CN104204076B - Compound resin composition and nontoxic PVC window for nontoxic PVC window - Google Patents
Compound resin composition and nontoxic PVC window for nontoxic PVC window Download PDFInfo
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- CN104204076B CN104204076B CN201380014645.4A CN201380014645A CN104204076B CN 104204076 B CN104204076 B CN 104204076B CN 201380014645 A CN201380014645 A CN 201380014645A CN 104204076 B CN104204076 B CN 104204076B
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
- E06B3/04—Wing frames not characterised by the manner of movement
- E06B3/06—Single frames
- E06B3/08—Constructions depending on the use of specified materials
-
- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
- E06B3/04—Wing frames not characterised by the manner of movement
- E06B3/06—Single frames
- E06B3/08—Constructions depending on the use of specified materials
- E06B3/20—Constructions depending on the use of specified materials of plastics
- E06B3/205—Constructions depending on the use of specified materials of plastics moulded or extruded around a core
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of compound resin composition for nontoxic PVC window, it demonstrates initial coloring, thermostability and the weatherability of excellence and does not contains harmful based on lead (Pb) or the stabilizer of cadmium (Cd), the invention still further relates to a kind of nontoxic PVC window.More specifically, present invention provide for the compound resin composition of nontoxic PVC window as stabiliser compositions, described stabiliser compositions includes (a) stabilizer based on Non-toxic metal soap, and (b) inorganic stabilizers based on nontoxic metal；And use compound resin composition pass through kneading and extrude the nontoxic PCV window obtained.
Description
Technical field
The present invention relates to a kind of compound resin composition for nontoxic PVC window, it demonstrates excellence
Initial coloring, thermostability and weatherability and without harmful based on lead (Pb) or cadmium
(Cd) stabilizer, the invention still further relates to a kind of nontoxic PVC window.
Background technology
In daily life, PVC window is used on a lot of building as residential architecture material.But,
Polrvinyl chloride (PVC) comprises substantial amounts of cl radical, and cl radical is very easy to dissociate, and makes this position become
It is a free radical, forms double bond immediately after.The so increase of double bond quantity can cause the change of PVC
Color and the rising along with temperature can make PVC suddenly become even worse redness or black.
The lowest thermostability makes to need to add have the stabilizer compensating low heat resistant effect, so that
Obtain PVC can process and molding.
Presently commercially available PVC window is mainly by adding the lead (Pb) containing severe toxicity or cadmium (Cd)
Stabilizer based on lead and manufacture.Lead (Pb) or cadmium (Cd) are not only harmful to human body and also have
The longest half-life allows it to residual all one's life in human body and causes poisoning symptom.Therefore one is used
The stabilizer kind being made up of harmless material is necessary, but due to technical problem and other
About quality and the problem of cost, the use of non-toxic stabilizer also has a lot of restriction.
The present invention is to solve the problem of stabilizer use and manufacturing without noxious substance, such as lead
Or the nontoxic PVC window of cadmium (Cd) (Pb).
The PVC window of leaded (Pb) or cadmium (Cd) to workman be in the fabrication process harmful and
Even also can be by the poisonous stabilizer within friction or abrasion release after being arranged on building, may
Human body is had the worst impact.Therefore, Europe and a lot of developed country of the U.S. it has been specified that make
With non-toxic stabilizer and develop much technology about non-toxic material.But, in terms of high-performance,
Non-toxic stabilizer is still difficult to replace stabilizer based on lead (Pb), because lead (Pb) or cadmium (Cd)
There is heat stability, processability or the weatherability of excellence.In other words, the enhancing of thermostability causes processing
The decline of performance, balances the problem that processability then causes weatherability with thermostability.Use too much having
Machine stabilizer with meet all of performance can produce other about the problem of performance or increase cost, therefore
Use non-toxic stabilizer to manufacture PVC window and be really highly difficult.
PVC window can use stabilizer based on metallic soap or stabilizer based on stannum (Sn).But
It is that the stabilizer based on stannum (Sn) of some type in use has problems, as environment lotus
Your illiteracy aspect has bad impact or discharges foul smell when it acts on, and causes causing and has been considered nothing
Do harm to and still in the avirulent dispute of the stabilizer based on stannum (Sn) used, thus for having realized
A lot of problem is left completely without toxicity.In order to manufacture the window of totally nontoxic, have been carried out many and grind
Study carefully to develop a kind of use stabilizer based on Non-toxic metal soap any as the controlled combination of main stabilizer
The method of the inner/outer lubricant of kind, described stabilizer based on metallic soap comprises and has combination
C to nontoxic metal (such as calcium, magnesium, zinc etc.)3-C50The fatty acid of alkyl.But, based on gold
Belong to the problem in terms of the use of stabilizer of soap is not enough to overcome processability and weatherability, and heat-resisting
Result in property or initial coloring can't be satisfactory.Therefore, have been carried out much research with
Solve these problems.
Especially, EP 1088032 discloses a kind of stabiliser compositions, its comprise as organic surely
Determine calcium acetylacetonate and trihydroxyethyl-isocyanuric acid ester (THEIC) that agent is added, to contribute to gold
Belong to soap stabilizer and strengthen thermostability, and adding calcium hydroxide as inorganic stabilizers.EP 1613696
Middle a kind of zinc octoate (zinc octoate) of having recorded as organic stabilizer and combines zinc stearate
Stabiliser compositions.
Additionally, EP 1692220 disclose one comprise zinc octoate (zinc caprylate) make organic surely
Determine agent and combine the stabiliser compositions of zinc stearate, to improve initial coloring and to strengthen thermostability.
But the use that this organic stabilizer is in the polymer can cause precipitation, weatherability difference and the most not
The problems such as profit.
Accordingly, it would be desirable to constantly study these technology to solve all about initial coloring,
The problems such as thermostability, weatherability and economic problems.
Summary of the invention
Technical problem
By for solving the problem of association area and stablizing of high performance nontoxic PVC window can be prepared
In the research of agent, the inventors found that a kind of stabiliser compositions, it includes based on nontoxic gold
Belong to the stabilizer of soap and combine inorganic stabilizers based on nontoxic metal, described based on Non-toxic metal soap
Stabilizer comprises and has the C being bound to nontoxic metal (such as calcium, magnesium, zinc etc.)3-C50The fat of alkyl
Fat acid, described stabiliser compositions can be used for solving all problems of association area and do not reduce organic surely
Determine agent consumption or do not use organic stabilizer, thus completing the present invention.
Therefore it is an object of the present invention to provide a kind of compound resin composition for nontoxic window
Compound resin composition as PVC window.
It is a further object to provide and a kind of use the above-mentioned synthetic resin for nontoxic window
The nontoxic PVC window of compositions, and therefore there is initial coloring, thermostability and the weatherability of excellence
On.
Technical scheme
According to the present invention, it is provided that a kind of compound resin composition for nontoxic PVC window, it includes
For the stabilizer for synthetic resin, described stabilizer includes: (a) is based on Non-toxic metal soap steady
Determine agent；(b) inorganic stabilizers based on nontoxic metal.
According to the present invention, additionally provide a kind of above-mentioned synthetic resin group for nontoxic PCV window
The nontoxic PCV window that compound is manufactured by kneading, extrusion, it has the performance of improvement, including heat-resisting
Property, weatherability and initial coloring.
The detailed description of the present invention is given below.
First, the compound resin composition for nontoxic PVC window of the present invention is characterised by this
Bright specific stabiliser compositions.
In other words, to be that (a) is based on Non-toxic metal soap stablize the technical characteristic of compound resin composition
Agent and the combination of (b) inorganic stabilizers based on nontoxic metal, wherein based on Non-toxic metal soap steady
Determine agent to comprise there is the C being bound to nontoxic metal (such as calcium, magnesium, zinc etc.)3-C50The fat of alkyl
Acid.
In the composition, stabilizer (a) based on Non-toxic metal soap can be following compound:
Hydrogen on the fatty acid of the alkyl wherein containing 3 to 50 carbon atoms be selected from Li, Na, K,
At least one metal of Mg, Ca, Al and Zn replaces.Under heat or other exacting terms, PVC
Tend to make chlorinolysis from and form free radical, and then become double bond, cause variable color or aging subsequently.Cause
This, the inactivation of free chlorine is the key factor improving thermostability.At this aspect, zinc stearate is public
Being considered a kind of representative nontoxic Organic substance, its energy fast Acquisition free chlorine is to provide very
Excellent initial stage thermostability.
On the other hand, calcium stearate or magnesium stearate capture free chlorine relatively slowly but can be effectively ensured length
The thermostability of phase, this is because be captured once free chlorine, it just becomes stable.Therefore, available tristearin
Acid calcium or magnesium stearate substitute zinc stearate.
Fatty acid can include any saturated or undersaturated fatty acid, and the fatty acid of straight or branched,
Or aromatic fatty acid.
PVC based on 100 weight portions count, and the content range of stabilizer based on Non-toxic metal soap is excellent
Elect 0.1 weight portion as to 15 weight portions.The content of stabilizer based on Non-toxic metal soap is less than 0.1
Weight portion causes PCV in the PCV course of processing not to be melted but carbonization, and based on nontoxic
The consumption of the stabilizer of metallic soap causes PVC to melt unsuccessfully, when being delayed gelling more than 15 weight portions
Between, thus deteriorating processing characteristics, result causes the precipitation difficulty of PVC dispersion.
In this article, to mean serving as general inorganic steady for term " inorganic stabilizers based on nontoxic metal "
Determine the compound of agent, such as inorganic matter based on metal-oxide or metal hydroxides, and scribble and be selected from
At least one metal of Li, Na, K, Mg, Ca, Al and Zn, or its compound.Such as:
Inorganic stabilizers can coat zinc (Zn), magnesium (Mg), calcium (Ca) or its compound.
In this, inorganic matter based on metal-oxide or metal hydroxides can include, but does not limits
In, at least one is selected from following material: calcium oxide, calcium hydroxide, magnesium oxide, magnesium hydroxide,
Hydrogen-oxygen aluminum, aluminium hydroxide, brucite, hydrocalumite, zeolite, magnesite, calcium phosphate, calcium carbonate
Magnesite and titanium oxide.
Concrete painting method used herein can include, but are not limited to following methods: uses zinc
(Zn) painting method of aqueous solution, the painting method of use electrolysis, use high speed pulverization and heat
Melted painting method and use are pulverized and the physical method of friction.
Metal-oxides based on 100 weight portions or the inorganic matter meter of metal hydroxides, nontoxic metal
Or the content range of nontoxic metal compound is preferably 0.01 weight portion to 10 weight portions, to realize early
Phase captures chlorine thus improves thermostability and prevent the purpose of initial coloring.
PVC based on 100 weight portions count, containing of inorganic stabilizers (b) based on nontoxic metal
Weight range is preferably 0.5 weight portion to 15 weight portions.As shown in example below, add above-mentioned containing
Inorganic stabilizers based on nontoxic metal in weight range will not cause thermal deformation, and is provided with excellent machine
The resin of tool performance, the mechanical performance of described excellence includes high thermostability, high dispersibility, resists
Coagulability, and high impact strength.
PVC based on 100 weight portions count, and the compositions of the present invention can farther include 0.1 to 5
At least one co-stabilizer (c) of weight portion, its be selected from 1,3-diketone, dihydropyridine, polyhydric alcohol,
Isocyanuric acid ester, amino acid derivativges, organophosphorus ester, epoxide, perchlorate and superpower
Hydrochlorate.The content of co-stabilizer is non-less than the effect of 0.1 weight portion heat stability to guaranteeing PVC
The least, the carbonization of PVC can be caused, and the content of co-stabilizer is steady owing to helping more than during 5 weight portion
Determining agent excess causes PVC to colour in the course of processing.
PVC based on 100 weight portions count, and the compositions of the present invention can farther include 0.01 to 5
At least one organic stabilizer (d) of weight portion, it is selected from zinc octoate (zinc octoate, zinc
Caprylate), calcium acetylacetonate and trihydroxyethyl-isocyanuric acid ester (THEIC).
The PVC that the present composition uses can include, but not limited at least one selected from following
Material: vinyl acetate and the copolymer of polrvinyl chloride, polyvinylidene chloride, chlorinated polyethylene,
Chlorosulfonated polyethylene, chlorinated polypropylene or ethlyene dichloride.
Being preferably based on the PVC meter of 100 weight portions, the compositions of the present invention can farther include
At least one is selected from following material: the processing aid of 0.5 to 10 weight portion, 5 to 15 weight portions
Impact modifying agent, the TiO of 2 to 10 weight portions2, the calcium carbonate of 10 to 30 weight portions, 0.5 to
The lubricant of 10 parts of weight and the antioxidant/UV blockers of 0.1 to 5 weight portion.
Processing aid can include that at least one is selected from processing aid based on acrylate, based on methyl-prop
The processing aid of olefin(e) acid ester and processing aid based on acrylonitrile.
Additionally, impact modifying agent can include that at least one is selected from impact modifying agent based on acryloyl and base
Impact modifying agent in chlorinated polyethylene.
Additionally, TiO can be added2As Chinese white the deficiency of the weatherability supplementing window, carbonic acid
Calcium can be used for strengthening impact resistance.
Additionally, lubricant can include that at least one is selected from following material: lignite wax, fatty acid ester,
Triglyceride or the esters of its part, glyceride type, Tissuemat E, paraffin, based on metallic soap
Lubricant, and lubricant based on amide.
Additionally, antioxidant/UV blockers can include that at least one is selected from following material: main anti-
Oxidant and auxiliary antioxidant and UV light stabilizing agent based on HALS.More specifically, anti-
Oxidant/UV blockers can include that at least one is selected from following material: 2,6-di-t-butyl-4-
Cresol, 2,6-dibenzyl-4-cresol, 3-(3-5-di-t-butyl-4'-hydroxyphenyl) propanoic acid stearoyl ester,
4,4'-thiobis-(3 methy 6 tert butyl phenol), 4-nonyl phenol, 2,2' methylene bis (4-
Methyl-6-tert-butylphenol), 2,5-di-t-butyl-hydroquinone and 4,4', 4 "-(1-methyl-1-propylene base-3-
Subunit)-three-2-(1,1-dimethyl ethyl)-5-cresol.
Additionally, described compositions can farther include other inorganic fillers, dyestuff, pigment, antistatic
Agent, surface conditioning agent, foaming agent, impact reinforcing agent etc..
Advantageously, described compound resin composition does not include noxious substance, as conventional steady in being used as
Determine lead (Pb) or the cadmium (Cd) of agent.Described compositions is had changed by kneading and extrusion preparation
The nontoxic PVC window of kind performance, described performance such as thermostability, weatherability and prevent initial coloring.
Beneficial effect
As it has been described above, the present invention can improve initial coloring the mid-term of Reinforced PVC or the most heat-resisting
Property.
Therefore, the PVC window of the present invention has chlorine resistance and the thermostability of excellence, and by using nothing
Machine stabilizer is actually characterized with good weatherability.Additionally, the PVC window of the present invention uses extremely
The suitable combination of few two kinds of different inorganic stabilizers, the inorganic stabilizers that described at least two is different
Feature is different, and cost is the most different, to obtain the advantage on cost, and therefore can be with the present invention's
PVC window substitutes and uses lead (Pb) or the PVC window of cadmium (Cd).
Accompanying drawing explanation
Fig. 1 shows the embodiment of the present invention 1 and as the inspection of lead in the comparative example 2 of prior art
Survey the photo of result.
Detailed description of the invention
Hereinafter, the detailed description of the present invention will be provided by following example.Embodiments of the invention
Can have a lot of changing and modifications, embodiments of the invention are not construed as the limit to the scope of the invention
System.
In the examples below, processing aid is methyl methacrylate-butyl-2-acrylic acid-ethylo benzene
Polymer；Impact modifying agent is chlorinated polyethylene；Lubricant is 1,2-benzene dicarboxylic acid dialkyl；Base
Compound in Non-toxic metal soap is zinc stearate or calcium stearate；Organic stabilizer is three-ethoxy
Isocyanuric acid ester；Antioxidant/UV blockers is tetramethylene methane or triguaiacyl phosphate；Based on
The inorganic matter of metal-oxide or metal hydroxides is lagoriolite or brucite；And auxiliary stabilizer
It it is dibenzoyl methanes metal mixture.
Embodiment
Embodiment 1
In order to prepare the measured homogeneous mixture of matter, at 110 DEG C, following material is added extremely
Henschel mixer high speed stirs 10 minutes and mixes: the PVC of 100 weight portions, 1 weight portion
Processing aid, the impact modifying agent of 8 weight portions, the TiO of 4 weight portions2, the carbonic acid of 12 weight portions
Calcium, the lubricant of 0.5 weight portion, the stabilizer based on Non-toxic metal soap of 2 weight portions, 0.2 weight
Part organic stabilizer, the antioxidant/UV blockers of 0.1 weight portion, 1 weight portion based on
The inorganic stabilizers of nontoxic metal (that is, by 100 weight portions based on metal-oxide or metal
The stabilizer coating the zinc of 10 weight portions on the inorganic matter of hydroxide and prepare), and 0.2 weight
The auxiliary agent of part.Then thus obtained mixture is passed through under the conditions of extruder defined below
The wheel of a window extruded by PVC window extruder (L/D is 25:1, parallel double-screw formula 90mm)
Wide.
Table 1
Comparative example 1
A window outline, difference is manufactured with the step identical with embodiment 1 manner described
Be: with do not have zinc coating or zinc compound based on metal-oxide or the inorganic matter of metal hydroxides
Replacing it is be coated with zinc or zinc compound based on metal-oxide or metal hydroxides inorganic
The inorganic stabilizers of thing.
Comparative example 2
A window outline, difference is manufactured with the step identical with embodiment 1 manner described
It is: use the PVC of 100 weight portions, the processing aid of 1 weight portion, the impact of 8 weight portions to change
Property agent, the TiO of 4 weight portions2, the calcium carbonate of 12 weight portions, the lubricant of 0.5 weight portion, 2 weights
The stabilizer based on Non-toxic metal soap of amount part and the lead stabilizer of 3 weight portions.
EXPERIMENTAL EXAMPLE 1: impact strength
Impact strength test is according to KS M 3056 method, uses I pattern product in standard temperature (23
± 2 DEG C) and the existence conditions of low temperature (-10 ± 1 DEG C) under respectively carry out 24h or longer time.According to KS F
5602 standards, impact strength is 12.7kJ/m under in standard temperature2Above and impact at low temperatures
Intensity is 4.9kJ/m2Time above, test sample reaches standard.Measurement result is shown in Table 2.
EXPERIMENTAL EXAMPLE 2: tensile yield strength and tensile break strength
Determine that the test of tensile yield strength and tensile break strength is being marked according to KS M 3006 method
II type test sample is used to carry out at quasi-temperature (23 ± 2 DEG C).According to KS F 5602 standard, when drawing
Stretching yield strength is 36.8MN/m2Above and time tensile break strength is more than 100%, test specimens
Product reach standard.Measurement result is shown in Table 2.
EXPERIMENTAL EXAMPLE 3: hardness
Hardness test is carried out according to the Rockwell hardness rank of KS M ISO 2039-2 method.According to KS
F 5602 standard, when hardness is more than 85, test sample reaches standard.Measurement result is listed in table 2
In.
EXPERIMENTAL EXAMPLE 4: vicat softening temperature
Vicat softening temperature test is carried out under 9.80N load according to KS M 3056 method.According to
KS F 5602 standard, when vicat softening temperature is more than 83 DEG C, test sample reaches standard.Measure
The results are shown in Table 2.
EXPERIMENTAL EXAMPLE 5: weatherability
Weatherability test according to the method for KS F 2274 by sample under the xenon arc of xenon arc device radiates
Exposing 1000 hours and carry out, wherein the temperature of black panel is 63 ± 3 DEG C, and spray cycles is every
120 minutes 18 minutes.Subsequently, the change of colourity is measured with colorimeter.Mark according to KS F 5602
Standard, when not having obvious variable color, test sample reaches standard.Measurement result is shown in Table 2.
EXPERIMENTAL EXAMPLE 6: initial coloring
Chromatic value uses CR-400 colorimeter to determine, to detect the outward appearance of initial coloration.Additionally, it is resistance to
Hot by sample putting into 20mm for 5 minutes every in masis (mathis) baking oven of 200 DEG C
Measure.Measurement result is shown in Table 2.
EXPERIMENTAL EXAMPLE 7: avirulence
Lead test is to use lead detection assay specimen to determine the existence of lead component.Lead detection assay specimen
There is lead in the proof that reddens, and lead detection does not redden to turn out and do not has lead.From figure 1 it will be seen that it is real
The lead detection executing example 1 is displayed without variable color, it was demonstrated that be not detected by lead.Contrary, comparative example
2 use lead stabilizer to cause test solution to redden proves that it is leaded.
Table 2
Initial coloring is represented by the initial value of extruded product.Additionally, masis baking oven is used for evaluating resistance to
Hot.After 20 minutes and 40 minutes, the aberration with the contrast of initial stage chromatic value is given by Δ E.Test
Display embodiment 1 has unconspicuous aberration, compares comparative example 1 and demonstrates high thermostability.
By lead detection test, avirulence determines that the existence of lead is assessed.
The detection completed by outside research mechanism KCL proves that nontoxic window does not contains lead, cadmium and hydrargyrum.
But described outside research mechanism does not assess the conventional window using lead.Therefore, use as shown in Figure 1
Lead detection assay specimen determines the existence of lead.
From the result of table 2 it will be seen that the window that all test results all demonstrate the present invention meets
KS F 5602 standard, and also prove that preventing also be extremely excellent in initial coloring and avirulence.
Claims (14)
1., for a compound resin composition for nontoxic PVC window, it includes that the stabilizer for synthetic resin, described stabilizer include: (a) stabilizer based on Non-toxic metal soap；(b) inorganic stabilizers based on nontoxic metal, wherein inorganic stabilizers (b) based on nontoxic metal is the compound comprising the metal-oxide being coated with Zn, wherein PVC based on 100 weight portions meter, described compound resin composition comprises the inorganic stabilizers based on nontoxic metal of 0.5 to 15 weight portion.
2. the compound resin composition for nontoxic PVC window of claim 1, wherein stabilizer (a) based on Non-toxic metal soap is following compound: the hydrogen on the fatty acid of the alkyl wherein containing 3 to 50 carbon atoms is selected from least one metal of Li, Na, K, Mg, Ca, Al and Zn and replaces, wherein PVC based on 100 weight portions meter, described compound resin composition comprises the stabilizer based on Non-toxic metal soap of 0.1 to 15 weight portion.
3. the compound resin composition for nontoxic PVC window of claim 1, wherein metal-oxide includes that at least one is selected from following material: calcium oxide, magnesium oxide, aluminium oxide and titanium oxide.
4. the compound resin composition for nontoxic PVC window of claim 1, wherein metal-oxide meters based on 100 weight portions, described compound resin composition comprises the nontoxic metal of 0.01 to 10 weight portion.
5., for a compound resin composition for nontoxic PVC window, it includes that the stabilizer for synthetic resin, described stabilizer include: (a) stabilizer based on Non-toxic metal soap；(b) inorganic stabilizers based on nontoxic metal, wherein inorganic stabilizers (b) based on nontoxic metal is the compound comprising the inorganic matter based on hydroxide being coated with Zn, wherein PVC based on 100 weight portions meter, described compound resin composition comprises the inorganic stabilizers based on nontoxic metal of 0.5 to 15 weight portion.
6. the compound resin composition for nontoxic PVC window of claim 5, wherein inorganic matter based on hydroxide includes that at least one is selected from following material: calcium hydroxide, magnesium hydroxide, aluminium hydroxide, brucite.
7. the compound resin composition for nontoxic PVC window of claim 5, wherein inorganic matter meters based on hydroxide based on 100 weight portions, described compound resin composition comprises the nontoxic metal of 0.01 to 10 weight portion.
8. the compound resin composition for nontoxic PVC window of claim 1 or 5, wherein PVC based on 100 weight portions meter, described compositions also includes at least one co-stabilizer of 0.1 to 5 weight portion, at least one co-stabilizer described is selected from 1,3-diketone, dihydropyridine, polyhydric alcohol, isocyanuric acid ester, amino acid derivativges, organophosphorus ester, epoxide, perchlorate, and superpower hydrochlorate.
9. the compound resin composition for nontoxic PVC window of claim 1 or 5, wherein PVC based on 100 weight portions meter, described compositions also includes at least one organic stabilizer of 0.01 to 5 weight portion, and at least one organic stabilizer described is selected from zinc octoate, calcium acetylacetonate and tris(2-hydroxy ethyl)isocyanurate (THEIC).
10. the compound resin composition for nontoxic PVC window of claim 1 or 5, wherein PVC includes that at least one is selected from following material: polrvinyl chloride, polyvinylidene chloride, chlorinated polyethylene, chlorosulfonated polyethylene, chlorinated polypropylene or ethlyene dichloride and the copolymer of vinyl acetate.
The compound resin composition for nontoxic PVC window of 11. claim 1 or 5, wherein PVC based on 100 weight portions meter, described compositions also includes that at least one is selected from following material: the processing aid of 0.5 to 10 weight portion, the impact modifying agent of 5 to 15 weight portions, the TiO of 2 to 10 weight portions2, the calcium carbonate of 10 to 30 weight portions, the lubricant of 0.5 to 10 weight portion and the antioxidant/UV blockers of 0.1 to 5 weight portion,
Wherein said processing aid includes that at least one is selected from following material: processing aid based on acrylate, processing aid based on methacrylate and processing aid based on acrylonitrile, described lubricant includes that at least one is selected from following material: lignite wax, fatty acid ester, glyceride type, Tissuemat E, paraffin, lubricant based on metallic soap, and lubricant based on amide.
The compound resin composition for nontoxic PVC window of 12. claim 11, wherein impact modifying agent includes that at least one is selected from following material: impact modifying agent based on acryloyl and impact modifying agent based on chlorinated polyethylene.
The compound resin composition for nontoxic PVC window of 13. claim 11, wherein antioxidant/UV blockers includes that at least one is selected from following material: 2, 6-di-t-butyl-4-cresol, 2, 6-dibenzyl-4-cresol, 3-(3-5-di-t-butyl-4'-hydroxyphenyl) propanoic acid stearoyl ester, 4, 4'-thiobis-(3 methy 6 tert butyl phenol), 4-nonyl phenol, 2, 2'-di-2-ethylhexylphosphine oxide (4-methyl-6-tert-butylphenol), 2, 5-di-t-butyl-hydroquinone and 4, 4', 4 "-(1-methyl-1-propylene base-3-subunit)-three-2-(1, 1-dimethyl ethyl)-5-cresol.
14. 1 kinds of nontoxic PVC windows, it uses compound resin composition for nontoxic PVC window as any one of claim 1 to 13 by kneading and extrusion manufacture, and has the performance of improvement, including thermostability, weatherability with prevent initial coloring.
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| Application Number | Priority Date | Filing Date | Title |
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| KR1020120027370A KR101505241B1 (en) | 2012-03-16 | 2012-03-16 | Synthetic resin composition for pvc nontoxic windows, and pvc nontoxic windows |
| KR10-2012-0027370 | 2012-03-16 | ||
| PCT/KR2013/002122 WO2013137688A1 (en) | 2012-03-16 | 2013-03-15 | Synthetic resin composition for pvc nontoxci windows, and nontoxic pvc windows |
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| CN104204076A CN104204076A (en) | 2014-12-10 |
| CN104204076B true CN104204076B (en) | 2016-10-19 |
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| KR (1) | KR101505241B1 (en) |
| CN (1) | CN104204076B (en) |
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| KR101529085B1 (en) * | 2013-10-11 | 2015-06-29 | 주식회사 재현인텍스 | Door frame |
| CN105524369A (en) * | 2015-12-14 | 2016-04-27 | 东莞市美饰家窗帘制品有限公司 | PVC foamed waterproof window and preparation technology thereof |
| CN109337248A (en) * | 2018-10-18 | 2019-02-15 | 合肥万之景门窗有限公司 | A kind of heat-resisting anti-aging Corvic |
| KR102130698B1 (en) * | 2020-03-12 | 2020-07-07 | 신백범 | PVC window frame comprising two-part polyurethane composition |
| KR102413422B1 (en) | 2020-12-29 | 2022-06-28 | (주) 홍익바이오텍 | Composite PVC manufacturing method for chassis and duct manufacturing containing antibacterial inorganic substances |
| CN117304571B (en) * | 2023-11-30 | 2024-04-02 | 慧科高新科技股份有限公司 | Nanoparticle modified PVC heat stabilizer and preparation method thereof |
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| Publication number | Publication date |
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| KR101505241B1 (en) | 2015-03-23 |
| KR20130105168A (en) | 2013-09-25 |
| WO2013137688A1 (en) | 2013-09-19 |
| CN104204076A (en) | 2014-12-10 |
| RU2014141618A (en) | 2016-05-10 |
| WO2013137688A9 (en) | 2013-11-07 |
| RU2585012C2 (en) | 2016-05-27 |
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