CN104194175A - Oil-resistant corrosion-resistant cable sheath material - Google Patents
Oil-resistant corrosion-resistant cable sheath material Download PDFInfo
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- CN104194175A CN104194175A CN201410409958.6A CN201410409958A CN104194175A CN 104194175 A CN104194175 A CN 104194175A CN 201410409958 A CN201410409958 A CN 201410409958A CN 104194175 A CN104194175 A CN 104194175A
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- cable sheath
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- sheath material
- resistant corrosion
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/32—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with compounds containing phosphorus or sulfur
- C08L23/34—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with compounds containing phosphorus or sulfur by chlorosulfonation
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an oil-resistant corrosion-resistant cable sheath material which is prepared from the following raw materials in parts by weight: 20-30 parts of chlorosulfonated polyethylene, 20-25 parts of ethylene-vinyl acetate resin, 25-32 parts of semi-reinforcing carbon black, 4-8 parts of light calcium carbonate, 5-7 parts of titanium white, 1-1.5 parts of antimony trioxide, 20-25 parts of nano magnesium hydroxide, 10-15 parts of nano clay, 1-1.5 parts of polyethylene wax, 2-4 parts of Aflux 25, 1-2 parts of anti-aging agent RD, 1-3 parts of oleate, 0.5-1.5 parts of tritolyl phosphate and 1-1.5 parts of dicumyl peroxide. The oil-resistant corrosion-resistant cable sheath material has the advantages of excellent oil resistance, excellent heat resistance, excellent flame retardancy, favorable corrosion resistance and favorable aging resistance.
Description
Technical field
The present invention relates to cable sheath technical field, relate in particular to a kind of oil resistant corrosion cable sheath material.
Background technology
Chlorosulfonated polyethylene is made through superchlorination and chlorosulfonation by Low Density Polyethylene or high density polyethylene(HDPE).For white or yellow elastomerics, can be dissolved in aromatic hydrocarbon and hydrochloric ether is insoluble in fat and alcohol, in ketone and ether, can only swelling can not dissolve, there are excellent ozone resistance, resistance to weathering, chemical resistance etc., preferably physical and mechanical properties, ageing-resistant performance, heat-resisting and lower temperature resistance, oil-proofness, flame resistivity, wear resistance and resistance to electrical insulating property.But the Jin You U.S., Japan, Russia and a few countries such as Chinese have device in the world at present, and approximately 7.5 ten thousand tons of the total annual capacities in the whole world, make product cost too high.
Ethylene-vinyl acetate resin is by ethene and thermoplastic resin vinyl acetate copolymerized and that make.The vinyl acetate content of Industrial products is 5%~95%, and between each kind, performance difference is larger.Generally, along with vinyl acetate content increases, degree of crystallinity hardness rigidity and heat-drawn wire reduce gradually, and glossiness, solubility, heat-shrinkable and the hot weld etc. of transparency shock-resistance snappiness stress cracking resistance in solvent have in various degree and improve.Mainly contain following kinds: vinyl acetate content is 5-15%, compare with Low Density Polyethylene, its outward appearance is very similar with physical and mechanical properties, but transparency, snappiness, hot weld and stress cracking resistance have obvious improvement, working method is also identical, be applicable to do agricultural film, heat-shrinkable film, various laminated film and generally use packaging film, also can make cable sheath; Vinyl acetate content is 15-40%, pliable and tough flexible, can be used as sole sealed strip cable goods and foam plastic product etc., be used as chemicals for papermaking with paraffin blending, also there is bonds well performance with many materials, extensively in order to prepare various hot melt adhesives and other types tackiness agent, for books unsewn binding and packaging seal; Vinyl acetate content is 40-50%, is elastomerics, can be used in cable industry, by vinylchlorid and its graft copolymerization, in order to improve rigid polyvinyl chloride shock resistance after being cross-linked; Vinyl acetate content is 70-95%, general direct with emulsion form sale, in order to prepare various coating, tackiness agent and to be used as paper and fabric coating.
Cable sheath is the indispensable intermediate structure part of cable; play a part protection cable; guarantee the energising safety of cable; make the media such as copper wire and water, air isolated; avoid occurring leaky; along with expanding economy; need to use the place of cable to become diversified; the performance index of cable jacket material have been had to stricter and various requirement; the performance that improves constantly sheath material is the active demand of economy and social development, is now badly in need of a kind of oil resistant, the cable sheath that ageing-resistant, resistance to elevated temperatures is good.
Summary of the invention
The technical problem that basic background technology exists, the present invention proposes a kind of oil resistant corrosion cable sheath material, has excellent oil resistant, heat-proof combustion-resistant performance, also has good corrosion-resistant and ageing-resistant performance.
A kind of oil resistant corrosion cable sheath material that the present invention proposes, its raw material comprises by weight: chlorosulfonated polyethylene 20-30 part, ethylene-vinyl acetate resin 20-25 part, semi-reinforcing hydrocarbon black 25-32 part, light calcium carbonate 4-8 part, titanium dioxide 5-7 part, antimonous oxide 1-1.5 part, nano-sized magnesium hydroxide 20-25 part, nanoclay 10-15 part, polyethylene wax 1-1.5 part, the Lay mattress 25 2-4 parts of faling apart, anti-aging agent RD 1-2 part, oleic acid ester 1-3 part, Tritolyl Phosphate 0.5-1.5 part, dicumyl peroxide 1-1.5 part;
In preparation process, by chlorosulfonated polyethylene, ethylene-vinyl acetate resin adds in Banbury mixer, be heated to 68-73 ℃ of mixing 1-2min, then be warming up to 90-100 ℃, add again antimonous oxide, nano-sized magnesium hydroxide, nanoclay, polyethylene wax, Lay mattress loose 25, anti-aging agent RD, the mixing 2-4min of dicumyl peroxide, then add semi-reinforcing hydrocarbon black, light calcium carbonate, titanium dioxide, oleic acid ester, Tritolyl Phosphate continues mixing 2-3min, then be cooled to the 55-65 ℃ of mixing 2-3min of continuation and obtain middle material, centre material is placed in to vulcanizing press and at 150-158 ℃, vulcanizes 2-3min, then cool the temperature to 128-135 ℃ of insulation 0.5-1h, obtain oil resistant corrosion cable sheath material.
Preferably, the weight ratio of chlorosulfonated polyethylene and ethylene-vinyl acetate resin is 25-27:23-24.
Preferably, the particle diameter of nano-sized magnesium hydroxide is 30-50nm.
Preferably, its raw material comprises by weight: chlorosulfonated polyethylene 25-27 part, ethylene-vinyl acetate resin 23-24 part, semi-reinforcing hydrocarbon black 27-30 part, light calcium carbonate 6-7 part, titanium dioxide 5.5-6 part, antimonous oxide 1.2-1.4 part, nano-sized magnesium hydroxide 22-23 part, nanoclay 12-14 part, polyethylene wax 1.1-1.3 part, the Lay mattress 25 3-3.6 parts of faling apart, anti-aging agent RD 1.1-1.2 part, oleic acid ester 1.3-2.6 part, Tritolyl Phosphate 0.7-1 part, dicumyl peroxide 1.2-1.4 part.
Preferably, in preparation process, chlorosulfonated polyethylene, ethylene-vinyl acetate resin are added in Banbury mixer, be heated to 70-72 ℃, mixing 1.3-1.5min, then be warming up to 95-99 ℃, add again antimonous oxide, nano-sized magnesium hydroxide, nanoclay, polyethylene wax, Lay mattress loose 25, anti-aging agent RD, the mixing 2.4-3min of dicumyl peroxide, then add semi-reinforcing hydrocarbon black, light calcium carbonate, titanium dioxide, oleic acid ester, Tritolyl Phosphate continues mixing 2.5-2.7min, then be cooled to the 58-60 ℃ of mixing 2.5-2.9min of continuation and obtain middle material, centre material is placed in to vulcanizing press and at 153-156 ℃, vulcanizes 2.2-2.5min, then cool the temperature to 130-133 ℃ of insulation 0.6-0.8h, obtain oil resistant corrosion cable sheath material.
Chlorosulfonated polyethylene of the present invention and ethylene-vinyl acetate resin are major ingredient, make the present invention there is excellent ozone resistance, resistance to weathering, chemical resistance, also possess good physical and mechanical properties, ageing-resistant performance, heat-resisting winter hardiness, oil-proofness, flame resistivity and wear resistance; Using semi-reinforcing hydrocarbon black, light calcium carbonate, titanium dioxide, antimonous oxide, nano-sized magnesium hydroxide and nanoclay as reinforcement system, significantly strengthen the performance of the wear-resisting and anti tear of the present invention, can also reduce the intermolecular gap of major ingredient, improve ventilation property of the present invention, thereby strengthen oil resistance of the present invention, antimonous oxide wherein and nano-sized magnesium hydroxide, as fire retardant, coordinate and produce synergy with the haloid element in major ingredient, improve the effect that heat-proof combustion-resistant of the present invention presses down cigarette; Anti-aging agent RD and chlorosulfonated polyethylene mating reaction, further improved ageing-resistant performance of the present invention.
Embodiment
Below, by specific embodiment, technical scheme of the present invention is elaborated.
Embodiment 1
A kind of oil resistant corrosion cable sheath material that the present invention proposes, its raw material comprises by weight: 20 parts of chlorosulfonated polyethylenes, 25 parts of ethylene-vinyl acetate resins, 25 parts of semi-reinforcing hydrocarbon blacks, 8 parts of light calcium carbonates, 5 parts of titanium dioxides, 1.5 parts of antimonous oxides, 20 parts of nano-sized magnesium hydroxides, 15 parts of nanoclays, 1 part of polyethylene wax, loose 25 4 parts of Lay mattress, 1 part of anti-aging agent RD, 3 parts of oleic acid esters, 0.5 part of Tritolyl Phosphate, 1.5 parts of dicumyl peroxides, wherein the particle diameter of nano-sized magnesium hydroxide is 30-50nm;
In preparation process, by chlorosulfonated polyethylene, ethylene-vinyl acetate resin adds in Banbury mixer, be heated to 68 ℃ of mixing 2min, then be warming up to 90 ℃, add again antimonous oxide, nano-sized magnesium hydroxide, nanoclay, polyethylene wax, Lay mattress loose 25, anti-aging agent RD, the mixing 4min of dicumyl peroxide, then add semi-reinforcing hydrocarbon black, light calcium carbonate, titanium dioxide, oleic acid ester, Tritolyl Phosphate continues mixing 2min, then be cooled to 65 ℃ of mixing 2min of continuation and obtain middle material, centre material is placed in to vulcanizing press and at 158 ℃, vulcanizes 2min, then cool the temperature to 135 ℃ of insulation 0.5h, obtain oil resistant corrosion cable sheath material.
Embodiment 2
A kind of oil resistant corrosion cable sheath material that the present invention proposes, its raw material comprises by weight: 25 parts of chlorosulfonated polyethylenes, 23 parts of ethylene-vinyl acetate resins, 30 parts of semi-reinforcing hydrocarbon blacks, 6 parts of light calcium carbonates, 6 parts of titanium dioxides, 1.2 parts of antimonous oxides, 23 parts of nano-sized magnesium hydroxides, 12 parts of nanoclays, 1.3 parts of polyethylene waxs, loose 25 3 parts of Lay mattress, 1.2 parts of anti-aging agent RDs, 1.3 parts of oleic acid esters, 1 part of Tritolyl Phosphate, 1.2 parts of dicumyl peroxides;
In preparation process, by chlorosulfonated polyethylene, ethylene-vinyl acetate resin adds in Banbury mixer, be heated to 73 ℃ of mixing 1min, then be warming up to 100 ℃, add again antimonous oxide, nano-sized magnesium hydroxide, nanoclay, polyethylene wax, Lay mattress loose 25, anti-aging agent RD, the mixing 2min of dicumyl peroxide, then add semi-reinforcing hydrocarbon black, light calcium carbonate, titanium dioxide, oleic acid ester, Tritolyl Phosphate continues mixing 3min, then be cooled to 55 ℃ of mixing 3min of continuation and obtain middle material, centre material is placed in to vulcanizing press and at 150 ℃, vulcanizes 3min, then cool the temperature to 128 ℃ of insulation 1h, obtain oil resistant corrosion cable sheath material.
Embodiment 3
A kind of oil resistant corrosion cable sheath material that the present invention proposes, its raw material comprises by weight: 30 parts of chlorosulfonated polyethylenes, 20 parts of ethylene-vinyl acetate resins, 32 parts of semi-reinforcing hydrocarbon blacks, 4 parts of light calcium carbonates, 7 parts of titanium dioxides, 1 part of antimonous oxide, 25 parts of nano-sized magnesium hydroxides, 10 parts of nanoclays, 1.5 parts of polyethylene waxs, loose 25 2 parts of Lay mattress, 2 parts of anti-aging agent RDs, 1 part of oleic acid ester, 1.5 parts of Tritolyl Phosphates, 1 part of dicumyl peroxide, wherein the particle diameter of nano-sized magnesium hydroxide is 30-50nm;
In preparation process, by chlorosulfonated polyethylene, ethylene-vinyl acetate resin adds in Banbury mixer, be heated to 70 ℃ of mixing 1.5min, then be warming up to 95 ℃, add again antimonous oxide, nano-sized magnesium hydroxide, nanoclay, polyethylene wax, Lay mattress loose 25, anti-aging agent RD, the mixing 3min of dicumyl peroxide, then add semi-reinforcing hydrocarbon black, light calcium carbonate, titanium dioxide, oleic acid ester, Tritolyl Phosphate continues mixing 2.5min, then be cooled to 60 ℃ of mixing 2.5min of continuation and obtain middle material, centre material is placed in to vulcanizing press and at 156 ℃, vulcanizes 2.5min, then cool the temperature to 130 ℃ of insulation 0.8h, obtain oil resistant corrosion cable sheath material.
Embodiment 4
A kind of oil resistant corrosion cable sheath material that the present invention proposes, its raw material comprises by weight: 27 parts of chlorosulfonated polyethylenes, 24 parts of ethylene-vinyl acetate resins, 27 parts of semi-reinforcing hydrocarbon blacks, 7 parts of light calcium carbonates, 5.5 parts of titanium dioxides, 1.4 parts of antimonous oxides, 22 parts of nano-sized magnesium hydroxides, 14 parts of nanoclays, 1.1 parts of polyethylene waxs, loose 25 3.6 parts of Lay mattress, 1.1 parts of anti-aging agent RDs, 2.6 parts of oleic acid esters, 0.7 part of Tritolyl Phosphate, 1.4 parts of dicumyl peroxides;
In preparation process, by chlorosulfonated polyethylene, ethylene-vinyl acetate resin adds in Banbury mixer, be heated to 72 ℃ of mixing 1.3min, then be warming up to 99 ℃, add again antimonous oxide, nano-sized magnesium hydroxide, nanoclay, polyethylene wax, Lay mattress loose 25, anti-aging agent RD, the mixing 2.4min of dicumyl peroxide, then add semi-reinforcing hydrocarbon black, light calcium carbonate, titanium dioxide, oleic acid ester, Tritolyl Phosphate continues mixing 2.7min, then be cooled to 58 ℃ of mixing 2.9min of continuation and obtain middle material, centre material is placed in to vulcanizing press and at 153 ℃, vulcanizes 2.5min, then cool the temperature to 133 ℃ of insulation 0.6h, obtain oil resistant corrosion cable sheath material.
The above; it is only preferably embodiment of the present invention; but protection scope of the present invention is not limited to this; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; according to technical scheme of the present invention and inventive concept thereof, be equal to replacement or changed, within all should being encompassed in protection scope of the present invention.
Claims (5)
1. an oil resistant corrosion cable sheath material, it is characterized in that, its raw material comprises by weight: chlorosulfonated polyethylene 20-30 part, ethylene-vinyl acetate resin 20-25 part, semi-reinforcing hydrocarbon black 25-32 part, light calcium carbonate 4-8 part, titanium dioxide 5-7 part, antimonous oxide 1-1.5 part, nano-sized magnesium hydroxide 20-25 part, nanoclay 10-15 part, polyethylene wax 1-1.5 part, the Lay mattress 25 2-4 parts of faling apart, anti-aging agent RD 1-2 part, oleic acid ester 1-3 part, Tritolyl Phosphate 0.5-1.5 part, dicumyl peroxide 1-1.5 part;
In preparation process, by chlorosulfonated polyethylene, ethylene-vinyl acetate resin adds in Banbury mixer, be heated to 68-73 ℃ of mixing 1-2min, then be warming up to 90-100 ℃, add again antimonous oxide, nano-sized magnesium hydroxide, nanoclay, polyethylene wax, Lay mattress loose 25, anti-aging agent RD, the mixing 2-4min of dicumyl peroxide, then add semi-reinforcing hydrocarbon black, light calcium carbonate, titanium dioxide, oleic acid ester, Tritolyl Phosphate continues mixing 2-3min, then be cooled to the 55-65 ℃ of mixing 2-3min of continuation and obtain middle material, centre material is placed in to vulcanizing press and at 150-158 ℃, vulcanizes 2-3min, then cool the temperature to 128-135 ℃ of insulation 0.5-1h, obtain oil resistant corrosion cable sheath material.
2. oil resistant corrosion cable sheath material according to claim 1, is characterized in that, the weight ratio of chlorosulfonated polyethylene and ethylene-vinyl acetate resin is 25-27:23-24.
3. oil resistant corrosion cable sheath material according to claim 1 and 2, is characterized in that, the particle diameter of nano-sized magnesium hydroxide is 30-50nm.
4. according to the oil resistant corrosion cable sheath material described in any one in claim 1-3, it is characterized in that, its raw material comprises by weight: chlorosulfonated polyethylene 25-27 part, ethylene-vinyl acetate resin 23-24 part, semi-reinforcing hydrocarbon black 27-30 part, light calcium carbonate 6-7 part, titanium dioxide 5.5-6 part, antimonous oxide 1.2-1.4 part, nano-sized magnesium hydroxide 22-23 part, nanoclay 12-14 part, polyethylene wax 1.1-1.3 part, the Lay mattress 25 3-3.6 parts of faling apart, anti-aging agent RD 1.1-1.2 part, oleic acid ester 1.3-2.6 part, Tritolyl Phosphate 0.7-1 part, dicumyl peroxide 1.2-1.4 part.
5. according to the oil resistant corrosion cable sheath material described in any one in claim 1-4, it is characterized in that, in preparation process, by chlorosulfonated polyethylene, ethylene-vinyl acetate resin adds in Banbury mixer, be heated to 70-72 ℃ of mixing 1.3-1.5min, then be warming up to 95-99 ℃, add again antimonous oxide, nano-sized magnesium hydroxide, nanoclay, polyethylene wax, Lay mattress loose 25, anti-aging agent RD, the mixing 2.4-3min of dicumyl peroxide, then add semi-reinforcing hydrocarbon black, light calcium carbonate, titanium dioxide, oleic acid ester, Tritolyl Phosphate continues mixing 2.5-2.7min, then be cooled to the 58-60 ℃ of mixing 2.5-2.9min of continuation and obtain middle material, centre material is placed in to vulcanizing press and at 153-156 ℃, vulcanizes 2.2-2.5min, then cool the temperature to 130-133 ℃ of insulation 0.6-0.8h, obtain oil resistant corrosion cable sheath material.
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104877243A (en) * | 2015-05-25 | 2015-09-02 | 南洋电缆(天津)有限公司 | Low-toxicity, high-fire-retardant, and uvioresistant cable sheath and preparation method thereof |
CN104945727A (en) * | 2015-07-16 | 2015-09-30 | 常州市武进凯利达电子有限公司 | Outdoor overhead ageing-resistant insulating polyolefin cable material and preparation method thereof |
CN105199251A (en) * | 2015-10-16 | 2015-12-30 | 鞍山市宏图防腐工程有限公司 | Magnesium hydroxide containing chlorosulfonated polyethylene rubber formula |
CN107286489A (en) * | 2017-07-06 | 2017-10-24 | 无为华兴高分子材料有限公司 | A kind of high rigidity chlorosulfonated polyethylene plastics |
CN110845805A (en) * | 2019-11-28 | 2020-02-28 | 王一然 | Rubber |
CN111675860A (en) * | 2020-07-23 | 2020-09-18 | 远东电缆有限公司 | Low-temperature-resistant oil-resistant torsion-resistant high-flame-retardant sheath material and preparation method thereof |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104877243A (en) * | 2015-05-25 | 2015-09-02 | 南洋电缆(天津)有限公司 | Low-toxicity, high-fire-retardant, and uvioresistant cable sheath and preparation method thereof |
CN104945727A (en) * | 2015-07-16 | 2015-09-30 | 常州市武进凯利达电子有限公司 | Outdoor overhead ageing-resistant insulating polyolefin cable material and preparation method thereof |
CN105199251A (en) * | 2015-10-16 | 2015-12-30 | 鞍山市宏图防腐工程有限公司 | Magnesium hydroxide containing chlorosulfonated polyethylene rubber formula |
CN107286489A (en) * | 2017-07-06 | 2017-10-24 | 无为华兴高分子材料有限公司 | A kind of high rigidity chlorosulfonated polyethylene plastics |
CN110845805A (en) * | 2019-11-28 | 2020-02-28 | 王一然 | Rubber |
CN110845805B (en) * | 2019-11-28 | 2022-08-26 | 王一然 | Rubber |
CN115612219A (en) * | 2019-11-28 | 2023-01-17 | 王一然 | Rubber |
CN111675860A (en) * | 2020-07-23 | 2020-09-18 | 远东电缆有限公司 | Low-temperature-resistant oil-resistant torsion-resistant high-flame-retardant sheath material and preparation method thereof |
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Application publication date: 20141210 |