蜀光石油化学有限公司 Method for treatment of waste emulsion
CN102391910A (en) * 2011-10-09 2012-03-28 东莞市威迪膜科技有限公司 System and method for recycling waste emulsified cutting fluid

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CN101486515A (en) * 2009-02-17 2009-07-22 宜兴市芳惠子环保设备厂 Oily wastewater treatment method and whole set apparatus thereof
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104944631A (en) * 2015-06-03 2015-09-30 安徽新天环保科技有限公司 Pretreatment method of high-concentration cutting fluid sewage
CN105439327A (en) * 2015-12-30 2016-03-30 北京清大国华环境股份有限公司 Method and device for demulsifying multiple mixed waste emulsions
CN105923861A (en) * 2016-05-10 2016-09-07 上海电力学院 Method for efficiently treating alkaline washing wastewater
CN107619141A (en) * 2017-11-10 2018-01-23 徐州华瑞机械锻造有限公司 A kind of processing method of used cutting liquid
CN108675490A (en) * 2018-05-16 2018-10-19 孟静 A kind of industrial wastewater catalytic reactor
CN108675490B (en) * 2018-05-16 2021-04-13 中节能环保投资发展(江西)有限公司 Industrial wastewater catalytic reactor
CN108689536A (en) * 2018-07-17 2018-10-23 苏州方舟环保科技有限公司 A kind of emulsion low-pressure treatment device
CN110540341A (en) * 2019-08-29 2019-12-06 四川拓璞环保科技有限公司 waste cutting emulsion wastewater treatment system and method
CN112960838A (en) * 2021-04-06 2021-06-15 江苏科技大学 Reduction treatment system and treatment method for machining emulsified waste liquid

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Application publication date: 20150128