CN104262718B - A kind of high oil resistant accumulator capsule glue - Google Patents

A kind of high oil resistant accumulator capsule glue Download PDF

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Publication number
CN104262718B
CN104262718B CN201410456680.8A CN201410456680A CN104262718B CN 104262718 B CN104262718 B CN 104262718B CN 201410456680 A CN201410456680 A CN 201410456680A CN 104262718 B CN104262718 B CN 104262718B
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China
Prior art keywords
capsule glue
accumulator
good
oil
glue
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CN201410456680.8A
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CN104262718A (en
Inventor
李善荣
周胜
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Chemchina Shuguang Rubber Industry Research and Design Institute Co Ltd
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Chemchina Shuguang Rubber Industry Research and Design Institute Co Ltd
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Abstract

The invention discloses a kind of high oil resistant accumulator capsule glue.This sizing material is with neoprene as main material, the most formulated with adjuvants such as nitrile rubber, soft carbon and sulfuration resistant reducing agents.Make accumulator capsule glue have good oil resistivity by adding nitrile rubber, add sulfuration resistant reducing agent and sizing material can be made to have good heat stability.Compared with prior art, aircraft accumulator capsule glue of the present invention has that hot strength is high, flex fatigue life is good, Heat stability is good and the advantage such as resistance to oil swell is stable.Using the accumulator of this capsule glue, its oil resistant swellability is good, and service life is long.

Description

A kind of high oil resistant accumulator capsule glue
Technical field
The present invention relates to accumulator capsule glue, be specifically related to high oil resistivity accumulator capsule glue.
Background technology
Accumulator is mounted in a significant components in plane hydraulic system voltage supply oil circuit.Its function is effectively to extend oil The lotus time of pump and the conversion times of unloader, extend working life, and guarantee that system working pressure is steady, prevent pressure arteries and veins Dynamic excessive, ensure that each executive component of brake system normally works.Additionally, under the case of emergency such as oil pump fault or conduit failure, Accumulator can utilize its hydraulic oil stored to brake for locomotive wheel, open and close front deck emergency hatch and the out of order electromotor of manipulation Carry out spiral feathering and engine cut-off.Therefore, accumulator plays most important effect in plane hydraulic system.If pressure accumulation Device lost efficacy, and can increase the conversion times of unloader and the working time of oil pump, shorten both working lives, and make in system Oil temperature significantly improves, and hydraulic pulsation strengthens, and affects each executive component and normally works, the most directly threatens flight safety.But, fly The most generally there is the problem leaked outside with internal hemorrhage due to trauma in machine accumulator, directly affects the use function of accumulator.Cause this problem Main cause is that hydraulic oil has swelling and be full of cracks effect to the elastomeric material of accumulator capsule so that it is pressure performance reduces, and And during using, oil temperature raises, and also can accelerate the aging of material.The elastomeric material research of current domestic resistance to aircraft fluid is also Immature, the existing resistance to aircraft fluid of accumulator capsule and durability all do not reach the design requirement of type aircraft.Therefore anxious A kind of elastomeric material with excellent resistance to aircraft fluid need to be developed, to fill up the vacancy of domestic technique, meet the need produced Want.
Summary of the invention
The invention aims to disclose a kind of high oil resistant accumulator capsule glue, this sizing material has excellent resistance to aviation oil soluble Swollen property and thermal ageing resistant performance, it is possible to ensure the use safety of capsule and extend its service life.
Height oil resistant accumulator capsule glue of the present invention, is divided two-stage nitration to carry out mixing system by the raw material of following weight parts ratio through banbury Become:
Neoprene 60 ~ 90
Nitrile rubber 10 ~ 40
Activating agent 4 ~ 10
Age resistor 2 ~ 6
Soft carbon 20 ~ 60
Vulcanizing agent 0.5 ~ 2
Accelerator 0.2 ~ 1
Protection wax 1 ~ 5
Plasticizer 8 ~ 15
Neoprene described in formula is CR322;Nitrile rubber is NBR1704;Activating agent is zinc oxide and magnesium oxide; Age resistor is age resistor IPPD and anti-aging agent RD, and wherein age resistor IPPD is N-isopropyl-N-diphenyl-para-phenylene diamine;Age resistor RD is 2,2,4-trimethyl-1,2-dihyaroquinoline polymer;Soft carbon is natural gas semi-reinforcing hydrocarbon black;Vulcanizing agent is sulfur And stearic acid;Accelerator is Vulcanization accelerator TMTD and altax;Protection wax is Rhein wax;Plasticizer is SA dioctyl ester.
The accumulator capsule glue of the present invention utilizes has high tensile strength, percentage elongation and reversible crystalline neoprene For material of main part.Meanwhile, for obtaining more preferable oil resistance, and a small amount of nitrile rubber has been used.Old in order to improve the heat of capsule Change performance, with the use of age resistor IPPD and anti-aging agent RD two class age resistor in formula.
This sizing material is for the test of accumulator capsule, and end properties is good, has passed through oil resistant swell test.Properties of rubber model Enclose such as table 1 below:
Table 1: properties of rubber
Project Performance
Conditions of vulcanization 151 oC×50´
Hardness, Shao Er A type 65±5
Hot strength, MPa ≥15
Elongation at break, % ≥600
Setafter break, % ≤15
Density, Mg/m3 1.32
Volume sweell(ing) rate, % (70oC × 168h, hydraulic engine oil) ≤15
Elongation change, % (100 is pulled apart after agingoC×48h) ≥-30
It is an advantage of the current invention that: the oil resistance of sizing material and thermal ageing resistant performance are excellent, solve current aircraft pressure accumulation Device capsule oil resistant swellability is poor, causes the problems such as accumulator gas leak phenomenon, extends the service life of accumulator capsule, ensures and stores The use safety of depressor.
Detailed description of the invention
Describe 1 embodiment of the present invention below, present invention is further elaborated, but present disclosure is complete Entirely it is not limited to this.
Embodiment:
A kind of high oil resistant accumulator capsule glue, is carried out mixing by the raw material of following weight parts proportioning point two-stage nitration in banbury Form:
Neoprene 80
Nitrile rubber 20
Zinc oxide 5
Magnesium oxide 4
Age resistor IPPD 2
Anti-aging agent RD 1
Semi-reinforcing hydrocarbon black 40
Stearic acid 1
Sulfur 0.5
Accelerant CZ 1
Vulcanization accelerator TMTD 0.5
Captax 0.3
Rhein wax 2
SA dioctyl ester 10.

Claims (2)

1. a high oil resistant accumulator capsule glue, is characterized in that: divided two-stage nitration to carry out by the raw material of following weight parts ratio through banbury Mixing make:
Neoprene CR322 60 ~ 90
Nitrile rubber NBR1704 10 ~ 40
Activating agent: zinc oxide and magnesium oxide 4 ~ 10
Age resistor 2 ~ 6
Natural gas semi-reinforcing hydrocarbon black 20 ~ 60
Vulcanizing agent: sulfur and stearic acid 0.5 ~ 2
Accelerator: TMTD and DM 0.2 ~ 1
Protection wax: Rhein wax 1 ~ 5
Plasticizer: SA dioctyl ester 8 ~ 15.
Capsule glue the most according to claim 1, is characterized in that: described age resistor is age resistor IPPD and anti-aging agent RD.
CN201410456680.8A 2014-09-10 2014-09-10 A kind of high oil resistant accumulator capsule glue Active CN104262718B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410456680.8A CN104262718B (en) 2014-09-10 2014-09-10 A kind of high oil resistant accumulator capsule glue

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410456680.8A CN104262718B (en) 2014-09-10 2014-09-10 A kind of high oil resistant accumulator capsule glue

Publications (2)

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CN104262718A CN104262718A (en) 2015-01-07
CN104262718B true CN104262718B (en) 2016-08-24

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Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105037845A (en) * 2015-09-11 2015-11-11 中国化工集团曙光橡胶工业研究设计院有限公司 High-oil-resistance conducting sealant
CN107189143A (en) * 2017-06-07 2017-09-22 浙江宏利汽车零部件有限公司 A kind of compounding rubber of oil-resisting type
CN111286098A (en) * 2018-12-10 2020-06-16 浙江峻和橡胶科技有限公司 Neoprene composition with good processability

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101747537A (en) * 2009-12-30 2010-06-23 中国化工橡胶桂林有限公司 Trend rubber for helicopter tires
CN101955603A (en) * 2010-10-28 2011-01-26 中橡集团曙光橡胶工业研究设计院 Heat cold and oil-resistant sizing material
CN103012887A (en) * 2012-11-30 2013-04-03 西安致泰橡塑工业有限公司 Low-expansion rate industrial oil-resistant rubber slab

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101747537A (en) * 2009-12-30 2010-06-23 中国化工橡胶桂林有限公司 Trend rubber for helicopter tires
CN101955603A (en) * 2010-10-28 2011-01-26 中橡集团曙光橡胶工业研究设计院 Heat cold and oil-resistant sizing material
CN103012887A (en) * 2012-11-30 2013-04-03 西安致泰橡塑工业有限公司 Low-expansion rate industrial oil-resistant rubber slab

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