CN104212384B - A kind of preparation method of the resistant to elevated temperatures adhesive being connected with PVC for metal - Google Patents
A kind of preparation method of the resistant to elevated temperatures adhesive being connected with PVC for metal Download PDFInfo
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- CN104212384B CN104212384B CN201410509026.9A CN201410509026A CN104212384B CN 104212384 B CN104212384 B CN 104212384B CN 201410509026 A CN201410509026 A CN 201410509026A CN 104212384 B CN104212384 B CN 104212384B
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- 239000000853 adhesive Substances 0.000 title claims abstract description 32
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 32
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 26
- 239000002184 metal Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 239000000203 mixture Substances 0.000 claims abstract description 35
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 21
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 19
- 239000005011 phenolic resin Substances 0.000 claims abstract description 19
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 12
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 12
- 238000003756 stirring Methods 0.000 claims abstract description 8
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910021626 Tin(II) chloride Inorganic materials 0.000 claims abstract description 7
- 229920005549 butyl rubber Polymers 0.000 claims abstract description 7
- 239000012467 final product Substances 0.000 claims abstract description 7
- 229920002689 polyvinyl acetate Polymers 0.000 claims abstract description 7
- 239000011118 polyvinyl acetate Substances 0.000 claims abstract description 7
- 229920005989 resin Polymers 0.000 claims abstract description 7
- 239000011347 resin Substances 0.000 claims abstract description 7
- 238000010074 rubber mixing Methods 0.000 claims abstract description 7
- 239000001119 stannous chloride Substances 0.000 claims abstract description 7
- 235000011150 stannous chloride Nutrition 0.000 claims abstract description 7
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003292 glue Substances 0.000 claims description 10
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical group C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 claims description 6
- 239000003822 epoxy resin Substances 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 229920000647 polyepoxide Polymers 0.000 claims description 6
- 238000007670 refining Methods 0.000 claims description 6
- 238000012986 modification Methods 0.000 claims description 5
- 230000004048 modification Effects 0.000 claims description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract description 12
- 229920001083 polybutene Polymers 0.000 abstract description 11
- 239000011787 zinc oxide Substances 0.000 abstract description 6
- 238000005516 engineering process Methods 0.000 abstract description 2
- 238000006243 chemical reaction Methods 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- -1 polyethylene Polymers 0.000 description 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 229920002313 fluoropolymer Polymers 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- NNNLYDWXTKOQQX-UHFFFAOYSA-N 1,1-di(prop-2-enoyloxy)propyl prop-2-enoate Chemical compound C=CC(=O)OC(CC)(OC(=O)C=C)OC(=O)C=C NNNLYDWXTKOQQX-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 241001330002 Bambuseae Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920005479 Lucite® Polymers 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 125000003709 fluoroalkyl group Chemical group 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
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- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to the preparation method of a kind of resistant to elevated temperatures adhesive being connected with PVC for metal, belong to field of adhesive technology.Comprise the steps: the 1st step, by weight, butyl rubber 50～70 parts, acrylic resin 10～20 parts, phenolic resin 5～10 parts, polybutene 3～5 parts, tributyl phosphate 4～8 parts, white carbon are mixed 10～20 parts and close uniformly, rubber mixing machine is plasticated uniformly, obtain mixture I；2nd step, polyvinyl acetate resin 5～10 parts are dissolved in acetone 10～20 parts, then age resistor, stannous chloride, zinc oxide, mix homogeneously, obtain mixtures II；3rd step, mixture I and mixtures II are added in ethyl acetate 70～90 parts, stir, to obtain final product.The adhesive that the metal that the present invention provides is connected with PVC can still be able to keep preferable adhesive strength after at high temperature using.
Description
Technical field
The present invention relates to the preparation method of a kind of resistant to elevated temperatures adhesive being connected with PVC for metal, belong to adhesive
Technical field.
Background technology
Metal and the adhesive that plastics connect can the viscous transparent or white plastic goods of bonding various difficulties such as: polyethylene
(PE), polypropylene (PP), polrvinyl chloride (PVC), ABS, nylon, sponge, thin film, foam plastics etc.；To lucite, rubber,
Metal, bamboo timber, fabric paper also have preferable bonding force. and especially plastics are glued with metal, the mutual of nonmetallic materials and intersect
Bonding have more distinctive feature, be that the industries such as household electrical appliances industry, radio industry, decoration, packages printing preferably bond material
Material.
CN102585739 B discloses a kind of adhesive for fluoroplastics with metal bonding, and concrete preparation method is to use
Crylic acid hydroxy ester and the di-isocyanate reaction self-control acrylate containing-NCO, closes-NCO with end-capping reagent, with its with
Fluoroalkyl and epoxy acrylate carry out copolymerization, and during use, heating makes the isocyanates of closing unseal, it is achieved glue
Glutinous agent self-curing.It is bonding with the metal such as rustless steel, copper that this adhesive is applicable to the fluoroplastics such as PTFE, PVDF, ETFE.But should
Adhesive is when being applied to metal and being connected with PVC, however it remains adhesive strength the highest, and at high temperature there will be connectivity
The problem that can decline.
Summary of the invention
The technical problem to be solved is: be applied to after the adhesive that metal is connected with PVC at high temperature uses
There will be adhesive strength to decline, its preparation method is improved, propose a kind of resistant to elevated temperatures be connected with PVC for metal
The preparation method of adhesive.
Technical scheme:
The preparation method of a kind of resistant to elevated temperatures adhesive being connected with PVC for metal, comprises the steps:
1st step, by weight, by butyl rubber 50～70 parts, acrylic resin 10～20 parts, phenolic resin 5～10
Part, polybutene 3～5 parts, tributyl phosphate 4～8 parts, white carbon mix 10～20 parts and close uniformly, plasticate uniformly on rubber mixing machine,
To mixture I；
2nd step, polyvinyl acetate resin 5～10 parts are dissolved in acetone 10～20 parts, then age resistor, stannous chloride,
Zinc oxide, mix homogeneously, obtain mixtures II；
3rd step, mixture I and mixtures II are added in ethyl acetate 70～90 parts, stir, to obtain final product.
Between the molecular weight 100000～200000 of described polybutene.
Described age resistor is antioxidant MB.
Described phenolic resin is phenolic resin 2123.
In the 1st described step, the temperature of refining glue controls between 150～160 DEG C.
The particle diameter of described white carbon is 200～400 mesh.
Described acrylic resin is through epoxy resin modification.
Beneficial effect
The adhesive that the metal that the present invention provides is connected with PVC can still be able to keep preferable viscose glue after at high temperature using
Intensity.
Detailed description of the invention
Embodiment 1
The preparation method of a kind of resistant to elevated temperatures adhesive being connected with PVC for metal, comprises the steps:
1st step, by butyl rubber 50Kg, acrylic resin 10Kg, phenolic resin 5Kg, polybutene 3Kg, tributyl phosphate
4Kg, white carbon mix 10Kg and close uniformly, plasticate uniformly on rubber mixing machine, and the temperature of refining glue controls, between 150 DEG C, to be mixed
Thing I；
2nd step, polyvinyl acetate resin 5Kg is dissolved in acetone 10Kg, then age resistor, stannous chloride, zinc oxide, mixed
Close uniformly, obtain mixtures II；
3rd step, mixture I and mixtures II are added in ethyl acetate 70Kg, stir, to obtain final product.
Between the molecular weight 100000～200000 of polybutene, age resistor is antioxidant MB, and phenolic resin is phenolic resin
2123, the particle diameter of white carbon is 200～400 mesh.
Embodiment 2
The preparation method of a kind of resistant to elevated temperatures adhesive being connected with PVC for metal, comprises the steps:
1st step, by butyl rubber 70Kg, acrylic resin 20Kg, phenolic resin 10Kg, polybutene 5Kg, tributyl phosphate
8Kg, white carbon mix 20Kg and close uniformly, plasticate uniformly on rubber mixing machine, and the temperature of refining glue controls, between 160 DEG C, to be mixed
Thing I；
2nd step, polyvinyl acetate resin 10Kg is dissolved in acetone 20Kg, then age resistor, stannous chloride, zinc oxide,
Mix homogeneously, obtains mixtures II；
3rd step, mixture I and mixtures II are added in ethyl acetate 90Kg, stir, to obtain final product.
Between the molecular weight 100000～200000 of polybutene, age resistor is antioxidant MB, and phenolic resin is phenolic resin
2123, the particle diameter of white carbon is 200～400 mesh.
Embodiment 3
The preparation method of a kind of resistant to elevated temperatures adhesive being connected with PVC for metal, comprises the steps:
1st step, by butyl rubber 60Kg, acrylic resin 16Kg, phenolic resin 6Kg, polybutene 4Kg, tributyl phosphate
6Kg, white carbon mix 16Kg and close uniformly, plasticate uniformly on rubber mixing machine, and the temperature of refining glue controls, between 156 DEG C, to be mixed
Thing I；
2nd step, polyvinyl acetate resin 7Kg is dissolved in acetone 17Kg, then age resistor, stannous chloride, zinc oxide, mixed
Close uniformly, obtain mixtures II；
3rd step, mixture I and mixtures II are added in ethyl acetate 80Kg, stir, to obtain final product.
Between the molecular weight 100000～200000 of polybutene, age resistor is antioxidant MB, and phenolic resin is phenolic resin
2123, the particle diameter of white carbon is 200～400 mesh.
Embodiment 4
Difference with embodiment 3 is: the acrylic resin in the 1st step is through epoxy resin modification.Method of modifying
It is: reactor adds E-44 epoxy resin 10 Kg, methyl methacrylate 20 Kg, starts stirring, be warmed up to 80 DEG C, drip
Add acrylic acid 3 Kg, after all dripping off, react 2 h.By 1-Octyl acrylate 15 Kg, styrene 10 Kg, Hydroxypropyl acrylate
10 Kg, trimethyol propane triacrylate 2 Kg mix with initiator azobisisobutyronitrile 2 Kg.After all dissolving, drip
Enter in reaction bulb.Reaction 2～3h.Cooling, stopped reaction, obtain the acrylic resin of epoxy resin modification.
The preparation method of a kind of resistant to elevated temperatures adhesive being connected with PVC for metal, comprises the steps:
1st step, by butyl rubber 60Kg, the acrylic resin 16Kg of epoxy resin modification, phenolic resin 6Kg, polybutene
4Kg, tributyl phosphate 6Kg, white carbon mix 16Kg and close uniformly, plasticate uniformly on rubber mixing machine, and the temperature of refining glue controls at 156 DEG C
Between, obtain mixture I；
2nd step, polyvinyl acetate resin 7Kg is dissolved in acetone 17Kg, then age resistor, stannous chloride, zinc oxide, mixed
Close uniformly, obtain mixtures II；
3rd step, mixture I and mixtures II are added in ethyl acetate 80Kg, stir, to obtain final product.
Between the molecular weight 100000～200000 of polybutene, age resistor is antioxidant MB, and phenolic resin is phenolic resin
2123, the particle diameter of white carbon is 200～400 mesh.
Performance test
Use adhesive viscose glue rubber and the metal sample of each embodiment:
PVC sheet, width is 25mm, and thickness is 3mm, and length is 300mm
Stainless steel substrates, width is 25mm, and thickness is 4mm, and length is 350 mm
Adhering method: the one side at PVC sheet and stainless steel substrates is uniformly coated with one layer of glue, gluing length more than 100 mm,
Coated face is glued together, and room temperature is placed 5 days under pressure, then places it in and dries 5 hours at 130 DEG C, cold
But can test to room temperature.Method of testing is GB/T2790-1995.
High temperature resistant test:
The sample made is put and keeps 1010 days at 100 DEG C, after taking-up, test peel strength.
Result of the test is:
As can be seen from the table, the adhesive strength of the adhesive that the present invention provides is good, after applied at elevated temperature is tested, still
So can keep higher adhesive strength, by acrylic resin is modified in embodiment 4, can significantly increase bonding
Intensity and resistance to elevated temperatures.
Claims (6)
1. the preparation method of the resistant to elevated temperatures adhesive being connected with PVC for metal, it is characterised in that include walking as follows
Rapid:
1st step, by weight, by butyl rubber 50～70 parts, acrylic resin 10～20 parts, phenolic resin 5～10 parts, poly-
Butylene 3～5 parts, tributyl phosphate 4～8 parts, white carbon 10～20 parts of mix homogeneously, plasticate on rubber mixing machine uniformly, mixed
Compound I；
2nd step, polyvinyl acetate resin 5～10 parts are dissolved in acetone 10～20 parts, then age resistor, stannous chloride, oxidation
Zinc, mix homogeneously, obtain mixtures II；
3rd step, mixture I and mixtures II are added in ethyl acetate 70～90 parts, stir, to obtain final product.
The preparation method of the resistant to elevated temperatures adhesive being connected with PVC for metal the most according to claim 1, its feature exists
In: described age resistor is antioxidant MB.
The preparation method of the resistant to elevated temperatures adhesive being connected with PVC for metal the most according to claim 1, its feature exists
In: described phenolic resin is phenolic resin 2123.
The preparation method of the resistant to elevated temperatures adhesive being connected with PVC for metal the most according to claim 1, its feature exists
In: in the 1st described step, the temperature of refining glue controls between 150～160 DEG C.
The preparation method of the resistant to elevated temperatures adhesive being connected with PVC for metal the most according to claim 1, its feature exists
In: the particle diameter of described white carbon is 200～400 mesh.
The preparation method of the resistant to elevated temperatures adhesive being connected with PVC for metal the most according to claim 1, its feature exists
In: described acrylic resin is through epoxy resin modification.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410509026.9A CN104212384B (en) | 2014-09-28 | 2014-09-28 | A kind of preparation method of the resistant to elevated temperatures adhesive being connected with PVC for metal |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410509026.9A CN104212384B (en) | 2014-09-28 | 2014-09-28 | A kind of preparation method of the resistant to elevated temperatures adhesive being connected with PVC for metal |
Publications (2)
| Publication Number | Publication Date |
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| CN104212384A CN104212384A (en) | 2014-12-17 |
| CN104212384B true CN104212384B (en) | 2016-09-14 |
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| CN201410509026.9A Active CN104212384B (en) | 2014-09-28 | 2014-09-28 | A kind of preparation method of the resistant to elevated temperatures adhesive being connected with PVC for metal |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105038660A (en) * | 2015-08-14 | 2015-11-11 | 重庆佐恩家具有限公司 | Metal adhesive glue used for high temperature |
| CN107129775A (en) * | 2017-05-22 | 2017-09-05 | 罗建华 | A kind of two-component butyl rubber adhesive and adhesive method |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6087047A (en) * | 1983-10-20 | 1985-05-16 | 三井化学株式会社 | Non-slip polyolefin molded shape |
| CN1195814C (en) * | 2003-01-30 | 2005-04-06 | 江西省励远化工科技实业公司 | Never solidified spot-welding sealant for car and making method |
| JP4572600B2 (en) * | 2004-03-09 | 2010-11-04 | 東海ゴム工業株式会社 | Rubber product manufacturing method and rubber product obtained thereby |
| JP2006123335A (en) * | 2004-10-28 | 2006-05-18 | Tokai Rubber Ind Ltd | Manufacturing method of rubber product and rubber product obtained by the same |
| CN102816535B (en) * | 2012-08-15 | 2014-05-28 | 烟台德邦科技有限公司 | Butyl hot melt adhesive tape and preparation method thereof |
| CN104004278B (en) * | 2014-06-11 | 2016-07-13 | 长春徳联化工有限公司 | A kind of butyl rubber heat insulating mattress material and preparation method thereof |
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2014
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Effective date of registration: 20160810 Address after: West Industrial Park, east of the town of Haian County of Jiangsu Province, Nantong City, 226600 Applicant after: Nantong Hengding Heavy Machine Tool Co., Ltd. Address before: 214000 Huishan Economic Development Zone, Jiangsu province Hui Cheng Road, No. 77, No. Applicant before: Wuxi Kangbaisi Machinery Technology Co., Ltd. |
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Address after: West Industrial Park, east of the town of Haian County of Jiangsu Province, Nantong City, 226600 Patentee after: Jiangsu Hengding Machine Co. Ltd Address before: West Industrial Park, east of the town of Haian County of Jiangsu Province, Nantong City, 226600 Patentee before: Nantong Hengding Heavy Machine Tool Co., Ltd. |
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Effective date of registration: 20191023 Address after: No.88, group 5, Kaiping village, Chengdong Town, Hai'an City, Nantong City, Jiangsu Province Patentee after: Jiangsu Haixun Hengding Machinery Technology Co., Ltd. Address before: West Industrial Park, east of the town of Haian County of Jiangsu Province, Nantong City, 226600 Patentee before: Jiangsu Hengding Machine Co. Ltd |
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| TR01 | Transfer of patent right |
Effective date of registration: 20200927 Address after: 226300 Daqing Road, Jinsha Town, Tongzhou District, Nantong, Jiangsu Province, No. 48 Patentee after: NANTONG TONGLI OIL PUMP Co.,Ltd. Address before: No.88, group 5, Kaiping village, Chengdong Town, Hai'an City, Nantong City, Jiangsu Province Patentee before: Jiangsu Haixun Hengding Machinery Technology Co.,Ltd. |