CN104231728B

CN104231728B - A kind of ultrawhite environmental protection safety glass ink and preparation method thereof

Info

Publication number: CN104231728B
Application number: CN201310246755.5A
Authority: CN
Inventors: 刘鸣强; 罗小丰
Original assignee: FOSHAN GAOMING GREEN DE CHEMICAL CO LTD
Current assignee: FOSHAN GAOMING GREEN DE CHEMICAL CO LTD
Priority date: 2013-06-20
Filing date: 2013-06-20
Publication date: 2016-07-06
Anticipated expiration: 2033-06-20
Also published as: CN104231728A

Abstract

The invention discloses a kind of ultrawhite environmental protection safety glass ink and preparation method thereof, the each component comprised and percentage by weight thereof are as follows: coloring agent: 18%～30%, glass base glaze: 50%～60%, varnish: 18%～30% additive: 0.1%～1%, a kind of ultrawhite environmental protection safety glass ink of the present invention, to environment and man body pollution, difficult drop-off, good weatherability, holding the most easy to change, long-term are attractive in appearance.

Description

A kind of ultrawhite environmental protection safety glass ink and preparation method thereof

Technical field

The present invention relates to glass ink technical field, specifically, relate to a kind of ultrawhite environmental protection safety glass oil Ink and preparation method thereof.

Background technology

Development and people along with industries such as building, automobile, decorations, furniture, information industry technology Raising to living space environmental requirement, the functional converted products such as safety glass, energy-conservation double glazing obtains To extensively application.The supply and demand general layout of plate glass and consumption structure change.

On safety glass goods, the application of typography is the most increasingly extensive.In our daily life, just There are a lot of safety glass goods such as sliding door, tea set, disinfection cabinet, baking box, furniture, windshield etc., These glasss become magnificent mansion, colourful through the decoration of typography.Not only add product The added value of product, has also beautified our life simultaneously.But this in riotous profusion color, how to show？ Yes the ink of leading role among these.

Can be in existing ink, the ink poor adhesive force to glass baseplate, poor water resistance, moist or muddy water connects Occurring coating shedding after touch, weatherability is poor, easy to change, can not long-term use attractive in appearance.Have for printing Ink, printing adaptability is poor, can have inconsistent because of the difference of the conditions such as season, humidity, temperature Using effect.

Some ink contains toxic stronger organic solvent, such as benzene class, ketones solvent or exists containing heavy metal element In ink, during Printing ink producing when solvent is dealt with improperly, easily the health of Workers Producing Printing Ink is made Become injury；During printing, the evaporation of the solvent that contained toxicity is stronger in ink, also can produce the health of printing worker Raw certain injury；Owing to remaining a certain amount of solvent on leaflet, these solvents are by generation abnormal flavour and affect Leaflet user healthy.

Summary of the invention

Instant invention overcomes shortcoming of the prior art, it is provided that a kind of ultrawhite environmental protection safety glass ink and Preparation method, its not only high-efficiency environment friendly, pollution-free, and there is high whiteness, high rigidity, super abrasive, resistance to The good characteristics such as soda acid.

In order to solve above-mentioned technical problem, the present invention is achieved by the following technical solutions:

A kind of ultrawhite environmental protection safety glass ink, each component comprised and percentage by weight thereof are as follows:

Coloring agent: 18%～30%；

Glass base glaze: 50%～60%；

Varnish: 18%～30%；

Additive: 0.1%～1%.

Further, described coloring agent is mainly zinc oxide or titanium dioxide.

Further, described glass base glaze mainly includes boron oxide, silicon oxide, zinc oxide, sodium oxide, oxygen Change potassium, aluminium oxide and Zirconium oxide.

Further, described glass base glaze include 35% boron oxide, 39% silicon oxide, 5% zinc oxide, 5% sodium oxide, 5% potassium oxide, 5% aluminium oxide and 1% Zirconium oxide.

Further, described varnish mainly includes Oleum Terebinthinae, Oleum Pini ester, rosin resin and ethyl cellulose.

Further, described varnish include 30% Oleum Terebinthinae, the Oleum Pini ester of 30%, 20% rosin resin, 20% Ethyl cellulose.

Further, described additive includes organic silicon defoamer.

A kind of preparation method of ultrawhite environmental protection safety glass ink,

First, boron oxide compound, Si oxide, zinc oxide, na oxide, potassium oxide, aluminum oxidation are taken Thing and Zirconium oxide put into 1100-1300 degree celsius temperature fusing in high temperature-resistant pliers boiler so that it is melt liquid stream Entering in water, after drying, then be broken into glass dust with gravity and i.e. obtain glass base glaze, mounted box is stand-by；

Secondly, take Oleum Terebinthinae, Oleum Pini ester, rosin resin, ethyl cellulose are stirred mix homogeneously, make Varnish, mounted box is stand-by；

Finally, take above-mentioned glass base glaze, varnish, coloring agent, add appropriate additive stirring mixing all Even, resulting materials is carried out ball mill grinding and packs to certain fineness.

Compared with prior art, the invention has the beneficial effects as follows:

A kind of ultrawhite environmental protection safety glass ink of the present invention, to environment and man body pollution, difficult drop-off, Good weatherability, holding the most easy to change, long-term are attractive in appearance.

Detailed description of the invention

A kind of ultrawhite environmental protection safety glass ink of the present invention, each component comprised and percentage by weight thereof As follows:

Coloring agent is mainly zinc oxide or titanium dioxide.

Glass base glaze mainly includes boron oxide, silicon oxide, zinc oxide, sodium oxide, potassium oxide, aluminium oxide And Zirconium oxide.

Glass base glaze include 35% boron oxide, 39% silicon oxide, 5% zinc oxide, 5% sodium oxide, 5% potassium oxide, 5% aluminium oxide and 1% Zirconium oxide.

Varnish mainly includes Oleum Terebinthinae, Oleum Pini ester, rosin resin and ethyl cellulose.

Varnish include 30% Oleum Terebinthinae, the Oleum Pini ester of 30%, 20% rosin resin, 20% ethyl cellulose.

Additive includes organic silicon defoamer.

The preparation method of a kind of ultrawhite environmental protection safety glass ink of the present invention is:

First, produce glass base glaze: in the following proportions: 35% boron oxide, 39% silicon oxide, 5% zinc oxide, 5% Sodium oxide, 5% potassium oxide, 5% aluminium oxide, 1% Zirconium oxide etc., put into 1300 degree of temperature in high temperature-resistant pliers boiler Fusing so that it is melt liquid flows in water, the melt after drying, then is broken into glass with gravity, to obtain final product Glass base glaze, mounted box is stand-by；

Secondly, the Oleum Terebinthinae, the Oleum Pini ester of 30%, 20% rosin resin, 20% ethyl cellulose that take 30% stir Mixing mix homogeneously, make varnish, mounted box is stand-by；

Finally, take 59.5% glass base glaze, the titanium dioxide coloring agent of 20%, the varnish of 20%, add 0.5% Silicone additives be uniformly mixed, pack after resulting materials is carried out being milled to certain fineness.

Last it is noted that these are only the preferred embodiments of the present invention, it is not limited to this Bright, although the present invention being described in detail with reference to embodiment, for a person skilled in the art, Technical scheme described in foregoing embodiments still can be modified by it, or to wherein portion of techniques Feature carries out equivalent, but all within the spirit and principles in the present invention, any amendment of being made, etc. With replacement, improvement etc., should be included within the scope of the present invention.

Claims

1. a ultrawhite environmental protection safety glass ink, it is characterised in that: each component comprised and percentage by weight thereof are as follows: 20% titanium dioxide coloring agent, 59.5% glass base glaze, 20% varnish and 0.5% organic silicon defoamer；Wherein, described glass base glaze is by the component composition of following percentage by weight: 35% boron oxide, 39% silicon oxide, 5% zinc oxide, 5% sodium oxide, 5% potassium oxide, 5% aluminium oxide, 1% Zirconium oxide；Described varnish is by the component composition of following percentage by weight: 30% Oleum Terebinthinae, 30% Oleum Pini ester, 20% rosin resin, 20% ethyl cellulose；

The preparation method of this ultrawhite environmental protection safety glass ink comprises the steps:

First, produce glass base glaze: in the following proportions: 35% boron oxide, 39% silicon oxide, 5% zinc oxide, 5% sodium oxide, 5% potassium oxide, 5% aluminium oxide, 1% Zirconium oxide, put in high temperature-resistant pliers boiler 1300 degree temperature melting, its melt liquid is made to flow in water, melt after drying, being broken into glass with gravity again, obtain glass base glaze, mounted box is stand-by；

Secondly, taking 30% Oleum Terebinthinae, 30% Oleum Pini ester, 20% rosin resin, 20% ethyl cellulose are stirred mix homogeneously, make varnish, mounted box is stand-by；

Finally, take 59.5% glass base glaze, 20% titanium dioxide coloring agent, 20% varnish, add 0.5% organic silicon defoamer and be uniformly mixed, pack after resulting materials is carried out being milled to certain fineness.