CN104193886A - High-breathability water absorbable acrylic ester foamed material as well as preparation method and application thereof - Google Patents
High-breathability water absorbable acrylic ester foamed material as well as preparation method and application thereof Download PDFInfo
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- CN104193886A CN104193886A CN201410353792.0A CN201410353792A CN104193886A CN 104193886 A CN104193886 A CN 104193886A CN 201410353792 A CN201410353792 A CN 201410353792A CN 104193886 A CN104193886 A CN 104193886A
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 135
- 238000002360 preparation method Methods 0.000 title claims abstract description 83
- -1 acrylic ester Chemical class 0.000 title claims abstract description 27
- 239000000463 material Substances 0.000 title abstract description 11
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 24
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 23
- 239000012071 phase Substances 0.000 claims description 52
- 238000003756 stirring Methods 0.000 claims description 47
- 239000006261 foam material Substances 0.000 claims description 42
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 39
- 239000003999 initiator Substances 0.000 claims description 35
- NQSLZEHVGKWKAY-UHFFFAOYSA-N 6-methylheptyl 2-methylprop-2-enoate Chemical group CC(C)CCCCCOC(=O)C(C)=C NQSLZEHVGKWKAY-UHFFFAOYSA-N 0.000 claims description 23
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 claims description 23
- 239000008346 aqueous phase Substances 0.000 claims description 19
- 239000000178 monomer Substances 0.000 claims description 15
- 239000004160 Ammonium persulphate Substances 0.000 claims description 13
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 13
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical group [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 13
- 235000019395 ammonium persulphate Nutrition 0.000 claims description 13
- VOBUAPTXJKMNCT-UHFFFAOYSA-N 1-prop-2-enoyloxyhexyl prop-2-enoate Chemical group CCCCCC(OC(=O)C=C)OC(=O)C=C VOBUAPTXJKMNCT-UHFFFAOYSA-N 0.000 claims description 12
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical group FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 claims description 12
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 9
- 239000003995 emulsifying agent Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- INQDDHNZXOAFFD-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOC(=O)C=C INQDDHNZXOAFFD-UHFFFAOYSA-N 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 8
- 150000002500 ions Chemical class 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 7
- 239000003792 electrolyte Substances 0.000 claims description 7
- 229910021645 metal ion Inorganic materials 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims description 5
- OWDBMKZHFCSOOL-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)propoxy]propoxy]propyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)COC(C)COC(C)COC(=O)C(C)=C OWDBMKZHFCSOOL-UHFFFAOYSA-N 0.000 claims description 5
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 5
- JFZBUNLOTDDXNY-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)propoxy]propyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(C)OCC(C)OC(=O)C(C)=C JFZBUNLOTDDXNY-UHFFFAOYSA-N 0.000 claims description 4
- VFZKVQVQOMDJEG-UHFFFAOYSA-N 2-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(=O)C=C VFZKVQVQOMDJEG-UHFFFAOYSA-N 0.000 claims description 4
- LVGFPWDANALGOY-UHFFFAOYSA-N 8-methylnonyl prop-2-enoate Chemical compound CC(C)CCCCCCCOC(=O)C=C LVGFPWDANALGOY-UHFFFAOYSA-N 0.000 claims description 4
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 claims description 4
- 150000002632 lipids Chemical class 0.000 claims description 4
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 claims description 3
- 239000004159 Potassium persulphate Substances 0.000 claims description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 3
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 3
- 235000019394 potassium persulphate Nutrition 0.000 claims description 3
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims description 2
- HWSSEYVMGDIFMH-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C HWSSEYVMGDIFMH-UHFFFAOYSA-N 0.000 claims description 2
- COCLLEMEIJQBAG-UHFFFAOYSA-N 8-methylnonyl 2-methylprop-2-enoate Chemical compound CC(C)CCCCCCCOC(=O)C(C)=C COCLLEMEIJQBAG-UHFFFAOYSA-N 0.000 claims description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 2
- 241000370738 Chlorion Species 0.000 claims description 2
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 claims description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 claims description 2
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 229940063013 borate ion Drugs 0.000 claims description 2
- 229910001424 calcium ion Inorganic materials 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 229910001425 magnesium ion Inorganic materials 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- 229910001414 potassium ion Inorganic materials 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 229910001415 sodium ion Inorganic materials 0.000 claims description 2
- 239000007858 starting material Substances 0.000 claims description 2
- 238000010521 absorption reaction Methods 0.000 abstract description 25
- 239000012530 fluid Substances 0.000 abstract description 19
- 210000002700 urine Anatomy 0.000 abstract description 19
- 239000002473 artificial blood Substances 0.000 abstract description 17
- 239000011358 absorbing material Substances 0.000 abstract description 5
- 239000006185 dispersion Substances 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 1
- 239000008367 deionised water Substances 0.000 abstract 1
- 229910021641 deionized water Inorganic materials 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- 238000003860 storage Methods 0.000 abstract 1
- 206010000269 abscess Diseases 0.000 description 35
- 238000009423 ventilation Methods 0.000 description 31
- 239000000839 emulsion Substances 0.000 description 20
- 150000003839 salts Chemical class 0.000 description 20
- 239000011259 mixed solution Substances 0.000 description 15
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 15
- 238000010792 warming Methods 0.000 description 15
- 238000005406 washing Methods 0.000 description 15
- 239000008151 electrolyte solution Substances 0.000 description 14
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 11
- 229920000053 polysorbate 80 Polymers 0.000 description 11
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 10
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 10
- 239000001110 calcium chloride Substances 0.000 description 10
- 229910001628 calcium chloride Inorganic materials 0.000 description 10
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 6
- 210000003677 hemocyte Anatomy 0.000 description 6
- 229940000351 hemocyte Drugs 0.000 description 6
- 210000004369 blood Anatomy 0.000 description 5
- 239000008280 blood Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 230000035699 permeability Effects 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 3
- 229920001214 Polysorbate 60 Polymers 0.000 description 3
- 239000002250 absorbent Substances 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- 150000002314 glycerols Chemical class 0.000 description 3
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 2
- 210000002381 plasma Anatomy 0.000 description 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
- 229920001213 Polysorbate 20 Polymers 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 150000008040 ionic compounds Chemical class 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 238000000643 oven drying Methods 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 229910000160 potassium phosphate Inorganic materials 0.000 description 1
- 229940093916 potassium phosphate Drugs 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- WUUHFRRPHJEEKV-UHFFFAOYSA-N tripotassium borate Chemical compound [K+].[K+].[K+].[O-]B([O-])[O-] WUUHFRRPHJEEKV-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
Landscapes
- Orthopedics, Nursing, And Contraception (AREA)
- Materials For Medical Uses (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
The invention discloses a high-breathability water absorbable acrylic ester foamed material as well as a preparation method and an application thereof. The prepared high-breathability water absorbable acrylic ester foamed material has strong toughness, and good breathability; the obtained foamed material is small in cell size, average deionized water absorption rate, average saline water absorption rate, average artificial urine absorption rate and average artificial blood absorption rate of the obtained foamed material are respectively higher than 15g/g, and water retention rate in half hour is more than 80%, so that the high-breathability water absorbable acrylic ester foamed material is applicable to dispersion and storage of water containing fluid; meanwhile, nano calcium carbonate is added, so that production cost is obviously reduced, and the high-breathability water absorbable acrylic ester foamed material is applicable to mass production; a block flexible water absorbing material in the invention is suitable for application in the field of health products.
Description
Technical field
The invention belongs to water-absorbing material field, be specifically related to a kind of highly air-permeable water suction acrylate foam materials and its preparation method and application.
Background technology
Present sanitary product, the water-absorbing material of the inside is mainly to have granular synthetic resins, water suction, inhale urine or suck blood after can form gel, easily agglomerating, cause the more difficult position that is fixed on, in actual use procedure, make us very uncomfortable.Therefore developing block soft water-absorbing material has great significance.
Common blood is comprised of hemocyte, blood plasma etc.The diameter of hemocyte is 8 μ m left and right, and the diameter of acrylic molecules is much smaller than the diameter of hemocyte.Therefore hemocyte is difficult for being absorbed by gelatinous super absorbent resin, can only rest on the surface of super absorbent resin, the compositions such as blood plasma in the just blood of absorption.So exploitation multi-hole type polymkeric substance, to expand specific surface area, improves perviousness, the aspects such as the absorption rate of accelerating liquid and specific absorption have important technical economic benefit and social benefit.
For the foam materials that adopts acrylic ester monomer to prepare, in prior art, be to improve the processing characteristics of goods with more expensive stopping composition or auxiliary agents of many interpolations such as dimensional stabilitys, this has caused production cost too high on the one hand, is not suitable for scale operation; On the other hand, the most permeability of the acrylate foam materials prepared in prior art are poor, are not suitable for being applied in hygiene article sector, and this has limited the application of acrylate foam materials in Shangdi largely.
Summary of the invention
The object of the invention is to overcome above-mentioned the deficiencies in the prior art, a kind of preparation method of highly air-permeable water suction acrylate foam materials is provided; Acrylate foam materials prepared by the present invention has higher water-intake rate and water retention property preferably, and permeability is excellent simultaneously, and production cost is low, has greatly widened the range of application of acrylate foam materials.
Another object of the present invention is to provide the highly air-permeable water suction acrylate foam materials being prepared by preparation method of the present invention.
Another object of the present invention is to provide the application of described highly air-permeable water suction acrylate foam materials in sanitary product.
Above-mentioned purpose of the present invention is achieved by following technical solution:
The preparation method of highly air-permeable water suction acrylate foam materials, comprises the steps:
S1. prepare oil-based system: percentage ratio meter takes 25%~95% monofunctional acrylate class monomer, 2%~60% linking agent by weight, 1%~10% nano-calcium carbonate, 1%~15% emulsifier for mixing mix;
S2. prepare aqueous phase system: the aqueous electrolyte liquid that preparation massfraction is 0.01~3%;
S3. at 60~80 ℃, aqueous phase system is divided and add in oil-based system for 2~4 times, stir, the volume ratio of final water and oil phase is 10~100:1;
S4. in the mixed system of step S3, add water soluble starter to carry out emulsion polymerization;
S5. step S4 gained polymerisate is placed in to isothermal curing at 80~100 ℃, washs, dehydrates and obtain product;
Described monofunctional acrylate class monomer is the mixture of simple function alkyl acrylate and simple function alkyl methacrylate, and wherein, the mass ratio of described simple function alkyl acrylate and simple function alkyl methacrylate is 7:1~11:1;
Described linking agent is one or more in multifunctional alkyl acrylate or multifunctional alkyl methacrylate.
The inventor finds in experiment, the mass ratio that changes simple function alkyl acrylate and alkyl methacrylate can significantly improve the water-absorbent of acrylate foam materials and the abscess-size of foam materials, further improves the specific absorption of acrylate foam materials and widens its Application Areas; Preferably, the mass ratio of described simple function alkyl acrylate and simple function alkyl methacrylate is 9:1.
The inventor is also discovery in experiment, and in the formula described in the application, in aqueous electrolyte liquid, the massfraction of solute, under the concentration conventional lower than prior art, still can make abscess-size more evenly, unanimously; Even and electrolytical concentration is low to moderate 0.01%, compare with not adding ionogen, still tool is significantly improved the effect of water absorbing properties, and the snappiness of material is better, is difficult for splitting.
Therefore, preferably, the massfraction of described aqueous electrolyte liquid is 0.01%~1%.
Further preferably, the massfraction of described aqueous electrolyte liquid is 0.02%~0.1%.
The present invention by adding nano-calcium carbonate to prepare oil-based system in reaction monomers, and then carry out compound experiment, described nano-calcium carbonate can replace the expensive stopping composition of part and auxiliary agent, reduce the consumption of resin, not only make the cost of acrylic ester synthesizing foam materials, also make the acrylate foam materials being synthesized there is better ventilation property.
Preferably, the consisting of of oil-based system described in step S1: percentage ratio meter takes 45%~75% monofunctional acrylate class monomer, 15%~40% linking agent, 2%~8% nano-calcium carbonate, 5%~15% emulsifying agent by weight.
Ionogen of the present invention is the conventional solubility ionogen in this area, and object is that the salt ionic concentration of raising system reduces oil-soluble monomer, the comonomer solubleness in water, and preferably, described ionogen is one or more in metal ion compound.
Preferably, the positively charged ion of described metal ion compound is potassium ion, sodium ion, calcium ion, magnesium ion, aluminum ion, zine ion or iron ion, and negatively charged ion is chlorion, nitrate ion, borate ion, phosphate anion or carbanion; The ionic compound of above-mentioned positively charged ion and negatively charged ion combination water insoluble or be slightly soluble in water except.
Preferably, described metal ion compound is calcium chloride, nitrocalcite, aluminum chloride, aluminum nitrate, magnesium chloride, magnesium nitrate, potassiumphosphate, sodium phosphate, potassium borate, Sodium Tetraborate, salt of wormwood or sodium carbonate.Above-mentioned ionogen comprises strong base-weak acid salt or strong acid soft base salt, and these salt have certain pH value shock-absorbing capacity, are more conducive to carrying out smoothly of letex polymerization.In addition, those skilled in the art can get rid of the situation that many kinds of metal ions compound combination is used generation precipitation according to general knowledge.
Preferably, described metal ion compound is calcium chloride, nitrocalcite or aluminum chloride.
Preferably, described simple function alkyl acrylate is Isooctyl acrylate monomer, isodecyl acrylate, vinylformic acid stearyl or lauryl acrylate, and described simple function alkyl methacrylate is Isooctyl methacrylate, isodecyl methacrylate, methacrylic acid stearyl or lauryl methacrylate(LMA).
Further preferably, described monofunctional acrylate class monomer is the mixture of Isooctyl acrylate monomer and Isooctyl methacrylate.
Described multifunctional alkyl acrylate is hexanediol diacrylate, triethylene glycol diacrylate, propylene glycol diacrylate or tripropylene glycol diacrylate, and described multifunctional alkyl methacrylate is Ethylene glycol dimethacrylate, TEGDMA, dipropylene glycol dimethacrylate or tripropylene glycol dimethacrylate.
It is to form emulsion with monomer that the present invention adds the effect of emulsifying agent, for letex polymerization provides condition, because monomer used in the present invention is substantially water insoluble, thereby use hydrophobic emulsifying agent to be more conducive to disperse monomer of the present invention and reduce its solubleness in water; Preferably, described emulsifying agent comprises side chain C
16~C
24lipid acid, the unsaturated C of straight chain
16~C
22the saturated C of lipid acid or straight chain
12~C
14the sorbitan monoesters of lipid acid.
Further preferably, described emulsifying agent is tween 20, Tween-40, Tween-60, tween-80 or Glycerol dimer list isostearate.
The consumption of the initiator that the present invention uses can be selected according to this area conventional emulsion polymerization, is generally 0.1%~20% of monomer weight.
The kind of described initiator also can be selected according to the kind of this area polymerization single polymerization monomer, and as persulfate initiator, preferably, described initiator is ammonium persulphate, Sodium Persulfate or Potassium Persulphate.
The present invention is after definite water and the final ratio of oil phase, water divides 2~4 times and adds in oil phase, in emulsion, become sticky before thick and add again water once, object is that the mode of adding the employing multistage can be under identical mixing residence time, make the emulsion of high water and oil phase weight ratio, can also make the abscess-size of product simultaneously evenly, unanimously.Preferably, water is divided into 2/3 and 1/3 two portions, first oil phase is mixed with 2/3 water, in emulsion, become sticky and add again 1/3 remaining water to mix before thick.
Described in step S5, be cured as reacted polymerisate emulsion is poured into and in mould, put into constant temperature oven and solidify, the object that is controlled at isothermal curing under 80~100 ℃ of conditions is that acrylate is quick-setting guarantees that water does not seethe with excitement simultaneously allowing, and avoids producing pore not of uniform size at material surface.
Described in step S5, wash object and be to remove remaining initial water and equate impurity, described in dehydrate also and carry out in constant temperature oven or vacuum drying oven, dehydrating temperature is 80~100 ℃.
The highly air-permeable water suction acrylate foam materials obtaining according to above-mentioned preparation method.
The present invention is by specific formula, adopt the highly air-permeable water suction acrylate foam materials that specific preparation method makes to have certain toughness, abscess-size is small, has good water suction, inhales urine, the performance of sucking blood, the specific absorption of material is high, in hygiene article sector, has great application prospect.Concrete preparation technology's flow process can be with reference to shown in figure 1.
The range of cell sizes that acrylate foam materials of the present invention has is 10 μ m to 30 μ m, so be applicable to disperseing and storing aqueous fluid.In addition, the diameter due to human body hemocyte is that about 8 μ m, the diameter of existing acrylic molecules is much smaller than the diameter of hemocyte, thereby acrylate foam materials of the present invention is particularly suitable for the Material Field of sucking blood.
Compared with prior art, the present invention has following beneficial effect:
The invention discloses a kind of preparation method of highly air-permeable water suction acrylate foam materials, by add nano-calcium carbonate in oil phase, then carry out compound experiment, the permeability of the highly air-permeable preparing water suction acrylate foam materials significantly improves; The abscess-size of foam materials is small, and it on average sucks ionized water rate, average absorption salt ratio, on average inhale artificial urine rate, on average inhale artificial blood rate is all greater than 15g/g, and halfhour water retention, all more than 80%, is suitable for disperseing and storing aqueous fluid; In addition, the present invention, because nano-calcium carbonate adds, has also improved the processing characteristics of product, can replace the expensive stopping composition of part and auxiliary agent, reduces the consumption of resin, thereby reduces the production cost of product; The soft water-absorbing material of bulk of the present invention is specially adapted to hygiene article sector.
Accompanying drawing explanation
Fig. 1 is highly air-permeable water suction acrylate foam materials preparation technology flow process reference drawing.
Embodiment
Below in conjunction with specific embodiment, the present invention is further explained, but embodiments of the present invention is not limited in any way.Unless stated otherwise, in embodiment, related reagent, method is the conventional reagent in this area and method.Gas-premeable test adopts GB T1038-2000 plastics film and thin slice gas-premeable test method.
embodiment 1
One, the preparation of highly air-permeable water suction acrylate foam materials
(1) preparation oil-based system, take nano-calcium carbonate, the tween-80 1.3g of Isooctyl acrylate monomer 7.2g, Isooctyl methacrylate 0.8g, Ethylene glycol dimethacrylate 4.8g, hexanediol diacrylate 0.4g, 0.8g, oil phase is stirred stand-by, wherein, the mass ratio of Isooctyl acrylate monomer and Isooctyl methacrylate is 9:1.
(2) preparation aqueous phase system, takes calcium chloride 0.096g, then adds water to 480g it is dissolved, and now, the massfraction of electrolytic solution is 0.02%, stand-by.
(3) preparation initiator phase, takes ammonium persulphate 1.71g, adds water to 10g it is dissolved, stand-by.
(4) the water 320g making is proceeded in the there-necked flask of 1000ml, start to stir, be warming up to 75 ℃, stirring velocity turns above 800, then the oil phase stirring is added in there-necked flask, etc. emulsion become sticky thick before, drip again 160g water in flask, finally drip initiator in flask, after polyreaction, mixed solution is poured in large tetrafluoroethylene square plate into cover lid, put into 97 ℃ of baking ovens 0.5 hour, after forming and hardening, take out extruding and washing, then take the oven dry of baking oven the inside.
Two, product test
Prepared product out has certain toughness, and ventilation property has obtained remarkable improvement, by gas permeation determinator, tests, and gas permeation amount is 1.15 * 10
-2cm
3/ (m
2pad); Abscess-size is small, and by scanning electronic microscope (SEM) test, the abscess-size of product is 10~30 μ m.It on average sucks ionized water rate be that 19.9g/g, average absorption salt ratio are 21.2g/g, on average to inhale artificial urine rate be 23.5g/g, on average inhale artificial blood rate is 22.6g/g, halfhour water retention is all more than 89%, products obtained therefrom has good ventilation property and has preferably water-intake rate and water retention simultaneously, be suitable for disperseing and storing aqueous fluid, be suitable for hygiene article sector.
embodiment 2
One, the preparation of highly air-permeable water suction acrylate foam materials
(1) preparation oil-based system, take nano-calcium carbonate, the tween-80 1.3g of Isooctyl acrylate monomer 5.6g, Isooctyl methacrylate 0.8g, Ethylene glycol dimethacrylate 4.8g, hexanediol diacrylate 0.4g, 0.9g, oil phase is stirred stand-by, wherein, the mass ratio of Isooctyl acrylate monomer and Isooctyl methacrylate is 7:1.
(2) preparation aqueous phase system, takes calcium chloride 0.48g, then adds water to 480g it is dissolved, and now, the massfraction of electrolytic solution is 0. 1%, stand-by.
(3) preparation initiator phase, takes ammonium persulphate 1.71g, adds water to 10g it is dissolved, stand-by.
(4) the water 320g making is proceeded in the there-necked flask of 1000ml, start to stir, be warming up to 75 ℃, stirring velocity turns above 800, then the oil phase stirring is added in there-necked flask, etc. emulsion become sticky thick before, drip again 160g water in flask, finally drip initiator in flask, after polyreaction, mixed solution is poured in large tetrafluoroethylene square plate into cover lid, put into 97 ℃ of baking ovens 0.5 hour, after forming and hardening, take out extruding and washing, then take the oven dry of baking oven the inside.
Two, product test
Prepared product out has certain toughness, and ventilation property has obtained remarkable improvement; By gas permeation determinator, test, gas permeation amount is 1.16 * 10
-2cm
3/ (m
2pad); Abscess-size is small, and by scanning electronic microscope (SEM) test, the abscess-size of product is 10~30 μ m.It on average sucks ionized water rate be that 18.9g/g, average absorption salt ratio are 18.9g/g, on average to inhale artificial urine rate be 18.5g/g, on average inhale artificial blood rate is 20.36g/g, halfhour water retention is all more than 88%, products obtained therefrom has good ventilation property and has preferably water-intake rate and water retention simultaneously, be suitable for disperseing and storing aqueous fluid, be suitable for hygiene article sector.
embodiment 3
One, the preparation of highly air-permeable water suction acrylate foam materials
(1) preparation oil-based system, take nano-calcium carbonate, the tween-80 1.3g of Isooctyl acrylate monomer 8.8g, Isooctyl methacrylate 0.8g, Ethylene glycol dimethacrylate 4.8g, hexanediol diacrylate 0.4g, 0.7g, oil phase is stirred stand-by, wherein, the mass ratio of Isooctyl acrylate monomer and Isooctyl methacrylate is 11:1.
(2) preparation aqueous phase system, takes calcium chloride 4.8g, then adds water to 480g it is dissolved, and now, the massfraction of electrolytic solution is 1%, stand-by.
(3) preparation initiator phase, takes ammonium persulphate 1.71g, adds water to 10g it is dissolved, stand-by.
(4) the water 320g making is proceeded in the there-necked flask of 1000ml, start to stir, be warming up to 75 ℃, stirring velocity turns above 800, then the oil phase stirring is added in there-necked flask, etc. emulsion become sticky thick before, drip again 160g water in flask, finally drip initiator in flask, after polyreaction, mixed solution is poured in large tetrafluoroethylene square plate into cover lid, put into 97 ℃ of baking ovens 0.5 hour, after forming and hardening, take out extruding and washing, then take the oven dry of baking oven the inside.
Two, product test
Prepared product out has certain toughness, and ventilation property has obtained remarkable improvement; By gas permeation determinator, test, gas permeation amount is 1.13 * 10
-2cm
3/ (m
2pad); Abscess-size is small, and by scanning electronic microscope (SEM) test, the abscess-size of product is 10~30 μ m.It on average sucks ionized water rate be that 18.8g/g, average absorption salt ratio are 20.5g/g, on average to inhale artificial urine rate be 20.2g/g, on average inhale artificial blood rate is 20.5g/g, halfhour water retention is all more than 88%, products obtained therefrom has good ventilation property and has preferably water-intake rate and water retention simultaneously, be suitable for disperseing and storing aqueous fluid, be suitable for hygiene article sector.
embodiment 4
One, the preparation of highly air-permeable water suction acrylate foam materials
(1) preparation oil-based system, take nano-calcium carbonate, the tween-80 1.3g of Isooctyl acrylate monomer 8.8g, Isooctyl methacrylate 0.8g, Ethylene glycol dimethacrylate 4.8g, hexanediol diacrylate 0.4g, 1g, oil phase is stirred stand-by, wherein, the mass ratio of Isooctyl acrylate monomer and Isooctyl methacrylate is 11:1.
(2) preparation aqueous phase system, takes nitrocalcite 14.4g, then adds water to 480g it is dissolved, and now, the massfraction of electrolytic solution is 3%, stand-by.
(3) preparation initiator phase, takes ammonium persulphate 1.71g, adds water to 10g it is dissolved, stand-by.
(4) the water 320g making is proceeded in the there-necked flask of 1000ml, start to stir, be warming up to 75 ℃, stirring velocity turns above 800, then the oil phase stirring is added in there-necked flask, etc. emulsion become sticky thick before, drip again 160g water in flask, finally drip initiator in flask, after polyreaction, mixed solution is poured in large tetrafluoroethylene square plate into cover lid, put into 97 ℃ of baking ovens 0.5 hour, after forming and hardening, take out extruding and washing, then take the oven dry of baking oven the inside.
Two, product test
Prepared product out has certain toughness, and ventilation property has obtained remarkable improvement; By gas permeation determinator, test, gas permeation amount is 1.17 * 10
-2cm
3/ (m
2pad); Abscess-size is small, and by scanning electronic microscope (SEM) test, the abscess-size of product is 10~30 μ m.It on average sucks ionized water rate be that 15.4g/g, average absorption salt ratio are 14.9g/g, on average to inhale artificial urine rate be 15.2g/g, on average inhale artificial blood rate is 16.0g/g, halfhour water retention is all more than 82%, products obtained therefrom has good ventilation property and has preferably water-intake rate and water retention simultaneously, be suitable for disperseing and storing aqueous fluid, be suitable for hygiene article sector.
embodiment 5
One, the preparation of highly air-permeable water suction acrylate foam materials
(1) preparation oil-based system, take nano-calcium carbonate, the tween-80 1.3g of Isooctyl acrylate monomer 8.8g, Isooctyl methacrylate 0.8g, Ethylene glycol dimethacrylate 4.8g, hexanediol diacrylate 0.4g, 0.6g, oil phase is stirred stand-by, wherein, the mass ratio of Isooctyl acrylate monomer and Isooctyl methacrylate is 11:1.
(2) preparation aqueous phase system, takes nitrocalcite 0.48g, then adds water to 480g it is dissolved, and now, the massfraction of electrolytic solution is 0.1%, stand-by.
(3) preparation initiator phase, takes ammonium persulphate 1.71g, adds water to 10g it is dissolved, stand-by.
(4) the water 320g making is proceeded in the there-necked flask of 1000ml, start to stir, be warming up to 75 ℃, stirring velocity turns above 800, then the oil phase stirring is added in there-necked flask, etc. emulsion become sticky thick before, drip again 160g water in flask, finally drip initiator in flask, after polyreaction, mixed solution is poured in large tetrafluoroethylene square plate into cover lid, put into 97 ℃ of baking ovens 0.5 hour, after forming and hardening, take out extruding and washing, then take the oven dry of baking oven the inside.
Two, product test
Prepared product out has certain toughness, and ventilation property has obtained remarkable improvement; By gas permeation determinator, test, gas permeation amount is 1.13 * 10
-2cm
3/ (m
2pad); Abscess-size is small, and by scanning electronic microscope (SEM) test, the abscess-size of product is 10~30 μ m.It on average sucks ionized water rate be that 19.8g/g, average absorption salt ratio are 18.8g/g, on average to inhale artificial urine rate be 18.3g/g, on average inhale artificial blood rate is 19.9g/g, halfhour water retention is all more than 90%, products obtained therefrom has good ventilation property and has preferably water-intake rate and water retention simultaneously, be suitable for disperseing and storing aqueous fluid, be suitable for hygiene article sector.
embodiment 6
One, the preparation of highly air-permeable water suction acrylate foam materials
(1) preparation oil-based system, take nano-calcium carbonate, the tween-80 1.3g of Isooctyl acrylate monomer 8.8g, Isooctyl methacrylate 0.8g, Ethylene glycol dimethacrylate 4.8g, hexanediol diacrylate 0.4g, 1.1g, oil phase is stirred stand-by, wherein, the mass ratio of Isooctyl acrylate monomer and Isooctyl methacrylate is 11:1.
(2) preparation aqueous phase system, takes nitrocalcite 0.096g, then adds water to 480g it is dissolved, and now, the massfraction of electrolytic solution is 0.02%, stand-by.
(3) preparation initiator phase, takes Potassium Persulphate 1.37g, adds water to 10g it is dissolved, stand-by.
(4) the water 320g making is proceeded in the there-necked flask of 1000ml, start to stir, be warming up to 80 ℃, stirring velocity turns above 800, then the oil phase stirring is added in there-necked flask, etc. emulsion become sticky thick before, drip again 160g water in flask, finally drip initiator in flask, after polyreaction, mixed solution is poured in large tetrafluoroethylene square plate into cover lid, put into 80 ℃ of baking ovens 1 hour, after forming and hardening, take out extruding and washing, then take the oven dry of baking oven the inside.
Two, product test
Prepared product out has certain toughness, and ventilation property has obtained remarkable improvement; By gas permeation determinator, test, gas permeation amount is 1.18 * 10
-2cm
3/ (m
2pad); Abscess-size is small, and by scanning electronic microscope (SEM) test, the abscess-size of product is 10~30 μ m.It on average sucks ionized water rate be that 17.8g/g, average absorption salt ratio are 18.8g/g, on average to inhale artificial urine rate be 18.6g/g, on average inhale artificial blood rate is 18.9g/g, halfhour water retention is all more than 90%, products obtained therefrom has good ventilation property and has preferably water-intake rate and water retention simultaneously, be suitable for disperseing and storing aqueous fluid, be suitable for hygiene article sector.
embodiment 7
One, the preparation of highly air-permeable water suction acrylate foam materials
(1) preparation oil-based system, takes lauryl acrylate 11.4g, tripropylene glycol dimethacrylate 3.0g, the nano-calcium carbonate of tripropylene glycol diacrylate 5.8g, 0.5g, Tween-40 2.0g, oil phase is stirred stand-by.
(2) preparation aqueous phase system, takes aluminum chloride 0.48g, then adds water to 480g it is dissolved, and now, the massfraction of electrolytic solution is 0.1%, stand-by.
(3) preparation initiator phase, takes Sodium Persulfate 1.81g, adds water to 10g it is dissolved, stand-by.
(4) the water 160g making is proceeded in the there-necked flask of 1000ml, start to stir, be warming up to 65 ℃, stirring velocity turns above 800, then the oil phase stirring is added in there-necked flask, etc. emulsion become sticky thick before, again 320g water is successively added drop-wise in flask at twice, finally drip initiator in flask, after polyreaction, mixed solution is poured in large tetrafluoroethylene square plate into cover lid, put into 85 ℃ of baking ovens 1 hour, after forming and hardening, take out extruding and washing, then take the oven dry of baking oven the inside.
Two, product test
Prepared product out has certain toughness, and ventilation property has obtained remarkable improvement; By gas permeation determinator, test, gas permeation amount is 1.12 * 10
-2cm
3/ (m
2pad); Abscess-size is small, and by scanning electronic microscope (SEM) test, the abscess-size of product is 10~30 μ m.It on average sucks ionized water rate be that 17.2g/g, average absorption salt ratio are 17.8g/g, on average to inhale artificial urine rate be 17.1g/g, on average inhale artificial blood rate is 18.1g/g, halfhour water retention is all more than 85%, products obtained therefrom has good ventilation property and has preferably water-intake rate and water retention simultaneously, be suitable for disperseing and storing aqueous fluid, be suitable for hygiene article sector.
embodiment 8
One, the preparation of highly air-permeable water suction acrylate foam materials
(1) preparation oil-based system, take methacrylic acid stearyl 9.4g, lauryl methacrylate(LMA) 3.8g, propylene glycol diacrylate 1.8g, the nano-calcium carbonate of tripropylene glycol dimethacrylate 1.4g, 0.4g, Tween-60 2.5g, oil phase is stirred stand-by.
(2) preparation aqueous phase system, takes aluminum chloride 0.288g, then adds water to 480g it is dissolved, and now, the massfraction of electrolytic solution is 0.06%, stand-by.
(3) preparation initiator phase, takes ammonium persulphate 1.91g, adds water to 10g it is dissolved, stand-by.
(4) the water 240g making is proceeded in the there-necked flask of 1000ml, start to stir, be warming up to 70 ℃, stirring velocity turns above 800, then the oil phase stirring is added in there-necked flask, etc. emulsion become sticky thick before, drip again 240g water in flask, finally drip initiator in flask, after polyreaction, mixed solution is poured in large tetrafluoroethylene square plate into cover lid, put into 90 ℃ of baking ovens 0.5 hour, after forming and hardening, take out extruding and washing, then take the oven dry of baking oven the inside.
Two, product test
Prepared product out has certain toughness, and ventilation property has obtained remarkable improvement; By gas permeation determinator, test, gas permeation amount is 1.11 * 10
-2cm
3/ (m
2pad); Abscess-size is small, and by scanning electronic microscope (SEM) test, the abscess-size of product is 10~30 μ m.It on average sucks ionized water rate be that 17.5g/g, average absorption salt ratio are 18.6g/g, on average to inhale artificial urine rate be 17.8g/g, on average inhale artificial blood rate is 18.3g/g, halfhour water retention is all more than 88%, products obtained therefrom has good ventilation property and has preferably water-intake rate and water retention simultaneously, be suitable for disperseing and storing aqueous fluid, be suitable for hygiene article sector.
embodiment 9
One, the preparation of highly air-permeable water suction acrylate foam materials
(1) preparation oil-based system, take methacrylic acid stearyl 9.4g, lauryl methacrylate(LMA) 3.8g, propylene glycol diacrylate 1.8g, the nano-calcium carbonate of tripropylene glycol dimethacrylate 1.4g, 0.3g, Tween-60 2.5g, oil phase is stirred stand-by.
(2) preparation aqueous phase system, takes aluminum chloride 0.384g, then adds water to 480g it is dissolved, and now, the massfraction of electrolytic solution is 0.08%, stand-by.
(3) preparation initiator phase, takes ammonium persulphate 1.91g, adds water to 10g it is dissolved, stand-by.
(4) the water 240g making is proceeded in the there-necked flask of 1000ml, start to stir, be warming up to 70 ℃, stirring velocity turns above 800, then the oil phase stirring is added in there-necked flask, etc. emulsion become sticky thick before, drip again 240g water in flask, finally drip initiator in flask, after polyreaction, mixed solution is poured in large tetrafluoroethylene square plate into cover lid, put into 90 ℃ of baking ovens 0.5 hour, after forming and hardening, take out extruding and washing, then take the oven dry of baking oven the inside.
Two, product test
Prepared product out has certain toughness, and ventilation property has obtained remarkable improvement; By gas permeation determinator, test, gas permeation amount is 1.09 * 10
-2cm
3/ (m
2pad); Abscess-size is small, and by scanning electronic microscope (SEM) test, the abscess-size of product is 10~30 μ m.It on average sucks ionized water rate be that 18.5g/g, average absorption salt ratio are 17.4g/g, on average to inhale artificial urine rate be 18.7g/g, on average inhale artificial blood rate is 19.4g/g, halfhour water retention is all more than 86%, products obtained therefrom has good ventilation property and has preferably water-intake rate and water retention simultaneously, be suitable for disperseing and storing aqueous fluid, be suitable for hygiene article sector.
comparative example 1
One, the preparation of highly air-permeable water suction acrylate foam materials
(1) preparation oil-based system, take Isooctyl acrylate monomer 7.2g, Isooctyl methacrylate 0.8g, Ethylene glycol dimethacrylate 4.8g, hexanediol diacrylate 0.4g, 0.8g silicon-dioxide, tween-80 1.3g, oil phase is stirred stand-by, wherein, the mass ratio of Isooctyl acrylate monomer and Isooctyl methacrylate is 9:1.
(2) preparation aqueous phase system, takes calcium chloride 0.096g, then adds water to 480g it is dissolved, and now, the massfraction of electrolytic solution is 0.02%, stand-by.
(3) preparation initiator phase, takes ammonium persulphate 1.71g, adds water to 10g it is dissolved, stand-by.
(4) the water 320g making is proceeded in the there-necked flask of 1000ml, start to stir, be warming up to 75 ℃, stirring velocity turns above 800, then the oil phase stirring is added in there-necked flask, etc. emulsion become sticky thick before, drip again 160g water in flask, finally drip initiator in flask, after polyreaction, mixed solution is poured in large tetrafluoroethylene square plate into cover lid, put into 97 ℃ of baking ovens 0.5 hour, after forming and hardening, take out extruding and washing, then take the oven dry of baking oven the inside.
Two, product test
Prepared product out has certain toughness, and ventilation property is poor; By gas permeation determinator, test, gas permeation amount is 0.5 * 10
-2cm
3/ (m
2pad); Abscess-size is small, and by scanning electronic microscope (SEM) test, the abscess-size of product is 10~30 μ m.It on average sucks ionized water rate be that 15.8g/g, average absorption salt ratio are 14.2g/g, on average to inhale artificial urine rate be 11.3g/g, on average inhale artificial blood rate is 12.6g/g, and halfhour water retention only has more than 55%; The ventilation property of products obtained therefrom is poor, and water-intake rate and water retention poor, be not suitable for disperseing and store aqueous fluid, be not suitable for hygiene article sector.
comparative example 2
One, the preparation of highly air-permeable water suction acrylate foam materials
(1) preparation oil-based system, take nano-calcium carbonate, the tween-80 1.3g of Isooctyl acrylate monomer 7.2g, Isooctyl methacrylate 0.8g, Ethylene glycol dimethacrylate 4.8g, hexanediol diacrylate 0.4g, 0.05g, oil phase is stirred stand-by, wherein, the mass ratio of Isooctyl acrylate monomer and Isooctyl methacrylate is 9:1.
(2) preparation aqueous phase system, takes calcium chloride 0.096g, then adds water to 480g it is dissolved, and now, the massfraction of electrolytic solution is 0.02%, stand-by.
(3) preparation initiator phase, takes ammonium persulphate 1.71g, adds water to 10g it is dissolved, stand-by.
(4) the water 320g making is proceeded in the there-necked flask of 1000ml, start to stir, be warming up to 75 ℃, stirring velocity turns above 800, then the oil phase stirring is added in there-necked flask, etc. emulsion become sticky thick before, drip again 160g water in flask, finally drip initiator in flask, after polyreaction, mixed solution is poured in large tetrafluoroethylene square plate into cover lid, put into 97 ℃ of baking ovens 0.5 hour, after forming and hardening, take out extruding and washing, then take the oven dry of baking oven the inside.
Two, product test
Prepared product out has certain toughness, and ventilation property is poor; By gas permeation determinator, test, gas permeation amount is 0.7 * 10
-2cm
3/ (m
2pad); Abscess-size is small, and by scanning electronic microscope (SEM) test, the abscess-size of product is 10~30 μ m.It on average sucks ionized water rate be that 15.8g/g, average absorption salt ratio are 14.2g/g, on average to inhale artificial urine rate be 13.6g/g, on average inhale artificial blood rate is 14.6g/g, and halfhour water retention only has more than 59%; The ventilation property of products obtained therefrom is poor, and water-intake rate and water retention poor, be not suitable for disperseing and store aqueous fluid, be not suitable for hygiene article sector.
comparative example 3
One, the preparation of highly air-permeable water suction acrylate foam materials
(1) preparation oil-based system, take nano-calcium carbonate, the tween-80 1.3g of Isooctyl acrylate monomer 16g, Isooctyl methacrylate 0.8g, Ethylene glycol dimethacrylate 4.8g, hexanediol diacrylate 0.4g, 1g, oil phase is stirred stand-by, wherein, the mass ratio of Isooctyl acrylate monomer and Isooctyl methacrylate is 20:1.
(2) preparation aqueous phase system, takes calcium chloride 0.096g, then adds water to 480g it is dissolved, and now, the massfraction of electrolytic solution is 0.02%, stand-by.
(3) preparation initiator phase, takes ammonium persulphate 1.71g, adds water to 10g it is dissolved, stand-by.
(4) water 320g is proceeded in the there-necked flask of 1000ml, start to stir, be warming up to 75 ℃, stirring velocity turns above 800, then the oil phase stirring is added in there-necked flask, etc. emulsion become sticky thick before, drip again 160g water in flask, finally drip initiator in flask, after polyreaction, mixed solution is poured in large tetrafluoroethylene square plate into cover lid, put into 97 ℃ of baking ovens 0.5 hour, after forming and hardening, take out extruding and washing, then take the oven dry of baking oven the inside.
Two, product test
Prepared product out has poor toughness and hard and crisp, and ventilation property is better, by gas permeation determinator, tests, and gas permeation amount is 1.05 * 10
-2cm
3/ (m
2pad); By scanning electronic microscope (SEM) test, the abscess-size of product is more than 100 μ m, the larger and skewness of abscess-size, and this also causes the permeability decline of product.It on average sucks ionized water rate be that 10.5g/g, average absorption salt ratio are 11.4g/g, on average to inhale artificial urine rate be 9.6g/g, on average inhale artificial blood rate is 9.5g/g, halfhour water retention only has 54% left and right, although products obtained therefrom has preferably ventilation property, but the water-intake rate of product and water retention are poor, the dispersion of product and store aqueous fluid ability a little less than, be not suitable for hygiene article sector.
comparative example 4
One, the preparation of highly air-permeable water suction acrylate foam materials
(1) preparation oil-based system, take Isooctyl acrylate monomer 7.2g, Isooctyl methacrylate 0.8g, Ethylene glycol dimethacrylate 4.8g, hexanediol diacrylate 0.4g, 0.8g nano-calcium carbonate, tween-80 1.3g, oil phase is stirred stand-by, wherein, the mass ratio of Isooctyl acrylate monomer and Isooctyl methacrylate is 9:1.
(2) preparation aqueous phase system, takes calcium chloride 19.2g, then adds water to 480g it is dissolved, and now, the massfraction of electrolytic solution is 4%, stand-by.
(3) preparation initiator phase, takes ammonium persulphate 1.71g, adds water to 10g it is dissolved, stand-by.
(4) the water 320g making is proceeded in the there-necked flask of 1000ml, start to stir, be warming up to 75 ℃, stirring velocity turns above 800, then the oil phase stirring is added in there-necked flask, etc. emulsion become sticky thick before, drip again 160g water in flask, finally drip initiator in flask, after polyreaction, mixed solution is poured in large tetrafluoroethylene square plate into cover lid, put into 97 ℃ of baking ovens 0.5 hour, after forming and hardening, take out extruding and washing, then take the oven dry of baking oven the inside.
Two, product test
Prepared product out has certain toughness, and ventilation property is better, by gas permeation determinator, tests, and gas permeation amount is 1.13 * 10
-2cm
3/ (m
2pad); Abscess-size is small, and by scanning electronic microscope (SEM) test, the abscess-size of product is 10~30 μ m.It on average sucks ionized water rate be that 10.2g/g, average absorption salt ratio are 11.7g/g, on average to inhale artificial urine rate be 11.0g/g, on average inhale artificial blood rate is 9.2g/g, halfhour water retention only has 60% left and right, although products obtained therefrom has preferably ventilation property, but the water-intake rate of product and water retention are poor, the dispersion of product and store aqueous fluid ability a little less than, be not suitable for hygiene article sector.
comparative example 5
One, the preparation of highly air-permeable water suction acrylate foam materials
(1) preparation oil-based system, takes isodecyl acrylate 16.4g, dipropylene glycol dimethacrylate 4.0g, triethylene glycol diacrylate 0.8g, 1g nano-calcium carbonate, Glycerol dimer list isostearate 2.0g, oil phase is stirred stand-by.
(2) preparation aqueous phase system, takes calcium chloride 17.71g, then adds water to 480g it is dissolved, and now, the massfraction of electrolytic solution is 3.6%, stand-by.
(3) preparation initiator phase, takes Sodium Persulfate 2.11g, adds water to 10g it is dissolved, stand-by.
(4) the water 320g making is proceeded in the there-necked flask of 1000ml, start to stir, be warming up to 60 ℃, stirring velocity turns above 800, then the oil phase stirring is added in there-necked flask, etc. emulsion become sticky thick before, drip again 160g water in flask, finally drip initiator in flask, after polyreaction, mixed solution is poured in large tetrafluoroethylene square plate into cover lid, put into 95 ℃ of baking ovens 0.5 hour, after forming and hardening, take out extruding and washing, then take the oven dry of baking oven the inside.
Two, product test
Prepared product out has certain toughness, and ventilation property is better, by gas permeation determinator, tests, and gas permeation amount is 1.25 * 10
-2cm
3/ (m
2pad); Abscess-size is small, and by scanning electronic microscope (SEM) test, the abscess-size of product is 10~30 μ m.It on average sucks ionized water rate be that 8.4g/g, average absorption salt ratio are 8.9g/g, on average to inhale artificial urine rate be 7.0g/g, on average inhale artificial blood rate is 7.0g/g, halfhour water retention only has 65% left and right, although products obtained therefrom has preferably ventilation property, but the water-intake rate of product and water retention are poor, the dispersion of product and store aqueous fluid ability a little less than, be not suitable for hygiene article sector.
comparative example 6
One, the preparation of highly air-permeable water suction acrylate foam materials
(1) preparation oil-based system, takes isodecyl acrylate 16.4g, dipropylene glycol dimethacrylate 4.0g, triethylene glycol diacrylate 0.8g, 1g nano-calcium carbonate, Glycerol dimer list isostearate 2.0g, oil phase is stirred stand-by.
(2) preparation aqueous phase system, 480g is stand-by in water intaking.
(3) preparation initiator phase, takes Sodium Persulfate 2.11g, adds water to 10g it is dissolved, stand-by.
(4) the water 320g making is proceeded in the there-necked flask of 1000ml, start to stir, be warming up to 60 ℃, stirring velocity turns above 800, then the oil phase stirring is added in there-necked flask, etc. emulsion become sticky thick before, drip again 160g water in flask, finally drip initiator in flask, after polyreaction, mixed solution is poured in large tetrafluoroethylene square plate into cover lid, put into 95 ℃ of baking ovens 0.5 hour, after forming and hardening, take out extruding and washing, then take the oven dry of baking oven the inside.
Two, product test
Prepared product out has poor toughness and hard and crisp, and ventilation property is better, by gas permeation determinator, tests, and gas permeation amount is 1.21 * 10
-2cm
3/ (m
2pad); By scanning electronic microscope (SEM) test, the abscess-size of product is more than 100 μ m, the larger and skewness of abscess-size, and this also causes the permeability decline of product.It on average sucks ionized water rate be that 4.1g/g, average absorption salt ratio are 4.4g/g, on average to inhale artificial urine rate be 4.2g/g, on average inhale artificial blood rate is 4.6g/g, halfhour water retention only has 21% left and right, and do not there is snappiness, be easy to split, although products obtained therefrom has preferably ventilation property, but the water-intake rate of product and water retention are poor, the dispersion of product and store aqueous fluid ability a little less than, be not suitable for disperseing and storing aqueous fluid.
Claims (10)
1. the preparation method of highly air-permeable water suction acrylate foam materials, is characterized in that, comprises the steps:
S1. prepare oil-based system: percentage ratio meter takes 25%~95% monofunctional acrylate class monomer, 2%~60% linking agent by weight, 1%~10% nano-calcium carbonate, 1%~15% emulsifier for mixing mix;
S2. prepare aqueous phase system: the aqueous electrolyte liquid that preparation massfraction is 0.01~3%;
S3. at 60~80 ℃, aqueous phase system is divided and add in oil-based system for 2~4 times, stir, the volume ratio of final water and oil phase is 10~100:1;
S4. in the mixed system of step S3, add water soluble starter to carry out emulsion polymerization;
S5. step S4 gained polymerisate is placed in to isothermal curing at 80~100 ℃, washs, dehydrates and obtain product;
Described monofunctional acrylate class monomer is the mixture of simple function alkyl acrylate and simple function alkyl methacrylate; Wherein, the mass ratio of described simple function alkyl acrylate and simple function alkyl methacrylate is 7:1~11:1;
Described linking agent is one or more in multifunctional alkyl acrylate or multifunctional alkyl methacrylate.
2. preparation method according to claim 1, is characterized in that, the mass ratio of described simple function alkyl acrylate and simple function alkyl methacrylate is 9:1.
3. preparation method according to claim 1 and 2, is characterized in that, the massfraction of described aqueous electrolyte liquid is 0.01%~1%.
4. preparation method according to claim 3, is characterized in that, the massfraction of described aqueous electrolyte liquid is 0.02%~0.1%.
5. preparation method according to claim 1, it is characterized in that the consisting of of oil-based system described in step S1: percentage ratio meter takes 45%~75% monofunctional acrylate class monomer, 15%~40% linking agent, 2%~8% nano-calcium carbonate, 5%~15% emulsifying agent by weight.
6. according to preparation method described in claim 1 or 2, it is characterized in that, described ionogen is one or more in metal ion compound, the positively charged ion of described metal ion compound is potassium ion, sodium ion, calcium ion, magnesium ion, aluminum ion, zine ion or iron ion, and negatively charged ion is chlorion, nitrate ion, borate ion, phosphate anion or carbanion.
7. according to preparation method described in claim 1 or 2, it is characterized in that, described simple function alkyl acrylate is Isooctyl acrylate monomer, isodecyl acrylate, vinylformic acid stearyl or lauryl acrylate, and described simple function alkyl methacrylate is Isooctyl methacrylate, isodecyl methacrylate, methacrylic acid stearyl or lauryl methacrylate(LMA);
Described multifunctional alkyl acrylate is hexanediol diacrylate, triethylene glycol diacrylate, propylene glycol diacrylate or tripropylene glycol diacrylate, and described multifunctional alkyl methacrylate is Ethylene glycol dimethacrylate, TEGDMA, dipropylene glycol dimethacrylate or tripropylene glycol dimethacrylate.
8. according to preparation method described in claim 1 or 2, it is characterized in that, described emulsifying agent is side chain C
16~C
24lipid acid, the unsaturated C of straight chain
16~C
22the saturated C of lipid acid or straight chain
12~C
14the sorbitan monoesters of lipid acid; Described initiator is ammonium persulphate, Sodium Persulfate or Potassium Persulphate.
9. the highly air-permeable water suction acrylate foam materials that described in any claim of claim 1 to 8, preparation method prepares.
10. the application of highly air-permeable water suction acrylate foam materials in preparing sanitary product described in claim 9.
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