CN104177888A - Preparation process of cable anti-corrosive coating - Google Patents

Preparation process of cable anti-corrosive coating Download PDF

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Publication number
CN104177888A
CN104177888A CN201410454747.4A CN201410454747A CN104177888A CN 104177888 A CN104177888 A CN 104177888A CN 201410454747 A CN201410454747 A CN 201410454747A CN 104177888 A CN104177888 A CN 104177888A
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weight ratio
auxiliary agent
nanometer
nano
base
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CN104177888B (en
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王吉震
常俊军
夏晓聪
高杨
吕学军
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Hebei Chenyang Industry and Trade Group Co Ltd
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JUNAN POWER SUPPLY CO Ltd
State Grid Corp of China SGCC
Linyi Power Supply Co of State Grid Shandong Electric Power Co Ltd
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Abstract

The invention belongs to the field of coatings, and discloses a preparation process of a cable anti-corrosive coating. The preparation process comprises the following steps of (1) preparing a base material; (2) preparing an auxiliary agent; (3) preparing nanometer auxiliary materials; and (4) stirring, and cooling. The preparation process disclosed by the invention has the advantages of simpleness, convenience, simple use method, reasonable raw material compatibility and good anti-corrosive effect, and is suitable for large-scale industrialized production.

Description

A kind of preparation technology of cable protective system
 
Technical field
The invention belongs to paint field, be specifically related to a kind of preparation technology of cable protective system.
 
Background technology
In power supply system, power cable is important transmitting line, and its conductor by one or more mutually insulated and outsourcing insulating protective layer are made, by electric power or information from a wire that is transferred to another place.Power cable is under outdoor environment, especially under damp and hot weather condition or the more serious region of acid-alkali salt effect, aging, burn into disrepair phenomenon very easily occurs, easily cause transmission line malfunction, bring greater impact to the normal production of people and life, also cause larger loss to power department.In order to overcome above-mentioned defect, there is cable protective system in prior art, general hot spray painted zinc or the method such as zinc-plated of adopting brushed, and part adopts protective system brushing, and the problem of its existence is: anticorrosion matrix processing requirements is high, film is blocked up easy to crack, when film curing, be subject to temperature, humidity effect larger, set time is long, and mostly exists weathering resistance poor, the shortcoming that cohesive force is not strong, therefore antiseptic property is generally undesirable.
Nanotechnology (nanotechnology) is to manufacture the science and technology of material, character and the application of research structure size material in 1 to 100 nanometer range with single atom, molecule.Nanometer is the least unit of length metering, the length of 1 nanometer be 1 millimeter 1,000,000/, directly assemble with the atom, atomic group, molecule, the molecular grouping that form various elements and material the high-quality precision and sophisticated technology that there is the material of specific function or there is special performance product.Successfully nanotechnology can be applicable to the every field such as electronics, chemical industry, military affairs, and countries in the world are all in research and development.Application of micron, in coating, is mainly to utilize the two vegetables mechanism of lotus leaf, improves water tolerance and the anti-fungi performance of coating.As coating, it is to be become to be grouped into by number of chemical, and through science preparation, unique physical and chemical reaction forms, if formula and technique are unreasonable, even if add some nano level raw materials, does not also have too large raising in quality, can cause on the contrary the raising of industrial cost.
 
Summary of the invention
In order to overcome cable material anticorrosive coating complicated process of preparation in prior art, the defect such as anticorrosion effect is poor, the invention provides a kind of preparation technology of cable protective system.
For achieving the above object, the technical solution adopted in the present invention is as follows:
A preparation technology for cable protective system, this technique comprises the steps:
Step 1) is prepared base-material: in reactor, add successively vinylformic acid, N-Methyl pyrrolidone, vinyltrimethoxy silane, ethoxylated dodecyl alcohol, acetone and phthalic ester, 1000 turn/min stir 3 minutes, obtain base-material; The weight ratio of vinylformic acid, N-Methyl pyrrolidone, vinyltrimethoxy silane, ethoxylated dodecyl alcohol, acetone and phthalic ester is 5:3:3:2:1:1;
Step 2) prepare auxiliary agent: quartz sand, white graphite and lithium bentonite are delivered to ball mill, and being milled to particle diameter is powder more than 500 orders, is auxiliary agent; The weight ratio of quartz sand, white graphite and lithium bentonite is 1:1:1;
Step 3) is prepared nanometer auxiliary material: nano-silicon rubber powder and nano titanium oxide are mixed according to the weight ratio of 1:1, be nanometer auxiliary material;
Step 4) stirs cooling: base-material, auxiliary agent and nanometer auxiliary material are mixed according to the weight ratio of 15-20:2-3:1-2, then put in high speed dispersor and stir, then the hygrothermal environment that to be placed in temperature and to be 60 DEG C, relative humidity be 80% 12 hours, finally be cooled to room temperature, pack and get final product.
Preferably, the particle diameter of nano-silicon rubber powder or nano titanium oxide is 10-100nm.
Use-pattern: power cable is soaked in to 10-15 minute in coating, takes out and dry.
The present invention obtain beneficial effect mainly comprise following some:
Protective system preparation technology of the present invention is easy, and using method is simple, and material combination is reasonable, and industrial cost is low, is applicable to large-scale industrial production; The present invention, by adding a certain amount of nano material, together with its special molecular structure can closely be fitted to each raw material, and has filled up the space between each raw material, makes coating top layer smooth; Coating of the present invention possesses good anti-acid-alkali salt character, in the work-ing life of having improved power cable, has reduced the generation of potential safety hazard.
 
Embodiment
Below in conjunction with embodiment, the present invention is further detailed explanation, but should not regard the restriction to initiative spirit of the present invention as.
Embodiment 1
A preparation technology for cable protective system, this technique comprises the steps:
Step 1) is prepared base-material: in reactor, add successively vinylformic acid, N-Methyl pyrrolidone, vinyltrimethoxy silane, ethoxylated dodecyl alcohol, acetone and phthalic ester, 1000 turn/min stir 3 minutes, obtain base-material; The weight ratio of vinylformic acid, N-Methyl pyrrolidone, vinyltrimethoxy silane, ethoxylated dodecyl alcohol, acetone and phthalic ester is 5:3:3:2:1:1;
Step 2) prepare auxiliary agent: quartz sand, white graphite and lithium bentonite are delivered to ball mill, and being milled to particle diameter is powder more than 500 orders, is auxiliary agent; The weight ratio of quartz sand, white graphite and lithium bentonite is 1:1:1;
Step 3) is prepared nanometer auxiliary material: nano-silicon rubber powder and nano titanium oxide are mixed according to the weight ratio of 1:1, be nanometer auxiliary material;
Step 4) stirs cooling: base-material, auxiliary agent and nanometer auxiliary material are mixed according to the weight ratio of 15:2:1, then put in high speed dispersor and stir, then the hygrothermal environment that to be placed in temperature and to be 60 DEG C, relative humidity be 80% 12 hours, is finally cooled to room temperature, packs and get final product.
Wherein, the particle diameter of nano-silicon rubber powder or nano titanium oxide is 20nm.
Use-pattern: power cable is soaked in coating to 10 minutes, takes out and dry.
Use the cable top layer performance perameter of protective system as follows: thickness is 80um, and be 43min time of drying, and Vickers' hardness is 20.7, uses respectively 10%H 2sO 4, 10%NaOH and 10% sodium-chlor soak 100 hours, and coatingsurface is unchanged, 0 grade of sticking power.
Embodiment 2
A preparation technology for cable protective system, this technique comprises the steps:
Step 1) is prepared base-material: in reactor, add successively vinylformic acid, N-Methyl pyrrolidone, vinyltrimethoxy silane, ethoxylated dodecyl alcohol, acetone and phthalic ester, 1000 turn/min stir 3 minutes, obtain base-material; The weight ratio of vinylformic acid, N-Methyl pyrrolidone, vinyltrimethoxy silane, ethoxylated dodecyl alcohol, acetone and phthalic ester is 5:3:3:2:1:1;
Step 2) prepare auxiliary agent: quartz sand, white graphite and lithium bentonite are delivered to ball mill, and being milled to particle diameter is powder more than 500 orders, is auxiliary agent; The weight ratio of quartz sand, white graphite and lithium bentonite is 1:1:1;
Step 3) is prepared nanometer auxiliary material: nano-silicon rubber powder and nano titanium oxide are mixed according to the weight ratio of 1:1, be nanometer auxiliary material;
Step 4) stirs cooling: base-material, auxiliary agent and nanometer auxiliary material are mixed according to the weight ratio of 20:3:2, then put in high speed dispersor and stir, then the hygrothermal environment that to be placed in temperature and to be 60 DEG C, relative humidity be 80% 12 hours, is finally cooled to room temperature, packs and get final product.
Wherein, the particle diameter of nano-silicon rubber powder or nano titanium oxide is 50nm.
Use-pattern: power cable is soaked in coating to 15 minutes, takes out and dry.
Use the cable top layer performance perameter of protective system as follows: thickness is 80um, and be 45min time of drying, and Vickers' hardness is 21.3, uses respectively 10%H 2sO 4, 10%NaOH and 10% sodium-chlor soak 100 hours, and coatingsurface is unchanged, 0 grade of sticking power.
 
What certainly note is, although carried out description above by example of the present invention, the present invention is made by those skilled in the art apparent like this and other improvement and change should think and fall into as in broad range of the present invention in this paper.Therefore, although the present invention with reference to be preferred embodiment described,, its meaning is not that the product of tool novelty is restricted therefrom, on the contrary, it is intended to comprise various improvement and equivalent modifications within the broad range that meets above-mentioned open part, claim.

Claims (3)

1. a preparation technology for cable protective system, is characterized in that, described technique comprises the steps:
Step 1) is prepared base-material, step 2) prepare auxiliary agent, step 3) prepares nanometer auxiliary material and step 4) stirs cooling.
2. technique according to claim 1, is characterized in that, described technique comprises the steps:
Step 1) is prepared base-material: in reactor, add successively vinylformic acid, N-Methyl pyrrolidone, vinyltrimethoxy silane, ethoxylated dodecyl alcohol, acetone and phthalic ester, 1000 turn/min stir 3 minutes, obtain base-material; The weight ratio of vinylformic acid, N-Methyl pyrrolidone, vinyltrimethoxy silane, ethoxylated dodecyl alcohol, acetone and phthalic ester is 5:3:3:2:1:1;
Step 2) prepare auxiliary agent: quartz sand, white graphite and lithium bentonite are delivered to ball mill, and being milled to particle diameter is powder more than 500 orders, is auxiliary agent; The weight ratio of quartz sand, white graphite and lithium bentonite is 1:1:1;
Step 3) is prepared nanometer auxiliary material: nano-silicon rubber powder and nano titanium oxide are mixed according to the weight ratio of 1:1, be nanometer auxiliary material; Wherein, the particle diameter of nano-silicon rubber powder or nano titanium oxide is 10-100nm;
Step 4) stirs cooling: base-material, auxiliary agent and nanometer auxiliary material are mixed according to the weight ratio of 15-20:2-3:1-2, then put in high speed dispersor and stir, then the hygrothermal environment that to be placed in temperature and to be 60 DEG C, relative humidity be 80% 12 hours, finally be cooled to room temperature, pack and get final product.
3. the coating of preparing according to technique described in claim 1 or 2.
CN201410454747.4A 2014-09-09 2014-09-09 A kind of preparation technology of cable anticorrosive paint Active CN104177888B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104962114A (en) * 2015-05-11 2015-10-07 江苏士林电气设备有限公司 Tubular bus-bar anticorrosion paint preparation method
CN105504908A (en) * 2015-08-24 2016-04-20 国网山东省电力公司临沂供电公司 Method for preventing high voltage line rod corrosion
CN108610665A (en) * 2016-12-02 2018-10-02 张连瑞 A kind of preparation method of pylon anticorrosive coating
CN108610686A (en) * 2016-12-03 2018-10-02 刘杰 A kind of preparation process of electric power material antiseptic agent

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60238372A (en) * 1984-05-14 1985-11-27 Toagosei Chem Ind Co Ltd Composition for preventing corrosion of metal
CN103756458A (en) * 2014-01-14 2014-04-30 李保国 Environmental-friendly anticorrosive paint for power transmission line
CN104098973A (en) * 2014-07-04 2014-10-15 国家电网公司 Anticorrosive paint adopting nano-materials and used for power cable
CN104151882A (en) * 2014-07-31 2014-11-19 国家电网公司 Anticorrosive paint for power cables
CN104151893A (en) * 2014-08-25 2014-11-19 国家电网公司 Paint used for preventing corrosion on electricity material

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60238372A (en) * 1984-05-14 1985-11-27 Toagosei Chem Ind Co Ltd Composition for preventing corrosion of metal
CN103756458A (en) * 2014-01-14 2014-04-30 李保国 Environmental-friendly anticorrosive paint for power transmission line
CN104098973A (en) * 2014-07-04 2014-10-15 国家电网公司 Anticorrosive paint adopting nano-materials and used for power cable
CN104151882A (en) * 2014-07-31 2014-11-19 国家电网公司 Anticorrosive paint for power cables
CN104151893A (en) * 2014-08-25 2014-11-19 国家电网公司 Paint used for preventing corrosion on electricity material

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104962114A (en) * 2015-05-11 2015-10-07 江苏士林电气设备有限公司 Tubular bus-bar anticorrosion paint preparation method
CN105504908A (en) * 2015-08-24 2016-04-20 国网山东省电力公司临沂供电公司 Method for preventing high voltage line rod corrosion
CN108610665A (en) * 2016-12-02 2018-10-02 张连瑞 A kind of preparation method of pylon anticorrosive coating
CN108610686A (en) * 2016-12-03 2018-10-02 刘杰 A kind of preparation process of electric power material antiseptic agent

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