CN104277653B - Ultrathin high-temperature-resistant thermal-insulation paint - Google Patents
Ultrathin high-temperature-resistant thermal-insulation paint Download PDFInfo
- Publication number
- CN104277653B CN104277653B CN201410507421.3A CN201410507421A CN104277653B CN 104277653 B CN104277653 B CN 104277653B CN 201410507421 A CN201410507421 A CN 201410507421A CN 104277653 B CN104277653 B CN 104277653B
- Authority
- CN
- China
- Prior art keywords
- temperature
- parts
- paint
- resin emulsion
- resistant thermal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000009413 insulation Methods 0.000 title claims abstract description 26
- 239000003973 paint Substances 0.000 title abstract description 8
- 238000010438 heat treatment Methods 0.000 claims abstract description 20
- 239000000839 emulsion Substances 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000000049 pigment Substances 0.000 claims abstract description 11
- 229910001404 rare earth metal oxide Inorganic materials 0.000 claims abstract description 11
- 239000000945 filler Substances 0.000 claims abstract description 8
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 6
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 6
- 239000011347 resin Substances 0.000 claims abstract description 6
- 229920005989 resin Polymers 0.000 claims abstract description 6
- 229910021331 inorganic silicon compound Inorganic materials 0.000 claims abstract description 4
- 229920001577 copolymer Polymers 0.000 claims abstract 4
- 238000000576 coating method Methods 0.000 claims description 38
- 239000011248 coating agent Substances 0.000 claims description 37
- 239000000178 monomer Substances 0.000 claims description 19
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 18
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 14
- 238000004132 cross linking Methods 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 11
- 229910021529 ammonia Inorganic materials 0.000 claims description 9
- 230000000844 anti-bacterial effect Effects 0.000 claims description 9
- 239000002270 dispersing agent Substances 0.000 claims description 9
- 239000002562 thickening agent Substances 0.000 claims description 9
- 239000012752 auxiliary agent Substances 0.000 claims description 8
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 6
- 238000010422 painting Methods 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000011324 bead Substances 0.000 claims description 5
- 239000000919 ceramic Substances 0.000 claims description 5
- 238000010790 dilution Methods 0.000 claims description 5
- 239000012895 dilution Substances 0.000 claims description 5
- 239000003063 flame retardant Substances 0.000 claims description 5
- 239000011521 glass Substances 0.000 claims description 5
- 239000002002 slurry Substances 0.000 claims description 5
- 238000007667 floating Methods 0.000 claims description 4
- 239000004005 microsphere Substances 0.000 claims description 4
- -1 after stirring Substances 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- PAZHGORSDKKUPI-UHFFFAOYSA-N lithium metasilicate Chemical compound [Li+].[Li+].[O-][Si]([O-])=O PAZHGORSDKKUPI-UHFFFAOYSA-N 0.000 claims description 3
- 229910052912 lithium silicate Inorganic materials 0.000 claims description 3
- 229910052684 Cerium Inorganic materials 0.000 claims description 2
- 235000000177 Indigofera tinctoria Nutrition 0.000 claims description 2
- 229910052779 Neodymium Inorganic materials 0.000 claims description 2
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 2
- 229940097275 indigo Drugs 0.000 claims description 2
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 claims description 2
- 229910052746 lanthanum Inorganic materials 0.000 claims description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims description 2
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims description 2
- 229910001954 samarium oxide Inorganic materials 0.000 claims description 2
- 229940075630 samarium oxide Drugs 0.000 claims description 2
- FKTOIHSPIPYAPE-UHFFFAOYSA-N samarium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[Sm+3].[Sm+3] FKTOIHSPIPYAPE-UHFFFAOYSA-N 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 229910052727 yttrium Inorganic materials 0.000 claims description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 2
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 claims 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 150000003377 silicon compounds Chemical class 0.000 claims 1
- 230000008901 benefit Effects 0.000 abstract description 4
- 230000005855 radiation Effects 0.000 abstract description 4
- 239000000853 adhesive Substances 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- 230000032683 aging Effects 0.000 abstract description 3
- 238000000137 annealing Methods 0.000 abstract description 3
- 238000005338 heat storage Methods 0.000 abstract description 3
- 238000003860 storage Methods 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 2
- 230000002349 favourable effect Effects 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 6
- 229910000420 cerium oxide Inorganic materials 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 5
- 238000007670 refining Methods 0.000 description 4
- 239000011247 coating layer Substances 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical class NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 238000007233 catalytic pyrolysis Methods 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 230000007850 degeneration Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- GJIDOLBZYSCZRX-UHFFFAOYSA-N hydroxymethyl prop-2-enoate Chemical compound OCOC(=O)C=C GJIDOLBZYSCZRX-UHFFFAOYSA-N 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000004643 material aging Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/24—Homopolymers or copolymers of amides or imides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F220/58—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-(meth)acryloylmorpholine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/32—Radiation-absorbing paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2272—Ferric oxide (Fe2O3)
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses an ultrathin high-temperature-resistant thermal-insulation paint which is used for thermal insulation of an industrial high-temperature heating furnace. The paint is prepared from 70-300 parts of resin emulsion, 10-30 parts of pigment, 50-80 parts of filler, 1-3 parts of rare-earth oxide, 10-40 parts of assistant and 100-300 parts of water. The resin emulsion is prepared by mixing a special monomer-modified self-crosslinked acrylate copolymer with one or two of pure acrylic resin emulsion and inorganic silicon compounds. By using the high flowability and film formation property of the special monomer-modified self-crosslinked acrylate copolymer and the high-temperature stability, low thermal conductivity and heat storage property of the rare-earth oxide, the formed paint has the advantages of high temperature resistance, high resilience and aging resistance. The paint with the thickness of only 2-3mm can enhance the heat efficiency of the heating furnace by more than 1.5%, and the heat radiation loss of the furnace body external surface is lowered by not less than 40%. After the paint is constructed at normal temperature, the cured paint can resist the high temperature of 200-300 DEG C, has the advantages of high adhesive force, favorable ductility and favorable corrosion resistance, and can be widely used for outer surface thermal insulation of heating furnaces, high-temperature medium storage tanks, high-temperature pipelines, annealing furnaces, thermal pipelines and the like.
Description
Technical field
The present invention relates to a kind of be mainly used in the ultrathin high-temperature-resistant thermal-insulation coating that industrial heating furnace is used.
Background technology
The petrochemical enterprise in the whole nation in 2013, processing refines crude oil total amount for 4.84 hundred million tons.PETROLEUM PROCESSING exists substantially
The main three phases of air-distillation, catalytic pyrolysiss and refinery gas processing.In order to make full use of crude resources and processing heavy former
Oil, the trend that developed to deep processing direction of modern times oil refining, i.e., using catalytic cracking, be hydrocracked, the process such as petroleum coking,
To obtain more light-end products from crude oil.In cracking process, not only need to consume substantial amounts of fuel, and can exclude big
The greenhouse gases of amount, how to improve the efficiency of heating furnace in the oil refining enterprise in the whole nation always one it is conflicting with production capacity
Outstanding problem.The development of ultrathin high-temperature-resistant thermal-insulation coating, is that industry energy conservation is reduced discharging, and improves the material that heat energy efficiency provides high-quality
Material is selected, and a heating furnace is after its outer surface coats the coating, you can thermal efficiency of heating furnace more than 1.5% is improved, outside body of heater
Surface heat radiating loss declines not less than 40%.At present the production capacity size of the heating furnace of petrochemical industry, can save mark oil heating furnace year
600~1300 tons/mono- stove, year, economic benefit was in 180~3,900,000 yuan/mono- stove.
Secondly, " 12 " plan that the target for proposing energy-saving and emission-reduction is：By 2015, national ten thousand yuan of GDPs
Energy consumption drops to 0.869 ton of standard coal（By calculation of price in 2005）, the 1.034 tons of standard coals decline 16% than 2010（Than
1.276 tons of standard coals of 2005 decline 32%）.During " 12 ", 6.7 hundred million tons of standard coals of energy saving are realized.Realize this
One target, what is stood in the breach is exactly a large amount of oil refining, iron and steel enterprises for consuming the energy.
At present China's industrial high temperature heating furnace includes hot-rolling heating furnace, petroleum chemical heating furnace, annealing furnace, ceramic roller kiln, water
Stall stove and tunnel kiln etc., its total amount about 1,000,000, at present the stove hull-skin temperature of these high-temperature heaters is higher（200
~250 DEG C）, and substantially without Insulation, the insulation of part heating furnace outer surface mostly using the excellent carborundum of fire resistance or
Zirconium dioxide is incubated for Main Ingredients and Appearance and waterglass for inorganic coating made by bonding agent, and the problem that it is primarily present is；For
Raising heat-insulating property, dope layer at least will spray man-hour and material cost be higher more than 8 millimeters；Two is this inorganic painting
Material aging speed is fast, and coating is easy to crack and bubbling, and radiation protection ability is not lasting, and thermal-insulation coating declines fast.
The content of the invention
The invention provides one kind is resistant to 300 DEG C, coating layer thickness in 2-3 millimeters, mainly for industrial high temperature heating furnace with
And the ultrathin high temperature resistant of a kind of energy-saving of exterior applications, feature such as high-temperature medium storage tank, high-temperature pipe and heat distribution pipeline
Thermal insulation coatings.
The present invention is adopted the following technical scheme that for achieving the above object：From 70~300 parts of resin emulsion, pigment 10~30
Part, 50~80 parts of filler, 1~3 part of rare earth oxide, 10~40 parts of auxiliary agent and 100~300 parts of water, the resin emulsion is spy
At least two in different three kinds of monomer modified self-cross linking type ACR, pure acrylic resin emulsion and inorganic silicon compound
It is mixed with and forms, particular monomers modified self-crosslinking type ACR hydroxymethylacrylate amide and the acrylic acid
It is prepared from for activated monomer and with seed emulsion polymerization, the inorganic silicon compound is Ludox or Lithium metasilicate, described to fill out
Expect for one or more of hollow ceramic microspheres, hollow glass micropearl or power plant's floating bead；Water is first added by weight stirred tank, so
After add dispersant, by vacuum pump, suction pigment, filler, with 500~600 revs/min of dispersed with stirring 40~60 minutes, system
Into slurry；Stirred tank rotating speed is adjusted to again 400~600 revs/min of rotating speed, with vacuum pump emulsion is sucked, added successively in order
Enter coalescents, antibacterial, ammonia, fire retardant, after stirring, thickening agent is slowly added to, reach 4 glass 40~60 of painting
Till the thick dilution of second, then filter, fill is prepared into ultrathin high-temperature-resistant thermal-insulation coating.
The seed emulsion polymerization is art methods.
Pigment of the present invention be rutile titanium dioxide, iron oxide red, iron oxide green, white carbon black, indigo one kind or
It is various.
The rare earth oxide is one or more in yttrium, cerium, praseodymium, lanthanum, neodymium, samarium oxide.
The auxiliary agent is 1~2 part of dispersant, 6~22 parts of coalescents, 1~2 part of antibacterial, 1~2 part of ammonia, thickening agent
1~12 part.
Described water is the pure water after purification.
Described hollow ceramic microspheres, hollow glass micropearl, power plant's floating bead be hollow structure that particle diameter is 10~250 μm,
Comprcssive strength height, fusing point height, light weight, it is nontoxic, do not fire, heat conductivity and Thermal Contraction Coefficient it is little, chemical stability is good, dispersibility
Height, can reduce the heat radiation that intrinsic silicon accumulation of heat is outwards produced.
The present invention mechanism be：Because rare earth element has two-orbit space, its valence state and ligancy with environment it is different and
The characteristic of change, by rare earth oxide by bead surface pore closure, forms microballon hollow, so as to improve the accumulation of heat of coating
Coefficient, reduces the heat conductivity of coating, can also increase the compactness of film forming matter, improves the stability of coating, lowers moisture content
Infiltration, improves the antiseptic property of coating, increases the service life, and effectively improves the heat storage coefficient and coating heat-resistance coefficient of matrix, from
And the temperature tolerance and heat insulating ability of raising coating, coating layer thickness is reduced, the coating for meeting 2-3 millimeters is held under 200-300 DEG C of high temperature
Kubo temperature, wherein pigment also can the effectively heat storage coefficient of coating and mid and far infrared ray absorbability.The present invention also uses hydroxyl first
Base acrylic acid amides and acrylic acid are activated monomer and the particular monomers modified self-crosslinking being prepared from seed emulsion polymerization
Type ACR, by rare earth oxide and particular monomers modified self-crosslinking type ACR collective effect,
Heat resisting temperature can be not only improved, heat conductivity is reduced, coating layer thickness is reduced, the rheological characteristic of coating is also greatly improved and is stablized
Property, be conducive to film forming and high resilience, so as to improve the cracking resistance degeneration of coating, polluting proofing property, resistance to water and weatherability extend and apply
The service life of layer.
Innovation of the invention maximum is to change traditional industry heating furnace using inorganic heat preservation coating, but using microballon with
The high-temperature-resistant thermal-insulation coating that rare earth oxide and particular monomers modified self-crosslinking type ACR are formed, using special list
It is the high fluidity of modifies self-cross linking type ACR and the heat-resistant stable of film property and rare earth oxide, low
Heat conductivity and recovery electric heating system are applied making resistant to elevated temperatures superthin layer high-temperature-resistant thermal-insulation forming resistant to elevated temperatures high resilience, ageing resistance
Material.
The ultrathin high-temperature-resistant thermal-insulation coating of the present invention has coating thin, only needs the thickness of 2~3mm, can improve heating furnace
The thermal efficiency more than 1.5%, body of heater outer surface radiation loss declines not less than 40%.；Room temperature is constructed, and 200-300 DEG C is resistant to after solidification
High temperature, and adhesive force is strong, ductility is good, antiseptic property is good, can extensive utilization to oil refining heating furnace, high-temperature medium storage tank,
The appearance such as high-temperature pipe and steel plant's heating furnace, annealing furnace, heat distribution pipeline is incubated.
Ultrathin type high-temperature-resistant thermal-insulation coating technical checking index of the invention is as shown in the table：
Above indices press GB/T9755-2001, GB/T9286-1998, GB/80502-1996 standard detection.
Heat insulation coating all technical is in prior art：Heatproof is generally less than 100 DEG C, acid resistance and alkaline-resisting
Property the time be less than 48 hours.
The present invention has advantages below relative to existing insulation material
1. the ultrathin high-temperature-resistant thermal-insulation coating of the present invention has coating thin, only needs the thickness of 2~3mm, so that it may improves and adds
The thermal efficiency of hot stove more than 1.5%；
2. the present invention is in use to the good airproof performance of matrix, and ductility is high, can effectively improve the anti-of heating furnace outer surface
Rotten function；
3. the ultrathin high-temperature-resistant thermal-insulation coating of the present invention has heatproof high, is resistant to 200-250 DEG C of high temperature, and adhesive force is strong,
Be not pulverized easily with it is aging；
4. the ultrathin high-temperature-resistant thermal-insulation coating of the present invention, produces, constructs simply, without potential safety hazard, its environmental-protecting performance
It is superior.
Specific embodiment
Embodiment 1, from the mixed of particular monomers modified self-crosslinking type ACR and pure acrylic resin emulsion
180 parts of compound（Respectively account for number 50%）, 20 parts of the iron oxide red of refractive index more than 2.0,50-100 μm of hollow ceramic microspheres 65
Part, 2 parts of cerium oxide, 25 parts of auxiliary agent（Wherein 1 part of dispersant, 15 parts of coalescents, 2 parts of antibacterial, 2 parts of ammonia, 5 parts of thickening agent）
With 200 parts of pure water, above number is weight portion, the particular monomers modified self-crosslinking type ACR hydroxyl first
Base acrylic acid acyl ammonium and acrylic acid are activated monomer and are prepared from seed emulsion polymerization.Water is first added by weight stirring
Kettle, is subsequently adding dispersant, by vacuum pump, suction pigment, filler, rotating speed（550 revs/min）Dispersed with stirring 45 minutes, system
Into slurry；Stirred tank rotating speed is adjusted to again 450 revs/min of rotating speed, with vacuum pump emulsion is sucked, film forming is sequentially added in order
Auxiliary agent, antibacterial, ammonia, fire retardant, after stirring, thickening agent are slowly added to, and reach 4 glasss of thick dilutions of 45 seconds of painting
Till, then filtration, fill is prepared into ultrathin high-temperature-resistant thermal-insulation coating.
After testing, all technical is shown in following table to coating made by embodiment 1：
Embodiment 2, from particular monomers modified self-crosslinking type ACR and Ludox（In acidity）Mixing
270 parts of thing（Wherein Ludox number accounts for 30%）, refractive index more than 2.0 iron oxide red and totally 15 parts of titanium dioxide（Respectively account for number
50%）, 100-250 μm of 55 parts of power plant's floating bead, 3 parts of cerium oxide and yittrium oxide（Wherein cerium oxide is 2 parts）, 36 parts of auxiliary agent（Wherein
2 parts of dispersant, 20 parts of coalescents, 2 parts of antibacterial, 2 parts of ammonia, 10 parts of thickening agent）With 270 parts of pure water, above number is equal
For weight portion, the particular monomers modified self-crosslinking type ACR hydroxymethylacrylate amide and acrylic acid are living
Property monomer is simultaneously prepared from seed emulsion polymerization.Water is first added by weight stirred tank, dispersant is subsequently adding, by true
Empty pump, suction pigment, filler, rotating speed（580 revs/min）Dispersed with stirring 55 minutes, makes slurry；Stirred tank rotating speed is adjusted to again
420 revs/min of rotating speed, with vacuum pump emulsion is sucked, and coalescents, antibacterial, ammonia, fire retardant are sequentially added in order,
After stirring, thickening agent is slowly added to, till reaching 4 glasss of thick dilutions of 55 seconds of painting, then filtration, fill is prepared into
Ultrathin high-temperature-resistant thermal-insulation coating.
After testing, all technical is shown in following table to coating made by embodiment 2：
Embodiment 3, from particular monomers modified self-crosslinking type ACR and pure acrylic resin emulsion and silicon
100 parts of the mixture of sour lithium（Wherein pure acrylic resin emulsion number accounts for 20%, Lithium metasilicate number and accounts for 30%）, refractive index 2.0 with
On iron oxide red and totally 28 parts of white carbon black（Respectively account for number 50%）, 100-250 μm hollow glass micropearl and 76 parts of hollow pottery microballon
（Respectively account for part 50%）, 1.5 parts of cerium oxide and lanthana（Wherein cerium oxide is 1 part）, 15 parts of auxiliary agent（Wherein 2 parts of dispersant, film forming
7 parts of auxiliary agent, 1 part of antibacterial, 2 parts of ammonia, 3 parts of thickening agent）With 120 parts of pure water, above number is weight portion, described special
Monomer modified self-cross linking type ACR hydroxymethylacrylate acyl ammonium and acrylic acid be activated monomer and with seed breast
Liquid polymerization is prepared from.Water is first added by weight stirred tank, dispersant is subsequently adding, by vacuum pump, pigment is sucked, is filled out
Material, rotating speed（580 revs/min）Dispersed with stirring 55 minutes, makes slurry；Again by stirred tank rotating speed be adjusted to 400 revs/min turn
Speed, with vacuum pump emulsion is sucked, and coalescents, antibacterial, ammonia, fire retardant are sequentially added in order, after stirring,
Thickening agent is slowly added to, till reaching 4 glasss of thick dilutions of 60 seconds of painting, then filtration, fill is prepared into ultrathin high temperature resistant and protects
Thermo-paint.
After testing, all technical is shown in following table to coating made by embodiment 3：
Claims (3)
1. a kind of ultrathin high-temperature-resistant thermal-insulation coating, is incubated for industrial high temperature heating furnace, it is characterised in that：It is by resin emulsion
70~300 parts, 10~30 parts of pigment, 50~80 parts of filler, 1~3 part of rare earth oxide, 10~40 parts of auxiliary agent and water 100~300
Part composition, the resin emulsion is particular monomers modified self-crosslinking type acrylate copolymer, pure acrylic resin emulsion and nothing
In three kinds of organic silicon compound at least two are mixed with and form, the particular monomers modified self-crosslinking type acrylate copolymer
With n-methylolacrylamide and acrylic acid it is activated monomer and is prepared from seed emulsion polymerization, the inorganic silicon compound
For Ludox or Lithium metasilicate, described filler is one or more of hollow ceramic microspheres, hollow glass micropearl or power plant's floating bead；And
It is prepared from as follows：Water is first added by weight stirred tank, dispersant is subsequently adding, by vacuum pump, suction pigment,
Filler and rare earth oxide, with 500~600 revs/min of dispersed with stirring 40~60 minutes, make slurry；Again by stirred tank rotating speed
400 revs/min of rotating speed is adjusted to, with vacuum pump emulsion is sucked, coalescents, antibacterial, ammonia, fire-retardant are sequentially added in order
Agent, after stirring, thickening agent is slowly added to, and till reaching 4 glasss of thick dilutions of 40~60 seconds of painting, is then filtered, is filled
Dress is prepared into ultrathin high-temperature-resistant thermal-insulation coating.
2. a kind of ultrathin high-temperature-resistant thermal-insulation coating according to claim 1, it is characterised in that：The pigment is rutile
Type titanium dioxide, iron oxide red, iron oxide green, white carbon black, indigo one or more.
3. a kind of ultrathin high-temperature-resistant thermal-insulation coating according to claim 1, it is characterised in that：The rare earth oxide is
One or more in yttrium, cerium, praseodymium, lanthanum, neodymium, samarium oxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410507421.3A CN104277653B (en) | 2014-09-29 | 2014-09-29 | Ultrathin high-temperature-resistant thermal-insulation paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410507421.3A CN104277653B (en) | 2014-09-29 | 2014-09-29 | Ultrathin high-temperature-resistant thermal-insulation paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104277653A CN104277653A (en) | 2015-01-14 |
| CN104277653B true CN104277653B (en) | 2017-05-17 |
Family
ID=52253018
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410507421.3A Active CN104277653B (en) | 2014-09-29 | 2014-09-29 | Ultrathin high-temperature-resistant thermal-insulation paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104277653B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113637363A (en) * | 2021-09-27 | 2021-11-12 | 天津包钢稀土研究院有限责任公司 | Cerium oxide reflective heat insulation color paste and preparation method thereof |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106010015A (en) * | 2016-07-28 | 2016-10-12 | 昆山初本电子科技有限公司 | Coating for radiation of LED (light-emitting diode) lamp |
| CN107216432B (en) * | 2017-06-27 | 2018-04-13 | 阜南县力韦包装材料有限公司 | A kind of preparation method of pressure sensitive adhesive for ultrathin double-face glue |
| CN115637084A (en) * | 2021-07-20 | 2023-01-24 | 山东鲁阳节能材料股份有限公司 | Temperature-resistant heat-insulating coating for metal surface |
| CN113831787A (en) * | 2021-09-27 | 2021-12-24 | 天津包钢稀土研究院有限责任公司 | Natural distribution lanthanum-cerium oxide reflective heat insulation color paste and preparation method thereof |
| CN118146660A (en) * | 2024-03-11 | 2024-06-07 | 中国科学院兰州化学物理研究所 | Functional high-temperature thermal protection coating with intrinsic low thermal conductivity and high emissivity |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102643074A (en) * | 2012-04-26 | 2012-08-22 | 萍乡通宇特种涂料有限公司 | Thermal-insulation ceramic and thermal-insulation ceramic coating |
| CN102850865A (en) * | 2012-09-19 | 2013-01-02 | 河南省超贝工程设备有限公司 | Environment-friendly rare-earth external wall thermal-insulation paint and preparation method thereof |
| CN102952446A (en) * | 2012-10-08 | 2013-03-06 | 江苏欣安新材料技术有限公司 | Preparation method of heat preservation insulating mold coating |
| CN103666147A (en) * | 2013-11-26 | 2014-03-26 | 北京卫星制造厂 | Reflection, radiation and blocking type external wall heat insulation coating |
| CN103740215A (en) * | 2013-12-05 | 2014-04-23 | 上海市建筑科学研究院(集团)有限公司 | High-performance architectural reflective thermal insulation coating, and preparation method and applications thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1094080A (en) * | 1993-04-16 | 1994-10-26 | 朱惠臣 | Insulating rare earth composite coatings and production technique thereof |
| CN102585698A (en) * | 2012-03-21 | 2012-07-18 | 北京国泰瑞华精藻硅特种材料有限公司 | Water-based industrial heat-proof coating |
-
2014
- 2014-09-29 CN CN201410507421.3A patent/CN104277653B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102643074A (en) * | 2012-04-26 | 2012-08-22 | 萍乡通宇特种涂料有限公司 | Thermal-insulation ceramic and thermal-insulation ceramic coating |
| CN102850865A (en) * | 2012-09-19 | 2013-01-02 | 河南省超贝工程设备有限公司 | Environment-friendly rare-earth external wall thermal-insulation paint and preparation method thereof |
| CN102952446A (en) * | 2012-10-08 | 2013-03-06 | 江苏欣安新材料技术有限公司 | Preparation method of heat preservation insulating mold coating |
| CN103666147A (en) * | 2013-11-26 | 2014-03-26 | 北京卫星制造厂 | Reflection, radiation and blocking type external wall heat insulation coating |
| CN103740215A (en) * | 2013-12-05 | 2014-04-23 | 上海市建筑科学研究院(集团)有限公司 | High-performance architectural reflective thermal insulation coating, and preparation method and applications thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113637363A (en) * | 2021-09-27 | 2021-11-12 | 天津包钢稀土研究院有限责任公司 | Cerium oxide reflective heat insulation color paste and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104277653A (en) | 2015-01-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104277653B (en) | Ultrathin high-temperature-resistant thermal-insulation paint | |
| CN103725074B (en) | A kind of high temperature resistant heat insulation coating and its preparation method and application | |
| CN102417356B (en) | Nano silicon carbide series infrared radiation paint and its preparation method | |
| CN104446325B (en) | A kind of high temperature resistant anti-Slagging ceramic coating and its preparation method and application | |
| CN103740215B (en) | A kind of high-performance building heat-reflecting insulating coating and its preparation method and application | |
| CN109504137A (en) | A kind of high temperature resistant antiwear coating material and preparation method thereof for boiler water wall | |
| CN105110766B (en) | Ceramic paint and application thereof | |
| CN103614071B (en) | A kind of pipeline outer wall organosilicon anticorrosion paint of resistance to 800 DEG C of high temperature and preparation method | |
| CN104877484B (en) | Petrochemical industry oil tank aqueous energy-saving heat-insulating thermal insulation coatings and preparation method thereof | |
| CN103864442B (en) | High emissivity high-temperature nano ceramic coating | |
| CN103740284A (en) | High temperature-resistant composite inorganic binder, as well as preparation method and application thereof | |
| CN102320806A (en) | Micronano superfine powder high-temperature high-radiance paint and preparation method thereof | |
| CN108531078A (en) | ceramic surface material and surface coating | |
| CN104710908A (en) | Special anticorrosion conductive powder coating for vertical shaft fluidized bed dip-coating as well as preparation method and application of coating | |
| CN102775863A (en) | Method for preparing anticorrosive paint for directly-buried thermal power pipeline insulating layer | |
| CN105152630A (en) | Ceramic paint and application thereof | |
| CN105174927A (en) | Anti-fouling and anti-slagging ceramic coating and preparation method | |
| CN102079948B (en) | Heat resistant, acid resistant and corrosion resistant paint used for brick desulphurization chimney and preparation method thereof | |
| CN109265181A (en) | Boiler water wall high-temperature anticorrosion dirt-resistant Anti-slagging ceramic coating | |
| CN103275531A (en) | Highly-heat-resistant liquid silicate water-based heat-insulating coating material and preparation method thereof | |
| CN108485516A (en) | ceramic surface material and surface coating | |
| CN105152631A (en) | Ceramic paint and application thereof | |
| CN104098936A (en) | Preparation method of high-emissivity energy-saving infrared radiation coating | |
| CN104293054A (en) | Ultrathin exterior wall heat insulation coating | |
| CN112028652B (en) | Super-silica powder cement composite material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180315 Address after: 337009, Muzi, Tong Xing Village, Futian Town, Shangli County, Pingxiang, Jiangxi Patentee after: Pingxiang Tongyu Special Paint Co., Ltd. Address before: 337000 No. 55, unit 5, unit 101, No. 55, No. 1, No. 55, Anyuan District, Anyuan District, Beijing Patentee before: Qian Weiqing |