CN104277357A - Antibacterial PVC foaming sole material and manufacturing method thereof - Google Patents
Antibacterial PVC foaming sole material and manufacturing method thereof Download PDFInfo
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- CN104277357A CN104277357A CN201410449088.5A CN201410449088A CN104277357A CN 104277357 A CN104277357 A CN 104277357A CN 201410449088 A CN201410449088 A CN 201410449088A CN 104277357 A CN104277357 A CN 104277357A
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- sole
- foam material
- pvc foam
- antibacterial pvc
- sheet stock
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/102—Azo-compounds
- C08J9/103—Azodicarbonamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention provides an antibacterial PVC foaming sole material. The antibacterial PVC foaming sole material is prepared from the following components in parts by weight: 40-60 parts of PVC, 5-10 parts of nano titanium dioxide, 20-40 parts of plasticizer, 1-5 parts of foaming agent, 0.1-3 parts of coupling agent, 2-5 parts of ACR, 1-3 parts of stabilizer and 0.1-2 parts of lubricant. The invention also discloses a manufacturing method of the antibacterial PVC foaming sole material. The PVC foaming sole material is excellent in antibacterial property and capable of effectively removing peculiar smell and bacteria out of shoes.
Description
Technical field:
The present invention relates to a kind of material for sole of shoe, particularly relate to a kind of antibacterial PVC foam material for sole of shoe and manufacture method thereof.
Background technology:
Peculiar smell in footwear, bacterium are the difficult problems perplexing people for a long time, and wherein, perspiring not easily distributes in footwear, causes bacterial reproduction, produce stink, form vicious cycle, even cause the generation of beriberi under the secretory product of the human sweat glands bacterial degradation in footwear.Beriberi not only affects the routine work life and work of self, but also can be transmitted to other people hidden danger.Existing material for sole of shoe mainly with for the purpose of raising comfort level, wear resisting property etc., seldom has the material for peculiar smell problem of bacteria in footwear greatly.
Summary of the invention:
The technical problem to be solved in the present invention is to provide a kind of antibacterial PVC foam material for sole of shoe, and its anti-microbial property is fine, effectively can remove peculiar smell and bacterium in footwear.
For solving the problems of the technologies described above, technical scheme of the present invention is:
An antibacterial PVC foam material for sole of shoe, its weight part consists of:
Preferably, softening agent of the present invention is dibenzyl sebacate, dioctyl sebacate or Octyl adipate.
Preferably, whipping agent of the present invention is AC whipping agent.
Preferably, coupling agent of the present invention is silane coupling agent.
Preferably, stablizer of the present invention is organic tin stablizer or complex lead salt stabilizer.
Preferably, lubricant of the present invention is oxidic polyethylene or fatty acid metal soap series lubricant agent.
Another technical problem that the present invention will solve is to provide the manufacture method of above-mentioned antibacterial PVC foam material for sole of shoe.
For solving the problems of the technologies described above, technical scheme is:
A manufacture method for antibacterial PVC foam material for sole of shoe, comprises the following steps:
(1) nano titanium oxide is configured to the suspension of 50g/l, regulates ph value to 4 with acetum, ultrasonic disperse 1 hour, add coupling agent, react 4 hours under the condition of high-speed stirring, filter, wash, at 100 DEG C, drying 10 hours, obtains modified nano-titanium dioxide after pulverizing;
(2) modified nano-titanium dioxide that other components and step (1) obtain is added kneader heating to mediate, mediate discharging after 2 hours;
(3) the complete compound of kneading is added twin-roll plastic mixing mill to plasticate pulling-on piece, plasticating temperature is 110 DEG C, obtains sheet stock;
(4) sheet stock is sent into thermocompressor heating plasticizing, foaming, cooling and shaping after foaming, obtains blank after the demoulding;
(5) blank to be sent in drying room foamable 40 minutes, temperature is 130 DEG C, and after obtaining foaming sheet stock, a few days is placed in cooling;
(6) foaming sheet stock stamping-out step (5) obtained is shaping, obtains antibacterial PVC foam material for sole of shoe.
Therefore compared with prior art, the present invention has following beneficial effect:
Nano titanium oxide is by its quantum size effect, produce electronics, hole pair, attack bacteria organism, play germicidal action, under action of ultraviolet radiation, bactericidal property is better, be a kind of antiseptic-germicide of permanent maintenance antibacterial effect, therefore the PVC foam material for sole of shoe adding nano titanium oxide has also possessed good anti-microbial property; Nano titanium oxide surfaces hydrophilic, be difficult to be dispersed in PVC matrix, therefore the present invention carries out surface modification by coupling agent to it, improves the hydrophobicity on its surface and the consistency in PVC matrix and dispersiveness, more can give full play to its anti-microbial property.
Embodiment:
Describe the present invention in detail below in conjunction with specific embodiment, be used for explaining the present invention in this illustrative examples of the present invention and explanation, but not as a limitation of the invention.
Embodiment 1
An antibacterial PVC foam material for sole of shoe, its weight part consists of:
Its manufacture method comprises the following steps:
(1) nano titanium oxide is configured to the suspension of 50g/l, regulates ph value to 4 with acetum, ultrasonic disperse 1 hour, add coupling agent, react 4 hours under the condition of high-speed stirring, filter, wash, at 100 DEG C, drying 10 hours, obtains modified nano-titanium dioxide after pulverizing;
(2) modified nano-titanium dioxide that other components and step (1) obtain is added kneader heating to mediate, mediate discharging after 2 hours;
(3) the complete compound of kneading is added twin-roll plastic mixing mill to plasticate pulling-on piece, plasticating temperature is 110 DEG C, obtains sheet stock;
(4) sheet stock is sent into thermocompressor heating plasticizing, foaming, cooling and shaping after foaming, obtains blank after the demoulding;
(5) blank to be sent in drying room foamable 40 minutes, temperature is 130 DEG C, and after obtaining foaming sheet stock, a few days is placed in cooling;
(6) foaming sheet stock stamping-out step (5) obtained is shaping, obtains antibacterial PVC foam material for sole of shoe.
Embodiment 2
An antibacterial PVC foam material for sole of shoe, its weight part consists of:
Its manufacture method comprises the following steps:
(1) nano titanium oxide is configured to the suspension of 50g/l, regulates ph value to 4 with acetum, ultrasonic disperse 1 hour, add coupling agent, react 4 hours under the condition of high-speed stirring, filter, wash, at 100 DEG C, drying 10 hours, obtains modified nano-titanium dioxide after pulverizing;
(2) modified nano-titanium dioxide that other components and step (1) obtain is added kneader heating to mediate, mediate discharging after 2 hours;
(3) the complete compound of kneading is added twin-roll plastic mixing mill to plasticate pulling-on piece, plasticating temperature is 110 DEG C, obtains sheet stock;
(4) sheet stock is sent into thermocompressor heating plasticizing, foaming, cooling and shaping after foaming, obtains blank after the demoulding;
(5) blank to be sent in drying room foamable 40 minutes, temperature is 130 DEG C, and after obtaining foaming sheet stock, a few days is placed in cooling;
(6) foaming sheet stock stamping-out step (5) obtained is shaping, obtains antibacterial PVC foam material for sole of shoe.
Embodiment 3
An antibacterial PVC foam material for sole of shoe, its weight part consists of:
Its manufacture method comprises the following steps:
(1) nano titanium oxide is configured to the suspension of 50g/l, regulates ph value to 4 with acetum, ultrasonic disperse 1 hour, add coupling agent, react 4 hours under the condition of high-speed stirring, filter, wash, at 100 DEG C, drying 10 hours, obtains modified nano-titanium dioxide after pulverizing;
(2) modified nano-titanium dioxide that other components and step (1) obtain is added kneader heating to mediate, mediate discharging after 2 hours;
(3) the complete compound of kneading is added twin-roll plastic mixing mill to plasticate pulling-on piece, plasticating temperature is 110 DEG C, obtains sheet stock;
(4) sheet stock is sent into thermocompressor heating plasticizing, foaming, cooling and shaping after foaming, obtains blank after the demoulding;
(5) blank to be sent in drying room foamable 40 minutes, temperature is 130 DEG C, and after obtaining foaming sheet stock, a few days is placed in cooling;
(6) foaming sheet stock stamping-out step (5) obtained is shaping, obtains antibacterial PVC foam material for sole of shoe.
Embodiment 4
An antibacterial PVC foam material for sole of shoe, its weight part consists of:
Its manufacture method comprises the following steps:
(1) nano titanium oxide is configured to the suspension of 50g/l, regulates ph value to 4 with acetum, ultrasonic disperse 1 hour, add coupling agent, react 4 hours under the condition of high-speed stirring, filter, wash, at 100 DEG C, drying 10 hours, obtains modified nano-titanium dioxide after pulverizing;
(2) modified nano-titanium dioxide that other components and step (1) obtain is added kneader heating to mediate, mediate discharging after 2 hours;
(3) the complete compound of kneading is added twin-roll plastic mixing mill to plasticate pulling-on piece, plasticating temperature is 110 DEG C, obtains sheet stock;
(4) sheet stock is sent into thermocompressor heating plasticizing, foaming, cooling and shaping after foaming, obtains blank after the demoulding;
(5) blank to be sent in drying room foamable 40 minutes, temperature is 130 DEG C, and after obtaining foaming sheet stock, a few days is placed in cooling;
(6) foaming sheet stock stamping-out step (5) obtained is shaping, obtains antibacterial PVC foam material for sole of shoe.
Embodiment 5
An antibacterial PVC foam material for sole of shoe, its weight part consists of:
Its manufacture method comprises the following steps:
(1) nano titanium oxide is configured to the suspension of 50g/l, regulates ph value to 4 with acetum, ultrasonic disperse 1 hour, add coupling agent, react 4 hours under the condition of high-speed stirring, filter, wash, at 100 DEG C, drying 10 hours, obtains modified nano-titanium dioxide after pulverizing;
(2) modified nano-titanium dioxide that other components and step (1) obtain is added kneader heating to mediate, mediate discharging after 2 hours;
(3) the complete compound of kneading is added twin-roll plastic mixing mill to plasticate pulling-on piece, plasticating temperature is 110 DEG C, obtains sheet stock;
(4) sheet stock is sent into thermocompressor heating plasticizing, foaming, cooling and shaping after foaming, obtains blank after the demoulding;
(5) blank to be sent in drying room foamable 40 minutes, temperature is 130 DEG C, and after obtaining foaming sheet stock, a few days is placed in cooling;
(6) foaming sheet stock stamping-out step (5) obtained is shaping, obtains antibacterial PVC foam material for sole of shoe.
Embodiment 6
An antibacterial PVC foam material for sole of shoe, its weight part consists of:
Its manufacture method comprises the following steps:
(1) nano titanium oxide is configured to the suspension of 50g/l, regulates ph value to 4 with acetum, ultrasonic disperse 1 hour, add coupling agent, react 4 hours under the condition of high-speed stirring, filter, wash, at 100 DEG C, drying 10 hours, obtains modified nano-titanium dioxide after pulverizing;
(2) modified nano-titanium dioxide that other components and step (1) obtain is added kneader heating to mediate, mediate discharging after 2 hours;
(3) the complete compound of kneading is added twin-roll plastic mixing mill to plasticate pulling-on piece, plasticating temperature is 110 DEG C, obtains sheet stock;
(4) sheet stock is sent into thermocompressor heating plasticizing, foaming, cooling and shaping after foaming, obtains blank after the demoulding;
(5) blank to be sent in drying room foamable 40 minutes, temperature is 130 DEG C, and after obtaining foaming sheet stock, a few days is placed in cooling;
(6) foaming sheet stock stamping-out step (5) obtained is shaping, obtains antibacterial PVC foam material for sole of shoe.
Above-described embodiment is illustrative principle of the present invention and effect thereof only, but not for limiting the present invention.Any person skilled in the art scholar all without prejudice under spirit of the present invention and category, can modify above-described embodiment or changes.Therefore, such as have in art usually know the knowledgeable do not depart from complete under disclosed spirit and technological thought all equivalence modify or change, must be contained by claim of the present invention.
Claims (7)
1. an antibacterial PVC foam material for sole of shoe, is characterized in that: its weight part consists of:
2. a kind of antibacterial PVC foam material for sole of shoe according to claim 1, is characterized in that: described softening agent is dibenzyl sebacate, dioctyl sebacate or Octyl adipate.
3. a kind of antibacterial PVC foam material for sole of shoe according to claim 1, is characterized in that: described whipping agent is AC whipping agent.
4. a kind of antibacterial PVC foam material for sole of shoe according to claim 1, is characterized in that: described coupling agent is silane coupling agent.
5. a kind of antibacterial PVC foam material for sole of shoe according to claim 1, is characterized in that: described stablizer is organic tin stablizer or complex lead salt stabilizer.
6. a kind of antibacterial PVC foam material for sole of shoe according to claim 1, is characterized in that: described lubricant is oxidic polyethylene or fatty acid metal soap series lubricant agent.
7. the manufacture method of a kind of antibacterial PVC foam material for sole of shoe according to claim 1 ~ 6 any one, is characterized in that: comprise the following steps:
(1) nano titanium oxide is configured to the suspension of 50g/l, regulates ph value to 4 with acetum, ultrasonic disperse 1 hour, add coupling agent, react 4 hours under the condition of high-speed stirring, filter, wash, at 100 DEG C, drying 10 hours, obtains modified nano-titanium dioxide after pulverizing;
(2) modified nano-titanium dioxide that other components and step (1) obtain is added kneader heating to mediate, mediate discharging after 2 hours;
(3) the complete compound of kneading is added twin-roll plastic mixing mill to plasticate pulling-on piece, plasticating temperature is 110 DEG C, obtains sheet stock;
(4) sheet stock is sent into thermocompressor heating plasticizing, foaming, cooling and shaping after foaming, obtains blank after the demoulding;
(5) blank to be sent in drying room foamable 40 minutes, temperature is 130 DEG C, and after obtaining foaming sheet stock, a few days is placed in cooling;
(6) foaming sheet stock stamping-out step (5) obtained is shaping, obtains antibacterial PVC foam material for sole of shoe.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410449088.5A CN104277357A (en) | 2014-09-04 | 2014-09-04 | Antibacterial PVC foaming sole material and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410449088.5A CN104277357A (en) | 2014-09-04 | 2014-09-04 | Antibacterial PVC foaming sole material and manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104277357A true CN104277357A (en) | 2015-01-14 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410449088.5A Pending CN104277357A (en) | 2014-09-04 | 2014-09-04 | Antibacterial PVC foaming sole material and manufacturing method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104672718A (en) * | 2015-03-09 | 2015-06-03 | 苏州市景荣科技有限公司 | Heat-resistant PVC shoe material and preparation method thereof |
| CN105124860A (en) * | 2015-07-28 | 2015-12-09 | 苏州市相城区明达复合材料厂 | Antibacterial rubber sole |
| CN105542357A (en) * | 2016-03-07 | 2016-05-04 | 太仓市晨洲塑业有限公司 | Multifunctional PVC (polyvinyl chloride) |
| CN107245202A (en) * | 2017-06-28 | 2017-10-13 | 湖南凯誉电气科技有限公司 | Antimicrobial polyvinyl chloride plastic and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2108352C1 (en) * | 1993-03-26 | 1998-04-10 | Татарский технологический научный центр КГТУ при кабинете Министров Республики Татарстан | Polyvinyl chloride composition |
| RU2295549C1 (en) * | 2006-01-10 | 2007-03-20 | Государственное образовательное учреждение высшего профессионального образования Волгоградский государственный технический университет (ВолгГТУ) | Polymeric composition for articles |
| CN103289234A (en) * | 2013-05-31 | 2013-09-11 | 苏州市景荣科技有限公司 | Production method for nano antimicrobial silylated polyurethane (SPU) shoe sole |
| CN103289246A (en) * | 2013-06-21 | 2013-09-11 | 苏州市景荣科技有限公司 | Fire retardation PVC foaming sole material |
-
2014
- 2014-09-04 CN CN201410449088.5A patent/CN104277357A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2108352C1 (en) * | 1993-03-26 | 1998-04-10 | Татарский технологический научный центр КГТУ при кабинете Министров Республики Татарстан | Polyvinyl chloride composition |
| RU2295549C1 (en) * | 2006-01-10 | 2007-03-20 | Государственное образовательное учреждение высшего профессионального образования Волгоградский государственный технический университет (ВолгГТУ) | Polymeric composition for articles |
| CN103289234A (en) * | 2013-05-31 | 2013-09-11 | 苏州市景荣科技有限公司 | Production method for nano antimicrobial silylated polyurethane (SPU) shoe sole |
| CN103289246A (en) * | 2013-06-21 | 2013-09-11 | 苏州市景荣科技有限公司 | Fire retardation PVC foaming sole material |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104672718A (en) * | 2015-03-09 | 2015-06-03 | 苏州市景荣科技有限公司 | Heat-resistant PVC shoe material and preparation method thereof |
| CN105124860A (en) * | 2015-07-28 | 2015-12-09 | 苏州市相城区明达复合材料厂 | Antibacterial rubber sole |
| CN105542357A (en) * | 2016-03-07 | 2016-05-04 | 太仓市晨洲塑业有限公司 | Multifunctional PVC (polyvinyl chloride) |
| CN107245202A (en) * | 2017-06-28 | 2017-10-13 | 湖南凯誉电气科技有限公司 | Antimicrobial polyvinyl chloride plastic and preparation method thereof |
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