CN104277506A - Antifouling agent for polished tile - Google Patents
Antifouling agent for polished tile Download PDFInfo
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- CN104277506A CN104277506A CN201310671696.6A CN201310671696A CN104277506A CN 104277506 A CN104277506 A CN 104277506A CN 201310671696 A CN201310671696 A CN 201310671696A CN 104277506 A CN104277506 A CN 104277506A
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- antifouling
- agent
- polished tile
- antifouling agent
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Abstract
The invention discloses an antifouling agent for a polished tile. The antifouling agent is prepared from the following substances in parts by weight: 5.0-5.5 parts of dodecafluoroheptyl methacrylate, 4.5-5.5 parts of gamma-methacryloyloxy propyl trimethoxysilane, 0.5-1.0 part of gamma-aminopropyl triethoxysilane, 15.5-17 parts of methyl silicone resin, 8.5-10.0 parts of polysiloxane, 0.1-0.5 part of benzoyl peroxide, 0.2-0.8 part of catalyst, 145-160 parts of solvent and 2.5-4.0 parts of curing agent. The antifouling agent for the polished tile prepared by the invention has the advantages that the cost is low, the antifouling capacity is strong, the result of the antifouling performance test is Level 5, the antifouling performance and abrasion resistance are high, the antifouling performance and durability are prominent and the antifouling agent still remains good antifouling effect after the antifouling agent is repeatedly scrubbed for more than 80 times.
Description
Technical field
The present invention relates to a kind of polished tile anti-fouling agent.
Background technology
Polished tile is the modem architectural ornament material that a class has the features such as hardness is high, intensity is large, wear resistance is good, surfacing is bright, decorative pattern enriches, imitative stone effect is true to nature.But polished tile is in the course of processing, and brick body glazed surface layer particle is damaged and weares and teares, and adds the Gibbs free energy on its surface, adsorptive power strengthens, and makes polished tile surface be very easy to hide dirty, soil pick-up, causes finished product antifouling property very poor.For this reason, need at surface-coated stain control agent.Current polished tile anti-fouling agent is mainly divided into paraffin, latex and organosilicon three class: paraffin class: generally use because it is inexpensive, but due to wax can only in surface-coated, and bad with the sticking power of base material, anti-fouling effect is undesirable, and the antifouling time is short; Latex class: price is comparatively cheap, but not scrubbing resistance, anti-fouling effect is undesirable; Silicone based: surface energy is lower, can polymeric film be formed, there is the features such as good penetrability, quick-drying, anti-fouling effect be lasting, but in grease proofness spot poor performance.
Summary of the invention
In order to overcome above shortcoming, the invention provides a kind of polished tile anti-fouling agent.
A kind of polished tile anti-fouling agent, is prepared from by the material of following parts by weight:
Dodecafluoroheptyl methacrylate 5.0-5.5 part;
γ-methacryloxypropyl trimethoxy silane 4.5-5.5 part;
γ-aminopropyl triethoxysilane 0.5-1.0 part;
Methyl silicon resin 15.5-17 part;
Polysiloxane 8.5-10.0 part;
Benzoyl peroxide 0.1-0.5 part;
Catalyzer 0.2-0.8 part;
Solvent 145-160 part;
Solidifying agent 2.5-4.0 part
Preferably, described catalyzer is ammoniacal liquor or sodium hydroxide.
Preferably, described solvent is sherwood oil or ether.
Preferably, described solidifying agent is diethyl amino propylamine or dipropylenetriamine.
Antifouling property is tested: selected polished tile sample (10 cm × 10 cm) surface cleaning is clean, then (110
5) be dried to constant weight in baking oven DEG C, and be cooled to room temperature.Drip 5g stain control agent in brick surface, smear evenly with gauze, after room temperature places 48h, by GB/T3810.14-1999, start the test of antifouling property, red ink paste is spread upon polished tile surface, after 24 h, by prescriptive procedure cleaning, its stain resistance rank is determined in the change in range estimation brick face, eye distance brick face 25-30 cm, light is fluorescent lamp.First, be (55 by temperature
5) hot water cleaning DEG C, washing is 5 grades; If can't be washed off clearly, clean with the weak clean-out system (commercial reagents) of pH=6.5-7.5, washing off is 4 grades; If can't be washed off, clean with the strong clean-out system (commercial reagents) of pH=9-10, washing off is 3 grades; If can't be washed off, by hydrochloric acid soln or potassium hydroxide solution or other solvent cleaning, washing is 2 grades; It is 1 grade that any method can't is washed off all clearly
Advantage of the present invention is:
The polished tile anti-fouling agent cost that the present invention obtains is low, and stain resistance is strong, and antifouling property test result is 5 grades, antifouling property and wear resistance high, anti-soil endurance quality is given prominence to, and repeats to scrub the anti-fouling effect still keeping good more than 80 times.
embodiment
Embodiment 1
Prepare the material of following parts by weight:
Dodecafluoroheptyl methacrylate 5.0 parts;
γ-methacryloxypropyl trimethoxy silane 4.5 parts;
γ-aminopropyl triethoxysilane 0.5 part;
Methyl silicon resin 15.5 parts;
Polysiloxane 8.5 parts;
Benzoyl peroxide 0.1 part;
Ammoniacal liquor 0.2 part;
Sherwood oil 145 parts;
Diethyl amino propylamine 2.5 parts
Carry out antifouling property test after obtained stain control agent, result display antifouling capacity is 5 grades.
Embodiment 2
Prepare the material of following parts by weight:
Dodecafluoroheptyl methacrylate 5.3 parts;
γ-methacryloxypropyl trimethoxy silane 5.0 parts;
γ-aminopropyl triethoxysilane 0.8 part;
Methyl silicon resin 16.3 parts;
Polysiloxane 9.2 parts;
Benzoyl peroxide 0.3 part;
Ammoniacal liquor 0.5 part;
Sherwood oil 155 parts;
Diethyl amino propylamine 3.0 parts
Carry out antifouling property test after obtained stain control agent, result display antifouling capacity is 5 grades.
Embodiment 3
Prepare the material of following parts by weight:
Dodecafluoroheptyl methacrylate 5.5 parts;
γ-methacryloxypropyl trimethoxy silane 5.5 parts;
γ-aminopropyl triethoxysilane 1.0 parts;
Methyl silicon resin 17 parts;
Polysiloxane 10.0 parts;
Benzoyl peroxide 0.5 part;
Ammoniacal liquor 0.8 part;
Sherwood oil 160 parts;
Diethyl amino propylamine 4.0 parts
Carry out antifouling property test after obtained stain control agent, result display antifouling capacity is 5 grades.
Last it is noted that above embodiment only in order to illustrate the present invention and and unrestricted technical scheme described in the invention; Therefore, although this specification sheets with reference to each above-mentioned embodiment to present invention has been detailed description, those of ordinary skill in the art should be appreciated that and still can modify to the present invention or equivalent to replace; And all do not depart from technical scheme and the improvement thereof of invention spirit and scope, it all should be encompassed in the middle of right of the present invention.
Claims (4)
1. a polished tile anti-fouling agent, is characterized in that: be prepared from by the material of following parts by weight:
Dodecafluoroheptyl methacrylate 5.0-5.5 part;
γ-methacryloxypropyl trimethoxy silane 4.5-5.5 part;
γ-aminopropyl triethoxysilane 0.5-1.0 part;
Methyl silicon resin 15.5-17 part;
Polysiloxane 8.5-10.0 part;
Benzoyl peroxide 0.1-0.5 part;
Catalyzer 0.2-0.8 part;
Solvent 145-160 part;
Solidifying agent 2.5-4.0 part.
2. stain control agent according to claim 1, is characterized in that: described catalyzer is ammoniacal liquor or sodium hydroxide.
3. stain control agent according to claim 1, is characterized in that: described solvent is sherwood oil or ether.
4. stain control agent according to claim 1, is characterized in that: described solidifying agent is diethyl amino propylamine or dipropylenetriamine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310671696.6A CN104277506A (en) | 2013-12-12 | 2013-12-12 | Antifouling agent for polished tile |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310671696.6A CN104277506A (en) | 2013-12-12 | 2013-12-12 | Antifouling agent for polished tile |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104277506A true CN104277506A (en) | 2015-01-14 |
Family
ID=52252874
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310671696.6A Pending CN104277506A (en) | 2013-12-12 | 2013-12-12 | Antifouling agent for polished tile |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104277506A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107936640A (en) * | 2017-12-23 | 2018-04-20 | 安徽国电能源设备工程有限公司 | A kind of preparation method of resistant hot water storage tank |
| CN115594851A (en) * | 2022-10-31 | 2023-01-13 | 华南理工大学（Cn） | Reactive amphiphilic additive and preparation method and application thereof |
Citations (5)
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|---|---|---|---|---|
| CN102212312A (en) * | 2011-04-07 | 2011-10-12 | 高建宾 | Ultraviolet light solidified antistatic organosilicon separant |
| CN102618165A (en) * | 2012-03-20 | 2012-08-01 | 中国科学院金属研究所 | Nanometer polysiloxane nontoxic low-surface-energy ship antifouling coating and preparation method thereof |
| CN102702975A (en) * | 2012-06-12 | 2012-10-03 | 天长市巨龙车船涂料有限公司 | Antifouling paint composition, antifouling coating as well as ship and underwater structure body |
| CN102786841A (en) * | 2012-08-24 | 2012-11-21 | 苏州金海薄膜科技发展有限公司 | Scratch-resistant and stain-repellent ink and preparation method thereof |
| KR101251066B1 (en) * | 2012-11-09 | 2013-04-05 | (주)새론테크 | Paint composition having excellent fouling resistance and anti-fouling, and method using the same |
-
2013
- 2013-12-12 CN CN201310671696.6A patent/CN104277506A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102212312A (en) * | 2011-04-07 | 2011-10-12 | 高建宾 | Ultraviolet light solidified antistatic organosilicon separant |
| CN102618165A (en) * | 2012-03-20 | 2012-08-01 | 中国科学院金属研究所 | Nanometer polysiloxane nontoxic low-surface-energy ship antifouling coating and preparation method thereof |
| CN102702975A (en) * | 2012-06-12 | 2012-10-03 | 天长市巨龙车船涂料有限公司 | Antifouling paint composition, antifouling coating as well as ship and underwater structure body |
| CN102786841A (en) * | 2012-08-24 | 2012-11-21 | 苏州金海薄膜科技发展有限公司 | Scratch-resistant and stain-repellent ink and preparation method thereof |
| KR101251066B1 (en) * | 2012-11-09 | 2013-04-05 | (주)새론테크 | Paint composition having excellent fouling resistance and anti-fouling, and method using the same |
Non-Patent Citations (3)
| Title |
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| 宋丽艳等: "有机硅透明树脂的研制", 《江西化工》 * |
| 沈一丁等: "氟硅防污剂的合成、复配及其作用机理研究", 《精细化工》 * |
| 沈春林: "《化学建材原材料手册》", 31 August 2008, 北京：中国标准出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107936640A (en) * | 2017-12-23 | 2018-04-20 | 安徽国电能源设备工程有限公司 | A kind of preparation method of resistant hot water storage tank |
| CN115594851A (en) * | 2022-10-31 | 2023-01-13 | 华南理工大学（Cn） | Reactive amphiphilic additive and preparation method and application thereof |
| CN115594851B (en) * | 2022-10-31 | 2024-02-13 | 华南理工大学 | Reactive amphiphilic additive and preparation method and application thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150114 |