CN104258703B - Sulfur recovery unit and utilize the technique that said apparatus carries out sulfur recovery - Google Patents
Sulfur recovery unit and utilize the technique that said apparatus carries out sulfur recovery Download PDFInfo
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- CN104258703B CN104258703B CN201410494895.9A CN201410494895A CN104258703B CN 104258703 B CN104258703 B CN 104258703B CN 201410494895 A CN201410494895 A CN 201410494895A CN 104258703 B CN104258703 B CN 104258703B
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
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Abstract
Sulfur recovery unit of the present invention and the technique utilizing said apparatus to carry out sulfur recovery relate to a kind of apparatus and method for reclaiming sulfur.Its purpose is to provide a kind of simple in construction, the sulfur recovery unit of the work efficiency of sulfur recovery can be improved.The present invention includes main chamber, the primary waste heat boiler being joined directly together with main chamber, the first steam heater being connected with primary waste heat boiler, the one-level claus reaction device being connected with the first steam heater, also include filter, described filter is arranged between described first steam heater and described one-level claus reaction device, it is provided with filter inlet valve on the main pipeline that described filter is connected with described first steam heater, it is provided with filter outlet valve on main pipeline between described filter and described one-level claus reaction device, at described filter, filter inlet valve, the side of filter outlet valve is provided with first branch pipe(tube) in parallel with three, filter by-pass valve it is provided with on described first branch pipe(tube).
Description
Technical field
The present invention relates to a kind of apparatus and method for reclaiming sulfur.
Background technology
As it is shown in figure 1, sulfur recovery unit of the prior art include that main chamber 2 ' and main chamber 2 ' be joined directly together useless
Heat boiler 3 ' is connected with steam heater 4 ' by the steam heater 4 ' that main pipeline 1 ' is connected with waste heat boiler 3 '
One-level claus reaction device 5 ', the side of main chamber 2 ' is provided with air intlet 21 ', connects and has for main chamber 2 '
The blower fan of interior conveying air, the port of export at waste heat boiler 3 ' has molten sulfur pond 6 ', at steam heater 4 ' also by pipeline connection
Entrance point be provided with middle pressure steam import 41 ' and condensate outlet 42 '.
The sulfur recovery technology of said apparatus is: by process gas, (its composition is mainly composed of CO2、H2S、CH3OH、N2And H2
Deng) be passed in the middle of main chamber 2 ', the temperature in combustor controls between 850 DEG C～1200 DEG C, hydrogen sulfide containing technique
Gas and air or oxygen-enriched air or pure oxygen mixed combustion, a part of hydrogen sulfide and oxygen reacts generation sulfur dioxide, its remaining part
Dividing hydrogen sulfide and sulfur dioxide to react and generate gaseous elemental sulfur, in main chamber 2 ', the main reaction occurred is as follows: H2S
+O2=SO2+H2O, H2S+O2=S+H2O, H2S+SO2=S+H2O；Enter directly into from main chamber 2 ' gas out
Carrying out cooling down in waste heat boiler 3 ' and reclaim heat energy, the temperature in waste heat boiler 3 ' is normally controlled in 135 DEG C to 155 DEG C
Between, it is cooled into molten sulfur at main chamber 2 ' reacted gaseous mixture gas through gaseous elemental sulfur therein of lowering the temperature and separates,
The molten sulfur obtained is by discharge of pipes to molten sulfur pond 6 ', and other compositions in gas keep gaseous state and are passed into steam heater 4 '
In, utilize high-temperature steam that gas is heated, by control steam be passed through speed and heating and temperature control is existed by intake
Between 210 DEG C to 230 DEG C, after high-temperature gas is heated to the temperature requirement of one-level Crouse's import, gas is passed into one-level gram labor
This reactor 5 ' reacts.
The sulfur recovery rate of this sulfur recovery technology reaches 99.5%, and product purity reaches more than 99.95%, and Exhaust Emission Control is always
Sulfur <below 100ppm, but the resistance utilizing this device to easily cause sulfur recovery system during carrying out sulfur recovery raises,
Cannot smoothly complete the recovery operation to sulfur, reason includes following several respects: be on the one hand: because traditional handicraft uses process gas
(it is mainly composed of CO, H with fuel gas2、CO2And N2Deng) mode burnt altogether carries out, add through steam heater 4 '
Gas after heat is passed directly to reaction in the middle of one-level claus reaction device 5 ', causes due to the formation of fuel gas incomplete combustion
White carbon black can be brought in claus reaction device, add the stove brick of main chamber 2 ' and brickwork joint by the powder of heat-barrier material with gas
Body enters in claus reaction device together, causes reactor bed dust stratification, and then causes bed resistance to raise, and then causes whole
Resistance in individual sulfur recovery system raises, and the pressure of fan outlet is normally controlled in about 23kpa, when in sulfur recovery system
When resistance is more than 23kpa, air cannot be sent in the middle of main chamber 2 ' by blower fan smoothly, causes amount of oxygen in main chamber 2 '
Deficiency, and oxygen deficiency to cause the reaction of the sulfur recovery in combustor to carry out thorough, also result in fuel gas incomplete combustion,
Reduce sulphur recovery efficiency, even result in the reaction in main chamber 2 ' time serious and interrupt, and then cause cannot completing sulfur is returned
Receive；
Still further aspect is: because sulfur recovery system add vapours and fuel gas is not the most that sulfur recovery unit provides, once outside
Boundary cannot provide when adding vapours and fuel gas, and sulfur recovery is stopped in emergency, and sulfur recovery system cannot be replaced with the displacement gas of heat,
Now contain the process gas reduction along with temperature of gaseous elemental sulfur, react the gaseous elemental sulfur of generation in the reactor in one-level gram
The catalyst surface condensation of Louth reactor 5 ' becomes solid-state, and catalyst surface once has ash, will form ash sulfur, ash sulfur
Fusion temperature is more than 450 DEG C, and when sulfur recovery system is again started up, reaction bed temperature is the highest only 300 DEG C, ash sulfur without
Method melts gasification, causes the bed heap dust stratification sulfur of one-level claus reaction device 5 ', causes sulfur recovery system resistance to raise, and just
Normal solid sulfur will become molten sulfur at 150 DEG C and start gasification.
When one-level claus reaction device 5 ' bed dust stratification or ash sulfur time cause SR to raise time, whole system be required for by
Urgent interruption clears up dust stratification with ash sulfur to eliminate resistance, but after clearing up dust stratification and the grey sulfur of bed, dust stratification and ash sulfur meeting. every time
Constantly accumulation, at most can only maintain 2-3 month, and SR can raise again, then need again to interrupt the work of whole device,
Bed to claus reaction device carries out clearing up dust stratification and ash sulfur again, thus causes the work efficiency of sulfur recovery lowly, cost liter
Height, is unfavorable for that produce is normally carried out.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of simple in construction, can improve the sulfur recovery dress of the work efficiency of sulfur recovery
Put.
Sulfur recovery unit of the present invention, the primary waste heat boiler being joined directly together including main chamber and main chamber, passes through main pipeline
The first steam heater of being connected with primary waste heat boiler, the one-level Crouse being connected by main pipeline and the first steam heater are anti-
Answering device, the side of described primary waste heat boiler connects has the first molten sulfur pond, the inlet end of described first steam heater to be provided with the
One middle pressure steam import and the first condensate outlet, main chamber is provided with air intlet, it is characterised in that: also include filtering
Device, described filter is arranged between described first steam heater and described one-level claus reaction device, described filter and institute
State and be provided with filter inlet valve on the main pipeline that the first steam heater is connected, anti-with described one-level Crouse at described filter
Answer and on the main pipeline between device, be provided with filter outlet valve, at described filter, filter inlet valve, filter outlet valve
Side is provided with first branch pipe(tube) in parallel with three, and described first branch pipe(tube) is provided with filter by-pass valve.
Sulfur recovery unit of the present invention, the inlet end of wherein said filter is also associated with the 3rd branch pipe(tube) one end, described 3rd arm
The other end in road is communicated with the second steam heater, the inlet end of described second steam heater be provided with the second middle pressure steam import,
Second condensate outlet and nitrogen inlet, the port of export at described filter passes through pipeline connection and releases flare, described emptying fire
Torch is for collecting the nitrogen emitted from described filter, and described second steam heater, for heating nitrogen, adds
Described filter is preheated before filter comes into operation by the nitrogen after temperature, to ensure that the temperature in filter reaches described
The inlet temperature of one-level claus reaction device.
Sulfur recovery unit of the present invention, the main pipeline between wherein said filter outlet valve and described one-level claus reaction device sets
Being equipped with secondary waste heat boiler, the side of described secondary waste heat boiler connects the second molten sulfur pond.
Sulfur recovery unit of the present invention, the material of wherein said filter has sulfur corrosion resistant.
Sulfur recovery unit of the present invention, the fill in wherein said filter is inertia protective agent or activity protecting agent.
A kind of technique utilizing above-mentioned sulfur recovery unit to carry out sulfur recovery, it is characterised in that: include filter progress: when gas is
When one steam heater is heated to 200 DEG C to 230 DEG C, the high-temperature gas after heating is passed in the middle of described filter, passes through
Ash in high-temperature gas is filtered out by described filter, and the clean gas after filtration is passed in described one-level claus reaction device
Row reaction, affects when normally producing of system when the resistance height detected in filter, opens described filter by-pass valve, close
Close described filter inlet valve and described filter outlet valve, after described filter is cut out, described filter is cleared up, remove
Remove the grieshoch in described filter, after cleaning out, more described filter is put in the middle of system again, and open described mistake
Filter inlet valve and described filter outlet valve, the most described closedown filter by-pass valve.
Sulfur recovery technology of the present invention, the most also includes preheating procedure: preheat filter before being come into operation by filter,
Nitrogen of heating it is passed through until the temperature in described filter reaches the import of requirement in described one-level claus reaction device in filter
Temperature also stops after constant a period of time being passed through nitrogen.
Sulfur recovery technology of the present invention, the most also includes the thermal response operation before being arranged on preheating procedure: process gas is passed into institute
State in the middle of main chamber, in main chamber, hydrogen sulfide containing process gas and air or oxygen-enriched air or pure oxygen mixed combustion,
Temperature in combustor controls between 850 DEG C to 1200 DEG C, and a part of hydrogen sulfide and oxygen react generation sulfur dioxide, its
The hydrogen sulfide that remaining part is divided and sulfur dioxide react and generate gaseous elemental sulfur, are directly entered from described main chamber gas out
Carrying out cooling down in described primary waste heat boiler and reclaim heat energy, the temperature in described waste heat boiler controls to arrive at 135 DEG C
Between 155 DEG C, gaseous elemental sulfur therein is cooled into molten sulfur and separates, and the molten sulfur obtained is discharged in described molten sulfur pond,
Other compositions in gas keep gaseous state and are passed in described first steam heater, utilize high-temperature steam to carry out above-mentioned gas
It is heated between 210 DEG C to 230 DEG C.
Sulfur recovery technology of the present invention, the most also includes being arranged on the cooling process after filter progress: the gas after filtering leads to
Entering in secondary waste heat boiler to carry out cooling down and reclaim heat energy, the temperature in described secondary waste heat boiler controls to arrive at 135 DEG C
Between 155 DEG C, gaseous elemental sulfur therein is cooled into molten sulfur and separates, and the molten sulfur obtained is discharged in molten sulfur pond, gas
In other compositions keep gaseous state, the gas of other compositions after cooling down is passed in the middle of one-level claus reaction device.
Sulfur recovery technology of the present invention, the fill in wherein said filter is inertia protective agent or activity protecting agent.
Sulfur recovery unit difference from prior art of the present invention is that sulfur recovery unit of the present invention also includes filter, and filter sets
Putting between described first steam heater and described one-level claus reaction device, emit from the first steam heater is mixed
Close gas the impurity in gas or filtering dust to be fallen by filter, it is to avoid it is anti-that dust or impurity enter directly into one-level Crouse
Answer and device causes reactor bed dust stratification, and then cause the bed main force high and be forced to clear up dust stratification and affect being normally carried out of work；With
Time by arranging filter, filter constantly filters out the dust stratification of sulfur recovery system, it is to avoid when sulfur recovery system stops in emergency
The formation of the one-level claus reaction mellow lime sulfur of device bed, and then avoid SR to raise, it is ensured that the stable fortune of sulfur recovery work
OK, improve the work efficiency of sulfur recovery；
The pipeline that filter and the first steam heater are connected arranges filter inlet valve, anti-with one-level Crouse at filter
Answer and on the pipeline that device is connected, filter outlet valve is set, limit passing through of gas by filter inlet valve and filter outlet valve
Amount；Described filter, filter inlet valve, the side of filter outlet valve are provided with first branch pipe(tube) in parallel with three simultaneously,
First branch pipe(tube) is set, for when needs cut out cleaning to filter, still can ensure that from the first steam heater
The mixed gas emitted can enter in the middle of one-level claus reaction device, it is ensured that being normally carried out of sulfur recovery work；Additionally,
It is provided with filter by-pass valve on described first branch pipe(tube), is gone out by controlling filter by-pass valve, filter inlet valve and filter
The opening and closing of mouth valve realizes, when needing filter is cut out cleaning, then connecting the first steam heater by the first branch pipe(tube)
During with one-level claus reaction device, cut off the connecting pipe between the first steam heater and filter and filter and one-level gram
Connecting pipe between the reactor of Louth, and by the first branch pipe(tube) by between the first steam heater and one-level claus reaction device
Form the path that is connected, in order to mixed gas normal through.
In sulfur recovery unit of the present invention, the entrance point at filter passes through pipeline communication the second steam heater, owing to throwing at filter
Enter use before temperature than relatively low or after filter cuts out system temperature can decline, in order to ensure that filter can before coming into operation
Filter is preheated, to ensure that the temperature of filter reaches the inlet temperature that one-level claus reaction device requires.
Below in conjunction with the accompanying drawings the sulfur recovery unit of the present invention and the technique that utilizes said apparatus to carry out sulfur recovery are made furtherly
Bright.
Accompanying drawing explanation
Fig. 1 is the front view of sulfur recovery unit in prior art；
Fig. 2 is the front view of embodiment 1 in sulfur recovery unit of the present invention；
Fig. 3 is the front view of embodiment 2 in sulfur recovery unit of the present invention.
Detailed description of the invention
Embodiment 1
As in figure 2 it is shown, sulfur recovery unit of the present invention includes the first waste heat boiler that main chamber 2 and main chamber 2 are joined directly together
Stove 3, the first steam heater 4 being connected with primary waste heat boiler 3 by main pipeline 1, added with the first steam by main pipeline 1
The one-level claus reaction device 6 that hot device 4 is connected, the side of primary waste heat boiler 3 connects the first molten sulfur pond 9, and the first steam adds
The inlet end of hot device 4 is provided with the first middle pressure steam import 41 and the first condensate outlet 42, also includes filter 5, filter
5 are arranged between the first steam heater 4 and one-level claus reaction device 6, and filter 5 is connected with the first steam heater 4
Main pipeline 1 on be provided with filter 5 inlet valve 51, the main pipeline 1 between filter 5 and one-level claus reaction device 6
On be provided with filter 5 outlet valve 52, the side of filter 5, filter inlet valve 51, filter outlet valve 52 arrange
There is first branch pipe(tube) in parallel with three, the first branch pipe(tube) is provided with filter by-pass valve 53.Fill in filter 5 is lazy
Property protective agent.Air intlet on main chamber 2 is connected with blower fan.The material of filter 5 has sulfur corrosion resistant.
The inlet end of filter 5 is also associated with the 3rd branch pipe(tube) one end, and the other end of the 3rd branch pipe(tube) is communicated with the second steam heating
Device 7, the inlet end of the second steam heater 7 is provided with second middle pressure steam import the 71, second condensate outlet 72 and nitrogen enters
Mouthfuls 73, connected by pipeline at the port of export of filter 5 and release flare 10, release flare 10 for collecting from filter 5
In the nitrogen that emits, the second steam heater 7 is for heating nitrogen, and the nitrogen after heating is thrown for filter 5
Enter and before using, filter 5 is preheated, to ensure that the temperature in filter 5 reaches the import temperature of one-level claus reaction device 6
Degree.
A kind of technique utilizing above-mentioned sulfur recovery unit to carry out sulfur recovery, including thermal response operation: process gas is passed into main burning
In the middle of room 2, in main chamber 2, hydrogen sulfide containing process gas and air or oxygen-enriched air or pure oxygen mixed combustion, burning
Indoor temperature controls between 850 DEG C to 1200 DEG C, and a part of hydrogen sulfide and oxygen react generation sulfur dioxide, its remaining part
The hydrogen sulfide divided and sulfur dioxide react and generate gaseous elemental sulfur, enter directly into first from main chamber 2 gas out
In waste heat boiler 3, being provided with a series of pipeline in primary waste heat boiler 3, in pipeline, the water of flowing is by tube wall and stove
High-temperature gas carries out heat exchange, it is achieved the cooling down of gas also reclaims heat energy, and the temperature in primary waste heat boiler 3 controls
Between 135 DEG C to 155 DEG C, gaseous elemental sulfur therein is cooled into molten sulfur and separates, and the molten sulfur obtained is discharged into molten sulfur pond
In 9, other compositions in gas keep gaseous state, and the gas of other compositions after cooling down is passed into the first steam heating
In device 4, utilize high-temperature steam that above-mentioned gas is heated between 210 DEG C to 230 DEG C；
Preheating procedure: before filter 5 is come into operation, filter 5 is preheated: be passed through, in filter 5, nitrogen of heating
Until the temperature in filter 5 reaches the inlet temperature of requirement in one-level claus reaction device 6 and stops logical after constant a period of time
Enter nitrogen；
Filter progress: when gas is heated to 200 DEG C to 230 DEG C in the first steam heater 4, by the high-temperature gas after heating
Being passed in the middle of filter 5, filtered out by the ash in high-temperature gas by filter 5, the clean gas after filtration is passed into one
Level claus reaction device 6 reacts, affects when normally producing of system when the resistance height detected in filter 5, beat
Opened filter by-pass valve 53, cuts out filter inlet valve 51 and filter outlet valve 52, to filter after being cut out by filter 5
5 clear up, and remove the grieshoch in filter 5, after cleaning out, then are re-assembled in the middle of system by filter 5, and
Opened filter inlet valve 51 and filter outlet valve 52, simultaneously close off filter by-pass valve 53.
Embodiment 2
As it is shown on figure 3, sulfur recovery system also includes that secondary waste heat boiler 8, secondary waste heat boiler 8 are arranged on filter outlet valve
On main pipeline 1 between 52 and one-level claus reaction device 6, the side of secondary waste heat boiler 8 connects the second molten sulfur pond 11.Cross
Implant in filter 5 is activity protecting agent.
The technique utilizing above-mentioned sulfur recovery system to carry out sulfur recovery also includes the cooling process after being arranged on filter progress: work as filtration
When implant in device 5 is activity protecting agent, the temperature discharging gas in filter is higher, needs be passed through after cooling
To one-level claus reaction device 6, the gas after filtering is passed in secondary waste heat boiler 8, sets in secondary waste heat boiler 8
Being equipped with a series of pipeline, in pipeline, the water of flowing carries out heat exchange by tube wall with the high-temperature gas in stove, it is achieved the fall of gas
Temperature cooling also reclaims heat energy, and the temperature in secondary waste heat boiler 8 controls between 135 DEG C to 155 DEG C, gaseous elemental sulfur therein
Being cooled into molten sulfur to separate, the molten sulfur obtained is discharged in the second molten sulfur pond 11, and other compositions in gas keep gaseous state,
The gas of other compositions after cooling down is passed in the middle of one-level claus reaction device 6.
Embodiment described above is only to be described the preferred embodiment of the present invention, not carries out the scope of the present invention
Limiting, on the premise of designing spirit without departing from the present invention, technical scheme is made by those of ordinary skill in the art
Various deformation and improvement, all should fall in the protection domain that claims of the present invention determines.
Claims (9)
1. a sulfur recovery unit, it is characterised in that: include that main chamber (2) and main chamber (2) are joined directly together
One waste heat boiler (3), the first steam heater (4) being connected with primary waste heat boiler (3) by main pipeline (1), pass through
One-level claus reaction device (6) that main pipeline (1) is connected with the first steam heater (4), described primary waste heat boiler (3)
Side connect have the first molten sulfur pond (9), the inlet end of described first steam heater (4) to be provided with the first middle pressure steam import
(41) and the first condensate outlet (42), main chamber (2) is provided with air intlet (21), it is characterised in that: also wrap
Including filter (5), described filter (5) is arranged on described first steam heater (4) and described one-level claus reaction device
(6), between, the main pipeline (1) that described filter (5) is connected with described first steam heater (4) is provided with filtration
Device inlet valve (51), the main pipeline (1) between described filter (5) and described one-level claus reaction device (6) sets
It is equipped with filter outlet valve (52), at described filter (5), filter inlet valve (51), filter outlet valve (52)
Side is provided with first branch pipe(tube) in parallel with three, and described first branch pipe(tube) is provided with filter by-pass valve (53),
The inlet end of described filter (5) is also associated with the 3rd branch pipe(tube) one end, and the other end of described 3rd branch pipe(tube) is communicated with
Two steam heaters (7), the inlet end of described second steam heater (7) be provided with the second middle pressure steam import (71),
Two condensate outlets (72) and nitrogen inlet (73), the port of export at described filter (5) has emptying fire by pipeline connection
Torch (10), described in release flare (10) for collecting the nitrogen that emits from described filter (5), described second steams
Vapour heater (7) for nitrogen is heated, the nitrogen after heating before filter (5) comes into operation to described filtration
Device (5) preheats, to ensure that the temperature in filter (5) reaches the inlet temperature of described one-level claus reaction device (6).
Sulfur recovery unit the most according to claim 1, it is characterised in that: described filter outlet valve (52) and described
It is provided with secondary waste heat boiler (8), described secondary waste heat boiler (8) on main pipeline (1) between level claus reaction device (6)
Side connect the second molten sulfur pond (11).
Sulfur recovery unit the most according to claim 2, it is characterised in that: the material of described filter (5) has resistant to sulfur
Corrosivity.
Sulfur recovery unit the most according to claim 3, it is characterised in that: the fill in described filter (5) is lazy
Property protective agent or activity protecting agent.
5. one kind utilizes the technique that the arbitrary described sulfur recovery unit of claim 1-4 carries out sulfur recovery, it is characterised in that: included
Filter operation: when gas is heated to 200 DEG C to 230 DEG C in the first steam heater (4), leads to the high-temperature gas after heating
Enter in the middle of described filter (5), by described filter (5), the ash in high-temperature gas is filtered out, the cleaning after filtration
Gas is passed in described one-level claus reaction device (6) and reacts, as the resistance Gao Erying detected in filter (5)
When normally producing of acoustic system, opens described filter by-pass valve (53), closes described filter inlet valve (51) and described mistake
Filter outlets valve (52), clears up described filter (5) after being cut out by described filter (5), removes described filter
(5) grieshoch in, after cleaning out, more again puts into described filter (5) in the middle of system, and opens described filtration
Device inlet valve (51) and described filter outlet valve (52), the most described closedown filter by-pass valve (53).
Sulfur recovery technology the most according to claim 5, it is characterised in that: described sulfur recovery technology also includes preheating procedure:
Before filter (5) is come into operation, filter (5) is preheated, in filter (5), be passed through nitrogen of heating until institute
State inlet temperature constant a period of time that the temperature in filter (5) reaches to require in described one-level claus reaction device (6)
Rear stopping is passed through nitrogen.
Sulfur recovery technology the most according to claim 6, it is characterised in that: described sulfur recovery technology also includes being arranged on preheating
Thermal response operation before operation: process gas is passed in the middle of described main chamber (2), in main chamber (2), contains
The process gas of hydrogen sulfide and air or oxygen-enriched air or pure oxygen mixed combustion, the temperature in combustor controls to arrive at 850 DEG C
Between 1200 DEG C, a part of hydrogen sulfide and oxygen react generation sulfur dioxide, and the hydrogen sulfide of remainder occurs with sulfur dioxide
Reaction generates gaseous elemental sulfur, enters directly into described primary waste heat boiler (3) from described main chamber (2) gas out
In carry out cooling down and reclaim heat energy, the temperature in described waste heat boiler controls between 135 DEG C to 155 DEG C, gaseous state therein
Elemental sulfur is cooled into molten sulfur and separates, and the molten sulfur obtained is discharged in described molten sulfur pond (9), other compositions in gas
Keep gaseous state and be passed in described first steam heater (4), utilizing high-temperature steam that above-mentioned gas is heated to 210 DEG C
Between 230 DEG C.
Sulfur recovery technology the most according to claim 7, it is characterised in that: described sulfur recovery technology also includes being arranged on filtration
Cooling process after operation: the gas after filtering is passed in secondary waste heat boiler (8) and carries out cooling down and reclaim heat
Can, the temperature in described secondary waste heat boiler (8) controls between 135 DEG C to 155 DEG C, and gaseous elemental sulfur therein is cooled
Becoming molten sulfur to separate, the molten sulfur obtained is discharged in molten sulfur pond (9), and other compositions in gas keep gaseous state, will be through fall
The gas of other compositions after temperature cooling is passed in the middle of one-level claus reaction device (6).
Sulfur recovery technology the most according to claim 8, it is characterised in that: the fill in described filter (5) is lazy
Property protective agent or activity protecting agent.
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| CN201410494895.9A CN104258703B (en) | 2014-09-24 | 2014-09-24 | Sulfur recovery unit and utilize the technique that said apparatus carries out sulfur recovery |
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| CN104258703B true CN104258703B (en) | 2016-11-23 |
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| CN107720705B (en) * | 2017-11-08 | 2024-02-13 | 中国石油化工集团公司 | Device and method for producing hydrogen by coupling ammonia decomposition in Claus sulfur production |
| CN108654337A (en) * | 2018-04-18 | 2018-10-16 | 陕西未来能源化工有限公司 | A kind of guard method of sulfur recovery system catalyst |
| CN115304034B (en) * | 2022-08-02 | 2024-01-26 | 新乡中新化工有限责任公司 | Application system and method of nitrogen pipeline of Claus sulfur recovery device |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10332794A1 (en) * | 2003-07-18 | 2005-02-10 | Siemens Ag | Improving the performance of a Claus unit for process gas desulfurization comprises selectively removing water from the process gas to increase the sulfur yield |
| CN101585511A (en) * | 2009-06-25 | 2009-11-25 | 中国石油化工集团公司 | Sulfur recycling technique |
| CN201785190U (en) * | 2010-08-28 | 2011-04-06 | 西南石油大学 | Novel sulphur reclaiming device |
| CN203359987U (en) * | 2013-06-21 | 2013-12-25 | 邵志辉 | Device for acquiring sulfur from sulfur compounds of coal chemical industry and power plant |
| CN204170602U (en) * | 2014-09-24 | 2015-02-25 | 安徽淮化股份有限公司 | Sulfur recovery unit |
-
2014
- 2014-09-24 CN CN201410494895.9A patent/CN104258703B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10332794A1 (en) * | 2003-07-18 | 2005-02-10 | Siemens Ag | Improving the performance of a Claus unit for process gas desulfurization comprises selectively removing water from the process gas to increase the sulfur yield |
| CN101585511A (en) * | 2009-06-25 | 2009-11-25 | 中国石油化工集团公司 | Sulfur recycling technique |
| CN201785190U (en) * | 2010-08-28 | 2011-04-06 | 西南石油大学 | Novel sulphur reclaiming device |
| CN203359987U (en) * | 2013-06-21 | 2013-12-25 | 邵志辉 | Device for acquiring sulfur from sulfur compounds of coal chemical industry and power plant |
| CN204170602U (en) * | 2014-09-24 | 2015-02-25 | 安徽淮化股份有限公司 | Sulfur recovery unit |
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