CN104277659B - A kind of fire prevention electronic component powdery paints and preparation method thereof - Google Patents

A kind of fire prevention electronic component powdery paints and preparation method thereof Download PDF

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Publication number
CN104277659B
CN104277659B CN201410474296.0A CN201410474296A CN104277659B CN 104277659 B CN104277659 B CN 104277659B CN 201410474296 A CN201410474296 A CN 201410474296A CN 104277659 B CN104277659 B CN 104277659B
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Prior art keywords
electronic component
powder
powdery paints
preparation
epoxy resin
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CN201410474296.0A
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CN104277659A (en
Inventor
马炎峰
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Zhongshan Runjia Plastic Powder Co ltd
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DEQING XINXIANGHUI LIGHTING ELECTRICAL APPLIANCE Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/03Powdery paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • C09D5/185Intumescent paints

Abstract

A kind of fire prevention electronic component powdery paints, mainly comprises following main component: epoxy resin, silicon powder, firming agent, fluorescent material, pigment, expanded vermiculite powder and organosilicon powder.Fire prevention electronic component powdery paints of the present invention is by the scientific matching of each raw material and rational preparation method, and described powdery paints has good fire line, wearability, impact resistance, adhesive force.

Description

A kind of fire prevention electronic component powdery paints and preparation method thereof
Technical field
Paint field of the present invention, is specifically related to a kind of fire prevention electronic component powdery paints and preparation method thereof.
Background technology
Powdery paints is a kind of dry state pressed powder not containing organic solvent, it and the coating of common solvent type and aqueous Coating is different, need not with solvent or water as disperse medium during application, but using air as disperse medium, application equably After surface of the work, heating, form a kind of new coating of film, this be with the significant difference of other coating in place of.Powdery paints It is the coating variety of a kind of high speed development, there is the advantage such as energy-conserving and environment-protective, three-waste free pollution, be used widely, But fireproof is required higher by some electronic components, and powdery paints in the market cannot meet its requirement.
Summary of the invention
It is an object of the invention to provide a kind of fire prevention electronic component powdery paints and preparation method.
The invention provides a kind of fire prevention electronic component powdery paints, be made up of the component of following percentage by weight:
Preferably, described silicon powder particle diameter is 200 mesh.
Preferably, described firming agent is organic acid or acid anhydride type curing agent.
Preferably, described epoxy resin epoxy equivalent is 5000-10000g/eq.
Preferably, described expanded vermiculite powder make a living vermiculite in flake grind after high-temperature roasting prepare, particle diameter is 250 mesh.
Preferably, the polydimethylsiloxane being mainly composed of polyester modification of described organosilicon powder.
One, epoxy resin:
Epoxy resin is the organic compound referring to and containing two or more epoxide groups in molecule, in addition to indivedual, Their relative molecular mass is the highest.The molecular structure of epoxy resin is to contain active epoxide group in strand for it Feature, epoxide group may be located at the end of strand, centre or structure circlewise.Owing to molecular structure containing active ring Oxygen groups, makes them can crosslink reaction with polytype firming agent and be formed and insoluble, insoluble have the netted knot of three-dimensional The high polymer of structure.
Epoxy resin is one of very important thermoset macromolecule material, has adhesion strength high, and electrical insulation capability is good, The advantages such as contractility is low, good processability, are widely used in each fields such as electronics, machinery, building.
The epoxy resin that the present invention selects epoxide equivalent to be 5000-10000g/eq is that primary raw material prepares powdery paints.
Two, silicon powder
Silicon powder is by natural quartz (SiO2) or vitreous silica (natural quartz amorphous state after high-temperature fusion, cooling SiO2) through the multiple tracks processes such as broken, ball milling (or vibration, airflow milling), flotation, pickling purification, high purity water process Micropowder.Silicon powder is a kind of Inorganic Non-metallic Materials nontoxic, tasteless, free of contamination.Owing to it possesses, temperature tolerance is good, acid and alkali-resistance is rotten The excellent performances such as erosion, poor thermal conductivity, high insulation, low bulk, stable chemical performance, hardness are big, are widely used in chemical industry, electricity The field such as son, integrated circuit (IC), electrical equipment, plastics, coating, senior paint, rubber, national defence.Swift and violent along with high-tech sector Development, silicon powder also will step into new historical periods.
Silicon powder is widely used in high-grade high-performance low-cement refractory pouring material and prefabricated component, and service life is common cast Three times of material, refractoriness improves about 100 DEG C, and elevated temperature strength and thermal shock resistance are all obviously improved.It is widely used in: coke oven, The industries such as ironmaking, steel-making, steel rolling, non-ferrous metal, glass, pottery and generating.
Three, firming agent
Firming agent has another name called sclerosing agent, curing agent or set agent, is a class enhancement or material or the mixing controlling curing reaction Thing.Resin solidification is through chemical reactions such as condensation, closed loop, addition or catalysis, makes thermosetting resin that irreversible change to occur Process, solidification completes by adding solidification (crosslinking) agent.
The present invention selects organic acid or acid anhydride type curing agent.
Four, expanded vermiculite powder:
Vermiculitum is a kind of clay mineral similar to montmorillonite, for the silicate of layer structure.Typically by biotite through heat Liquid corrosion becomes or air slaking are formed.There is (this is the biotite illusion of Vermiculitum) with thick biotite appearance sometimes in it, the thinnest So micro-that to become soil shape.When Vermiculitum is heated to 300 DEG C, its expansion 20 times also bends.At this moment Vermiculitum is somewhat like water Trematodiasis (is commonly called as Hirudo), and therefore it has had so one name.Vermiculitum is the most brown, yellow, dirty-green, has the gloss that oil is the same, adds Lycoperdon polymorphum Vitt is become after heat.Vermiculitum can be used as construction material, adsorbent, fire-retardant insulating material, mechanical lubrication agent, soil conditioner etc. Deng, of many uses.Fabric and raw-vermiculite sheet is after high-temperature roasting, and its volume energy expands rapidly several times to tens times, after volumetric expansion Vermiculitum is just expanded vermiculite, and it is layer structure, and interlayer contains water of crystallization, and unit weight is at 50-200kg/m3, thermal conductivity is little, is good Good heat-barrier material.The second best in quality expanded vermiculite, maximum operation (service) temperature is up to 1100 DEG C.Additionally, expanded vermiculite has well Electrical insulating property.
The present invention selects expanded vermiculite powder to include as main modifying agent, the effect played: one is to utilize expanded vermiculite The resistance to elevated temperatures of powder self, two is to utilize its layer structure, and after stirring, silicon powder, with it as carrier, therein may be used To effectively play, temperature tolerance is good, acid-alkali-corrosive-resisting, the effect of high insulation.
Five, organosilicon powder
The main component of the organosilicon powder that the present invention uses is the polyxylene siloxanes of polyester modification.This kind is used to have The Main Function of machine Si powder is: one is to be modified epoxy resin, improves the adhesion property of powdery paints, and two is 1000 Under high temperature more than DEG C, organosilicon powder can react with silicon powder in the carrier of expanded vermiculite powder, is formed a kind of attached The network structure more closely on expanded vermiculite surface and inside, improve the fire protecting performance of coating.
Present invention also offers the preparation method of a kind of electronic component powdery paints of preventing fires, comprise the steps of
Step one: after being opened by blender, by epoxy resin-firming agent-expanded vermiculite powder-silicon powder-pigment-organosilicon The order of powder-fluorescent material stirs in adding blender;
Step 2: being put into by the raw material stirred and heat in extruder and extrude, heating-up temperature is 80-140 DEG C, squeezes The semi-finished product gone out are lamellar.
Step 3: lamellar semi-finished product are put into and pulverizes and grind to form powdery in pulverizer, screened i.e. obtain of the present invention Electronic component powdery paints.
The useful of the present invention is effectively: the fire prevention electronic component powdery paints of the present invention science by each raw material Proportioning and rational preparation method, described powdery paints has good fire line, wearability, impact resistance, adhesive force.
Detailed description of the invention
Embodiment 1
The invention provides a kind of fire prevention electronic component powdery paints, be made up of the component of following percentage by weight:
Described firming agent is organic acid or acid anhydride type curing agent.
Described epoxy resin epoxy equivalent is 5000-10000g/eq.
Described expanded vermiculite powder make a living vermiculite in flake grind after high-temperature roasting prepare.
The preparation method of a kind of electronic component powdery paints of preventing fires, comprises the steps of
Step one: after being opened by blender, by epoxy resin-firming agent-expanded vermiculite powder-silicon powder-pigment-organosilicon The order of powder-fluorescent material stirs in adding blender;
Step 2: put into by the raw material stirred and heat in extruder and extrude, heating-up temperature is 120 DEG C, extrusion Semi-finished product be lamellar.
Step 3: lamellar semi-finished product are put into and pulverizes and grind to form powdery in pulverizer, screened i.e. obtain of the present invention Fire prevention electronic component powdery paints.
Embodiment 2
The invention provides a kind of fire prevention electronic component powdery paints, be made up of the component of following percentage by weight:
Described firming agent is organic acid or acid anhydride type curing agent.
Described epoxy resin epoxy equivalent is 5000-10000g/eq.
Described expanded vermiculite powder make a living vermiculite in flake grind after high-temperature roasting prepare.
The preparation method of a kind of electronic component powdery paints of preventing fires, comprises the steps of
Step one: after being opened by blender, by epoxy resin-firming agent-expanded vermiculite powder-silicon powder-pigment-organosilicon The order of powder-fluorescent material stirs in adding blender;
Step 2: put into by the raw material stirred and heat in extruder and extrude, heating-up temperature is 80 DEG C, extrusion Semi-finished product are lamellar.
Step 3: lamellar semi-finished product are put into and pulverizes and grind to form powdery in pulverizer, screened i.e. obtain of the present invention Fire prevention electronic component powdery paints.
Embodiment 3
The invention provides a kind of fire prevention electronic component powdery paints, be made up of the component of following percentage by weight:
Described firming agent is organic acid or acid anhydride type curing agent.
Described epoxy resin epoxy equivalent is 5000-10000g/eq.
Described expanded vermiculite powder make a living vermiculite in flake grind after high-temperature roasting prepare.
The preparation method of a kind of electronic component powdery paints of preventing fires, comprises the steps of
Step one: after being opened by blender, by epoxy resin-firming agent-expanded vermiculite powder-silicon powder-pigment-organosilicon The order of powder-fluorescent material stirs in adding blender;
Step 2: put into by the raw material stirred and heat in extruder and extrude, heating-up temperature is 140 DEG C, extrusion Semi-finished product be lamellar.
Step 3: lamellar semi-finished product are put into and pulverizes and grind to form powdery in pulverizer, screened i.e. obtain of the present invention Fire prevention electronic component powdery paints.
Embodiment 4
The invention provides a kind of fire prevention electronic component powdery paints, be made up of the component of following percentage by weight:
Described firming agent is organic acid or acid anhydride type curing agent.
Described epoxy resin epoxy equivalent is 5000-10000g/eq.
Described expanded vermiculite powder make a living vermiculite in flake grind after high-temperature roasting prepare.
The preparation method of a kind of electronic component powdery paints of preventing fires, comprises the steps of
Step one: after being opened by blender, by epoxy resin-firming agent-expanded vermiculite powder-silicon powder-pigment-organosilicon The order of powder-fluorescent material stirs in adding blender;
Step 2: put into by the raw material stirred and heat in extruder and extrude, heating-up temperature is 120 DEG C, extrusion Semi-finished product be lamellar.
Step 3: lamellar semi-finished product are put into and pulverizes and grind to form powdery in pulverizer, screened i.e. obtain of the present invention Fire prevention electronic component powdery paints.
Embodiment 5
The invention provides a kind of fire prevention electronic component powdery paints, be made up of the component of following percentage by weight:
Described firming agent is organic acid or acid anhydride type curing agent.
Described epoxy resin epoxy equivalent is 5000-10000g/eq.
Described expanded vermiculite powder make a living vermiculite in flake grind after high-temperature roasting prepare.
The preparation method of a kind of electronic component powdery paints of preventing fires, comprises the steps of
Step one: after being opened by blender, by epoxy resin-firming agent-expanded vermiculite powder-silicon powder-pigment-organosilicon The order of powder-fluorescent material stirs in adding blender;
Step 2: put into by the raw material stirred and heat in extruder and extrude, heating-up temperature is 100 DEG C, extrusion Semi-finished product be lamellar.
Step 3: lamellar semi-finished product are put into and pulverizes and grind to form powdery in pulverizer, screened i.e. obtain of the present invention Fire prevention electronic component powdery paints.
The method of electrostatic spraying is used to be sprayed at electronical elements surface with the fire prevention electronic component powdery paints of above proportioning, Electronic component is detected.
Fire protecting performance is tested: above-described embodiment 1-5 film, with alcohol blast burner flame away from coating 5cm, baking, coating layer thickness 1mm, fire duration 5min.Result: above film all can form the carburization zone comparing even compact.
These detection data are just for above-mentioned detection sample.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto, Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.

Claims (5)

1. the preparation method of an electronic component powdery paints of preventing fires, it is characterised in that comprise the steps of
Step one: after being opened by blender, by epoxy resin-firming agent-expanded vermiculite powder-silicon powder-pigment-silicone powder The order of end-fluorescent material stirs in adding blender;
Step 2: being put into by the raw material stirred and heat in extruder and extrude, heating-up temperature is 80-140 DEG C, extrusion Semi-finished product are lamellar;
Step 3: lamellar semi-finished product are put into and pulverizes and grind to form powdery in pulverizer, screened i.e. obtain of the present invention anti- Thermoelectricity component powders coating;
Described fire prevention electronic component powdery paints, is made up of the component of following percentage by weight:
Epoxy resin 30%-50%
Silicon powder 15%-40%
Firming agent 5%-15%
Fluorescent material 3%-5%
Pigment 10%-20%
Expanded vermiculite powder 3%-10%
Organosilicon powder 0.5%-2%;
The polydimethylsiloxane being mainly composed of polyester modification of described organosilicon powder.
2. the preparation method of electronic component powdery paints of preventing fires as claimed in claim 1, it is characterised in that described silicon powder grain Footpath is 200 mesh.
3. the preparation method of electronic component powdery paints of preventing fires as claimed in claim 1, it is characterised in that described firming agent For organic acid or acid anhydride type curing agent.
4. the preparation method of electronic component powdery paints of preventing fires as claimed in claim 1, it is characterised in that described asphalt mixtures modified by epoxy resin Fat epoxide equivalent is 5000-10000g/eq.
5. the preparation method of electronic component powdery paints of preventing fires as claimed in claim 1, it is characterised in that described expansion trematodiasis Stone powder make a living vermiculite in flake grind after high-temperature roasting prepare, particle diameter is 250 mesh.
CN201410474296.0A 2014-09-17 2014-09-17 A kind of fire prevention electronic component powdery paints and preparation method thereof Expired - Fee Related CN104277659B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104761997A (en) * 2015-03-25 2015-07-08 牛无畏 Epoxy resin powder paint
CN105419559B (en) * 2015-11-25 2018-10-19 浙江华彩新材料有限公司 A kind of antifouling and antibiosis electronic component fluorescent powder coating and preparation method thereof
CN105419558B (en) * 2015-11-25 2019-02-01 浙江华彩新材料有限公司 A kind of antibacterial electronic component fluorescent powder coating and preparation method thereof
CN105778712A (en) * 2016-03-18 2016-07-20 浙江华彩化工有限公司 Flame-retardant high-temperature-resistant insulating powder coating for conductive copper bar and preparation method of flame-retardant high-temperature-resistant insulating powder coating for conductive copper bar
CN106167666A (en) * 2016-07-28 2016-11-30 华巧波 A kind of impact resistance fire prevention electronic component powdery paints and preparation method thereof
CN112300660A (en) * 2020-10-22 2021-02-02 河北盛可居装饰材料有限公司 Polymer electrostatic powder capable of improving flame retardant property of plate

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* Cited by examiner, † Cited by third party
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JP2004107431A (en) * 2002-09-17 2004-04-08 Sumitomo Bakelite Co Ltd Epoxy resin powder coating
CN101983985A (en) * 2009-11-06 2011-03-09 西安贝克电子材料科技有限公司 Halogen-free and stibium-free flame-retarding insulation epoxy powder encapsulating material and preparation method thereof
CN103131307B (en) * 2011-12-01 2016-03-30 上海纳米技术及应用国家工程研究中心有限公司 A kind of aluminium alloy extrusions heat-insulation and heat-preservation powder coating and preparation method thereof
CN103059516B (en) * 2013-01-08 2015-12-23 天津市凯华绝缘材料有限公司 A kind of Fast-cure epoxy powder composition

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Inventor after: Huang Yuxia

Inventor after: Cai Lihong

Inventor before: Ma Yanfeng

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Effective date of registration: 20171011

Address after: 246121 Anhui city of Anqing province Huaining County High Town neighborhood Johor Tao Tang Group No. 032

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Patentee after: Huang Yuxia

Address before: The Ming Hui Street 313000 Zhejiang city of Huzhou province Deqing County Qianyuan town No. 388

Patentee before: DEQING XINXIANGHUI LIGHTING ELECTRICAL APPLIANCE Co.,Ltd.

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Effective date of registration: 20181228

Address after: 528427 No. 68 Feiyue Road, Shenghuibei Industrial Zone, Nantou Town, Zhongshan City, Guangdong Province

Patentee after: ZHONGSHAN RUNJIA PLASTIC POWDER Co.,Ltd.

Address before: 246121 Taotang Group 032, Xinshan Residential Committee, Gaohe Town, Huaining County, Anqing City, Anhui Province

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