CN104259157B - The preparation method of gel composite tube cleaner and cross-linked polyacrylamide aqueous gel - Google Patents

The preparation method of gel composite tube cleaner and cross-linked polyacrylamide aqueous gel Download PDF

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Publication number
CN104259157B
CN104259157B CN201410399770.8A CN201410399770A CN104259157B CN 104259157 B CN104259157 B CN 104259157B CN 201410399770 A CN201410399770 A CN 201410399770A CN 104259157 B CN104259157 B CN 104259157B
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China
Prior art keywords
gel
tube cleaner
cross
composite tube
hpam
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CN201410399770.8A
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Chinese (zh)
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CN104259157A (en
Inventor
程磊
杨法杰
郭海峰
张志恒
李国平
常维纯
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China Oil and Gas Pipeline Network Corp
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China Petroleum and Natural Gas Co Ltd
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Priority to CN201410399770.8A priority Critical patent/CN104259157B/en
Publication of CN104259157A publication Critical patent/CN104259157A/en
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B9/00Cleaning hollow articles by methods or apparatus specially adapted thereto 
    • B08B9/02Cleaning pipes or tubes or systems of pipes or tubes
    • B08B9/027Cleaning the internal surfaces; Removal of blockages
    • B08B9/04Cleaning the internal surfaces; Removal of blockages using cleaning devices introduced into and moved along the pipes
    • B08B9/053Cleaning the internal surfaces; Removal of blockages using cleaning devices introduced into and moved along the pipes moved along the pipes by a fluid, e.g. by fluid pressure or by suction
    • B08B9/055Cleaning the internal surfaces; Removal of blockages using cleaning devices introduced into and moved along the pipes moved along the pipes by a fluid, e.g. by fluid pressure or by suction the cleaning devices conforming to, or being conformable to, substantially the same cross-section of the pipes, e.g. pigs or moles
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L55/00Devices or appurtenances for use in, or in connection with, pipes or pipe systems
    • F16L55/26Pigs or moles, i.e. devices movable in a pipe or conduit with or without self-contained propulsion means
    • F16L55/28Constructional aspects
    • F16L55/30Constructional aspects of the propulsion means, e.g. towed by cables
    • F16L55/38Constructional aspects of the propulsion means, e.g. towed by cables driven by fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B2209/00Details of machines or methods for cleaning hollow articles
    • B08B2209/02Details of apparatuses or methods for cleaning pipes or tubes
    • B08B2209/027Details of apparatuses or methods for cleaning pipes or tubes for cleaning the internal surfaces
    • B08B2209/04Details of apparatuses or methods for cleaning pipes or tubes for cleaning the internal surfaces using cleaning devices introduced into and moved along the pipes
    • B08B2209/053Details of apparatuses or methods for cleaning pipes or tubes for cleaning the internal surfaces using cleaning devices introduced into and moved along the pipes being moved along the pipes by a fluid, e.g. by fluid pressure or by suction
    • B08B2209/055Details of apparatuses or methods for cleaning pipes or tubes for cleaning the internal surfaces using cleaning devices introduced into and moved along the pipes being moved along the pipes by a fluid, e.g. by fluid pressure or by suction the cleaning devices conforming to, or being conformable to, substantially the same cross-section of the pipes, e.g. pigs or moles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/24Homopolymers or copolymers of amides or imides
    • C08J2333/26Homopolymers or copolymers of acrylamide or methacrylamide

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • General Engineering & Computer Science (AREA)
  • Cleaning In General (AREA)

Abstract

The invention discloses a kind of gel composite tube cleaner and the preparation method of cross-linked polyacrylamide aqueous gel, including roller brush type tube cleaner, cross-linked polyacrylamide aqueous gel and polyurethane wiper, wherein, the roller brush type tube cleaner is arranged on the front portion of the gel composite tube cleaner, the polyurethane wiper is arranged on the afterbody of the gel composite tube cleaner, and the cross-linked polyacrylamide aqueous gel is arranged on the middle part of the gel composite tube cleaner.

Description

The preparation method of gel composite tube cleaner and cross-linked polyacrylamide aqueous gel
Technical field
The present invention relates to oil-gas pipeline field, specially a kind of gel composite tube cleaner and cross-linked polyacrylamide are water base solidifying The preparation method of glue.
Background technology
In order to ensure in-service pipeline is long-term normal, safe operation, it is necessary to periodically using the wax deposition in wiper discharge pipe, The debris such as water, sandstone, condensed liquid.The mechanical pipe-cleaner of work is probably due to pipe is contained within excessive debris, can not pass through in pipe Pipeline reducing diameter and elbow deform upon and blocking pipeline itself, substantially reduce the efficiency of pigging work, or even cause whole Bar pipeline is paralysed, and causes serious consequence, therefore the blocking problems demand of mechanical pipe-cleaner to solve.
In the prior art, being cleaned with chemical reagent merely can reduce the pipeline in-service life-span, improve cleaning cost, and some Dirt is also difficult to chemically process clean completely;Equally, it is simple to use to long-term conveying, deposition velocity oil pipeline faster Mechanical pipe-cleaner be also difficult to reach change it is defeated after ideal effect;Physical cleaning is used in combination oneself with chemical cleaning method turns into current Pipeline cleaning technology development a kind of trend, gel filtering tube device combined type cleaning technology be by pigging gel, mechanical pipe-cleaner and specially Formed with chemical reagent sequential combination, the technological synthesis have used physics and chemical pigging technology, with conventional mechanical wiper Or the incomparable advantage of Chemical cleaning, various practical Composite cleaning technologies obtain excellent effect in pigging operation Really.
The content of the invention
The present invention provides the preparation method of a kind of gel composite tube cleaner and cross-linked polyacrylamide aqueous gel, its purpose Be the appearance blocking situation in wiper work that solves probability it is high, and the ineffective problem of pigging.
It is water base solidifying the invention provides a kind of gel composite tube cleaner, including roller brush type tube cleaner, cross-linked polyacrylamide Glue and polyurethane wiper, wherein, the roller brush type tube cleaner is arranged on the front portion of the gel composite tube cleaner, the poly- ammonia Ester wiper is arranged on the afterbody of the gel composite tube cleaner, and the cross-linked polyacrylamide aqueous gel is arranged on described solidifying The middle part of the compound wiper of glue.
Optionally, the preparation method of the cross-linked polyacrylamide aqueous gel is comprised the following steps:
Aluminium citrate AlCit mother liquors and polyacrylamide HPAM mother liquors are added to the water well mixed, then thiocarbamide and chlorine Change sodium, regulation pH value is 5.0~7.0 so that the concentration of HPAM is 2500mg/L-3500mg/L in the mixture after adding water, The concentration of AlCit is 105mg/L-125mg/L, and the concentration of NaCl is 140mg/L-160mg/L, and the concentration of thiocarbamide is 140mg/L- 170mg/L;
(date, abbreviation the d) -7d that cross-linking reaction carried out at 20 DEG C -85 DEG C 3 days during polyacrylamide is added into the mixture , wherein, the concentration of polyacrylamide is 1000mg/L-4500mg/ after the polyacrylamide adds the mixture L。
Optionally, the HPAM relative molecular weights in the HPAM mother liquors are 1.0 × 107-2.0×107
Optionally, also include:In polyacrylamide is added into the mixture cross-linking reaction is carried out at 20 DEG C -85 DEG C When, added aluminium citrate as crosslinking agent in the mixture.
Optionally, it is described polyacrylamide is added the mixture in carry out cross-linking reaction 3d-7d at 20 DEG C -85 DEG C When, methods described also includes:
Polyacrylamide is hydrolyzed, partially hydrolyzed polyacrylamide (PHPA) is obtained, wherein, the partial hydrolysis polyacrylamide The relative molecular weight of amine is 1.0 × 107-2.0×107, the degree of hydrolysis 20%-30% of the polyacrylamide.
Beneficial effects of the present invention are as follows:
In gel composite tube cleaner of the invention, the roller brush type tube cleaner of front end can effectively be brushed off or loosened on inner-walls of duct The more firm debris of adhesion, such as wax deposition, iron rust, and certain dredging effect is played, convenient cross-linked polyacrylamide below is water base Gel and polyurethane wiper pass through, before the cross-linked polyacrylamide aqueous gel behind adjacent roller brush type tube cleaner is along pipeline During row, by its strongly adherent and shear shinning, loose wax deposition, iron rust thing etc. can be glued from tube wall, and simultaneously The debris such as the water in pipeline, sandstone, condensed liquid are included in gel in the form of suspension together, pipeline is finally taken out of, with And cross-linked polyacrylamide aqueous gel and promotion medium are kept apart positioned at the polyurethane wiper of rearmost end, itself is not only Cross-linked polyacrylamide aqueous gel and roller brush type tube cleaner can be promoted to advance forward, can also further remove what is remained on tube wall Debris and cross-linked polyacrylamide aqueous gel, push in cross-linked polyacrylamide aqueous gel above in the lump, effectively improve Overall pigging ability and effect, so so that the present invention combines the advantage of pipeline physical cleaning and Chemical cleaning, not only The brushing ability that mechanical pipe-cleaner is stronger is make use of, and cross-linked polyacrylamide aqueous gel used can be by most of debris It is contained within, greatly reduces when use merely mechanical pipe-cleaner and the probability of blocking occurs, while whole being combined clearly can be reduced Promotion pressure needed for the operation of pipe device, mitigates the abrasion to inner tubal wall, effectively reduces pigging cost.
Brief description of the drawings
Fig. 1 is the structural representation of gel composite tube cleaner in the embodiment of the present invention.
Reference is specific as follows:
1 --- roller brush type tube cleaner, 2 --- cross-linked polyacrylamide aqueous gel, 3 --- polyurethane wiper, 4 --- Promotion medium.
Specific embodiment
The present invention provides the preparation method of a kind of gel composite tube cleaner and cross-linked polyacrylamide aqueous gel, its purpose Be the appearance blocking situation in wiper work that solves probability it is high, and the ineffective problem of pigging.
Below in conjunction with the accompanying drawings and embodiment is explained in detail and illustrates to above technical scheme.
As shown in figure 1, the invention provides a kind of gel composite tube cleaner, including roller brush type tube cleaner 1, crosslinked polypropylene Acid amides aqueous gel 2 and polyurethane wiper 3, wherein, roller brush type tube cleaner 1 is arranged on the front portion of the compound wiper of the glue, Polyurethane wiper 3 is arranged on the afterbody of the gel composite tube cleaner, and cross-linked polyacrylamide aqueous gel 2 is arranged on described The middle part of gel composite tube cleaner.
Wherein, when the gel composite tube cleaner is put into pipeline, it is situated between by promoting in the rear end of polyurethane wiper 3 Matter 4 is promoted so that the gel composite tube cleaner is moved in the pipeline, promotion medium 4 can be gas or Liquid promotion medium.
Wherein, roller brush type tube cleaner 1 is specifically as follows chrome-silicon alloy roller brush type tube cleaner, to extend roller brush type tube cleaner 1 Service life, and roller brush type tube cleaner 1 is arranged on the front end of the gel composite tube cleaner, and then can be clear by roller brush type Pipe device 1 can effectively be brushed off or loosened and more firm debris are adhered on inner-walls of duct, such as wax deposition, iron rust, and play certain dredging Effect, convenient cross-linked polyacrylamide aqueous gel below and polyurethane wiper pass through.
Further, cross-linked polyacrylamide aqueous gel 2 is a kind of pigging gel, is arranged on the compound pigging of the gel The middle part of device, by its strongly adherent and shear shinning, from tube wall can glue loose wax deposition, iron rust thing etc. get off, and The debris such as the water in pipeline, sandstone, condensed liquid are included in gel in the form of suspension together simultaneously, last band outlet pipe Road so that can be contained within for most of debris by cross-linked polyacrylamide aqueous gel 2, greatly reduces simple using mechanical There is the probability of blocking during wiper, while the promotion pressure needed for reducing whole compound wiper operation, mitigates to inner tube The abrasion of wall, effectively reduces pigging cost
Further, polyurethane wiper 3 is specifically as follows polyurethane foam wiper, is arranged on the gel compound clear The afterbody of pipe device, can keep apart cross-linked polyacrylamide aqueous gel 2 and promotion medium 4, and itself can not only promote friendship Connection Polyacrylamide Aqueous Gel 2 and roller brush type tube cleaner 1 advance forward, can also further remove on tube wall remain debris and Cross-linked polyacrylamide aqueous gel, pushes in cross-linked polyacrylamide aqueous gel 2 above in the lump, effectively increases entirety Pigging ability and effect,
Lower mask body is specifically described to the preparation method of cross-linked polyacrylamide aqueous gel:
Embodiment one
Suitable quantity of water is taken in reaction vessel, adds aluminium citrate AlCit mother liquors and the mixing of polyacrylamide HPAM mother liquors equal It is even, wherein, HPAM relative molecular weights are 1.0 × 107, thiocarbamide and sodium chloride are subsequently adding, after stirring and dissolving is complete, use 0.1M PH is to 5.0~7.0 for NaOH solution regulation system, adds water and is diluted to required concentration, make in mixture HPAM, AlCit, NaCl and Thiourea concentration is followed successively by 3500mg/L, 105mg/L, 140mg/L and 175mg/L, and system finally is warming up into 20 DEG C~45 DEG C enters Row static state constant-temperature cross-linking reaction, stops reaction after 7 days, gained cross-linked polyacrylamide aqueous gel is deposited into standby.
Embodiment two
Suitable quantity of water is taken in reaction vessel, adds AlCit mother liquors and HPAM mother liquors well mixed, wherein, relative point of HPAM Son amount is 2.0 × 107, thiocarbamide and sodium chloride are subsequently adding, after stirring and dissolving is complete, with 0.1M NaOH solution regulation systems pH To 7.0, add water and be diluted to required concentration, make the concentration in mixture in HPAM be for the concentration of 2500mg/L, AlCit 125mg/L, NaCl are 160mg/L and thiourea concentration is 140mg/L, and the mixture finally is warming up into 80 DEG C~85 DEG C is carried out Static state constant-temperature cross-linking reaction, stops reaction after 3d, gained cross-linked polyacrylamide aqueous gel is deposited into standby.
After cross-linked polyacrylamide aqueous gel is prepared, roller brush type tube cleaner 1 is sent out using ball device is received and dispatched Enter in pipeline to be cleaned, then slowly cut cross-linked polyacrylamide aqueous gel 2, treat that the roller brush type in its adjacent front is clear After pipe device 1 forms the stable slug of certain length, then polyurethane wiper 3 is sent out into gel slug rear end, finally with liquid Or pneumatic power source is promoted and moved ahead.To improve the job stability and efficiency of the compound wiper, the He of roller brush type tube cleaner 1 The diameter of polyurethane wiper 3 should be slightly larger than internal diameter of the pipeline, be advisable with beyond 4 millimeters of (mm) -8mm.
Our experiments show that, during using embodiment of above pigging, the plural gel wiper is under low-pressure medium promotion Smooth can pass through pipeline, debris can be cleaned in most pipelines, substantially without any residue on inner tubal wall, and The generation of blocking phenomenon is found no, pigging working stability is safe and efficient.
Beneficial effects of the present invention are as follows:
In gel composite tube cleaner of the invention, the roller brush type tube cleaner of front end can effectively be brushed off or loosened on inner-walls of duct The more firm debris of adhesion, such as wax deposition, iron rust, and certain dredging effect is played, convenient cross-linked polyacrylamide below is water base Gel and polyurethane wiper pass through, before the cross-linked polyacrylamide aqueous gel behind adjacent roller brush type tube cleaner is along pipeline During row, by its strongly adherent and shear shinning, loose wax deposition, iron rust thing etc. can be glued from tube wall, and simultaneously The debris such as the water in pipeline, sandstone, condensed liquid are included in gel in the form of suspension together, pipeline is finally taken out of, with And cross-linked polyacrylamide aqueous gel and promotion medium are kept apart positioned at the polyurethane wiper of rearmost end, itself is not only Cross-linked polyacrylamide aqueous gel and roller brush type tube cleaner can be promoted to advance forward, can also further remove what is remained on tube wall Debris and cross-linked polyacrylamide aqueous gel, push in cross-linked polyacrylamide aqueous gel above in the lump, effectively improve Overall pigging ability and effect, so so that the present invention combines the advantage of pipeline physical cleaning and Chemical cleaning, not only The brushing ability that mechanical pipe-cleaner is stronger is make use of, and cross-linked polyacrylamide aqueous gel used can be by most of debris It is contained within, greatly reduces when use merely mechanical pipe-cleaner and the probability of blocking occurs, while whole being combined clearly can be reduced Promotion pressure needed for the operation of pipe device, mitigates the abrasion to inner tubal wall, effectively reduces pigging cost.
The foregoing description of the disclosed embodiments, enables professional and technical personnel in the field to realize or uses the present invention. Various modifications to these embodiments will make it will be apparent that defined herein one for those skilled in the art As principle can in other embodiments be realized in the case of the spirit or scope for not departing from invention.Therefore, the present invention will not Can be limited and the embodiments shown herein, and be to fit to consistent with principles disclosed herein and novel features Scope most wide.

Claims (3)

1. a kind of gel composite tube cleaner, it is characterised in that including roller brush type tube cleaner, cross-linked polyacrylamide aqueous gel and Polyurethane wiper, wherein, the roller brush type tube cleaner is arranged on the front portion of the gel composite tube cleaner, and the polyurethane is clear Pipe device is arranged on the afterbody of the gel composite tube cleaner, and the cross-linked polyacrylamide aqueous gel is arranged on the gel and answers The middle part of wiper is closed, wherein:
The preparation method of the cross-linked polyacrylamide aqueous gel is comprised the following steps:
Aluminium citrate AlCit mother liquors and polyacrylamide HPAM mother liquors are added to the water well mixed, are subsequently adding thiocarbamide and chlorine Change sodium, regulation pH value is 5.0~7.0, is diluted with water so that the concentration of HPAM is 2500mg/L-3500mg/L in mixture, The concentration of AlCit is 105mg/L-125mg/L, and the concentration of NaCl is 140mg/L-160mg/L, and the concentration of thiocarbamide is 140mg/L- 170mg/L;
The mixture carries out cross-linking reaction 3d-7d at 20 DEG C -85 DEG C.
2. gel composite tube cleaner as claimed in claim 1, it is characterised in that the HPAM average moleculars in the HPAM mother liquors Measure is 1.0 × 107-2.0×107
3. gel composite tube cleaner as claimed in claim 2, it is characterised in that the mixture is handed at 20 DEG C -85 DEG C During connection reaction 3d-7d, methods described also includes:
The polyacrylamide is hydrolyzed, partially hydrolyzed polyacrylamide (PHPA) is obtained, wherein, the HPAM in the HPAM mother liquors Relative molecular weight be 1.0 × 107-2.0×107, the degree of hydrolysis 20%-30% of the polyacrylamide.
CN201410399770.8A 2014-08-14 2014-08-14 The preparation method of gel composite tube cleaner and cross-linked polyacrylamide aqueous gel Active CN104259157B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105080916A (en) * 2015-07-30 2015-11-25 河南中拓石油工程技术股份有限公司 Water sweeping and drying pipe cleaner train of natural gas pipeline
CN105107801A (en) * 2015-07-30 2015-12-02 河南中拓石油工程技术股份有限公司 Water-sweeping, drying and inerting integrated process for natural gas transportation pipeline
CN105396850B (en) * 2015-10-26 2018-01-02 中国石油天然气股份有限公司 One kind water suction wiper
CN109364418A (en) * 2018-11-26 2019-02-22 山东科技大学 A kind of plastigel material for preventing and treating spontaneous combustionof coal
CN111889463B (en) * 2020-07-30 2021-11-09 苏州普滤得净化股份有限公司 Long-distance pipeline cleaning system

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US3108012A (en) * 1960-07-20 1963-10-22 Pipelife Corp Method of conditioning transmission lines in situ
US4416703A (en) * 1981-11-20 1983-11-22 Shell Oil Company System for removing debris from pipelines
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JPH06185203A (en) * 1992-07-08 1994-07-05 Ryoju Shoji Kk Piping cleaning unit pipe
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CN100579674C (en) * 2008-12-26 2010-01-13 中冶建工有限公司 Method for cleaning or corrosion-protective coating inner wall of industrial pipeline and device

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Effective date of registration: 20211105

Address after: Room 08-10, 6 / F, block a, No. 5, Dongtucheng Road, Chaoyang District, Beijing 100013

Patentee after: National Petroleum and natural gas pipeline network Group Co.,Ltd.

Address before: PetroChina building, No. 9, Dongzhimen North Street, Dongcheng District, Beijing 100029

Patentee before: PETROCHINA Co.,Ltd.

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