Summary of the invention
Technical problem to be solved by this invention is to provide a kind of biomass coal-water slurry utilizing feather to prepare.
Solving the problems of the technologies described above adopted technical scheme is: this biomass coal-water slurry is by feather hydrolysis liquid or feather hydrolysis sulfonated liquid, coal dust, water forms, wherein in feather hydrolysis liquid or feather hydrolysis sulfonated liquid, in the quality of solid matter and coal dust, the mass ratio of butt coal is 0.15 ~ 1.5:100, the mass percentage concentration of described biomass coal-water slurry is not less than 60%, the size-grade distribution of biomass coal-water slurry is < 14 order 100%, < 20 order 98% ~ 100%, < 40 order 90% ~ 98%, < 120 order 50% ~ 60%, < 200 order 40% ~ 50%, < 320 order 25% ~ 40%.
In the preferred feather hydrolysis liquid of the present invention or feather hydrolysis sulfonated liquid, in the quality of solid matter and coal dust, the mass ratio of butt coal is 0.3 ~ 0.5:100.
The preparation method of above-mentioned feather hydrolysis liquid is: by sodium hydroxide, feather, water mixing, in mixture, the mass percentage of sodium hydroxide is 3% ~ 7%, the mass percentage of feather is 20% ~ 35%, at 60 ~ 90 DEG C, stir hydrolysis 2 ~ 10 hours, obtain feather hydrolysis liquid.
The preferred preparation method of above-mentioned feather hydrolysis liquid is: by sodium hydroxide, feather, water mixing, in mixture, the mass percentage of sodium hydroxide is 3% ~ 7%, the mass percentage of feather is 30%, stirs hydrolysis 3 hours, obtain feather hydrolysis liquid at 80 DEG C.
The preparation method of above-mentioned feather hydrolysis sulfonated liquid is: by sodium hydroxide, feather, S-WAT, water mixing, in mixture, the mass percentage of sodium hydroxide is 4% ~ 7%, the mass percentage of S-WAT is 5% ~ 12%, the mass percentage of feather is 17% ~ 25%, at 70 ~ 90 DEG C, stir hydrolysis sulfonation 1.5 ~ 4 hours, obtain feather hydrolysis sulfonated liquid.
The preferred preparation method of above-mentioned feather hydrolysis sulfonated liquid is: by sodium hydroxide, feather, S-WAT, water mixing, in mixture, the mass percentage of sodium hydroxide is 4% ~ 7%, the mass percentage of S-WAT is 8% ~ 11%, the mass percentage of feather is 20% ~ 25%, at 85 DEG C, stir hydrolysis sulfonation 2 hours, obtain feather hydrolysis sulfonated liquid.
Feather is first used basic hydrolysis by the present invention, or sulfonation while hydrolysis, obtain feather hydrolysis liquid or feather hydrolysis sulfonated liquid, the slurrying together with coal, water by feather hydrolysis liquid or feather hydrolysis sulfonated liquid again, obtains the biomass coal-water slurry of feather hydrolysis liquid or feather hydrolysis sulfonated liquid replacement slurries additive agent.The present invention is that the recycling of feather opens a new way, achieves the utilization of indumentaum hair, also the residuum of the other utilization technology of feather (as: cock skin produced in eider down preparation process, pinna rachis etc.) can be used.The present invention, while recycling feather, does not need to add slurries additive agent, further saves slurrying cost.In addition, the process that the present invention prepares feather hydrolysis liquid or feather hydrolysis sulfonated liquid is carried out under high temperature and strong alkaline condition, under the qualified condition of protection condition, and the recycling of the poultry that likely realizes dying of illness.
Embodiment
Below in conjunction with embodiment, the present invention is described in more detail, but protection scope of the present invention is not limited only to these embodiments.
Embodiment 1
Middle coal is covered large mining industry coal (water ratio is 7%) to join in sampling machine and grind, obtain the coal dust that size-grade distribution is < 14 order 100%, < 20 order 98.93%, < 40 order 96.46%, < 120 order 61.76%, < 200 order 44.4%, < 320 order 36.37%.
Cutting to length by 30.0g chicken feather scissors is about 0.5cm, puts into three mouthfuls of round-bottomed flasks, adds 5.0g sodium hydroxide, 65.0g water, stirs hydrolysis 3 hours, obtain feather hydrolysis liquid at 80 DEG C.
300.0g coal dust (water ratio is 7%), 1.3g feather hydrolysis liquid (mass percentage concentration of solid matter is 32.5%) are added in 136.8g water, wherein in feather hydrolysis liquid, in the quality of solid matter and coal dust, the mass ratio of butt coal is 0.15:100, stir 20 minutes, obtain biomass coal-water slurry.The mass percentage concentration utilizing DSH-50-5 type moisture teller (Yue Ping scientific instrument company limited provides by Shanghai) to measure biomass coal-water slurry according to GB GB/T18856.2-2008 is 62.15%, the viscosity utilizing NDJ-5S type rotational viscosimeter (Yue Ping scientific instrument company limited provides by Shanghai) to measure biomass coal-water slurry according to GB GB/T18856.4-2008 is 502.0mPas, utilizing pH meter to measure its pH value according to GB GB/T18856.7-2008 is 8.45, size-grade distribution is < 14 order 100%, < 20 order 99.02%, < 40 order 96.21%, < 120 order 58.01%, < 200 order 43.64%, < 320 order 36.66%, within 24 hours, syneresis rate is 4.5%, place and produce without hard-caked sediment for 5 days.
Embodiment 2
Cutting to length by 30.0g chicken feather scissors is about 0.5cm, puts into three mouthfuls of round-bottomed flasks, adds 3.0g sodium hydroxide, 77.0g water, stirs hydrolysis 2 hours, obtain feather hydrolysis liquid at 90 DEG C.
300g embodiment 1 is ground the coal dust (water ratio is 7%) obtained, 1.75g feather hydrolysis liquid (mass percentage concentration of solid matter is 31.39%) adds in 123.7g water, wherein in feather hydrolysis liquid, in the quality of solid matter and coal dust, the mass ratio of butt coal is 0.2:100, stir 15 minutes, obtain biomass coal-water slurry, its mass percentage concentration is 65.08%, viscosity is 648mPas, pH value is 8.34, size-grade distribution is < 14 order 100%, < 20 order 99.50%, < 40 order 97.21%, < 120 order 58.01%, < 200 order 41.64%, < 320 order 36.66%, within 24 hours, syneresis rate is 4.0%, place and produce without hard-caked sediment for 3 days.
Embodiment 3
Cutting to length by 35.0g chicken feather scissors is about 0.5cm, puts into three mouthfuls of round-bottomed flasks, adds 7.0g sodium hydroxide, 58.0g water, stirs hydrolysis 10 hours, obtain feather hydrolysis liquid at 60 DEG C.
300g embodiment 1 is ground the coal dust (water ratio is 7%) obtained, 10.5g feather hydrolysis liquid (mass percentage concentration of solid matter is 40%) adds in 101.3g water, wherein in feather hydrolysis liquid, in the quality of solid matter and coal dust, the mass ratio of butt coal is 1.5:100, stir 15 minutes, obtain biomass coal-water slurry, its mass percentage concentration is 70.77%, viscosity is 1125.0mPas, pH value is 8.43, size-grade distribution is < 14 order 100%, < 20 order 99.50%, < 40 order 97.21%, < 120 order 58.01%, < 200 order 41.64%, < 320 order 36.66%, within 24 hours, syneresis rate is 0.71%, place and produce without hard-caked sediment for 3 days.
Embodiment 4
Yulin Hang Laiwan coal (water ratio is 8%) is joined in sampling machine and grinds, obtains the coal dust that size-grade distribution is < 14 order 100%, < 20 order 98.93%, < 40 order 93.27%, < 120 order 58.93%, < 200 order 47.10%, < 320 order 37.06%.
Cutting to length by 20.0g chicken feather scissors is about 0.5cm, puts into three mouthfuls of round-bottomed flasks, adds 4.0g sodium hydroxide, 8.0g S-WAT, 59.0g water, stirs hydrolysis sulfonation 2 hours, obtain feather hydrolysis sulfonated liquid at 85 DEG C.
By 130.0g coal dust (water ratio is 8%), 1.1g feather hydrolysis sulfonated liquid (mass percentage concentration of solid matter is 33.9%) adds in 75.4g water, wherein in feather hydrolysis sulfonated liquid, in the quality of solid matter and coal dust, the mass ratio of butt coal is 0.3:100, stir 15 minutes, obtain biomass coal-water slurry, its mass percentage concentration is 62.63%, viscosity is 691mPas, pH value is 8.0, size-grade distribution is < 14 order 100%, < 20 order 99.50%, < 40 order 97.21%, < 120 order 58.01%, < 200 order 41.64%, < 320 order 36.66%, within 24 hours, syneresis rate is 4.54%, place and produce without hard-caked sediment for 24 hours.
Embodiment 5
Cutting to length by 20.0g chicken feather scissors is about 0.5cm, puts into three mouthfuls of round-bottomed flasks, adds 6.67g sodium hydroxide, 6.67g S-WAT, 62.0g water, stirs hydrolysis sulfonation 4 hours, obtain feather hydrolysis sulfonated liquid at 70 DEG C.
130.0g embodiment 5 is ground the coal dust (water ratio is 8%) obtained, 0.5g feather hydrolysis sulfonated liquid (mass percentage concentration of solid matter is 34.32%) adds in 66.0g water, wherein in feather hydrolysis sulfonated liquid, in the quality of solid matter and coal dust, the mass ratio of butt coal is 0.15:100, stir 15 minutes, obtain biomass coal-water slurry, its mass percentage concentration is 65.1%, viscosity is 1010.3mPas, pH value is 8.63, size-grade distribution is < 14 order 100%, < 20 order 99.50%, < 40 order 97.21%, < 120 order 58.01%, < 200 order 41.64%, < 320 order 36.66%, within 24 hours, syneresis rate is 2.96%, place and produce without hard-caked sediment for 24 hours.
Embodiment 6
Cutting to length by 20.0g chicken feather scissors is about 0.5cm, puts into three mouthfuls of round-bottomed flasks, adds 6.7g sodium hydroxide, 13.3g S-WAT, 74.0g water, stirs hydrolysis sulfonation 4 hours, obtain feather hydrolysis sulfonated liquid at 70 DEG C.
130.0g embodiment 5 is ground the coal dust (water ratio is 8%) obtained, 5.3g feather hydrolysis sulfonated liquid (mass percentage concentration of solid matter is 33.8%) adds in 75.5g water, wherein in feather hydrolysis sulfonated liquid, in the quality of solid matter and coal dust, the mass ratio of butt coal is 1.5:100, stir 15 minutes, obtain biomass coal-water slurry, its mass percentage concentration is 62.5%, viscosity is 725mPas, pH value is 8.1, size-grade distribution is < 14 order 100%, < 20 order 99.50%, < 40 order 97.21%, < 120 order 58.01%, < 200 order 41.64%, < 320 order 36.66%, within 24 hours, syneresis rate is 5.5%, place and produce without hard-caked sediment for 24 hours.
Embodiment 7
Cutting to length by 20.0g chicken feather scissors is about 0.5cm, puts into three mouthfuls of round-bottomed flasks, adds 4g sodium hydroxide, 4.3g S-WAT, 52.0g water, stirs hydrolysis sulfonation 4 hours, obtain feather hydrolysis sulfonated liquid at 70 DEG C.
130.0g embodiment 5 is ground the coal dust (water ratio is 8%) obtained, 2.05g feather hydrolysis sulfonated liquid (mass percentage concentration of solid matter is 31.0%) adds in 75.5g water, wherein in feather hydrolysis sulfonated liquid, in the quality of solid matter and coal dust, the mass ratio of butt coal is 0.5:100, stir 15 minutes, obtain biomass coal-water slurry, its mass percentage concentration is 62.2%, viscosity is 837mPas, pH value is 8.6, size-grade distribution is < 14 order 100%, < 20 order 99.60%, < 40 order 97.31%, < 120 order 57.03%, < 200 order 42.60%, < 320 order 35.56%, within 24 hours, syneresis rate is 4.5%, place and produce without hard-caked sediment for 24 hours.