CN104277719A - Method for preparing anti-freezing wood floor adhesive - Google Patents
Method for preparing anti-freezing wood floor adhesive Download PDFInfo
- Publication number
- CN104277719A CN104277719A CN201410608013.7A CN201410608013A CN104277719A CN 104277719 A CN104277719 A CN 104277719A CN 201410608013 A CN201410608013 A CN 201410608013A CN 104277719 A CN104277719 A CN 104277719A
- Authority
- CN
- China
- Prior art keywords
- tackiness agent
- reactor
- preparation
- timber floor
- freeze proof
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention belongs to the field of adhesives, and discloses a method for preparing an anti-freezing wood floor adhesive. The method for preparing the anti-freezing wood floor adhesive comprises the following steps: (1) adding polytetrafluoroethylene, chloroprene rubber and 2-methyl propylene into a reactor, and stirring the above adhesive materials at a high speed; (2) further feeding sodium methyl silicate, polyurethane and isopropyl palmitate into the reactor, and further stirring; (3) further adding n-butyl alcohol into the reactor, further uniformly stirring, and shearing the adhesive inside the reactor by using a high-speed shearing machine; and (4) naturally cooling the material inside the reactor, thereby obtaining the anti-freezing wood floor adhesive.
Description
Technical field
The invention belongs to adhesive area, relate to a kind of preparation method of tackiness agent, particularly relate to a kind of preparation method of freeze proof timber floor tackiness agent.
Background technology
Gluingly refer to the technology that homogeneity or heterogeneous body surface stick with glue agent and link together, there is stress distribution continuous, lightweight, or sealing, the features such as most technological temperature is low.The gluing connection being specially adapted to unlike material, different thickness, ultra-thin specification and complex component.Gluing RECENT DEVELOPMENTS is the fastest, and application industry is extremely wide, and has great effect to high-and-new science and technology progress and people's daily life improvement.Therefore, study, all kinds of tackiness agent of development and production is very important.The properties of tackiness agent determines the extensive degree of its application, the especially shelf lives of tackiness agent, directly determines its use cost and effect.Such as, to acrylate series products, the temperature higher shelf lives is shorter, prior art have developed thermotolerance tackiness agent, same, to water base series products if temperature is at subzero less than 1 DEG C, directly affect quality product, visible, the anti-freezing property of tackiness agent is also vital.
Summary of the invention
The technical problem solved: the freeze proof intensity of tackiness agent is lower, the stripping strength of tackiness agent can be reduced when using at low ambient temperatures, and then cause its plybonding effect poor, in order to improve the anti-freezing property of tackiness agent in low temp area, the preparation method of the present invention to tackiness agent develops, and provides a kind of preparation method of freeze proof timber floor tackiness agent.
Technical scheme: for the problems referred to above, the invention discloses a kind of preparation method of freeze proof timber floor tackiness agent, and preparation method's step of described freeze proof timber floor tackiness agent is as follows:
(1) in reactor, add tetrafluoroethylene, chloroprene rubber, 2-methacrylic, above-mentioned tackiness agent material is carried out high-speed stirring;
(2) in reactor, drop into sodium methyl silicate, urethane, Wickenol 111 again, stir again after adding;
(3) again stir after adding propyl carbinol again in reactor, re-use high-speed shearing machine and shearing treatment is carried out to tackiness agent in reactor;
(4), in question response device after naturally cooling, be the freeze proof timber floor tackiness agent of preparation.
The preparation method of described a kind of freeze proof timber floor tackiness agent, preparation method's step is as follows:
(1) reactor temperature is fixed as 72-82 DEG C, in question response device after temperature-stable, in reactor, add that tetrafluoroethylene is 13-19 part, chloroprene rubber is 18-26 part, 2-methacrylic is 4-9 part, above-mentioned tackiness agent material is carried out high-speed stirring, mixing speed is 130-180r/min, and churning time is 20min-40min;
(2) reactor temperature is increased to 85-95 DEG C, in reactor, drop into that sodium methyl silicate is 3-7 part, urethane is 13-20 part, Wickenol 111 is 8-16 part again, stir after adding, mixing speed is 120-150r/min again, and churning time is 15min-50min;
(3) in reactor, add propyl carbinol is again again stir after 6-10 part, and re-use high-speed shearing machine and carry out shearing treatment to tackiness agent in reactor, shearing rotating speed is 3000-4500rpm, and shear time is 20min-50min;
(4), in question response device after naturally cooling, be the freeze proof timber floor tackiness agent of preparation.
The preparation method of described a kind of freeze proof timber floor tackiness agent, step is as follows:
(1) reactor temperature is fixed as 76 DEG C, in question response device after temperature-stable, in reactor, add that tetrafluoroethylene is 15-17 part, chloroprene rubber is 20-23 part, 2-methacrylic is 5-8 part, above-mentioned tackiness agent material is carried out high-speed stirring, mixing speed is 160r/min, and churning time is 30min;
(2) reactor temperature is increased to 90 DEG C, in reactor, drop into that sodium methyl silicate is 4-6 part, urethane is 14-18 part, Wickenol 111 is 10-13 part again, stir after adding, mixing speed is 130r/min again, and churning time is 40min;
(3) in reactor, add propyl carbinol is again again stir after 7-9 part, and re-use high-speed shearing machine and carry out shearing treatment to tackiness agent in reactor, shearing rotating speed is 4000rpm, and shear time is 30min;
(4), in question response device after naturally cooling, be the freeze proof timber floor tackiness agent of preparation.
The preparation method of described a kind of freeze proof timber floor tackiness agent, in preparation method, tetrafluoroethylene is 16 parts.
The preparation method of described a kind of freeze proof timber floor tackiness agent, in preparation method, chloroprene rubber is 22 parts.
The preparation method of described a kind of freeze proof timber floor tackiness agent, in preparation method, 2-methacrylic is 7 parts.
The preparation method of described a kind of freeze proof timber floor tackiness agent, in preparation method, sodium methyl silicate is 5 parts, urethane is 17 parts, Wickenol 111 is 12 parts.
Arbitrary described freeze proof timber floor tackiness agent is for pasting the purposes of timber floor above.
Beneficial effect: determine tackiness agent of the present invention anti-freezing property at low ambient temperatures, tackiness agent of the present invention at temperature is-20 DEG C tackiness agent without performance variation, 30 day later stage stripping strength is placed still higher at-20 DEG C, effectively overcome conventional tackiness agent performance variation its stripping strength also significantly reduced problem simultaneously at low temperatures, therefore under tackiness agent of the present invention can be used for low temperature environment, in the use of some low temp area timber floors, tackiness agent of the present invention can ensure the stickup stability of timber floor.
Embodiment
Embodiment 1
(1) reactor temperature is fixed as 76 DEG C, in question response device after temperature-stable, in reactor, add that tetrafluoroethylene is 15Kg, chloroprene rubber be 23Kg, 2-methacrylic is 8Kg, above-mentioned tackiness agent material is carried out high-speed stirring, mixing speed is 160r/min, and churning time is 30min; (2) reactor temperature is increased to 90 DEG C, then in reactor, drops into that sodium methyl silicate is 6Kg, urethane is 18Kg, Wickenol 111 is 13Kg, stir after adding, mixing speed is 130r/min again, and churning time is 40min; (3) in reactor, add propyl carbinol is again again stir after 7Kg, and re-use high-speed shearing machine and carry out shearing treatment to tackiness agent in reactor, shearing rotating speed is 4000rpm, and shear time is 30min; (4), in question response device after naturally cooling, be the freeze proof timber floor tackiness agent of preparation.
Embodiment 2
(1) reactor temperature is fixed as 76 DEG C, in question response device after temperature-stable, in reactor, add that tetrafluoroethylene is 17Kg, chloroprene rubber be 20Kg, 2-methacrylic is 5Kg, above-mentioned tackiness agent material is carried out high-speed stirring, mixing speed is 160r/min, and churning time is 30min; (2) reactor temperature is increased to 90 DEG C, then in reactor, drops into that sodium methyl silicate is 4Kg, urethane is 14Kg, Wickenol 111 is 10Kg, stir after adding, mixing speed is 130r/min again, and churning time is 40min; (3) in reactor, add propyl carbinol is again again stir after 9Kg, and re-use high-speed shearing machine and carry out shearing treatment to tackiness agent in reactor, shearing rotating speed is 4000rpm, and shear time is 30min; (4), in question response device after naturally cooling, be the freeze proof timber floor tackiness agent of preparation.
Embodiment 3
(1) reactor temperature is fixed as 82 DEG C, in question response device after temperature-stable, in reactor, add that tetrafluoroethylene is 19Kg, chloroprene rubber be 26Kg, 2-methacrylic is 4Kg, above-mentioned tackiness agent material is carried out high-speed stirring, mixing speed is 180r/min, and churning time is 40min; (2) reactor temperature is increased to 95 DEG C, then in reactor, drops into that sodium methyl silicate is 3Kg, urethane is 20Kg, Wickenol 111 is 16Kg, stir after adding, mixing speed is 150r/min again, and churning time is 50min; (3) in reactor, add propyl carbinol is again again stir after 10Kg, and re-use high-speed shearing machine and carry out shearing treatment to tackiness agent in reactor, shearing rotating speed is 4500rpm, and shear time is 20min; (4), in question response device after naturally cooling, be the freeze proof timber floor tackiness agent of preparation.
Embodiment 4
(1) reactor temperature is fixed as 72 DEG C, in question response device after temperature-stable, in reactor, add that tetrafluoroethylene is 13Kg, chloroprene rubber be 18Kg, 2-methacrylic is 9Kg, above-mentioned tackiness agent material is carried out high-speed stirring, mixing speed is 130r/min, and churning time is 20min; (2) reactor temperature is increased to 85 DEG C, then in reactor, drops into that sodium methyl silicate is 7Kg, urethane is 13Kg, Wickenol 111 is 8Kg, stir after adding, mixing speed is 120r/min again, and churning time is 15min; (3) in reactor, add propyl carbinol is again again stir after 6Kg, and re-use high-speed shearing machine and carry out shearing treatment to tackiness agent in reactor, shearing rotating speed is 3000rpm, and shear time is 50min; (4), in question response device after naturally cooling, be the freeze proof timber floor tackiness agent of preparation.
Embodiment 5
(1) reactor temperature is fixed as 76 DEG C, in question response device after temperature-stable, in reactor, add that tetrafluoroethylene is 16Kg, chloroprene rubber be 22Kg, 2-methacrylic is 7Kg, above-mentioned tackiness agent material is carried out high-speed stirring, mixing speed is 160r/min, and churning time is 30min; (2) reactor temperature is increased to 90 DEG C, then in reactor, drops into that sodium methyl silicate is 5Kg, urethane is 17Kg, Wickenol 111 is 12Kg, stir after adding, mixing speed is 130r/min again, and churning time is 40min; (3) in reactor, add propyl carbinol is again again stir after 9Kg, and re-use high-speed shearing machine and carry out shearing treatment to tackiness agent in reactor, shearing rotating speed is 4000rpm, and shear time is 30min; (4), in question response device after naturally cooling, be the freeze proof timber floor tackiness agent of preparation.
Tackiness agent tackiness agent at temperature is for-20 DEG C of embodiments of the invention 1 to 5 changes without physicals.Place at-20 DEG C in addition after 30 days stripping strength as follows:
As above, shown in result, the tackiness agent of preparation is placed rear stripping strength at low ambient temperatures and is still reached 6.5-11.8N/mm.
Claims (8)
1. a preparation method for freeze proof timber floor tackiness agent, is characterized in that, preparation method's step of described freeze proof timber floor tackiness agent is as follows:
(1) in reactor, add tetrafluoroethylene, chloroprene rubber, 2-methacrylic, above-mentioned tackiness agent material is carried out high-speed stirring;
(2) in reactor, drop into sodium methyl silicate, urethane, Wickenol 111 again, stir again after adding;
(3) again stir after adding propyl carbinol again in reactor, re-use high-speed shearing machine and shearing treatment is carried out to tackiness agent in reactor;
(4), in question response device after naturally cooling, be the freeze proof timber floor tackiness agent of preparation.
2. the preparation method of a kind of freeze proof timber floor tackiness agent according to claim 1, is characterized in that, preparation method's step of described freeze proof timber floor tackiness agent is as follows:
(1) reactor temperature is fixed as 72-82 DEG C, in question response device after temperature-stable, in reactor, add that tetrafluoroethylene is 13-19 part, chloroprene rubber is 18-26 part, 2-methacrylic is 4-9 part, above-mentioned tackiness agent material is carried out high-speed stirring, mixing speed is 130-180r/min, and churning time is 20min-40min;
(2) reactor temperature is increased to 85-95 DEG C, in reactor, drop into that sodium methyl silicate is 3-7 part, urethane is 13-20 part, Wickenol 111 is 8-16 part again, stir after adding, mixing speed is 120-150r/min again, and churning time is 15min-50min;
(3) in reactor, add propyl carbinol is again again stir after 6-10 part, and re-use high-speed shearing machine and carry out shearing treatment to tackiness agent in reactor, shearing rotating speed is 3000-4500rpm, and shear time is 20min-50min;
(4), in question response device after naturally cooling, be the freeze proof timber floor tackiness agent of preparation.
3. the preparation method of a kind of freeze proof timber floor tackiness agent according to claim 2, is characterized in that, preparation method's step of described freeze proof timber floor tackiness agent is as follows:
(1) reactor temperature is fixed as 76 DEG C, in question response device after temperature-stable, in reactor, add that tetrafluoroethylene is 15-17 part, chloroprene rubber is 20-23 part, 2-methacrylic is 5-8 part, above-mentioned tackiness agent material is carried out high-speed stirring, mixing speed is 160r/min, and churning time is 30min;
(2) reactor temperature is increased to 90 DEG C, in reactor, drop into that sodium methyl silicate is 4-6 part, urethane is 14-18 part, Wickenol 111 is 10-13 part again, stir after adding, mixing speed is 130r/min again, and churning time is 40min;
(3) in reactor, add propyl carbinol is again again stir after 7-9 part, and re-use high-speed shearing machine and carry out shearing treatment to tackiness agent in reactor, shearing rotating speed is 4000rpm, and shear time is 30min;
(4), in question response device after naturally cooling, be the freeze proof timber floor tackiness agent of preparation.
4. the preparation method of a kind of freeze proof timber floor tackiness agent according to claim 2, is characterized in that, in the preparation method of described freeze proof timber floor tackiness agent, tetrafluoroethylene is 16 parts.
5. the preparation method of a kind of freeze proof timber floor tackiness agent according to claim 2, is characterized in that, in the preparation method of described freeze proof timber floor tackiness agent, chloroprene rubber is 22 parts.
6. the preparation method of a kind of freeze proof timber floor tackiness agent according to claim 2, is characterized in that, in the preparation method of described freeze proof timber floor tackiness agent, 2-methacrylic is 7 parts.
7. the preparation method of a kind of freeze proof timber floor tackiness agent according to claim 2, is characterized in that, in the preparation method of described freeze proof timber floor tackiness agent, sodium methyl silicate is 5 parts, urethane is 17 parts, Wickenol 111 is 12 parts.
8. according to the arbitrary described freeze proof timber floor tackiness agent of claim 1 to 7 for pasting the purposes of timber floor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410608013.7A CN104277719B (en) | 2014-10-31 | 2014-10-31 | A kind of preparation method of freeze proof timber floor tackiness agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410608013.7A CN104277719B (en) | 2014-10-31 | 2014-10-31 | A kind of preparation method of freeze proof timber floor tackiness agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104277719A true CN104277719A (en) | 2015-01-14 |
| CN104277719B CN104277719B (en) | 2015-12-30 |
Family
ID=52253082
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410608013.7A Active CN104277719B (en) | 2014-10-31 | 2014-10-31 | A kind of preparation method of freeze proof timber floor tackiness agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104277719B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108949043A (en) * | 2018-07-16 | 2018-12-07 | 广州昱辰元创节能环保科技有限公司 | A kind of building board marine glue and its preparation method and application |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1093730A (en) * | 1994-03-04 | 1994-10-19 | 郑凯 | Self-lubricating compound sealing material |
| JP2008274119A (en) * | 2007-04-27 | 2008-11-13 | Kaneka Corp | Curable composition |
| CN102212318A (en) * | 2010-04-06 | 2011-10-12 | 孙昕 | Novel anti-freezing moisture resistant adhesive agent |
| CN103013356A (en) * | 2012-12-12 | 2013-04-03 | 滁州市鑫彩印务有限公司 | Low-temperature-resistant binding agent for packaging material |
| CN103173140A (en) * | 2013-02-26 | 2013-06-26 | 安徽明珠颜料科技有限公司 | Neoprene adhesive for woodworking |
| CN103265895A (en) * | 2013-05-23 | 2013-08-28 | 苏州富通高新材料科技股份有限公司 | Solvent type chloroprene rubber adhesive with excellent weather ability and preparation method thereof |
-
2014
- 2014-10-31 CN CN201410608013.7A patent/CN104277719B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1093730A (en) * | 1994-03-04 | 1994-10-19 | 郑凯 | Self-lubricating compound sealing material |
| JP2008274119A (en) * | 2007-04-27 | 2008-11-13 | Kaneka Corp | Curable composition |
| CN102212318A (en) * | 2010-04-06 | 2011-10-12 | 孙昕 | Novel anti-freezing moisture resistant adhesive agent |
| CN103013356A (en) * | 2012-12-12 | 2013-04-03 | 滁州市鑫彩印务有限公司 | Low-temperature-resistant binding agent for packaging material |
| CN103173140A (en) * | 2013-02-26 | 2013-06-26 | 安徽明珠颜料科技有限公司 | Neoprene adhesive for woodworking |
| CN103265895A (en) * | 2013-05-23 | 2013-08-28 | 苏州富通高新材料科技股份有限公司 | Solvent type chloroprene rubber adhesive with excellent weather ability and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108949043A (en) * | 2018-07-16 | 2018-12-07 | 广州昱辰元创节能环保科技有限公司 | A kind of building board marine glue and its preparation method and application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104277719B (en) | 2015-12-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103435899B (en) | A kind of footwear material environment-friendly materials and preparation method thereof and purposes | |
| CN104277719B (en) | A kind of preparation method of freeze proof timber floor tackiness agent | |
| CN104789156A (en) | Novel paperboard adhesive and preparation method thereof | |
| CN104059574A (en) | Preparation method of polyvinyl formal adhesive | |
| CN105400458B (en) | A kind of food packaging Environment-friendlyglue glue and preparation method | |
| CN104017244B (en) | A kind of montmorillonite intercalation nano composite membrane and its preparation method and application | |
| CN102108264B (en) | Single-component epoxy structure adhesive tape and preparation method thereof | |
| CN104263263A (en) | Novel high-performance double-sided adhesive tape | |
| CN103554279B (en) | The composite modified starch of alternative gelatin and application | |
| WO2019190434A3 (en) | Surface veil and surface film integrated prepreg layer and processes for making the same | |
| CN107828225A (en) | A kind of compound package material and preparation method thereof | |
| CN104927676A (en) | Adhesive and preparation method thereof | |
| CN109385248A (en) | A kind of environment protection type high-strength UV glue | |
| CN104387699A (en) | Medical PVC paste material and preparation method thereof | |
| CN103788894A (en) | EVA (Ethylene-Vinyl Acetate) hot melt adhesive | |
| CN104087201B (en) | A kind of ethene-vinyl acetate PUR | |
| CN105925213A (en) | Weather-proof chloroprene rubber adhesive and preparing method thereof | |
| CN104293270B (en) | A kind of epoxyn for timber floor and preparation method thereof | |
| CN106047235B (en) | A kind of quartz repair sheets and preparation method thereof | |
| CN202907934U (en) | Environment-friendly shoe material | |
| CN107629723A (en) | A kind of high viscosity adhesive and preparation method thereof | |
| CN102329588B (en) | High-abrasion-resistant metal adhesive and preparation method thereof | |
| CN105038667A (en) | Environment-friendly acid-resisting and wear-resisting adhesive and preparing method thereof | |
| CN104109484A (en) | Chloroprene rubber-based pressure sensitive tape and preparation method thereof | |
| CN105176444A (en) | Rubber adhesive and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information |
Inventor after: Gao Shezhang Inventor after: Chen Yonglin Inventor before: Gao Shezhang |
|
| COR | Change of bibliographic data | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Wu Haiping Inventor after: Xiang Jinsong Inventor after: Shen Huihua Inventor before: Gao Shezhang Inventor before: Chen Yonglin |
|
| COR | Change of bibliographic data | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20161207 Address after: 201514 Shanghai city Jinshan District Zhangyan town Qin village seven groups Patentee after: SHANGHAI HANSI INDUSTRIAL CO., LTD. Address before: Ding Hong Kong Village Economic Development Zone, Zhejiang province Huzhou city Nanxun District 313000 Patentee before: Zhejiang Honggaoliang Wood Co., Ltd. |