CN104206536A - Fat-containing acidic beverage - Google Patents

Fat-containing acidic beverage Download PDF

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Publication number
CN104206536A
CN104206536A CN201410341480.8A CN201410341480A CN104206536A CN 104206536 A CN104206536 A CN 104206536A CN 201410341480 A CN201410341480 A CN 201410341480A CN 104206536 A CN104206536 A CN 104206536A
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fatty
fatty acid
ester
weight
acidic beverages
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松浦传史
元田兼一郎
苫米地正基
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Mitsubishi Chemical Foods Corp
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Mitsubishi Chemical Foods Corp
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    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52—Adding ingredients
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs

Abstract

Disclosed is a fat-containing acidic beverage that has a pH of no more than 5 and wherein the occurrence of oil-off and cream separation resulting from the surfacing of fat content during storage is suppressed. The fat-containing acidic beverage has a pH of no more than 5 and contains a water-soluble hemicellulose and a fatty acid ester having a polyoxyalkene chain that has an HLB of at least 11.

Description

Fatty acidic beverages
The application is divisional application, the international application no of its original application is PCT/JP2011/056102, and international filing date is on March 15th, 2011, and China national application number is 201180012927.1, the date entering China is on September 7th, 2012, and denomination of invention is " fatty acidic beverages ".
Technical field
The present invention relates to fatty acidic beverages.
Background technology
In the acidic milk drink containing sour composition and milk composition, propose and do not use skimmed milk power and use the milk composition containing butter oil as the creaminess acidic milk drink (such as, see patent document 1) of milk composition.Disclose in this motion, by containing 0.01 % by weight ~ 5 % by weight water-soluble hemicellulose, suppress long-term between the butterfat that occurs when preserving float, namely breast analyse (ク リ ー ミ Application グ) generation.
In addition, recent preference be there is refrigerant sense, there is more low viscous smooth acidic milk drink, but for this low viscous acidic milk drink, be very difficult to the generation suppressing the precipitation of lactoprotein to be separated with butterfat, require to there is higher emulsion stability, namely require fully to suppress butterfat separation or grease to separate out (oil off, lipochondrion unification or aggegation, fat float due to separation) generation.
Prior art document
Patent document
Patent document 1: Japanese Unexamined Patent Publication 2005-40024 publication
Summary of the invention
Invent problem to be solved
The present invention makes in view of the foregoing, its object is to provide a kind of fatty acidic beverages, even if when being made into low viscous acidic beverages, also can suppress the precipitation of lactoprotein, fully can suppress the generation that butterfat is separated or grease is separated out simultaneously.
For solving the means of problem
The present inventor conducts in-depth research to solve above-mentioned problem, and result has drawn following opinion: namely, by being share together with water-soluble hemicellulose by specific fatty acid ester, easily can reach above-mentioned purpose.
The present invention completes based on above-mentioned opinion, and its main points are that a kind of pH is the fatty acidic beverages of less than 5, and its feature is having, and it contains the fatty acid ester with polyoxyalkylene chain that water-soluble hemicellulose and HLB are more than 11.
The effect of invention
According to the present invention, provide the fatty acidic beverages that a kind of pH is less than 5, even when making low viscous acidic beverages, the precipitation of the protein components such as the lactoprotein contained by also can suppressing in beverage, fully can suppress the generation that butterfat is separated or grease is separated out simultaneously.
Detailed description of the invention
Below describe the present invention in detail.
In the present invention, said fatty acidic beverages refers to by adding the organic acids such as citric acid, lactic acid, acetic acid, fumaric acid, malic acid, gluconic acid, butanedioic acid and/or its salt and carried out the beverage of acidification in fat constituent; Or for the addition of the beverage of fruit juice, fruit vinegar, grain vinegar etc. containing these organic acids and/or its salt; Further for having carried out the beverage of acidification by utilizing Bifidobacterium or lactic acid bacteria etc. to make milk composition ferment.
Fat source used in fatty acidic beverages of the present invention indefinite, use animal fat or vegetablefats usually, from the view point of the taste of gained beverage, and preferred animal fat.
As animal fat sources, as long as just do not limit for the grease of animal origin, usually suitably use the butter oil taked by the mammal such as ox, goat.As the milk composition containing butter oil, suitably whole milk powder be can use, lactogenesis, cow's milk, goat dairy, sweet condensed milk, evaporated milk, cream, acidified milk, butter, modified milk, cheese etc. also can be.Further, they appropriately combinedly can be used, also can use and with food enzymes such as amylase, protease, lipase, phosphatidases, modification be carried out to them and the material obtained.Further, also can use and with emulsifying agent or powder base material etc., they are processed and the liquid state obtained or pulverous emulsion, such as coffeemate, fresh milk wet goods.
As vegetal fat source, as long as the grease of plant origin does not just limit, usually can enumerate: soya-bean milk, cocoa butter, coconut oil, palm oil, palm kernel oil, coconut oil, soybean oil, corn oil, sunflower oil, rice bran oil, vegetable seed wet goods vegetative grease; The grease these vegetative greases refined or is processed by hydrogenation or ester exchange etc.; Or the liquid state utilizing emulsifying agent or powder base material etc. to process these vegetative greases or pulverous emulsion, such as plant fat coffeemate, plant fat whipping cream, plant fat butterfat etc.
The content of fat in acidic beverages indefinite, but be usually preferably 0.015 % by weight ~ 10 % by weight, be more preferably 0.02 % by weight ~ 4 % by weight, more preferably 0.04 % by weight ~ 2 % by weight.If fat is less than above-mentioned lower limit, then the raising of taste is less; If exceed above-mentioned higher limit, then sometimes can not give full play of effect of the present invention.It should be noted that, in fatty acidic beverages of the present invention, also can share the milk composition that the content containing fat constituent or fat constituent such as skimmed milk power, sweetened condensed skimmed milk, skimmed milk is low.
The pH of fatty acidic beverages of the present invention is less than 5, is preferably 3.0 ~ 5.0, more preferably 3.3 ~ 4.6.Thus, by the pH for this scope, can using fatty acidic beverages of the present invention and clearly distinguishing containing newborn coffee (milk coffee) as faintly acid beverage.If pH is higher than above-mentioned higher limit, then easily there is the coagulation sedimentation of lactoprotein.In addition, if acid degree becomes too high, then tart flavour is strong, is sometimes not suitable for as beverage.
Fatty acidic beverages of the present invention contains the fatty acid ester with polyoxyalkylene chain that water-soluble hemicellulose and HLB are more than 11.
The water-soluble hemicellulose used in the present invention can obtain as follows: adopt oily seed (soybean, palm, coconut, corn cottonseed etc.), cereals (rice, wheat etc.), beans (red bean, pea etc.) etc. as raw material, adopt usual way from these raw materials except degrease, protein, starchiness, use the cereal or poor slag (dregs of rice) that obtain, under the condition of acid ~ alkalescence, under pH preferably near the isoelectric point of each protein, be generally 80 DEG C ~ 130 DEG C, at being preferably 100 DEG C ~ 130 DEG C, heat resolve is carried out to it, the separation carrying out water-soluble component directly carries out drying afterwards, or such as carry out charcoal treatment, resin adsorption process or alcohol settling process remove lyophobic dust or lower-molecular substance carries out drying again, thus obtain described water-soluble hemicellulose.
If raw material is soybean, then can utilize the bean dregs (オ カ ラ) as accessory substance when manufacturing bean curd, soya-bean milk and soy protein isolate.The mean molecule quantity of the water-soluble hemicellulose obtained like this is tens thousand of ~ millions of, and it is polysaccharide that roughly 8 of its composition becomes above, and containing coarse ash, crude protein and moisture.In addition, as formation sugar, galactolipin be maximum, next can enumerate uronic acid and arabinose and wood sugar, fucose, rhamnose and glucose.
In the present invention, the raw material as water-soluble hemicellulose is not particularly limited, and from the viewpoint of dissolubility and industrialness, the material in legume sources, particularly soybean-source, wherein cotyledon source is preferred.That is, as water-soluble hemicellulose, preferred feedstock is the polysaccharide (soybean polysaccharides) of the soybean-source of soybean.As the commercially available product of water-soluble hemicellulose, " SOYAFIBE-S-DA100 ", " SOYAFIBE-S-ZR100 " can be enumerated, " SOYAFIBE-S-LA200 " (is manufactured by only liquefaction society above; Trade name) etc.
When using soybean polysaccharides as water-soluble hemicellulose, even if having when carrying out lowering viscousity to fatty acidic beverages, also can suppress lactoprotein that the advantage of precipitation occurs in storage.
For the content (addition) of water-soluble hemicellulose, be preferably 0.001 % by weight ~ 5 % by weight in the ratio in fatty acidic beverages, be more preferably 0.01 % by weight ~ 2 % by weight, more preferably 0.05 % by weight ~ 1 % by weight.When the addition of water-soluble hemicellulose is less than above-mentioned lower limit, sometimes can not give full play of the effect of the precipitation of the protein components such as the lactoprotein suppressing contained in beverage; On the other hand, when exceeding above-mentioned higher limit, from the viewpoint of taste or cost of material sometimes not preferred.
In fatty acidic beverages of the present invention, can containing one or more water-soluble hemicellulose, but be preferably a kind of.Containing when two or more, above-mentioned content represents its total amount.
The feature of fatty acidic beverages of the present invention is, it contains the fatty acid ester with polyoxyalkylene chain that HLB is more than 11.As long as HLB is more than 11, is preferably more than 12, is more preferably more than 13.If lower than lower limit, then there is the tendency that can not give full play of the effect that storage stability improves.
The carbon number of aliphatic acid forming fatty acid ester is generally 6 ~ 24, preferably 8 ~ 22, more preferably 12 ~ 18.As the concrete example of aliphatic acid, sad, 2-ethyl hexyl alkanoic acid, capric acid, laurate, different tridecanoic acid, tetradecylic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, linoleic acid, castor oil acid, behenic acid, erucic acid etc. can be enumerated.
In the present invention, so-called polyoxyalkylene chain is the group represented with repetitive following formula (1) Suo Shi.As polyoxyalkylene chain, preferred polyethylene oxide base chain or the middle n of PPOX base chain, i.e. following formula (1) are 2 or 3.
In formula (1), n and m represents the integer of more than 1 respectively.As mentioned above, n be preferably 2 or 3, m be preferably 3 ~ 40 integer, more preferably 4 ~ 35 integer, be particularly preferably 5 ~ 30 integer.In addition, the hydrogen atom in formula (1) can replace by hydroxyl or be not substituted.
With above-mentioned formula (1) if shown in the group represented by repetitive formed the part of compound, such as, for with the end of the group represented by the repetitive shown in above-mentioned formula (1), one end is by carrying out the replacement of the groups such as hydroxyl and becoming the end of compound, the main framing bonding of the other end and compound, thus can compound be formed.Further, also can be that two ends are all used as a main framing part with other group bonding.
In fatty acidic beverages of the present invention, by being the fatty acid ester with polyoxyalkylene chain of more than 11 containing this HLB together with water-soluble hemicellulose, the precipitation of lactoprotein can being suppressed, fully can suppress the generation that butterfat is separated or grease is separated out simultaneously.
As the fatty acid ester with polyoxyalkylene chain of the present invention, specifically, there are polyglyceryl fatty acid ester or polyoxyethylene sorbitan fatty acid esters, polyoxyethylene xylitol fatty acid ester, cithrol etc., preferred polyglyceryl fatty acid ester and polyoxyethylene sorbitan fatty acid esters.
As above-mentioned polyglyceryl fatty acid ester, wherein the average degree of polymerization of preferably glycerine is the polyglyceryl fatty acid ester of 4 ~ 20, and more preferably average degree of polymerization is 5 ~ 10.
As polyglyceryl fatty acid ester, be known food emulsifying agent, can commercially available product be used, also can use the material obtained by the known production method of polyglyceryl fatty acid ester.The known production method of polyglyceryl fatty acid ester can be enumerated such as: based on polyglycereol and the direct esterification (aliphatic acid, fat acyl chloride etc.) of fatty acid or the method for ester exchange (fatty acid methyl ester, grease etc.); Based on the method etc. of the polyaddition reaction of glycidol and fatty acid (aliphatic acid, glycerine monofatty ester etc.).
Autofrettage for obtaining polyglycereol industrially extensively adopts the method for the dehydration condensation based on glycerine, also there will be a known the method for the addition reaction based on glycidol.As the dehydration condensation of glycerine or the polyaddition reaction of glycidol, can carry out according to known method.Specifically, such as, in the dehydration condensation of glycerine, usually in glycerine, add alkali as catalyst, be blown into the high temperature of the inert gases such as nitrogen more than 200 DEG C and heat, thus obtain polyglycereol.Reaction time is generally 3 hours ~ 10 hours.Such as, in the polyaddition reaction of glycidol, can enumerate: use relative to glycerine be 0.01 % by weight ~ 10 % by weight phosphoric acid series catalysts, make to correspond to the method that the glycidol (targeted degree of polymerization-1 mole) of targeted degree of polymerization carries out polyaddition reaction; Make to be equivalent to after the carboxylic acids such as the glycidol of targeted degree of polymerization and acetic acid react, by the method etc. of hydrolysis removing carboxylic acid.
For polyaddition reaction, be usually 80 DEG C ~ 140 DEG C in reaction temperature, preferably under the inert gas flows such as nitrogen, undertaken by the method for adding glycidol in reaction system bit by bit on a small quantity.After reaction terminating, utilize alkali to come neutralising phosphoric acid catalyst or residual carboxylic acid, carry out dehydration and separate out.Product is refined by diatomite filtration etc. according to object.The polyglycereol obtained be painted less, the liquid of thickness.
In the esterification of polyglycereol the carbon number of aliphatic acid used be generally 6 ~ 24, preferably 8 ~ 22, more preferably 12 ~ 18.As the concrete example of aliphatic acid, sad, 2-ethyl hexyl alkanoic acid, capric acid, laurate, different tridecanoic acid, tetradecylic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, linoleic acid, castor oil acid, behenic acid, erucic acid etc. can be enumerated.The formation aliphatic acid of polyglyceryl fatty acid ester can be the two or more combination of these aliphatic acid.
Esterification is such as carried out under the existence of the base catalysts such as potash, sodium carbonate, potassium hydroxide, NaOH.For the consumption of base catalyst, be generally 0.001 % by weight ~ 3 % by weight relative to raw material (summation of polyglycereol and aliphatic acid), be preferably 0.001 % by weight ~ 1 % by weight.Reaction temperature is generally 150 DEG C ~ 300 DEG C, is preferably 180 DEG C ~ 260 DEG C.For reaction, usually in stirring tank reactor, drop into polyglycereol, aliphatic acid, catalyst, while stirring, be heated to predetermined temperature, generation water is distilled except going to reaction system while react.It should be noted that, in a series of reaction, preferably make the inert gases such as nitrogen circulate in reactor gas phase portion.
The average esterification rate of the polyglyceryl fatty acid ester used in the present invention is preferably 5% ~ 50% usually, be more preferably 5% ~ 40%, more preferably 5% ~ 30%, be particularly preferably 5% ~ 20%.This average esterification rate can be regulated by the molar ratio of aliphatic acid relative to polyglycereol.Aliphatic acid is also determined by the average degree of polymerization of polyglycereol relative to the molar ratio of polyglycereol, is usually preferably 0.5 ~ 6, is more preferably 0.5 ~ 3, more preferably 0.5 ~ 2.The polyglyceryl fatty acid ester obtained is colourless or slightly brownish liquid state or semi-solid.
It is the commercially available product of the polyglyceryl fatty acid ester of more than 11 as above-mentioned HLB, can enumerate: " Ryoto Polygly Ester S-10D ", " Ryoto Polygly Ester SWA-10D ", " Ryoto Polygly Ester SWA-15D ", " Ryoto Polygly Ester SWA-20D ", " Ryoto Polygly Ester P-8D ", " Ryoto Polygly Ester M-7D ", " Ryoto Polygly Ester M-10D ", " Ryoto Polygly Ester O-15D ", " Ryoto Polygly Ester L-7D ", " Ryoto Polygly Ester L-10D " (is manufactured by food society of Mitsubishi Chemical above, trade name), " SY-GLYSTER MSW-7S ", " SY-GLYSTER MS-5S ", " SY-GLYSTER MO-7S ", " SY-GLYSTER MO-5S ", " SY-GLYSTER ML-750 ", " SY-GLYSTER ML-500 " (are manufactured by this pharmaceutical industries of slope society above, trade name), " Sunsoft Q-14F ", " Sunsoft Q-12F ", " Sunsoft Q-18S ", " Sunsoft Q-182S ", " Sunsoft Q-17S ", " Sunsoft Q-14S ", " Sunsoft Q-12S ", " Sunsoft A-121C ", " Sunsoft A-141C ", " Sunsoft A-121E ", " Sunsoft A-141E ", " Sunsoft A-171E ", " Sunsoft A-181E " (are manufactured by sun chemistry society above, trade name), " Poem TRP-97RF ", " Poem J-0021 ", " Poem J-0081HV ", " Poem J-0381V " (are manufactured by Li Yan vitamin society above, trade name), " NIKKOL Hexaglyn1-M ", " NIKKOL Hexaglyn1-L ", " NIKKOL Decaglyn1-SV ", " NIKKOL Decaglyn1-OV ", " NIKKOL Decaglyn1-M ", " NIKKOL Decaglyn1-L " (are manufactured by daylight chemistry society above, trade name) etc.
As above-mentioned polyoxyethylene sorbitan fatty acid esters, wherein, the adduct number of oxirane be preferably 3 ~ 40, more preferably 4 ~ 35, be particularly preferably 10 ~ 30.
Be the commercially available product of the polyoxyethylene sorbitan fatty acid esters of more than 11 as above-mentioned HLB, can enumerate: " Emasol S-120V ", " Emasol L-120V ", " Emasol O-120V ", " Rheodol TW-S120V ", " Rheodol TW-L120 ", " Rheodol TW-O120V ", " Rheodol TW-L106 ", " Rheodol TW-P120 ", " Rheodol TW-O320V ", " Rheodol Super TW-L120 ", " Rheodol440V ", " Rheodol460V " (are manufactured by Hua Wangshe above; Trade name); " Solgen TW-60F ", " Solgen TW-20F ", " Solgen TW-80F " (are manufactured by the first industrial pharmaceutical society above; Trade name); " Admul T60K ", " Admul T80K " (are manufactured by Kerry society above; Trade name); " T-Maz60K ", " T-Maz80K " (are manufactured by BASF society above; Trade name); " Wilsurf TF-60 ", " Wilsurf TF-80 " (are manufactured by You society above; Trade name); " Glycosperse S-20K FG ", " Glycosperse O-20K FG " (are manufactured by Lonza society above; Trade name) etc.
In fatty acidic beverages, HLB be more than 11 the content (addition) with the fatty acid ester of polyoxyalkylene chain be preferably 0.001 % by weight ~ 1 % by weight, be more preferably 0.005 % by weight ~ 0.75 % by weight, more preferably 0.01 % by weight ~ 0.5 % by weight.When being less than above-mentioned lower limit, sometimes can not giving full play of and suppressing the effect that butterfat is separated or grease is separated out; When exceeding above-mentioned higher limit, the impact of suiting one's taste becomes large sometimes.
In addition, in the scope of above-mentioned addition, the polyglyceryl fatty acid ester of more than two kinds that the degree of polymerization, HLB, the carbon number of formation aliphatic acid, average esterification rate are different can be share.
Further, in fatty acidic beverages of the present invention, HLB be more than 11 the fatty acid ester with polyoxyalkylene chain can contain one or more.Containing in situation of more than two kinds, above-mentioned content represents its total amount.
In addition, in fatty acidic beverages, water-soluble hemicellulose and HLB be more than 11 the weight ratio (water-soluble hemicellulose: HLB is the fatty acid ester with polyoxyalkylene chain of more than 11) with the fatty acid ester of polyoxyalkylene chain be preferably 100:1 ~ 0.1:1, be more preferably 50:1 ~ 0.2:1, more preferably 25:1 ~ 0.4:1.
For the fatty acid ester with polyoxyalkylene chain, according to its architectural characteristic, there is following advantage: in acidic domain (pH is less than 5), compared with other emulsifying agent, give play to stable emulsifying ability, and be adsorbed on the surface of lipochondrion, by the steric repulsion power etc. of polyoxyalkylene chain, the unification of lipochondrion or aggegation can be suppressed, floating (grease precipitation) that fat causes by being separated.
Fatty acidic beverages of the present invention can contain other emulsifying agent further.As other emulsifying agent, can enumerate and be selected from sucrose fatty ester; The fatty acid ester with polyoxyalkylene chain that HLB is less than 11; The organic acid mono-glycerides such as the acid of succinylated monoglyceride, diacyl-tartaric monoglyceride, citric acid monoglyceride, acetic acid esters of mono, lactic acid esters of mono; The emulsifying agent of more than a kind in sorbitan fatty acid esters, anhydro xylitol fatty acid ester, methyl glycol fatty acid ester, stearyl lactylic acid salt, yucca extract, saponin, lecithin, lysolecithin.Among these, preferably sucrose fatty acid ester; The fatty acid ester with polyoxyalkylene chain that HLB is less than 11; The organic acid mono-glycerides such as the acid of succinylated monoglyceride, diacyl-tartaric monoglyceride, citric acid monoglyceride, acetic acid esters of mono, lactic acid esters of mono; Sorbitan fatty acid esters, anhydro xylitol fatty acid ester, stearyl lactylic acid salt, lysolecithin, particularly preferably sucrose fatty ester, the HLB fatty acid ester with polyoxyalkylene chain, sorbitan fatty acid esters, the anhydro xylitol fatty acid ester that are less than 11.By share this suitable emulsifying agent, the generation that butterfat is separated can be suppressed, simultaneously also oil-control can separate out the generation of (オ イ Le オ イ Off).
As the HLB of sucrose fatty ester of the present invention, be usually preferably more than 3, be more preferably more than 5, more preferably more than 7, be preferably less than 20.When HLB is lower than above-mentioned value, there is the tendency that can not give full play of the effect improving storage stability.
The aliphatic acid forming sucrose fatty ester is not particularly limited, and preferred carbon number is the saturated or undersaturated aliphatic acid of 6 ~ 24, can enumerate such as laurate, tetradecylic acid, palmitic acid, stearic acid, oleic acid, behenic acid, erucic acid etc.Among these, from the view point of taste, preferably with the aliphatic acid that stearic acid, palmitic acid, tetradecylic acid are principal component.
As the commercially available product of above-mentioned sucrose fatty ester, can enumerate: " Ryoto Sugar Ester S-1670 ", " Ryoto Sugar Ester S-1570 ", " Ryoto Sugar Ester S-1170 ", " Ryoto Sugar Ester S-970 ", " Ryoto Sugar Ester S-770 ", " Ryoto Sugar Ester S-570 ", " Ryoto Sugar Ester S-370 ", " Ryoto Sugar Ester P-1670 ", " Ryoto Sugar Ester P-1570 ", " Ryoto Sugar Ester M-1695 ", " Ryoto Sugar Ester O-1570 ", " Ryoto Sugar Ester L-1695 ", " Ryoto Sugar Ester LWA-1570 " " Ryoto Sugar Ester L-595 ", " Ryoto Sugar Ester B-370 " (is manufactured by food society of Mitsubishi Chemical above, trade name), " DK ESTER SS ", " DK ESTER F-160 ", " DK ESTER F-140 ", " DK ESTER F-110 ", " DK ESTER F-90 ", " DK ESTER F-70 ", " DK ESTER F-50 " (are manufactured by the first industrial pharmaceutical society above, trade name) etc.
The HLB with the fatty acid ester of polyoxyalkylene chain that above-mentioned HLB is less than 11 is usually preferably more than 4, is more preferably more than 6, more preferably more than 8.If lower than lower limit, then the dispersiveness in water has the tendency of reduction.Be less than the concrete example with the fatty acid ester of polyoxyalkylene chain of 11 as HLB, polyglyceryl fatty acid ester and polyoxyethylene sorbitan fatty acid esters can be enumerated.
The average degree of polymerization that above-mentioned HLB is less than the polyglyceryl fatty acid ester of 11 is usually preferably below 2 to 20, is more preferably 2 to 15, more preferably 2 to 10.In addition, the carbon number of the aliphatic acid of formation is not particularly limited, and is usually preferably more than 10, is more preferably more than 12, is usually preferably less than 22, is more preferably less than 18.
Be less than the commercially available product of the polyglyceryl fatty acid ester of 11 as above-mentioned HLB, can enumerate: " Ryoto Polygly Ester S-24D ", " Ryoto Polygly Ester S-28D ", " Ryoto Polygly Ester O-50D ", " Ryoto Polygly Ester B-70D ", " Ryoto Polygly Ester ER-60D " (are manufactured by food society of Mitsubishi Chemical above; Trade name); " SY-GLYSTER TS-7S ", " SY-GLYSTER SS-5S ", " SY-GLYSTER TS-5S ", " SY-GLYSTER PS-5S ", " SY-GLYSTER MS-3S ", " SY-GLYSTER TS-3S ", " SY-GLYSTER PO-5S ", " SY-GLYSTER MO-3S ", " SY-GLYSTER ML-310 " (are manufactured by this pharmaceutical industries of slope society above; Trade name); " Sunsoft Q-18B ", " Sunsoft Q-18D ", " Sunsoft Q-17B ", " Sunsoft Q-18F ", " Sunsoft Q-17F ", " Sunsoft A-171C ", " Sunsoft A-181C ", " Sunsoft A-143E ", " Sunsoft A-173E ", " Sunsoft A-183E ", " Sunsoft A-186E " (are manufactured by sun chemistry society above; Trade name); " Poem DS-100A ", " Poem DO-100V ", " Poem DP-95RF ", " Poem J-2081V " (are manufactured by Li Yan vitamin society above; Trade name); " NIKKOL Hexaglyn DGMS ", " NIKKOL Tetraglyn1-SV ", " NIKKOL Tetraglyn1-OV ", " NIKKOL Decaglyn 3-OV ", " NIKKOL Decaglyn3-SV ", " NIKKOL Hexaglyn1-SV ", " NIKKOL Hexaglyn 1-OV ", " NIKKOL Decaglyn2-SV " (are manufactured by daylight chemistry society above; Trade name) etc.
Be less than the polyoxyethylene sorbitan fatty acid esters of 11 as above-mentioned HLB, wherein, the adduct number of oxirane be preferably 3 ~ 40, more preferably 4 ~ 35, be particularly preferably 10 ~ 30.
Be less than the commercially available product of the polyoxyethylene sorbitan fatty acid esters of 11 as above-mentioned HLB, can enumerate: " Rheodol TW-S106V ", " Rheodol TW-S320V ", " Rheodol TW-O106V ", " Rheodol430V " (are manufactured by Hua Wangshe above; Trade name) etc.
As the commercially available product of the sorbitan fatty acid esters of other above-mentioned emulsifying agent, can enumerate: " Poem S-60V ", " Solman S-300 (V) ", " Poem O-80V ", " L-300 ", " Poem SMV-302 " (grind his name society of dimension by reason to manufacture above; Trade name); " Emasol L-10V ", " Emasol P-10V ", " Emasol S-10V ", " Emasol O-10V ", " Rheodol SP-L10 ", " Rheodol SP-P10 ", " Rheodol SP-S10V ", " Rheodol SP-O10V ", " Rheodol Super SP-L10 ", " Rheodol AS-10V ", " Rheodol AO-10V " (are manufactured by Hua Wangshe above; Trade name) etc.
When share other emulsifying agent, its consumption also can be different according to the difference of the kind of the kind of water-soluble hemicellulose or addition, other emulsifying agent, but the fatty acid ester of polyoxyalkylene chain that has that HLB is more than 11 is usually preferably 1:99 ~ 99:1 with the amount of other emulsifying agent than (weight ratio), is more preferably 10:90 ~ 99:1, more preferably 1:4 ~ 9:1.
When using other emulsifying agent, this emulsifying agent and HLB be more than 11 the fatty acid ester with polyoxyalkylene chain be together adsorbed on the surface of lipochondrion, by the formation etc. of steric repulsion power, electrically repulsive force, hydration layer, there is the effect that can improve the floating (grease precipitation) that causes by being separated the unification of lipochondrion or aggegation, fat further and suppress.Particularly when using sucrose fatty ester, the protected effect of the butter oil particle surface caused by the rigidity stereochemical structure of sucrose and strong hydration layer formation power and given play to more excellent effect.
For other emulsifying agent above-mentioned, in the ratio in fatty acidic beverages, be usually preferably 0.001 % by weight ~ 1 % by weight, be more preferably 0.005 % by weight ~ 0.75 % by weight, more preferably 0.01 % by weight ~ 0.5 % by weight.
Further, protein can be contained in fatty acidic beverages of the present invention.As protein, can be included in above-mentioned as fat source use in the milk composition of animal origin grease or the grease of plant origin, also can distinguish with it ground, add the lactoprotein such as lactalbumin, casein and salt thereof or their analyte; Or the protein in other plant and animal source or their analyte.
The content of the protein of fatty acidic beverages of the present invention is preferably more than 0.01 % by weight usually, be more preferably more than 0.1 % by weight, more preferably more than 0.3 % by weight, be particularly preferably more than 0.9 % by weight, be usually preferably less than 10 % by weight, be more preferably less than 5 % by weight, more preferably less than 3 % by weight, be particularly preferably less than 2 % by weight.If lower than lower limit, then taste dies down sometimes; If higher than the upper limit, then sometimes cannot give full play of the effect of the precipitation of CKIs matter composition.
The viscosity of fatty acidic beverages of the present invention 25 DEG C time is usually preferably below 5mPas, is more preferably below 2.5mPas, more preferably below 2.0mPas, is further preferably below 1.8mPas, is particularly preferably below 1.7mPas, most preferably is below 1.6mPas.The lower limit of viscosity is preferably more than 0.1mPas usually.By being such low viscosity, the fluidity that pasty state sense is few, be easy to experience refrigerant sense can be obtained.Further, in the present invention, even if be such low viscosity, the precipitation of the protein components such as lactoprotein can also be suppressed.
Further, in fatty acidic beverages of the present invention, its intermediate value footpath is preferably less than 1 μm, is more preferably less than 0.5 μm.
In fatty acidic beverages of the present invention, also following substances can not can added further as required to the limit that effect of the present invention has an impact: granulated sugar, fructose, glucose, maltose, galactolipin, mannose, fucose, wood sugar, trehalose, lactose, mannan-oligosaccharides, oligomeric maltose, α ?cyclodextrin, β ?cyclodextrin, γ ?cyclodextrin, dextrin, indigestible dextrins, pectin, alginic acid, propylene glycol alginate, sodium carboxymethylcellulose, carragheen, tamarind gum, tara gum, karaya, guar gum, locust bean gum, tragacanth, amylopectin, gellan gum, natural gellan gum, Arabic gum, xanthans, agar, avicel cellulose, fermented cellulosic, shitosan, Farceran (フ ァ ー セ ラ Application), starch, producing starch, glycan etc. comprise monose, compound sugar, the carbohydrate of polysaccharide, the sugar alcohols such as red moss alcohol, xylitol, maltitol, D-sorbite, sweet mellow wine, inositol, the various sweeteners such as Sucralose, Aspartame, acesulfame potassium, knob are sweet, qualities of stevia extract, the protein in the various animal and plant source such as casein-sodium, lactalbumin, albumin, gelatin, soybean protein and its analyte, lemon oil, orange oil, peppermint wet goods spices, the pigments such as carotenoid, chlorophyll such as beta carotene, astaxanthin, lycopene, capsochrome, fruit juice or pulp and the local flavor adding material such as cereal or its powder, coffee, black tea, cardiac hypertrophy, salt such as crushed material or thickener, cocoa powder, soybean or red bean, rice, wheat thereof, the mineral material such as calcium, iron, the nutrient material of vitamin, Co-Q10, amino acid, peptide etc. and so on, carbon dioxide, the drinks such as ligueur, vodka, liquor, ethanol, the antioxidants such as Rosmarinus officinalis extract, tea extraction, mountain peach extract, the shelf-life such as Semen Brassicae Junceae extract, lysozyme improving agent (holding upwards drug day), material etc. preserved by nisin, sorbic acid and salt thereof etc.
As the manufacture method of fatty acidic beverages of the present invention, as long as the method carrying out manufacturing according to the mode with the fatty acid ester of polyoxyalkylene chain being more than 11 containing water-soluble hemicellulose and HLB is just not particularly limited, such as can enumerate following method etc.: respectively the system of preparation containing fat constituent and containing water-soluble hemicellulose and HLB be more than 11 there is the aqueous solution of the system of the fatty acid ester of polyoxyalkylene chain after, both are merged, pH is adjusted to acidic domain, homogenize, after pasteurization, be filled to container, thus manufacture.It should be noted that, the condition homogenized does not limit, preferably at least 10kg/cm 2above pressure carries out, and this pressure is more preferably 50kg/cm 2~ 500kg/cm 2.
Even if fatty acidic beverages of the present invention is in the situation of low viscous acidic beverages or when using whole milk powder to make acidic beverages in milk composition, butterfat also can be fully suppressed to be separated or grease is separated out, the generation of protein precipitation.Therefore, it is useful especially for containing acidic milk drink for the fat loading pet container.
Embodiment
Illustrate in greater detail the present invention below by embodiment, but for the present invention, only otherwise exceed its main points, be not limited to following examples.
(embodiment and comparative example)
The manufacture > of the fatty acidic beverages of <
Xiang Shuizhong adds granulated sugar, skimmed milk power (manufacture of Hokkaido dairy industry society, fatty containing ratio 0.9 % by weight, protein containing ratio 34.5 % by weight), whole milk powder (manufacture of Hokkaido dairy industry society, fatty containing ratio 26.2 % by weight, protein containing ratio 25.5 % by weight) in right amount, dissolves 50 DEG C of heating.Thereafter, the concentration being table 1 by final content respectively by the aqueous solution of the material had described in the tables 1 such as the fatty acid ester of polyoxyalkylene chain being more than 11 containing the water-soluble hemicellulose be dissolved or dispersed in advance in water, HLB carries out adding, mixing.
Add citric acid, lactic acid, natrium citricum in right amount wherein, the pH being table 2 record by the pH after sterilization is prepared.Thereafter, water is utilized to adjust constituent concentration.Prepare after liquid is heated to 65 DEG C, with 200kg/cm by obtained 2carry out the process that homogenizes, be sealing in vial.Be heated to 90 DEG C, keep after 2 minutes, cool immediately, obtain the fatty acidic beverages of fat constituent and the protein recorded containing table 2.
PH mensuration is carried out for obtained fatty acidic beverages, further in accordance with the following methods or benchmark carry out viscosity, the evaluation of emulsion stability, the mensuration of precipitation capacity.The result obtained is shown in table 2.
In addition, the material of materials'use the following stated of table 1 record.Further, the composition that table 1 is recorded is recorded with % by weight.In addition, the precipitation capacity in table 2, albumen quality and fat mass are recorded with % by weight.
< material >
Zero water-soluble hemicellulose: soybean polysaccharides, only liquefaction society manufactures, SOYAFIBE S-DA100
Zero HLB is the fatty acid ester with polyoxyalkylene chain of more than 11:
(A1) ten polyglycerol stearate, SWA-10D, HLB14, solid constituent 40 % by weight, food society of Mitsubishi Chemical manufactures
(A2) ten polyglycerol stearate, SWA-15D, HLB13, solid constituent 30 % by weight, food society of Mitsubishi Chemical manufactures
(A3) ten polyglyceryl laurate, L-10D, HLB16, food society of Mitsubishi Chemical manufactures
(A4) polyoxyethylene sorbitan stearate, TW-S120V, HLB14.9, Hua Wangshe manufacture
(A5) polyoxyethylene sorbitan laurate, TW-L120V, HLB16.7, Hua Wangshe manufacture
Zero other emulsifying agents
The fatty acid ester with polyoxyalkylene chain that HLB is less than 11:
(B1) four stearines, MS-3S, HLB8.4, this pharmaceutical industries of slope society manufactures
(B2) diglycerol palmitate, DP-95RF, HLB8.0, Li Yan vitamin society manufactures
(B3) ten polyglycerol stearate, S-28D, HLB9, food society of Mitsubishi Chemical manufactures
Sucrose fatty ester:
(C1) sucrose palmitate, P-1570, HLB15, food society of Mitsubishi Chemical manufactures
(C2) sucrose palmitate, P-1670, HLB16, food society of Mitsubishi Chemical manufactures
(C3) sucrose stearate, S-1570, HLB15, food society of Mitsubishi Chemical manufactures
(C4) sucrose stearate, S-1170, HLB11, food society of Mitsubishi Chemical manufactures
Sorbitan fatty acid esters: sorbitan stearate, S-60V, HLB5.1, Li Yan vitamin society manufactures
Zero glycerine monofatty ester: single stearine, DIMODAN HP/20-M, HLB4, Danisco Japan society manufactures
Zero pectin: HM, GENU pectin type YM-150-LJ, three brilliant societies manufacture
Zero tamarind gum: Glyate, DSP GOKYO FOOD & CHEMICAL society manufactures
○CMC-Na
(D1) sodium carboxymethylcellulose, Celogen F-907A, the first industrial pharmaceutical society manufactures
(D2) sodium carboxymethylcellulose, CMC FL100, Xin Rong society manufactures
< viscosity >
Use Co., Ltd. TOKIMEC system " VISCONIC ELD type " viscosimeter, viscosity when measuring 25 DEG C.
Evaluation (1) > of < emulsion stability
The fatty acidic beverages obtained utilizing said method is undertaken evaluating (evaluation of first stage) by following benchmark visualization after preserving 4 weeks at 35 DEG C.
(metewand)
AA: be separated without grease precipitation, butterfat, or slightly confirm butterfat separation.
A: slightly confirm grease and separate out.
B: know and confirm grease precipitation, butterfat separation.
C: confirm grease precipitation, butterfat separation in a large number, emulsification is destroyed.
Evaluation (2) > of < emulsion stability
After the fatty acidic beverages obtained utilizing said method preserves 4 weeks at 35 DEG C, set the benchmark more tighter than the evaluation of first stage, visualization is carried out evaluating (evaluation of second stage).
(metewand)
Using full marks as 10 points, calculate mark by following evaluation result in deduction mode.It should be noted that, for intermediate value footpath coarsening (more than 1 μm) person ,-5 points further.When the mark calculated is below 5 points, be judged as that emulsified state is unstable.
(butterfat is dispersed)
0: the good dispersion of butterfat, the attachment on container is also few
-1: the bad dispersibility of butterfat, but substantially disappear after stirring.Attachment on container is few.
-2: the bad dispersibility of butterfat, but substantially disappear after stirring.Attachment on container is many.
-3: the bad dispersibility of butterfat, also have quite residual after stirring.
(grease precipitation)
0: separate out without grease.
-2: slightly grease is separated out.
-4: the clear grease that confirms is separated out.
-6: confirm grease in a large number and separate out.
< intermediate value footpath >
After the fatty acidic beverages obtained utilizing said method preserves 4 weeks at 35 DEG C, size distribution meter (hole field makes society of institute and manufactures LA-920) is used to measure intermediate value footpath.
The mensuration > of < precipitation capacity
The fatty acidic beverages obtained utilizing said method is taked a part for sample, is carried out centrifugation in 20 minutes with 5000rpm after preserving 4 weeks at 35 DEG C.Thereafter, discard supernatant liquor, reversing left standstill after 20 minutes, measured the weight of residual precipitation.The amount of precipitation is gone out with the form calculus of the part by weight relative to taked fatty acidic beverages.
[table 2]
From above result, for of the present invention containing water-soluble hemicellulose and HLB be more than 11 the fatty acidic beverages with the fatty acid ester of polyoxyalkylene chain, its precipitation capacity is also few, and grease is separated out, butterfat is separated few, and emulsion stability is excellent.In addition we know, even if be protein or lardy system, have also been obtained high emulsion stability.
The beverage of pectin, tamarind gum, CMC-Na is employed, emulsion stability difference (comparative example 2,3,15,13) for replacing water-soluble hemicellulose.
In addition, for do not use HLB be more than 11 the fatty acid ester with polyoxyalkylene chain employ sucrose fatty ester (comparative example 4,5,12), glycerine monofatty ester (comparative example 5,14) and the HLB fatty acid ester (comparative example 7 with polyoxyalkylene chain that is less than 11,8,12), sorbitan fatty acid esters (comparative example 9) as the beverage of emulsifying agent, emulsion stability is also very poor.
To explain invention has been with reference to specific embodiment, but for a person skilled in the art, knownly can carry out various changes and modifications under the condition not departing from the spirit and scope of the present invention.Based on the Japanese patent application (Japanese Patent Application 2010-179389) that the Japanese patent application (Japanese Patent Application 2010-059754) that the application submitted to by March 16th, 2010, on August 10th, 2010 submit to, with the form of reference, its content is introduced this description.
Industrial applicibility
According to the present invention, a kind of fatty acidic beverages can be provided, even if when this fatty acidic beverages is low viscous acidic beverages, the precipitation of the protein components such as the lactoprotein contained by also can suppressing in beverage, fully can suppress the generation that butterfat is separated or grease is separated out simultaneously.

Claims (7)

1. a pH is the fatty acidic beverages of less than 5, it contains the fatty acid ester with polyoxyalkylene chain that water-soluble hemicellulose and HLB are more than 11, the content of described water-soluble hemicellulose is 0.001 % by weight ~ 5 % by weight, described water-soluble hemicellulose and described HLB be more than 11 the weight ratio with the fatty acid ester of polyoxyalkylene chain be 50:1 ~ 0.2:1, the content of protein is more than 0.1 % by weight.
2. pH as claimed in claim 1 is the fatty acidic beverages of less than 5, and wherein, described polyoxyalkylene chain represents with the repetitive shown in following formula (1):
In formula (1), n and m represents the integer of more than 1 respectively; Hydrogen atom in formula (1) replace by hydroxyl or be not substituted.
3., as the fatty acidic beverages that pH according to claim 1 or claim 2 is less than 5, wherein, described polyoxyalkylene chain is polyethylene oxide base chain or PPOX base chain.
4. the pH as described in any one of claims 1 to 3 is the fatty acidic beverages of less than 5, its further containing being selected from sucrose fatty ester, HLB be less than 11 the fatty acid ester with polyoxyalkylene chain, organic acid mono-glyceride, sorbitan fatty acid esters, anhydro xylitol fatty acid ester, methyl glycol fatty acid ester, stearyl lactylic acid salt, yucca extract, saponin, lecithin, lysolecithin group in the emulsifying agent of more than a kind.
5. the pH as described in any one of Claims 1 to 4 is the fatty acidic beverages of less than 5, and wherein, water-soluble hemicellulose is soybean polysaccharides.
6. the pH as described in any one of Claims 1 to 5 is the fatty acidic beverages of less than 5, and it contains the fat of more than 0.015 % by weight.
7. the pH as described in any one of claim 1 ~ 6 is the fatty acidic beverages of less than 5, and its viscosity 25 DEG C time is below 5mPas.
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000093082A (en) * 1998-09-25 2000-04-04 Mitsubishi Kagaku Foods Kk Protein-containing acidic drink
JP2005040024A (en) * 2003-07-24 2005-02-17 Sanei Gen Ffi Inc Milk fat-containing acidic milk beverage
CN1691891A (en) * 2002-12-03 2005-11-02 三菱化学株式会社 Milk beverage containing sucrose fatty acid ester and polyglycerol fatty acid ester
CN101553138A (en) * 2006-11-29 2009-10-07 史蒂文森集团有限公司 Improvements in or relating to carbonated beverages

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0686633A (en) * 1991-12-26 1994-03-29 Nitsusee:Kk Protein-containing acidic drink
JP3381349B2 (en) * 1993-12-28 2003-02-24 不二製油株式会社 Method for producing emulsified composition and food utilizing the same
JP3390269B2 (en) * 1994-10-24 2003-03-24 三栄源エフ・エフ・アイ株式会社 Milk drink stabilization
JP3490529B2 (en) * 1995-03-02 2004-01-26 三栄源エフ・エフ・アイ株式会社 Prevention method of sedimentation of milk canned coffee
JP2006325603A (en) * 1997-11-07 2006-12-07 Kyowa Hakko Kogyo Co Ltd Protein-containing acidic food and drink
JP4457568B2 (en) * 2003-03-27 2010-04-28 不二製油株式会社 Acid emulsified food

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000093082A (en) * 1998-09-25 2000-04-04 Mitsubishi Kagaku Foods Kk Protein-containing acidic drink
CN1691891A (en) * 2002-12-03 2005-11-02 三菱化学株式会社 Milk beverage containing sucrose fatty acid ester and polyglycerol fatty acid ester
JP2005040024A (en) * 2003-07-24 2005-02-17 Sanei Gen Ffi Inc Milk fat-containing acidic milk beverage
CN101553138A (en) * 2006-11-29 2009-10-07 史蒂文森集团有限公司 Improvements in or relating to carbonated beverages

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