CN104211821B - A kind of method that air-flow premixing prepares rice starch phosphate monoester - Google Patents
A kind of method that air-flow premixing prepares rice starch phosphate monoester Download PDFInfo
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- 229940100486 rice starch Drugs 0.000 title claims abstract description 48
- 229910019142 PO4 Inorganic materials 0.000 title claims abstract description 39
- 239000010452 phosphate Substances 0.000 title claims abstract description 37
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 title claims abstract description 33
- 238000000034 method Methods 0.000 title claims abstract description 29
- 229920002472 Starch Polymers 0.000 claims abstract description 44
- 239000008107 starch Substances 0.000 claims abstract description 44
- 235000019698 starch Nutrition 0.000 claims abstract description 44
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 238000001035 drying Methods 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 235000021317 phosphate Nutrition 0.000 claims description 34
- 238000006243 chemical reaction Methods 0.000 claims description 17
- 238000010438 heat treatment Methods 0.000 claims description 16
- 239000011259 mixed solution Substances 0.000 claims description 16
- 238000005243 fluidization Methods 0.000 claims description 13
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical class [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims description 12
- 235000019799 monosodium phosphate Nutrition 0.000 claims description 12
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical class [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims description 12
- 238000006467 substitution reaction Methods 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 10
- 238000000889 atomisation Methods 0.000 claims description 9
- 239000000376 reactant Substances 0.000 claims description 9
- 230000004044 response Effects 0.000 claims description 9
- 210000002700 urine Anatomy 0.000 claims 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract description 15
- 239000004202 carbamide Substances 0.000 abstract description 15
- 239000000047 product Substances 0.000 abstract description 14
- 239000007788 liquid Substances 0.000 abstract description 8
- 230000032050 esterification Effects 0.000 abstract description 7
- 238000005886 esterification reaction Methods 0.000 abstract description 7
- 230000008569 process Effects 0.000 abstract description 6
- 230000003712 anti-aging effect Effects 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 235000013305 food Nutrition 0.000 abstract description 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- 238000011031 large-scale manufacturing process Methods 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- 238000004073 vulcanization Methods 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 241000209094 Oryza Species 0.000 description 16
- 235000007164 Oryza sativa Nutrition 0.000 description 16
- 235000009566 rice Nutrition 0.000 description 16
- 238000002156 mixing Methods 0.000 description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
- 239000000243 solution Substances 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 6
- 239000012530 fluid Substances 0.000 description 6
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 4
- 229920002261 Corn starch Polymers 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000008120 corn starch Substances 0.000 description 3
- 229940099112 cornstarch Drugs 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 3
- -1 phosphate ester Chemical class 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- 239000011609 ammonium molybdate Substances 0.000 description 2
- 229940010552 ammonium molybdate Drugs 0.000 description 2
- 235000018660 ammonium molybdate Nutrition 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- WUJISAYEUPRJOG-UHFFFAOYSA-N molybdenum vanadium Chemical compound [V].[Mo] WUJISAYEUPRJOG-UHFFFAOYSA-N 0.000 description 2
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical class O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 238000004380 ashing Methods 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000001079 digestive effect Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000011964 heteropoly acid Substances 0.000 description 1
- 239000010903 husk Substances 0.000 description 1
- ALTWGIIQPLQAAM-UHFFFAOYSA-N metavanadate Chemical compound [O-][V](=O)=O ALTWGIIQPLQAAM-UHFFFAOYSA-N 0.000 description 1
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 1
- 235000019796 monopotassium phosphate Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 238000002798 spectrophotometry method Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Polysaccharides And Polysaccharide Derivatives (AREA)
Abstract
The present invention relates to a kind of method that use air-flow premixing prepares rice starch phosphate monoester, belong to starch field of deep.With rice starch as raw material, orthophosphates is esterifying agent to the present invention, and product is prepared with urea as catalyst, is mainly comprised the following steps：The mixed liquor of orthophosphates and urea and water is adjusted to appropriate pH and is sufficiently mixed by air-flow conveying blender with rice starch, being re-fed into vulcanization bed reactor carries out hot esterification, and end product obtains rice starch phosphate monoester by washing, drying.The inventive method process is simple, low cost, are suitable to industrialization large-scale production, and obtained rice starch phosphate paste liquid is transparent, anti-aging, have good retentiveness, can be used for field of food as emulsifying agent, stabilizer, thickener.
Description
Technical field
The present invention relates to a kind of method that air-flow premixing prepares rice starch phosphate monoester, belong to starch deep processing neck
Domain.
Technical background
In rice, wheat and the generalized grain crop of corn 3, the content of starch in rice tops the list, and content is up to more than 70%.
But because cost of material and domestic consumption level etc. store up multifactor restriction, the existing rank of domestic starch industry material is disconnected with corn and Ma Ling
Based on potato, rice starch only accounts for 13%, but due to the peculiar property of rice starch granule fine uniform, rice starch and its derivative
Special potential value, is just gradually paid close attention to by people.
China's rice has its advantageous superiority, at home and abroad market share consequence, with living standard
Raising, people to rice mouthfeel requirement more and more higher.Due to traditional husk rice technology, and pernicious beating in process is followed
Ring can produce 10%~15% to crack rice, and these crack rice and typically used as feed, but the protein in cracking rice, starch etc. are sought
Support material close with rice, and price only has the 30%~50% of rice, if insufficient rice can be caused to provide original if
Very big waste, therefore research and development product of cracking rice just seems more and more urgent.Due in rice up to 70% content of starch,
Cracking rice can be used as the raw material of production converted starch.
Starch phosphate monoester is the derivative of starch anion, because its gelatinized corn starch has good dispersed transparent degree, viscous
Degree and good freeze-thaw stability, phosphate ester starch are widely used to the industries such as food, chemical industry and medicine.It is with cornstarch
The research that raw material prepares starch phosphate monoester is more, but with rice starch as raw material, prepares starch phosphate monoester, does not see
Systematic account.Therefore, research carries out deep processing making full use of for rice resource by raw material of rice starch, has very
Important meaning.
Current starch phosphate mainly using based on cornstarch and farina, method include wet method, semidry method and
Dry method is several.Wet method esterification degree is than relatively low, it is necessary to substantial amounts of water and organic solvent, subsequent product complex disposal process；Semidry method
Increased with the shortcoming that dry method overcomes wet method, and esterification degree, but, phosphoric acid, phosphate, urea and a small amount of water and starch
Mixing it is uneven, and there are more starch phosphate diester even because of the excessive concentration of local phosphoric acid and phosphate etc.
The products such as three esters, have partial starch not to be esterified when causing reaction, there is ative starch and starch phosphate two more than comparing in product
The ester even product such as three esters, both reduces esterification degree, and product quality is had a strong impact on again.
The content of the invention
Present invention seek to address that the starch resource caused in rice process wastes problem.Therefore, the present invention proposes one
Kind can overcome traditional starch phosphate production method defect, be suitable to industrial-scale production, can to prepare paste liquid saturating
Bright, anti-aging, stability and the good rice starch phosphate monoester of retentiveness, for rice starch deep processing provides a new way
Footpath.
To achieve the above object, the present invention provides following technical scheme：
A kind of method that air-flow premixing prepares rice starch phosphate monoester, with rice starch as raw material, including following step
Suddenly：
(1) a certain amount of sodium dihydrogen phosphate, disodium hydrogen phosphate and water are mixed, adds a certain amount of urea, be made mixed liquor；
(2) in 180 parts of rice starch hot-airs being delivered into fluidization tower, and with setting up at the top of fluidization tower
In fluidization tower be sufficiently mixed uniformly mixed liquor atomisation obtained in step (1) with starch by sprayer；
(3) fluidized-bed reactor is directly entered from the mixture of fluidization tower starch out and orthophosphates mixed solution to enter
Row reaction；
(4) after reaction terminates, reactant is washed, is dried, obtain rice starch phosphate monoester.
In the step (1), by 30~40 parts of sodium dihydrogen phosphates, 80~100 parts of disodium hydrogen phosphates and 80~100 parts of water,
And 8~10 parts of urea are added, it is made mixed liquor.
By mixed liquor and pH to 5~6 is adjusted, be heated to 30~50 DEG C.
During 180 parts of rice starch are delivered into fluidization tower by the step (2) with 50 DEG C of hot-airs.
Step (3) reaction condition is 130~160 DEG C of 2~4h of heating response.
The step (4) is dried to be vacuum dried 24h at pneumatic conveying drying or 50 DEG C.
The step (4) obtains the rice starch phosphate monoester that substitution value is 0.01~0.025.
A kind of rice starch phosphate monoester, is prepared from using method of the present invention, substitution value be 0.01~
0.025。
Beneficial effects of the present invention：The present invention prepares rice starch with rice starch as raw material using air-flow premixed method
Phosphate.The method can belong to semidry method, both overcome wet method esterification degree than relatively low, it is necessary to substantial amounts of water and organic molten
Agent, the shortcoming of subsequent product complex disposal process overcomes original semidry method and dry method phosphoric acid, phosphate, urea and few again
The mixing of amount water and starch is uneven, has partial starch not to be esterified during reaction, there is the ative starch more than comparing and shallow lake in product
The powder di-phosphate ester even shortcomings such as product such as three esters, products obtained therefrom esterification degree is higher, esterification is uniform, do not have ester in product
The starch and starch phosphate diester of the change even product such as three esters are few, product quality stabilization.
Brief description of the drawings
Fig. 1 is present invention process flow chart.
Specific embodiment
A kind of method that air-flow premixing prepares rice starch phosphate monoester, with rice starch as raw material, including following step
Suddenly：
(1) by 30~40 parts of sodium dihydrogen phosphates, 80~100 parts of disodium hydrogen phosphates and 80~100 parts of water, and 8~10 are added
Part urea, is made mixed liquor, and adjusts pH to 5~6, is heated to 30~50 DEG C；
(2) in 180 parts of rice starch being delivered into fluidization tower with 50 DEG C of hot-air, and used at the top of fluidization tower
In fluidization tower be sufficiently mixed the orthophosphates mixed solution atomisation of foregoing heating with starch by the sprayer set up
It is even；
(3) mixture from fluidization tower starch out and orthophosphates mixed solution is directly entered a fluidized-bed reaction
Device, in 130~160 DEG C of 2~4h of heating response；
(4) after reaction terminates, reactant is washed, then by being vacuum dried 24h at pneumatic conveying drying or 50 DEG C, is obtained
Substitution value is 0.01~0.025 rice starch phosphate monoester.
The assay method of rice starch phosphate monoester substitution value：
(1) vanadium molybdenum Huang AAS
0.3g sodium carbonate is dissolved into 2ml distilled water, and 0.5g rice starch phosphates are added to it, by it 100
After fully being dried in the environment of DEG C, 9h is ashed at 550 DEG C.Mixture after ashing is cooled to room temperature, is added to it
The hydrochloric acid of 10ml25%, solution is poured into the beaker containing 50ml distilled water, and be transferred to for filtrate by filtering and collecting filter liquid
In the volumetric flask of 250ml and constant volume, sample test liquid is obtained.10ml sample test liquid is taken, 2ml vanadium ammonium molybdate solution is added, shaken
, after placing 45min, at 435nm wavelength, its absorbance is surveyed, phosphorus content is read from standard curve, standard curve is with two grades
Standard substance potassium dihydrogen phosphate makes.
(2) P-Mo blue AAS
0.5g rice starch phosphates are taken, is put into triumphant formula flask, add 15ml sulfonitric reagents, be gradually heated to
Micro-boiling in bottle, continues to boil to Brown gas and becomes white, untill liquid is clarified.After digestive juice is cooled to room temperature, add
45ml water, pH is brought up into 7 with the sodium hydroxide solution of 10mol/L, then solution in bottle is quantitatively moved into one has suitably
In the volumetric flask of capacity and constant volume, appropriate amount of sample liquid is drawn in 50ml conical flasks, adding 4ml ammonium molybdate solutions in order, then
2ml ascorbic acid solutions are added, is mixed at once after addition and conical flask is placed in 10min in boiling water bath, place into cooling in cold water
To room temperature, quantitatively move into 50ml volumetric flasks, add water to scale.With spectrophotometer in 820nm wavelength mensuration absorbances, from mark
Phosphorus content is read on directrix curve.
Because the P-Mo blue colour developing of, P-Mo blue AAS generation is unstable, change over time larger, and influenceed by pH
It is larger, it is not easy to operate.And under certain acidity, phosphorus and metavanadate and molybdic acid salt action in solution are formed sufficiently stable
Yellow ternary heteropoly acid vanadium molybdic acid phosphoric acid, therefore using vanadium molybdenum Huang spectrophotometry substitution value.
With reference to embodiment, the present invention is further detailed explanation, but the present invention is not limited thereto.
Embodiment 1
(1) by 35 parts of sodium dihydrogen phosphates, 96 parts of disodium hydrogen phosphates and 90 parts of water, and 8 parts of urea are added, are made mixed liquor,
And pH to 5.5 is adjusted, it is heated to 50 DEG C；
(2) in 180 parts of rice starch being delivered into pneumatic conveyer with 50 DEG C of hot-air, and in pneumatic conveyer
The orthophosphates mixed solution atomisation of foregoing heating is filled in pneumatic conveyer with starch with sprayer at front end 1/3
Divide mixing；
(3) mixture from pneumatic conveyer starch out and orthophosphates mixed solution is directly entered a fluid bed
Reactor, in 150 DEG C of heating response 2.5h；
(4) after reaction terminates, reactant is washed, then by being vacuum dried 24h at pneumatic conveying drying or 50 DEG C, is obtained
Substitution value is 0.018 rice starch phosphate monoester.
Embodiment 2
(1) by 30 parts of sodium dihydrogen phosphates, 100 parts of disodium hydrogen phosphates and 90 parts of water, and 9 parts of urea are added, are made mixed liquor,
And pH to 6 is adjusted, it is heated to 45 DEG C；
(2) in 180 parts of rice starch being delivered into pneumatic conveyer with 50 DEG C of hot-air, and in pneumatic conveyer
The orthophosphates mixed solution atomisation of foregoing heating is filled in pneumatic conveyer with starch with sprayer at front end 1/3
Divide mixing；
(3) mixture from pneumatic conveyer starch out and orthophosphates mixed solution is directly entered a fluid bed
Reactor, in 130 DEG C of heating response 4h；
(4) after reaction terminates, reactant is washed, then by being vacuum dried 24h at pneumatic conveying drying or 50 DEG C, is obtained
Substitution value is 0.021 rice starch phosphate monoester.
Embodiment 3
(1) by 40 parts of sodium dihydrogen phosphates, 85 parts of disodium hydrogen phosphates and 100 parts of water, and 10 parts of urea are added, is made mixing
Liquid, and pH to 5 is adjusted, it is heated to 30 DEG C；
(2) in 180 parts of rice starch being delivered into pneumatic conveyer with 50 DEG C of hot-air, and in pneumatic conveyer
The orthophosphates mixed solution atomisation of foregoing heating is filled in pneumatic conveyer with starch with sprayer at front end 1/3
Divide mixing；
(3) mixture from pneumatic conveyer starch out and orthophosphates mixed solution is directly entered a fluid bed
Reactor, in 140 DEG C of heating response 3h；
(4) after reaction terminates, reactant is washed, then by being vacuum dried 24h at pneumatic conveying drying or 50 DEG C, is obtained
Substitution value is 0.015 rice starch phosphate monoester.
Embodiment 4
(1) by 40 parts of sodium dihydrogen phosphates, 92 parts of disodium hydrogen phosphates and 90 parts of water, and 9 parts of urea are added, are made mixed liquor,
And pH to 6 is adjusted, it is heated to 40 DEG C；
(2) in 180 parts of rice starch being delivered into pneumatic conveyer with 50 DEG C of hot-air, and in pneumatic conveyer
The orthophosphates mixed solution atomisation of foregoing heating is filled in pneumatic conveyer with starch with sprayer at front end 1/3
Divide mixing；
(3) mixture from pneumatic conveyer starch out and orthophosphates mixed solution is directly entered a fluid bed
Reactor, in 160 DEG C of heating response 3h；
(4) after reaction terminates, reactant is washed, then by being vacuum dried 24h at pneumatic conveying drying or 50 DEG C, is obtained
Substitution value is 0.022 rice starch phosphate monoester.
Embodiment 5
(1) by 40 parts of sodium dihydrogen phosphates, 80 parts of disodium hydrogen phosphates and 80 parts of water, and 8 parts of urea are added, are made mixed liquor,
And pH to 6 is adjusted, it is heated to 40 DEG C；
(2) in 180 parts of rice starch being delivered into pneumatic conveyer with 50 DEG C of hot-air, and in pneumatic conveyer
The orthophosphates mixed solution atomisation of foregoing heating is filled in pneumatic conveyer with starch with sprayer at front end 1/3
Divide mixing；
(3) mixture from pneumatic conveyer starch out and orthophosphates mixed solution is directly entered a fluid bed
Reactor, in 160 DEG C of heating response 4h；
(4) after reaction terminates, reactant is washed, then by being vacuum dried 24h at pneumatic conveying drying or 50 DEG C, is obtained
Substitution value is 0.019 rice starch phosphate monoester.
Embodiment 6
(1) by 35 parts of sodium dihydrogen phosphates, 80 parts of disodium hydrogen phosphates and 100 parts of water, and 9 parts of urea are added, are made mixed liquor,
And pH to 5 is adjusted, it is heated to 40 DEG C；
(2) in 180 parts of rice starch being delivered into pneumatic conveyer with 50 DEG C of hot-air, and in pneumatic conveyer
The orthophosphates mixed solution atomisation of foregoing heating is filled in pneumatic conveyer with starch with sprayer at front end 1/3
Divide mixing；
(3) mixture from pneumatic conveyer starch out and orthophosphates mixed solution is directly entered a fluid bed
Reactor, in 150 DEG C of heating response 2h；
(4) after reaction terminates, reactant is washed, then by being vacuum dried 24h at pneumatic conveying drying or 50 DEG C, is obtained
Substitution value is 0.013 rice starch phosphate monoester.
It is only above better embodiment of the invention, above-mentioned design of the invention, those skilled in the art
Can also to this various modification can be adapted and conversion.For example, ratio between sodium dihydrogen phosphate, disodium hydrogen phosphate, urea and water and
The temperature and pH value of mixed liquor, the ratio of sodium dihydrogen phosphate, disodium hydrogen phosphate, urea, water and starch, reaction time temperature and when
Between, etc.；However, similar this conversion and modification belongs to essence of the invention.
Claims (1)
1. a kind of method that air-flow premixing prepares rice starch phosphate monoester, it is characterised in that with rice starch as raw material, bag
Include following steps：
(1) by 30~40 parts of sodium dihydrogen phosphates, 80~100 parts of disodium hydrogen phosphates and 80~100 parts of water, and 8~10 parts of urine are added
Element, is made mixed liquor；Mixed liquor is adjusted into pH to 5~6,30~50 DEG C are heated to；
(2) in 180 parts of rice starch being delivered into fluidization tower with 50 DEG C of hot-airs, and with setting up at the top of fluidization tower
In fluidization tower be sufficiently mixed uniformly mixed liquor atomisation obtained in step (1) with starch by sprayer；
(3) being directly entered fluidized-bed reactor from the mixture of fluidization tower starch out and orthophosphates mixed solution is carried out instead
Should；Reaction condition is 130~160 DEG C of 2~4h of heating response；
(4) after reaction terminates, reactant is washed, is dried, obtain rice starch phosphate monoester；The drying be pneumatic conveying drying or
24h is vacuum dried at 50 DEG C of person；Obtain the rice starch phosphate monoester that substitution value is 0.01~0.025.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB815358A (en) * | 1956-06-26 | 1959-06-24 | Scholten Chemische Fab | A process for the manufacture of derivatives of polysaccharides, more particularly of starch, by a dry process |
| CN1337409A (en) * | 2000-08-07 | 2002-02-27 | 国家淀粉及化学投资控股公司 | Improved starch phosphate-ester composition, process and method used for food |
| CN101544702A (en) * | 2009-05-06 | 2009-09-30 | 中南林业科技大学 | Preparation method of phosphate rice starch |
| CN101962414A (en) * | 2010-10-13 | 2011-02-02 | 广西明阳生化科技股份有限公司 | Method for producing aquatic granulated feed adhesive modified starch |
| CN103897068A (en) * | 2014-04-02 | 2014-07-02 | 枣庄超越玉米淀粉有限公司 | Efficient energy-saving production method of modified starch |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3284443A (en) * | 1963-04-17 | 1966-11-08 | American Maize Prod Co | Starch-phosphate reaction products and method of making same |
-
2014
- 2014-09-10 CN CN201410458610.6A patent/CN104211821B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB815358A (en) * | 1956-06-26 | 1959-06-24 | Scholten Chemische Fab | A process for the manufacture of derivatives of polysaccharides, more particularly of starch, by a dry process |
| CN1337409A (en) * | 2000-08-07 | 2002-02-27 | 国家淀粉及化学投资控股公司 | Improved starch phosphate-ester composition, process and method used for food |
| CN101544702A (en) * | 2009-05-06 | 2009-09-30 | 中南林业科技大学 | Preparation method of phosphate rice starch |
| CN101962414A (en) * | 2010-10-13 | 2011-02-02 | 广西明阳生化科技股份有限公司 | Method for producing aquatic granulated feed adhesive modified starch |
| CN103897068A (en) * | 2014-04-02 | 2014-07-02 | 枣庄超越玉米淀粉有限公司 | Efficient energy-saving production method of modified starch |
Non-Patent Citations (1)
| Title |
|---|
| "碎米淀粉及其磷酸酯的制备和理化性质研究";毛海锋;《中国优秀硕士学位论文全文数据库 工程科技I辑》;20111215(第S1期);第B024-73页 * |
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