CN104231831A - Abrasion-resistant paint and preparation method thereof - Google Patents
Abrasion-resistant paint and preparation method thereof Download PDFInfo
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- CN104231831A CN104231831A CN201410475745.3A CN201410475745A CN104231831A CN 104231831 A CN104231831 A CN 104231831A CN 201410475745 A CN201410475745 A CN 201410475745A CN 104231831 A CN104231831 A CN 104231831A
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Abstract
The invention discloses abrasion-resistant paint and a preparation method thereof. The paint comprises a first component and a second component, wherein the first component is double-component composition formed by mixing of a component A and a component B in a ratio of 1:1, the component A in the first component comprises components as follows: E-20 epoxy resin, silicon carbide micro powder, carbon monofluoride and a coupling agent; the component B in the first component comprises components as follows: methyl methacrylate, butyl acrylate, aluminum isopropoxide, triethoxy vinyl silane and 20-25 parts of a solvent; the second component comprises components as follows: a curing agent, an antifoaming agent, a leveling agent and a solvent. The components A and B in the first component are prepared separately and then mixed, and finally, the first and second components are cured to obtain the abrasion-resistant paint.
Description
Technical field
The invention belongs to technical field of coatings, be specifically related to a kind of wear-resistant paint and preparation method thereof.
Background technology
Along with progress and the development of science and technology, novel material is as one of the three large leading industries of 21 century, obviously particularly important, and also represent industrial progress and the development of country to a certain extent, coating is one of of paramount importance field as corrosion resistant material.
Coating coats body surface can form film under certain conditions and play protection, decoration or other specific functions, as insulation, antirust, mildew-resistant, heat-resisting an etc. class I liquid I or solid material.The kind of coating is a lot, and the different specific function that can reach of its formula is just different.
Wear-resistant paint is in the market mainly used in steel industry and machinery industry, and wearing and tearing are the problems often run in the equipment run up, and therefore equipment can break down, damage, even scrap.The protection of wearing piece and the reparation of abrading section are the problems that the fields such as industrial equipments, bearing, lathe, engine are paid close attention to the most always.And wear-resistant paint just plays important role, in industry, military domain, the effect of repairing with protection is played incisively and vividly, improve the wear resistance of industry correlated parts, reduce the consumption of high-abrasive material, extend the work-ing life of high-abrasive material, to raising equipment operation efficiency, reduce costs, save energy has great importance.
For the protection of equipment attrition, normally add lubricant, use the methods such as metal plating, and the use of lubricant has its working conditions and field, the high loading of metal plating, high rotating speed, long-time condition still easily wear and tear.Wear-resistant paint is a kind of solid material self with good lubrication condition and corresponding resistance to mechanical effect, and it can make up the wear-out defect that two contact surfaces cause due to friction, and two relative movement masks can be made again to have good lubrication anti-attrition effect.Meanwhile, wear-resistant paint also has certain pre-buried property to the metallic impurity between engaging friction two contact surface.
At present, the wear resistance of existing coating is general, need to be exposed to outer position of smearing at some to be often subject to friction coating and to be easy to wearing and tearing, in the prior art, normally used coating increases the wear resistance of equipment component, but the wear resistance of coating in the environment easy to wear below 600 DEG C, gloss, there is many deficiencies in the performances such as attachment, wearing and tearing have regular and inevitable property, the high-abrasive material of research wearing and tearing and development has important using value, along with the develop rapidly of science and technology and the continuous progress of society, the application of high-performance abrasion-proof coating more and more will be subject to people and pay attention to.
Summary of the invention
Technical problem to be solved by this invention is, for the shortcoming that above prior art exists, a kind of wear-resistant paint and preparation method thereof is proposed, this wear-resistant paint has the transparency and uvioresistant ability preferably, and this wear-resistant paint has good wear-resistant scratch-resistant, and coating is smooth, and strong adhesion tool has good wearability, excellent thermostability, the preparation method of this wear-resistant paint is simple, energy-conservation, with low cost.
The technical scheme that the present invention solves above technical problem is:
A kind of wear-resistant paint, comprise first and second liang of components, first component is that a pair of component combine thing is mixed in the ratio of A:B=1:1.5 by A, B component, and first and second comprise following component in mass fraction:
Component A in first component comprises following component according to the mass fraction:
E-20 epoxy resin: 10-15 part, silicon carbide micro-powder: 15-25 part, fluorographite: 15-20 part; Coupling agent: 20-25 part;
B component in first component comprises following component according to the mass fraction:
Methyl methacrylate: 40-45 part, butyl acrylate: 25-30 part, aluminum isopropylate: 5-10 part, vinyltriethoxysilane: 10-15 part; Solvent: 20-25 part;
Second component comprises containing following component in mass fraction:
Solidifying agent: 20-50 part, defoamer: 2-8 part, flow agent: 2-8 part, solvent: 10-15 part;
Wherein, silicon carbide micro-powder is black silicon carbide and particle diameter is 6 μm; Fluorographite particle diameter is 5-10 μm; Coupling agent is one or more mixtures in γ-aminopropyl triethoxysilane, γ-(2,3 glycidoxy) propyl trimethoxy silicane or 3-methacryloxypropyl trimethoxy silane.
The technical scheme that the present invention limits further is:
In foregoing wear coating, the epoxy equivalent (weight) 450-500g/eq of E-20 epoxy resin.
In foregoing wear coating, the solvent in the first and second components is one or more mixtures in dimethylbenzene, ethyl acetate or propyl carbinol.
In foregoing wear coating, solidifying agent is the one in mphenylenediamine, diethylenetriamine, polymeric amide.
In foregoing wear coating, defoamer is the one in dimethyl silicone oil, organosilicon, polyvinyl acetate (PVA).
In foregoing wear coating, flow agent is the one in polydimethylsiloxane, PSI or vinylformic acid.
The preparation method of above-mentioned wear-resistant paint, concrete steps are as follows:
(1) preparation of first component
A: get the melting at certain 150-200 DEG C of E-20 epoxy resin, then add solvothermal to stir, after resin is solvent, add silane coupling agent, continue to stir 10-15min, add silicon carbide micro-powder and fluorographite, fully stir, adopt ultrasonic wave dispersion 5-10min, the component A obtained in wear-resistant paint first component is stand-by;
B: the mixed solution adding methyl methacrylate, butyl acrylate, vinyltriethoxysilane and dimethylbenzene composition in the there-necked flask that thermometer, agitator, prolong are housed successively, heating in water bath to 80 DEG C, stirring velocity is that 100-150 turns/min, the mixed solution of benzoyl peroxide and dimethylbenzene is added in dropping funnel simultaneously, with 1-2 drip/speed of s drips 1h, after 80 DEG C continue reaction 1h, namely obtain prepolymer; Get 100ml deionized water in there-necked flask, be heated to 85 DEG C, compare for 200:1 adds in there-necked flask by water and the amount of substance of aluminum isopropylate, hydrolysis reaction 1.5h, then be warming up to 95 DEG C, wait to boil off most of alcohol, dripping peptizing agent makes it precipitate plastic, control PH is 3-5,85 DEG C of fluxion 2-3h next time, obtained transparent Alumina gel; Be added drop-wise in performed polymer by obtained Alumina gel by dropping funnel, vigorous stirring certain hour under the effect of hydrochloric acid, the B component finally obtained in wear-resistant paint first component is stand-by;
C: the B component that the component A prepared in step a and step b are obtained in mass ratio 1:1.5 weigh mix stand-by;
(2) preparation of second component
Get measure solidifying agent, defoamer and advection agent, be made into mixed solution with a small amount of solvent cut stand-by;
(3) compound of first, second component
The second component that first component step () prepared and step (two) prepare weighs the finished product mixing and solidify and obtain wear-resistant paint in mass ratio.
The invention has the beneficial effects as follows:
A kind of wear-resistant paint of the present invention, have good wear-resistant scratch-resistant, and coating is smooth, strong adhesion.
The present invention is by adding silicon carbide micro-powder and fluorographite, silicon carbide differential is a kind of stupalith, tool has good wearability, excellent thermostability, fluorographite has excellent lubricity, silicon carbide micro-powder and fluorographite are evenly dispersed in coating, make this coating have good abrasion resistant effect.
The present invention with E-20 epoxy resin for bonding agent, polymeric amide is solidifying agent, fluorographite is lubricant, silicon carbide micro-powder is wear resistant filler, adopt Chemical bonding legal system for a kind of wear-resistant paint, comparatively adopt thermospray and vapour deposition process to prepare coating, the glutinous legal system of chemistry has simple, the energy-conservation advantage of technique for wear-resistant paint.
It is that raw material has prepared the wear-resistant paint of aluminium by sol-gel method that the present invention have employed Alumina gel simultaneously, have the transparency and uvioresistant ability preferably, and the wear resistance of coating is also very strong.
Embodiment
embodiment 1
The present embodiment provides a kind of wear-resistant paint, comprises first and second liang of components, and first component is that a pair of component combine thing is mixed in the ratio of A:B=1:1.5 by A, B component, and first and second comprise following component in mass fraction:
Component A in first component comprises following component according to the mass fraction:
Epoxy equivalent (weight) is the E-20 epoxy resin of 450g/eq: 10 parts, and particle diameter is 6 μm of black silicon carbides: 25 parts, and particle diameter is 7 μm of fluorographites: 17 parts; γ-aminopropyl triethoxysilane: 20 parts;
B component in first component comprises following component according to the mass fraction:
Methyl methacrylate: 43 parts, butyl acrylate: 25 parts, aluminum isopropylate: 10 parts, vinyltriethoxysilane: 10 parts; Dimethylbenzene: 20 parts;
Second component comprises containing following component in mass fraction:
Mphenylenediamine: 42 parts, organosilicon: 5 parts, polydimethylsiloxane: 6 parts, dimethylbenzene: 13 parts;
The preparation method of above-mentioned wear-resistant paint, concrete steps are as follows:
(1) preparation of first component
A: get the melting at certain 200 DEG C of E-20 epoxy resin, then add solvothermal to stir, after resin is solvent, add silane coupling agent, continue to stir 10min, add silicon carbide micro-powder and fluorographite, fully stir, adopt ultrasonic wave dispersion 8min, the component A obtained in wear-resistant paint first component is stand-by;
B: the mixed solution adding methyl methacrylate, butyl acrylate, vinyltriethoxysilane and dimethylbenzene composition in the there-necked flask that thermometer, agitator, prolong are housed successively, heating in water bath to 80 DEG C, stirring velocity is 100 turns/min, the mixed solution of benzoyl peroxide and dimethylbenzene is added in dropping funnel simultaneously, 1h is dripped with the speed of 1/s, after 80 DEG C continue reaction 1h, namely obtain prepolymer; Get 100ml deionized water in there-necked flask, be heated to 85 DEG C, compare for 200:1 adds in there-necked flask by water and the amount of substance of aluminum isopropylate, hydrolysis reaction 1.5h, then be warming up to 95 DEG C, wait to boil off most of alcohol, dripping peptizing agent makes it precipitate plastic, control PH is 3,85 DEG C of fluxion 2.5h next time, obtained transparent Alumina gel; Be added drop-wise in performed polymer by obtained Alumina gel by dropping funnel, vigorous stirring certain hour under the effect of hydrochloric acid, the B component finally obtained in wear-resistant paint first component is stand-by;
C: the B component that the component A prepared in step a and step b are obtained in mass ratio 1:1.5 weigh mix stand-by;
(2) preparation of second component
Get solidifying agent, defoamer and advection agent, be made into mixed solution with solvent cut stand-by;
(3) compound of first, second component
The second component that first component step () prepared and step (two) prepare weighs the finished product mixing and solidify and obtain wear-resistant paint in mass ratio.
embodiment 2
The present embodiment provides a kind of wear-resistant paint, comprises first and second liang of components, and first component is that a pair of component combine thing is mixed in the ratio of A:B=1:1.5 by A, B component, and first and second comprise following component in mass fraction:
Component A in first component comprises following component according to the mass fraction:
Epoxy equivalent (weight) is the E-20 epoxy resin of 500g/eq: 14 parts, and particle diameter is 6 μm of black silicon carbides: 15 parts, and particle diameter is 10 μm of fluorographites: 20 parts; 3-methacryloxypropyl trimethoxy silane: 25 parts;
B component in first component comprises following component according to the mass fraction:
Methyl methacrylate: 45 parts, butyl acrylate: 25 parts, aluminum isopropylate: 5 parts, vinyltriethoxysilane: 13 parts; Propyl carbinol: 23 parts;
Second component comprises containing following component in mass fraction:
Diethylenetriamine: 35 parts, dimethyl silicone oil: 8 parts, vinylformic acid: 2 parts, propyl carbinol: 10 parts;
The preparation method of above-mentioned wear-resistant paint, concrete steps are as follows:
(1) preparation of first component
A: get the melting at certain 150 DEG C of E-20 epoxy resin, then add solvothermal to stir, after resin is solvent, add silane coupling agent, continue to stir 15min, add silicon carbide micro-powder and fluorographite, fully stir, adopt ultrasonic wave dispersion 5min, the component A obtained in wear-resistant paint first component is stand-by;
B: the mixed solution adding methyl methacrylate, butyl acrylate, vinyltriethoxysilane and dimethylbenzene composition in the there-necked flask that thermometer, agitator, prolong are housed successively, heating in water bath to 80 DEG C, stirring velocity is 125 turns/min, the mixed solution of benzoyl peroxide and dimethylbenzene is added in dropping funnel simultaneously, 1h is dripped with the speed of 1/s, after 80 DEG C continue reaction 1h, namely obtain prepolymer; Get 100ml deionized water in there-necked flask, be heated to 85 DEG C, compare for 200:1 adds in there-necked flask by water and the amount of substance of aluminum isopropylate, hydrolysis reaction 1.5h, then be warming up to 95 DEG C, wait to boil off most of alcohol, dripping peptizing agent makes it precipitate plastic, control PH is 5,85 DEG C of fluxion 2h next time, obtained transparent Alumina gel; Be added drop-wise in performed polymer by obtained Alumina gel by dropping funnel, vigorous stirring certain hour under the effect of hydrochloric acid, the B component finally obtained in wear-resistant paint first component is stand-by;
C: the B component that the component A prepared in step a and step b are obtained in mass ratio 1:1.5 weigh mix stand-by;
(2) preparation of second component
Get solidifying agent, defoamer and advection agent, be made into mixed solution with solvent cut stand-by;
(3) compound of first, second component
The second component that first component step () prepared and step (two) prepare weighs the finished product mixing and solidify and obtain wear-resistant paint in mass ratio.
embodiment 3
The present embodiment provides a kind of wear-resistant paint, comprises first and second liang of components, and first component is that a pair of component combine thing is mixed in the ratio of A:B=1:1.5 by A, B component, and first and second comprise following component in mass fraction:
Component A in first component comprises following component according to the mass fraction:
Epoxy equivalent (weight) is the E-20 epoxy resin of 480g/eq: 15 parts, and particle diameter is 6 μm of black silicon carbides: 22 parts, and particle diameter is 5 μm of fluorographites: 15 parts; γ-(2,3 glycidoxy) propyl trimethoxy silicane: 22 parts;
B component in first component comprises following component according to the mass fraction:
Methyl methacrylate: 40 parts, butyl acrylate: 30 parts, aluminum isopropylate: 6 parts, vinyltriethoxysilane: 15 parts; Ethyl acetate: 20 parts;
Second component comprises containing following component in mass fraction:
Polymeric amide: 50 parts, polyvinyl acetate (PVA): 2 parts, PSI: 8 parts, ethyl acetate: 15 parts;
The preparation method of above-mentioned wear-resistant paint, concrete steps are as follows:
(1) preparation of first component
A: get the melting at certain 185 DEG C of E-20 epoxy resin, then add solvothermal to stir, after resin is solvent, add silane coupling agent, continue to stir 13min, add silicon carbide micro-powder and fluorographite, fully stir, adopt ultrasonic wave dispersion 10min, the component A obtained in wear-resistant paint first component is stand-by;
B: the mixed solution adding methyl methacrylate, butyl acrylate, vinyltriethoxysilane and dimethylbenzene composition in the there-necked flask that thermometer, agitator, prolong are housed successively, heating in water bath to 80 DEG C, stirring velocity is 150 turns/min, the mixed solution of benzoyl peroxide and dimethylbenzene is added in dropping funnel simultaneously, 1h is dripped with the speed of 2/s, after 80 DEG C continue reaction 1h, namely obtain prepolymer; Get 100ml deionized water in there-necked flask, be heated to 85 DEG C, compare for 200:1 adds in there-necked flask by water and the amount of substance of aluminum isopropylate, hydrolysis reaction 1.5h, then be warming up to 95 DEG C, wait to boil off most of alcohol, dripping peptizing agent makes it precipitate plastic, control PH is 4,85 DEG C of fluxion 3h next time, obtained transparent Alumina gel; Be added drop-wise in performed polymer by obtained Alumina gel by dropping funnel, vigorous stirring certain hour under the effect of hydrochloric acid, the B component finally obtained in wear-resistant paint first component is stand-by;
C: the B component that the component A prepared in step a and step b are obtained in mass ratio 1:1.5 weigh mix stand-by;
(2) preparation of second component
Get solidifying agent, defoamer and advection agent, be made into mixed solution with solvent cut stand-by;
(3) compound of first, second component
The second component that first component step () prepared and step (two) prepare weighs the finished product mixing and solidify and obtain wear-resistant paint in mass ratio.
In addition to the implementation, the present invention can also have other embodiments.All employings are equal to the technical scheme of replacement or equivalent transformation formation, all drop on the protection domain of application claims.
Claims (7)
1. a wear-resistant paint, is characterized in that: comprise first and second liang of components, and described first component is that a pair of component combine thing is mixed in the ratio of A:B=1:1.5 by A, B component, and described first and second comprise following component in mass fraction:
Component A in described first component comprises following component according to the mass fraction:
E-20 epoxy resin: 10-15 part, silicon carbide micro-powder: 15-25 part, fluorographite: 15-20 part; Coupling agent: 20-25 part;
B component in described first component comprises following component according to the mass fraction:
Methyl methacrylate: 40-45 part, butyl acrylate: 25-30 part, aluminum isopropylate: 5-10 part, vinyltriethoxysilane: 10-15 part; Solvent: 20-25 part;
Described second component comprises containing following component in mass fraction:
Solidifying agent: 20-50 part, defoamer: 2-8 part, flow agent: 2-8 part, solvent: 10-15 part;
Wherein, described silicon carbide micro-powder is black silicon carbide and particle diameter is 6 μm; Described fluorographite particle diameter is 5-10 μm; Described coupling agent is one or more mixtures in γ-aminopropyl triethoxysilane, γ-(2,3 glycidoxy) propyl trimethoxy silicane or 3-methacryloxypropyl trimethoxy silane.
2. wear-resistant paint according to claim 1, is characterized in that: the epoxy equivalent (weight) 450-500g/eq of described E-20 epoxy resin.
3. wear-resistant paint according to claim 1, is characterized in that: the solvent in the first and second described components is one or more mixtures in dimethylbenzene, ethyl acetate or propyl carbinol.
4. wear-resistant paint according to claim 1, is characterized in that: described solidifying agent is the one in mphenylenediamine, diethylenetriamine, polymeric amide.
5. according to wear-resistant paint according to claim 1, it is characterized in that: described defoamer is the one in dimethyl silicone oil, organosilicon, polyvinyl acetate (PVA).
6. according to wear-resistant paint according to claim 1, it is characterized in that: described flow agent is the one in polydimethylsiloxane, PSI or vinylformic acid.
7. the preparation method of wear-resistant paint as described in claim as arbitrary in claim 1-6, it is characterized in that, concrete steps are as follows:
(1) preparation of first component
A: get the melting at certain 150-200 DEG C of E-20 epoxy resin, then add solvothermal to stir, after resin is solvent, add silane coupling agent, continue to stir 10-15min, add silicon carbide micro-powder and fluorographite, fully stir, adopt ultrasonic wave dispersion 5-10min, the component A obtained in wear-resistant paint first component is stand-by;
B: the mixed solution adding methyl methacrylate, butyl acrylate, vinyltriethoxysilane and dimethylbenzene composition in the there-necked flask that thermometer, agitator, prolong are housed successively, heating in water bath to 80 DEG C, stirring velocity is that 100-150 turns/min, the mixed solution of benzoyl peroxide and dimethylbenzene is added in dropping funnel simultaneously, with 1-2 drip/speed of s drips 1h, after 80 DEG C continue reaction 1h, namely obtain prepolymer; Get 100ml deionized water in there-necked flask, be heated to 85 DEG C, compare for 200:1 adds in there-necked flask by water and the amount of substance of aluminum isopropylate, hydrolysis reaction 1.5h, then be warming up to 95 DEG C, wait to boil off most of alcohol, dripping peptizing agent makes it precipitate plastic, control PH is 3-5,85 DEG C of fluxion 2-3h next time, obtained transparent Alumina gel; Be added drop-wise in performed polymer by obtained Alumina gel by dropping funnel, vigorous stirring certain hour under the effect of hydrochloric acid, the B component finally obtained in wear-resistant paint first component is stand-by;
C: the B component that the component A prepared in step a and step b are obtained in mass ratio 1:1.5 weigh mix stand-by;
(2) preparation of second component
Get measure solidifying agent, defoamer and advection agent, be made into mixed solution with a small amount of solvent cut stand-by;
(3) compound of first, second component
The second component that first component step () prepared and step (two) prepare weighs the finished product mixing and solidify and obtain wear-resistant paint in mass ratio.
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