CN104294078B - A kind of preparation technology of anti-oxidant color changed silver alloy - Google Patents
A kind of preparation technology of anti-oxidant color changed silver alloy Download PDFInfo
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- CN104294078B CN104294078B CN201410626726.6A CN201410626726A CN104294078B CN 104294078 B CN104294078 B CN 104294078B CN 201410626726 A CN201410626726 A CN 201410626726A CN 104294078 B CN104294078 B CN 104294078B
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- 229910001316 Ag alloy Inorganic materials 0.000 title claims abstract description 39
- 239000003963 antioxidant agent Substances 0.000 title claims abstract description 9
- 230000003078 antioxidant effect Effects 0.000 title claims abstract description 9
- 235000006708 antioxidants Nutrition 0.000 title claims abstract description 9
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000007788 liquid Substances 0.000 claims abstract description 31
- 229910002058 ternary alloy Inorganic materials 0.000 claims abstract description 26
- 238000003756 stirring Methods 0.000 claims abstract description 19
- 229910000838 Al alloy Inorganic materials 0.000 claims abstract description 18
- 229910052707 ruthenium Inorganic materials 0.000 claims abstract description 18
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 13
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000002844 melting Methods 0.000 claims abstract description 13
- 230000008018 melting Effects 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 13
- 229910052718 tin Inorganic materials 0.000 claims abstract description 13
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 13
- 239000011701 zinc Substances 0.000 claims abstract description 13
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 12
- 239000011572 manganese Substances 0.000 claims abstract description 12
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 12
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract description 12
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052738 indium Inorganic materials 0.000 claims abstract description 11
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 238000001816 cooling Methods 0.000 claims abstract description 7
- 238000009413 insulation Methods 0.000 claims abstract description 7
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052709 silver Inorganic materials 0.000 claims abstract description 5
- 239000004332 silver Substances 0.000 claims abstract description 5
- 238000009617 vacuum fusion Methods 0.000 claims description 6
- 239000002918 waste heat Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims 2
- 229910045601 alloy Inorganic materials 0.000 abstract description 12
- 239000000956 alloy Substances 0.000 abstract description 12
- 238000010438 heat treatment Methods 0.000 abstract description 6
- 230000003647 oxidation Effects 0.000 abstract description 4
- 238000007254 oxidation reaction Methods 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000003064 anti-oxidating effect Effects 0.000 abstract description 2
- 238000005494 tarnishing Methods 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 229910052732 germanium Inorganic materials 0.000 description 4
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 4
- 229910052684 Cerium Inorganic materials 0.000 description 3
- 238000005275 alloying Methods 0.000 description 3
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 238000002845 discoloration Methods 0.000 description 3
- 229910052746 lanthanum Inorganic materials 0.000 description 3
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 3
- 229910052727 yttrium Inorganic materials 0.000 description 3
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 206010015150 Erythema Diseases 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 241001074085 Scophthalmus aquosus Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- ROZSPJBPUVWBHW-UHFFFAOYSA-N [Ru]=O Chemical compound [Ru]=O ROZSPJBPUVWBHW-UHFFFAOYSA-N 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 231100000321 erythema Toxicity 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
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Abstract
The present invention is a kind of preparation technology of anti-oxidant color changed silver alloy, belongs to alloy field. Concrete technology is: 1) get the raw materials ready: 2) by silver, tin and ruthenium respectively in vacuum melting furnace heating and melting make Yin-Xi-ruthenium ternary alloy three-partalloy liquid; 3) get the 10%-20% weight portion of ternary alloy three-partalloy liquid gross mass, the zinc, vanadium, manganese and the indium that in normal pressure, add respectively wherein components by weight percent described above to weigh, mixing and stirring, insulation; 4) by 3) in the intermediate aluminium alloy of step, add to step 2) in remaining ternary alloy three-partalloy liquid final silver alloy liquid, in normal pressure, cooling forming obtains silver alloy piece. Alloy Anti oxidation stain of the present invention is good, and can reduce silver alloy fusing point, not only can put forward heavy alloyed mechanical performance and processing characteristics, can also improve alloy quality hard and corrosion-resistant and oxidation.
Description
Technical field
The present invention is a kind of preparation technology of anti-oxidant color changed silver alloy, belongs to alloy field.
Background technology
Silver is the widest element that distributes in noble metal, is 20 times of gold content. Can improve silver-colored performance and add other alloy elements in silver, as copper can improve silver-colored hardness, reduce fusing point, improve castability etc. Therefore, silver alloy is widely used in jewellery industry, silverware, photograph, electric and electronic, plating and health care industry, in new and high technology, also gets more and more applications. Use easy generation sulphide discoloration and produce oxidation erythema but silver alloy is long-term, affecting attractive in appearance and use. And in world wide, all carried out the research work of anti-tarnishing silver alloy aspect, under condition, improve the performance of silver alloy fastness cheaply, but produce little effect, fruitful anti-tarnishing silver alloy goods listing that so far there are no.
July 18 in 2007, Zhong state invention patent application publication number CN100999792A disclosed a kind of anti-tarnishing silver alloy, was that to adopt the multiple alloying elements such as rare earth and zinc, silicon, germanium, tin, indium, brill to carry out multi-element alloyed, silver-colored Ag92.5-93.0%, copper Cu3-5%, zinc Znl-3%, germanium Ge0-0.8%, silicon SiO-0.12%, tin Sn0-1%, indium In0-0.5%, yttrium Y0-0.15%, cerium Ce0-0.15%, lanthanum La0-0.15%, cobalt Co0-0.3%, boron-0.1%, magnesium Mg0-0.01%. Although this formula can improve the tissue of alloy, crystal grain thinning, purifies crystal boundary, improve anti-oxidant metachrosis, but this alloy use a large amount of thuliums such as: germanium, yttrium, cerium, lanthanum and cobalt carry out alloying, and cost is still higher, and simultaneously mechanical performance is not high.
Summary of the invention
For addressing the above problem, the invention provides a kind of preparation technology of anti-oxidant color changed silver alloy, in this technique, adopt ternary alloy three-partalloy liquid to be combined with intermediate aluminium alloy technology, make Alloy Anti oxidation stain good, and can reduce silver alloy fusing point, not only can put forward heavy alloyed mechanical performance and processing characteristics, can also improve alloy quality hard and corrosion-resistant and oxidation.
Technical scheme of the present invention is, a kind of preparation technology of anti-oxidant color changed silver alloy, and concrete manufacturing process comprises the following steps:
1) get the raw materials ready: the components in weight percent that weighs following raw materials according: silver-colored 87%-93%, tin 0.5%-2%, zinc 1-2.2%, vanadium 0.5%-3%, manganese 2%-5%, ruthenium 1.5%-3.5%, indium 0.6%-3.1%;
2) vacuum fusion: by the silver of components by weight percent described above, tin and ruthenium heating and melting in vacuum melting furnace respectively, control temperature 500-1000 DEG C, vacuum 0.001Mpa; Mixing and stirring in vacuum environment afterwards, makes Yin-Xi-ruthenium ternary alloy three-partalloy liquid;
3) get the 10%-20% weight portion of ternary alloy three-partalloy liquid gross mass, the zinc, vanadium, manganese and the indium that in normal pressure, add respectively wherein components by weight percent described above to weigh, control temperature 700-1400 DEG C; Mixing and stirring, insulation;
4) by 3) in the intermediate aluminium alloy of step, add to step 2) in remaining ternary alloy three-partalloy liquid; Control vacuum 0.001Mpa, utilize the waste heat of intermediate aluminium alloy, stir rapidly 10 minutes; Emit final silver alloy liquid, in normal pressure, cooling forming obtains silver alloy piece.
The present invention, by add tin in silver alloy, can reduce silver alloy fusing point; Add zinc and can improve the mobility of alloy, and there is bleaching effect. With the comparison of CN100999792A technology, the present invention does not use germanium, yttrium, cerium, lanthanum and cobalt; Creationary use ruthenium, vanadium and manganese. Wherein hard and the corrosion-resistant and oxidation of the quality of ruthenium, can increase non-oxidizability and the wearability of silver alloy; The interpolation of vanadium not only can be made deoxidier, and can increase silver alloy ductility; The interpolation of manganese can improve the hardness of silver alloy. In preparation technology of the present invention, adopt ternary alloy three-partalloy liquid to be combined with intermediate aluminium alloy technology; Make first to make tin, ruthenium oxygen activity element in lower temperature environment, first form stable ternary alloy three-partalloy; Recycling zinc, vanadium, manganese and phosphide element make part ternary alloy three-partalloy form polynary intermediate aluminium alloy, further improve the plasticity of growth mechanism and the oxide-film of oxide, improve the adhesiveness of oxide-film, reduce the tendency of oxide-film cracking, and suppress the illeffects of sulphur. The comprehensive function of these alloying elements of the present invention makes alloy have good anti-sulphide discoloration and anti-oxidant discoloration. Polynary intermediate aluminium alloy of the present invention only accounts for 1/5th or principle still less of whole aluminium alloy, can play effective solution strengthening effect to all ternary alloy three-partalloy liquid alloys, make it have higher hardness, plasticity of the present invention is good, make it to have good mechanical performance and processing characteristics, silver alloy is improved aspect fastness, and be more widely used.
Detailed description of the invention
The present invention is described further below in conjunction with specific embodiment, but is not restriction the present invention.
The present embodiment 1
A kind of its concrete manufacturing process of anti-tarnishing silver alloy comprises the following steps:
1) get the raw materials ready;
2) vacuum fusion: take silver-colored 87g, tin 0.5g and ruthenium 2g, heating and melting in vacuum melting furnace respectively, controls 500 DEG C of temperature, vacuum 0.001Mpa; Mixing and stirring in vacuum environment afterwards, makes 89.5g Yin-Xi-ruthenium ternary alloy three-partalloy liquid;
3) get 10g ternary alloy three-partalloy liquid, the zinc 1g that adds respectively wherein components by weight percent described above to weigh in normal pressure, vanadium 3g, manganese 5g, indium 1.5g, controls 1000 DEG C of temperature; Mixing and stirring, insulation;
4) by 3) in the intermediate aluminium alloy of step, add to step 2) in remaining ternary alloy three-partalloy liquid; Control vacuum 0.001Mpa, utilize the waste heat of intermediate aluminium alloy, stir rapidly 10 minutes; Emit final silver alloy liquid, in normal pressure, cooling forming obtains silver alloy piece.
The present embodiment 2
A kind of its concrete manufacturing process of anti-tarnishing silver alloy comprises the following steps:
1) get the raw materials ready;
2) vacuum fusion: take silver-colored 93g, tin 0.5g and ruthenium 1.5g, heating and melting in vacuum melting furnace respectively, controls 1000 DEG C of temperature, vacuum 0.001Mpa; Mixing and stirring in vacuum environment afterwards, makes 95g Yin-Xi-ruthenium ternary alloy three-partalloy liquid;
2) get 9.5g ternary alloy three-partalloy liquid, the zinc 1.9g that adds respectively wherein components by weight percent described above to weigh in normal pressure, vanadium 0.5g, manganese 2g, indium 0.6g, controls 1400 DEG C of temperature; Mixing and stirring, insulation;
3) by 3) in the intermediate aluminium alloy of step, add to step 2) in remaining ternary alloy three-partalloy liquid; Control vacuum 0.001Mpa, utilize the waste heat of intermediate aluminium alloy, stir rapidly 10 minutes; Emit final silver alloy liquid, in normal pressure, cooling forming obtains silver alloy piece.
The present embodiment 3
A kind of its concrete manufacturing process of anti-tarnishing silver alloy comprises the following steps:
1) get the raw materials ready;
2) vacuum fusion: take silver-colored 87g, tin 0.7g and ruthenium 3.5g, heating and melting in vacuum melting furnace respectively, controls 800 DEG C of temperature, vacuum 0.001Mpa; Mixing and stirring in vacuum environment afterwards, makes 91.2g Yin-Xi-ruthenium ternary alloy three-partalloy liquid;
2) get 18g ternary alloy three-partalloy liquid, the zinc 2.2g that adds respectively wherein components by weight percent described above to weigh in normal pressure, vanadium 1.5g, manganese 2g, indium 3.1g, controls 1200 DEG C of temperature; Mixing and stirring, insulation;
3) by 3) in the intermediate aluminium alloy of step, add to step 2) in remaining ternary alloy three-partalloy liquid; Control vacuum 0.001Mpa, utilize the waste heat of intermediate aluminium alloy, stir rapidly 10 minutes; Emit final silver alloy liquid, in normal pressure, cooling forming obtains silver alloy piece.
The present embodiment 4
A kind of its concrete manufacturing process of anti-tarnishing silver alloy comprises the following steps:
1) get the raw materials ready;
2) vacuum fusion: take silver-colored 89g, tin 2g and ruthenium 2g, heating and melting in vacuum melting furnace respectively, controls 500 DEG C of temperature, vacuum 0.001Mpa; Mixing and stirring in vacuum environment afterwards, makes 93g Yin-Xi-ruthenium ternary alloy three-partalloy liquid;
2) 9.3g gets ternary alloy three-partalloy liquid, the zinc 1.2g that adds respectively wherein components by weight percent described above to weigh in normal pressure, and vanadium 1g, manganese 3g, indium 1.8g, controls 700 DEG C of temperature; Mixing and stirring, insulation;
3) by 3) in the intermediate aluminium alloy of step, add to step 2) in remaining ternary alloy three-partalloy liquid; Control vacuum 0.001Mpa, utilize the waste heat of intermediate aluminium alloy, stir rapidly 10 minutes; Emit final silver alloy liquid, in normal pressure, cooling forming obtains silver alloy piece.
Claims (1)
1. a preparation technology for anti-oxidant color changed silver alloy, specific features is to comprise the following steps:
1) get the raw materials ready: the components in weight percent that weighs following raw materials according: silver-colored 87%-93%, tin 0.5%-2%, zinc 1-2.2%, vanadium 0.5%-3%, manganese 2%-5%, ruthenium 1.5%-3.5%, indium 0.6%-3.1%;
2) vacuum fusion: by the silver of composition by weight described above, tin and ruthenium heat fused in vacuum melting furnace respectively, control temperature 500-1000 DEG C, vacuum 0.001MPa; Mixing and stirring in vacuum environment afterwards, makes Yin-Xi-ruthenium ternary alloy three-partalloy liquid;
3) get the 10%-20% weight portion of ternary alloy three-partalloy liquid gross mass, the zinc, vanadium, manganese and the indium that in normal pressure, add respectively wherein composition by weight described above to weigh, control temperature 700-1400 DEG C; Mixing and stirring, insulation;
4) by 3) in the intermediate aluminium alloy of step, add to step 2) in remaining ternary alloy three-partalloy liquid; Control vacuum 0.001MPa, utilize the waste heat of intermediate aluminium alloy, stir rapidly 10 minutes; Emit final silver alloy liquid, in normal pressure, cooling forming obtains silver alloy piece.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410626726.6A CN104294078B (en) | 2014-11-10 | 2014-11-10 | A kind of preparation technology of anti-oxidant color changed silver alloy |
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|---|---|---|---|
| CN201410626726.6A CN104294078B (en) | 2014-11-10 | 2014-11-10 | A kind of preparation technology of anti-oxidant color changed silver alloy |
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| CN104294078A CN104294078A (en) | 2015-01-21 |
| CN104294078B true CN104294078B (en) | 2016-05-11 |
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| CN102312119B (en) * | 2010-06-29 | 2013-07-10 | 福达合金材料股份有限公司 | Preparation method for silver tin oxide electrical contact material |
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Address after: No. 1 Fucheng Avenue, Chenzhou Nonferrous Metals Industrial Park, Bailutang Town, Suxian District, Chenzhou City, Hunan Province, China 423038 Patentee after: Hunan Baiyin Co.,Ltd. Country or region after: China Address before: No. 1 Fucheng Avenue, Chenzhou Nonferrous Metals Industrial Park, Bailutang Town, Suxian District, Chenzhou City, Hunan Province, China 423038 Patentee before: JINGUI SILVER INDUSTRY Co.,Ltd. Country or region before: China |