CN104310400A - Boron carbide neutron absorber - Google Patents

Boron carbide neutron absorber Download PDF

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Publication number
CN104310400A
CN104310400A CN201410525417.XA CN201410525417A CN104310400A CN 104310400 A CN104310400 A CN 104310400A CN 201410525417 A CN201410525417 A CN 201410525417A CN 104310400 A CN104310400 A CN 104310400A
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boron carbide
norbide
neutron absorber
neutron
colloid
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CN201410525417.XA
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CN104310400B (en
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邹建军
孙振忠
何伦华
康乐
陈洁
卢怀乐
许楚滨
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CHEN Jie
He Lunhua
Kang Le
LU HUAILE
Sun Zhenzhong
XU CHUBIN
Zou Jianjun
Institute of High Energy Physics of CAS
Dongguan University of Technology
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Dongguan University of Technology
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Abstract

The invention relates to a neutron absorber for absorbing stray neutrons, in particular to a boron carbide absorber which is prepared by raw materials with low cost and wide sources, does not influence the detection of a detector and is used for absorbing stray neutrons in a radial neutron collimator. The raw materials of the boron carbide neutron absorber mainly comprise boron carbide powder, colloid and a curing agent, wherein the content ratio of the colloid to the curing agent is 5 to 2, and the content ratio of the colloid to the boron carbide powder is 1 to (19-4). The boron carbide neutron absorber has easily-available raw materials, can solve the problem that the neutron absorption is influenced by hydrogen element due to the formula, has low cost, overcomes the defects that the used boron carbide ceramic material at the present stage is expensive and is difficult to obtain, can achieve the effect equal to or better than that of the boron carbide ceramic material, can be widely applied and can obtain long-term economic benefit.

Description

A kind of norbide neutron absorber
Technical field
The present invention relates to a kind of neutron absorber for absorbing stray neutron, the cartridge that espespecially a kind of, originate wide raw material low by cost is made also realizes not affecting the detection of detector and in radial neutron howitzer, absorbing a kind of norbide neutron absorber of stray neutron target.
Background technology
Neutron and X-ray are all the powerful measure that the mankind explore material microstructure, neutron is not charged, there is magnetic moment, penetrance is strong, light element can be differentiated, isotropic substance and neighbour's element, and have the nondestructive feature to sample, therefore neutron not only can explore the static microtexture of material, its kinetic mechanism can also be studied, at present, Neutron scattering technology is at biology, life, the research fields such as medicine play the effect that X-ray cannot replace, Neutron scattering technology carries out in neutron spectrometer, for the raising of the performance perameters such as the normal operation of neutron spectrometer and the resolving power of spectrometer, neutron howitzer as one of its key part plays an important role.
One of Main Function of radial neutron howitzer is exactly the loss of the neutron being reduced by collimator internal cavity, and the method realizing this effect vacuumizes or pass in cavity certain atmosphere surrounding (helium or argon gas) at cavity; Its another main method utilizes the neutron absorber be attached on collimator inwall to absorb background neutron, therefore to ensure that the vacuum deformation of cavity can't impact the attachment of neutron absorber, and inserted sheet can not be caused to depart from physical plane, stop effective neutron.
Conventional neutron absorber material comprises boron, gadolinium and cadmium etc., because the position sensitive detector of majority is more weak for the separating capacity of neutron and gamma ray, the nuclear reaction of neutron and gadolinium element is mainly n-gamma reaction, absorb neutron and release gamma ray, be unfavorable for the neutron detection of back-end location sensitive detector, and the nuclear reaction of neutron and boron is mainly n-alpha reaction, a lot of unfavorable factors can't be brought to the detection of detector, boron carbide material therefore can be selected as the neutron absorber material of radial neutron howitzer.
Conventional neutron absorber has boron carbide ceramics plate, norbide-aluminum composite plate, boron carbide powder colloid mixture is cold-pressed into template and boron carbide powder painting mode etc., but, boron carbide powder colloid mixture is cold-pressed into template and contains more epoxies colloid, form containing more hydrogen and oxygen element, cause spuious scattering; The mode of boron carbide powder painting needs to introduce epoxies colloid equally, and thickness is restricted, and easily loses efficacy by irradiation; Aluminium base boron carbide composite material, boron carbide ceramics material Weldability are still to be tested, the norbide content simultaneously adulterated is few, same restricted in thickness requirement, and present stage such material price costly, and the neutron absorber that fully can absorb stray neutron in collimator inside of the batch production that generally needs from external import, therefore need a kind of price appropriateness, is convenient to.
Summary of the invention
For solving the problem, the present invention is intended to openly a kind of neutron absorber for absorbing stray neutron, and the cartridge that espespecially a kind of, originate wide raw material low by cost is made also realizes not affecting the detection of detector and in radial neutron howitzer, absorbing a kind of norbide neutron absorber of stray neutron target.
For achieving the above object, the technical solution used in the present invention is: a kind of norbide neutron absorber, the raw material of described norbide neutron absorber mainly comprises boron carbide powder, colloid and solidifying agent, described colloid and the content ratio of solidifying agent are 5:2, and the ratio range of colloidal content and boron carbide powder content is 1:19-1:4.
Described norbide neutron absorber mainly comprises 70-85 part boron carbide powder, 4.5-17.5 part colloid and 1.8-7 part solidifying agent.
Have coarse grain powder in described boron carbide powder, the size range of coarse grain powder is 450-500 μm.
Have particulate powders in described boron carbide powder, the size range of particulate powders is 60-120 μm.
Described boron carbide powder to be mixed with the particulate powders of 15%-22% content by the coarse grain powder of 78%-85% content and forms.
Described norbide neutron absorber can casting be square, or be spherical shape.
Prepare a kind of norbide neutron absorber, the content ratio of described boron carbide powder, colloid and solidifying agent is 45:5:2, and the content ratio that is thick, particulate powders wherein in boron carbide powder is 4:1.
Norbide neutron absorber described in preparation comprises 81 parts of boron carbide powders, 9 parts of colloids and 3.6 parts of solidifying agent, and the coarse grain powder wherein in boron carbide powder is 64.8 parts, and particulate powders is 16.2 parts.
Beneficial effect of the present invention is: norbide neutron absorber of the present invention is mainly used in being attached to radial neutron howitzer inwall to absorb stray neutron, its raw material mainly includes boron carbide powder, colloid and solidifying agent, overcome the defect that too much protium affects neutron-absorbing, make can obtain the abundant stop of neutron absorber and absorb during the scattering of neutrons of collimator inside, the present invention selects to adopt 4.5-17.5 part colloid mixing 70-85 part boron carbide powder, both the composition of protium had been controlled, the thickness of norbide neutron absorber can be made again to reach controllability effect, both can reach the object not affecting neutron-absorbing, colloid and boron carbide powder can be made again to stir, again because the collocation of norbide coarse grain powder and norbide particulate powders controls, protium is reduced, form because adopting the coarse grained boron carbide powder of 78%-82% to mix with the fine grain boron carbide powder of 18%-22%, the colloid of boron carbide powder and low levels is made fully to stir rightly, while being conducive to stirring, more can reach effect shaping smoothly.
The raw material of norbide neutron absorber of the present invention easily obtains, the formula adopted solves the problem that protium affects neutron-absorbing, and cost reduces greatly, overcome the boron carbide ceramics material price of present stage use costly, the shortcoming of the more difficult acquisition of raw material, and the norbide neutron absorber of gained of the present invention can reach effect that boron carbide ceramics material can reach or reach better effect, the neutron-absorbing body thickness prepared as boron carbide ceramics material is generally 4mm, and the neutron-absorbing body thickness of formula preparation of the present invention is generally 8mm, but cost of material of the present invention is boron carbide ceramics material 1/10th, therefore the present invention a kind ofly can be mass widespread use and can bring the neutron absorber of long-term economic benefit.
Embodiment
The following detailed description of the specific embodiment of the present invention:
embodiment one
A kind of norbide neutron absorber, the raw material of described norbide neutron absorber mainly comprises boron carbide powder, colloid and solidifying agent, norbide neutron absorber can injection moulding be square or other shapes, the ratio of described colloidal content and boron carbide powder content is 1:9, the ratio of colloidal content and curing agent content is 5:2, described norbide neutron absorber mainly comprises 81 parts of boron carbide powders and 9 parts of colloids, and 3.6 parts of solidifying agent, the unit forming colloid have more hydrogen and oxygen element, too much protium affects neutron-absorbing, cause abundant stop or the absorption that neutron absorber during the scattering of neutrons of collimator inside, cannot be obtained, described boron carbide powder to be mixed with the particulate powders of 20% content by the coarse grain powder of 80% content and forms, comprise 64.8 parts of norbide coarse grain powder and 16.2 parts of norbide particulate powders, the particle of boron carbide powder is thinner, need the colloid for mix and blend more, protium is directly caused to increase, but the particle of boron carbide powder is thicker, the degree stirred with colloid is more weak, thus shaping norbide neutron absorber effect is bad, the grain thickness of boron carbide powder controlled well can decline for making colloid amount, protium reduces, the size range of the coarse grain powder in described boron carbide powder is 500 μm, the size range of particulate powders is 100 μm, when preparing norbide neutron absorber, cartridge is prepared by described composition ratio, and control shaping absorbed thickness as required, if thickness can be 8mm, colloid can select epoxy resin E51 type or epoxy resin E44 type or other colloids, described colloid and norbide thick, the content of particulate powders had both controlled the composition of protium, the molding thickness of norbide neutron absorber can be made again to reach required effect, make the effect that can reach efficient absorption neutron in neutron howitzer inside, the colloidal content of appropriateness both can reach the object not affecting neutron-absorbing, colloid and boron carbide powder can be made again to stir, reach effect shaping smoothly.
embodiment two
A kind of norbide neutron absorber, the raw material of described norbide neutron absorber mainly comprises boron carbide powder, colloid and solidifying agent, norbide neutron absorber can be square or other shapes, the ratio of described colloidal content and boron carbide powder content is 1:4, the ratio of colloidal content and curing agent content is 5:2, described norbide neutron absorber mainly comprises 70 parts of boron carbide powders and 17.5 parts of colloids, and 7 parts of solidifying agent, the unit forming colloid have more hydrogen and oxygen element, too much protium affects neutron-absorbing, cause abundant stop or the absorption that neutron absorber during the scattering of neutrons of collimator inside, cannot be obtained, described boron carbide powder to be mixed with the particulate powders of 22% content by the coarse grain powder of 78% content and forms, comprise 54.6 parts of norbide coarse grain powder and 15.4 parts of norbide particulate powders, the particle of boron carbide powder is thinner, need the colloid for mix and blend more, protium is directly caused to increase, but the particle of boron carbide powder is thicker, the degree stirred with colloid is more weak, thus shaping norbide neutron absorber effect is bad, the grain thickness of boron carbide powder controlled well can decline for making colloid amount, protium reduces, the size range of the coarse grain powder in described boron carbide powder is 480 μm, the size range of particulate powders is 100 μm, when preparing norbide neutron absorber, cartridge is prepared by described composition ratio, and control shaping absorbed thickness as required, if thickness can be 8mm, colloid can select epoxy resin E51 type or epoxy resin E44 type or other colloids, described colloid and norbide thick, the content of particulate powders had both controlled the composition of protium, the molding thickness of norbide neutron absorber can be made again to reach required effect, make the effect that can reach efficient absorption neutron in neutron howitzer inside, the colloidal content of appropriateness both can reach the object not affecting neutron-absorbing, colloid and boron carbide powder can be made again to stir, reach effect shaping smoothly.
The above, it is only preferred embodiment of the present invention, not technical scope of the present invention is imposed any restrictions, the technician of the industry, under the inspiration of the technical program, some distortion and amendment can be made, every above embodiment is done according to technical spirit of the present invention any amendment, equivalent variations and modification, all still belong in the scope of technical solution of the present invention.

Claims (8)

1. a norbide neutron absorber, it is characterized in that: the raw material of described norbide neutron absorber mainly comprises boron carbide powder, colloid and solidifying agent, described colloid and the content ratio of solidifying agent are 5:2, and the ratio range of colloidal content and boron carbide powder content is 1:19-1:4.
2. a kind of norbide neutron absorber according to claim 1, is characterized in that: described norbide neutron absorber mainly comprises 70-85 part boron carbide powder, 4.5-17.5 part colloid and 1.8-7 part solidifying agent.
3. a kind of norbide neutron absorber according to claim 1, is characterized in that: have coarse grain powder in described boron carbide powder, and the size range of coarse grain powder is 450-500 μm.
4. a kind of norbide neutron absorber according to claim 1, is characterized in that: have particulate powders in described boron carbide powder, and the size range of particulate powders is 60-120 μm.
5. a kind of norbide neutron absorber according to claim 1 or 3 or 4, is characterized in that: described boron carbide powder to be mixed with the particulate powders of 15%-22% content by the coarse grain powder of 78%-85% content and forms.
6. a kind of norbide neutron absorber according to claim 1, is characterized in that: described norbide neutron absorber can casting be square, or be spherical shape.
7. use a kind of norbide neutron absorber described in claim 1 to prepare a kind of norbide neutron absorber, it is characterized in that: the content ratio of described boron carbide powder, colloid and solidifying agent is 45:5:2, the content ratio that is thick, particulate powders wherein in boron carbide powder is 4:1.
8. a kind of norbide neutron absorber according to claim 7, it is characterized in that: the norbide neutron absorber described in preparation comprises 81 parts of boron carbide powders, 9 parts of colloids and 3.6 parts of solidifying agent, and the coarse grain powder wherein in boron carbide powder is 64.8 parts, and particulate powders is 16.2 parts.
CN201410525417.XA 2014-10-09 2014-10-09 A kind of boron carbide neutron absorber Expired - Fee Related CN104310400B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105845191A (en) * 2016-05-06 2016-08-10 东莞中子科学中心 Plug-in shell structure used for neutron collimator
CN108333192A (en) * 2018-01-25 2018-07-27 中国科学院高能物理研究所 A kind of coarse collimator in rear end for neutron scattering
CN108750983A (en) * 2018-06-07 2018-11-06 东莞理工学院 A kind of neutron beam window maintenance platform hanging apparatus and its hanging method to work under the radiation
CN108806818A (en) * 2018-04-17 2018-11-13 东莞理工学院 A kind of four knife diaphragms of adjustable neutron flow

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4198322A (en) * 1977-12-01 1980-04-15 The Carborundum Company One-step curing method for manufacture of neutron absorbing plates
US4213883A (en) * 1977-12-30 1980-07-22 The Carborundum Company Method for manufacture of neutron absorbing articles
CN102214488A (en) * 2011-05-31 2011-10-12 航天材料及工艺研究所 Boron-carbide-containing graphite absorber ball and preparation process thereof
CN102485810A (en) * 2009-11-30 2012-06-06 北京市射线应用研究中心 Dual-component low-temperature curing type putty for mixed nuclear radiation environment

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4198322A (en) * 1977-12-01 1980-04-15 The Carborundum Company One-step curing method for manufacture of neutron absorbing plates
US4213883A (en) * 1977-12-30 1980-07-22 The Carborundum Company Method for manufacture of neutron absorbing articles
CN102485810A (en) * 2009-11-30 2012-06-06 北京市射线应用研究中心 Dual-component low-temperature curing type putty for mixed nuclear radiation environment
CN102214488A (en) * 2011-05-31 2011-10-12 航天材料及工艺研究所 Boron-carbide-containing graphite absorber ball and preparation process thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
柯于斌等: "粘结碳化硼材料中子屏蔽性能及制备工艺研究", 《材料科学与工艺》 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105845191A (en) * 2016-05-06 2016-08-10 东莞中子科学中心 Plug-in shell structure used for neutron collimator
CN108333192A (en) * 2018-01-25 2018-07-27 中国科学院高能物理研究所 A kind of coarse collimator in rear end for neutron scattering
CN108806818A (en) * 2018-04-17 2018-11-13 东莞理工学院 A kind of four knife diaphragms of adjustable neutron flow
CN108750983A (en) * 2018-06-07 2018-11-06 东莞理工学院 A kind of neutron beam window maintenance platform hanging apparatus and its hanging method to work under the radiation
CN108750983B (en) * 2018-06-07 2024-04-26 东莞理工学院 Neutron beam window maintenance platform lifting device working under radiation and lifting method thereof

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